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Title: Process for preparing schottky diode contacts with predetermined barrier heights

Abstract

A process is provided for producing a Schottky diode having a preselected barrier height .phi..sub.Bn. The substrate is preferably n-GaAs, the metallic contact is derived from a starting alloy of the Formula [.SIGMA.M.sub..delta. ](Al.sub.x Ga.sub.1-x) wherein: .SIGMA.M is a moiety which consists of at least one M, and when more than one M is present, each M is different, M is a Group VIII metal selected from the group consisting of nickel, cobalt, ruthenium, rhodium, indium and platinum, .delta. is a stoichiometric coefficient whose total value in any given .SIGMA.M moiety is 1, and x is a positive number between 0 and 1 (that is, x ranges from greater than 0 to less than 1). Also, the starting alloy is capable of forming with the substrate a two phase equilibrium reciprocal system of the binary alloy mixture [.SIGMA.M.sub..delta. ]Ga-[.SIGMA.M.sub..delta. ]Al-AlAs-GaAs. When members of an alloy subclass within this Formula are each preliminarily correlated with the barrier height .phi..sub.Bn of a contact producable therewith, then Schottky diodes of predetermined barrier heights are producable by sputtering and annealing. Further provided are the product Schottky diodes that are produced according to this process.

Inventors:
 [1];  [2];  [3]
  1. Middleton, WI
  2. Portland, OR
  3. Madison, WI
Issue Date:
Research Org.:
Univ. of Wisconsin, Madison, WI (United States)
OSTI Identifier:
870414
Patent Number(s):
5516725
Assignee:
Wisconsin Alumni Research Foundation (Madison, WI)
Patent Classifications (CPCs):
C - CHEMISTRY C22 - METALLURGY C22C - ALLOYS
C - CHEMISTRY C23 - COATING METALLIC MATERIAL C23C - COATING METALLIC MATERIAL
DOE Contract Number:  
FG02-86ER45274
Resource Type:
Patent
Country of Publication:
United States
Language:
English
Subject:
process; preparing; schottky; diode; contacts; predetermined; barrier; heights; provided; producing; preselected; height; phi; bn; substrate; preferably; n-gaas; metallic; contact; derived; starting; alloy; formula; sigma; delta; 1-x; moiety; consists; viii; metal; selected; consisting; nickel; cobalt; ruthenium; rhodium; indium; platinum; stoichiometric; coefficient; total; value; positive; ranges; capable; forming; phase; equilibrium; reciprocal; binary; mixture; ga-; al-alas-gaas; subclass; preliminarily; correlated; producable; therewith; diodes; sputtering; annealing; product; produced; according; produced according; viii metal; metal selected; schottky diode; barrier height; metallic contact; /438/

Citation Formats

Chang, Y Austin, Jan, Chia-Hong, and Chen, Chia-Ping. Process for preparing schottky diode contacts with predetermined barrier heights. United States: N. p., 1996. Web.
Chang, Y Austin, Jan, Chia-Hong, & Chen, Chia-Ping. Process for preparing schottky diode contacts with predetermined barrier heights. United States.
Chang, Y Austin, Jan, Chia-Hong, and Chen, Chia-Ping. Mon . "Process for preparing schottky diode contacts with predetermined barrier heights". United States. https://www.osti.gov/servlets/purl/870414.
@article{osti_870414,
title = {Process for preparing schottky diode contacts with predetermined barrier heights},
author = {Chang, Y Austin and Jan, Chia-Hong and Chen, Chia-Ping},
abstractNote = {A process is provided for producing a Schottky diode having a preselected barrier height .phi..sub.Bn. The substrate is preferably n-GaAs, the metallic contact is derived from a starting alloy of the Formula [.SIGMA.M.sub..delta. ](Al.sub.x Ga.sub.1-x) wherein: .SIGMA.M is a moiety which consists of at least one M, and when more than one M is present, each M is different, M is a Group VIII metal selected from the group consisting of nickel, cobalt, ruthenium, rhodium, indium and platinum, .delta. is a stoichiometric coefficient whose total value in any given .SIGMA.M moiety is 1, and x is a positive number between 0 and 1 (that is, x ranges from greater than 0 to less than 1). Also, the starting alloy is capable of forming with the substrate a two phase equilibrium reciprocal system of the binary alloy mixture [.SIGMA.M.sub..delta. ]Ga-[.SIGMA.M.sub..delta. ]Al-AlAs-GaAs. When members of an alloy subclass within this Formula are each preliminarily correlated with the barrier height .phi..sub.Bn of a contact producable therewith, then Schottky diodes of predetermined barrier heights are producable by sputtering and annealing. Further provided are the product Schottky diodes that are produced according to this process.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Mon Jan 01 00:00:00 EST 1996},
month = {Mon Jan 01 00:00:00 EST 1996}
}

Works referenced in this record:

A Tunable Schottky Barrier to n-GaAs Using Ni(Ga,Al) Contacts
journal, January 1992


Hybridised sol-gel process for optical fibres
journal, January 1987


Reactions of (100) Multilayered Metal Structures Containing Fe Grown on (100) Si
journal, January 1992


Epitaxial growth of GaAs/NiAl/GaAs heterostructures
journal, April 1988


Growth of Ni3Ga2, NiGa and Ni2Ga3 on GaAs (001) and (111) in a molecular beam epitaxy system
journal, February 1989


NiAl/ n ‐GaAs Schottky diodes: Barrier height enhancement by high‐temperature annealing
journal, April 1988