Enhanced magnetocaloric effects in metastable phases of Mn1-xCoxNiGe generated through thermal quenching and high-pressure annealing
Abstract
Metastable phases were formed in Mn1-xCoxNiGe (x = 0.05 and 0.08) by annealing at 800 °C followed by rapid cooling, i.e., quenching, at ambient pressure (P = 0) and under a pressure of P = 3.5 GPa, and their phase transitions and associated magnetocaloric properties were investigated. The crystal cell volumes of the metastable phases decreased, and their structural transitions significantly shifted to lower temperatures relative to those of the slow-cooled compounds, with a greater reduction observed in the samples where the rapid cooling occurred under high pressures. The magnetic and structural transitions coupled to form a magnetostructural transition in the metastable phases, resulting in large magnetic entropy changes up to -79.6 J kg-1 K-1 (x = 0.08 ) for a 7-T field change. As a result, the experimental results demonstrate thermal quenching and high-pressure annealing as alternative methods to create magnetostructural transitions, without modifying the compositions of the materials.
- Authors:
-
[1];
[1];
[1];
[2];
[2];
[2];
[1]
- Louisiana State University, Baton Rouge, LA (United States)
- Southern Illinois University, Carbondale, IL (United States)
- Publication Date:
- Research Org.:
- Louisiana State Univ., Baton Rouge, LA (United States); Southern Illinois Univ., Carbondale, IL (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1975220
- Alternate Identifier(s):
- OSTI ID: 1923820
- Grant/Contract Number:
- FG02-13ER46946; SC0010521
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of Applied Physics
- Additional Journal Information:
- Journal Volume: 133; Journal Issue: 6; Journal ID: ISSN 0021-8979
- Publisher:
- American Institute of Physics (AIP)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; 75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; 32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATION; magnetocaloric; barocaloric; magnetic refrigeration; phase transitions; crystallography; magnetism; high pressure instruments; annealing
Citation Formats
Chhetri, Tej Poudel, Chen, Jing-Han, Grant, Anthony T., Young, David P., Dubenko, Igor, Talapatra, Saikat, Ali, Naushad, and Stadler, Shane. Enhanced magnetocaloric effects in metastable phases of Mn1-xCoxNiGe generated through thermal quenching and high-pressure annealing. United States: N. p., 2023.
Web. doi:10.1063/5.0129401.
Chhetri, Tej Poudel, Chen, Jing-Han, Grant, Anthony T., Young, David P., Dubenko, Igor, Talapatra, Saikat, Ali, Naushad, & Stadler, Shane. Enhanced magnetocaloric effects in metastable phases of Mn1-xCoxNiGe generated through thermal quenching and high-pressure annealing. United States. https://doi.org/10.1063/5.0129401
Chhetri, Tej Poudel, Chen, Jing-Han, Grant, Anthony T., Young, David P., Dubenko, Igor, Talapatra, Saikat, Ali, Naushad, and Stadler, Shane. Wed .
"Enhanced magnetocaloric effects in metastable phases of Mn1-xCoxNiGe generated through thermal quenching and high-pressure annealing". United States. https://doi.org/10.1063/5.0129401. https://www.osti.gov/servlets/purl/1975220.
@article{osti_1975220,
title = {Enhanced magnetocaloric effects in metastable phases of Mn1-xCoxNiGe generated through thermal quenching and high-pressure annealing},
author = {Chhetri, Tej Poudel and Chen, Jing-Han and Grant, Anthony T. and Young, David P. and Dubenko, Igor and Talapatra, Saikat and Ali, Naushad and Stadler, Shane},
abstractNote = {Metastable phases were formed in Mn1-xCoxNiGe (x = 0.05 and 0.08) by annealing at 800 °C followed by rapid cooling, i.e., quenching, at ambient pressure (P = 0) and under a pressure of P = 3.5 GPa, and their phase transitions and associated magnetocaloric properties were investigated. The crystal cell volumes of the metastable phases decreased, and their structural transitions significantly shifted to lower temperatures relative to those of the slow-cooled compounds, with a greater reduction observed in the samples where the rapid cooling occurred under high pressures. The magnetic and structural transitions coupled to form a magnetostructural transition in the metastable phases, resulting in large magnetic entropy changes up to -79.6 J kg-1 K-1 (x = 0.08 ) for a 7-T field change. As a result, the experimental results demonstrate thermal quenching and high-pressure annealing as alternative methods to create magnetostructural transitions, without modifying the compositions of the materials.},
doi = {10.1063/5.0129401},
journal = {Journal of Applied Physics},
number = 6,
volume = 133,
place = {United States},
year = {Wed Feb 08 00:00:00 EST 2023},
month = {Wed Feb 08 00:00:00 EST 2023}
}
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Works referenced in this record:
Giant magnetocaloric effect of MnAs1−xSbx
journal, November 2001
- Wada, H.; Tanabe, Y.
- Applied Physics Letters, Vol. 79, Issue 20
Magnetostructural Transformation and Magnetoresponsive Properties of ${\rm MnNiGe}_{1-x}{\rm Sn}_{x}$ Alloys
journal, October 2011
- Liu, Enke; Du, Yin; Chen, Jinglan
- IEEE Transactions on Magnetics, Vol. 47, Issue 10
Giant barocaloric effect in hexagonal Ni2In-type Mn-Co-Ge-In compounds around room temperature
journal, December 2015
- Wu, Rong-Rong; Bao, Li-Fu; Hu, Feng-Xia
- Scientific Reports, Vol. 5, Issue 1
The investigation of magnetic phase transitions and magnetocaloric properties in high-pressure annealed MnNiFeGe alloy
journal, January 2021
- Wang, Chuancong; Hu, Qiubo; Zhang, Lei
- Philosophical Magazine, Vol. 101, Issue 8
Giant magnetocaloric effects by tailoring the phase transitions
journal, April 2010
- Trung, N. T.; Zhang, L.; Caron, L.
- Applied Physics Letters, Vol. 96, Issue 17
Review of the structural, magnetic and magnetocaloric properties in ternary rare earth RE2T2X type intermetallic compounds
journal, May 2019
- Zhang, Yikun
- Journal of Alloys and Compounds, Vol. 787
Magnetostructural transition and magnetocaloric effect in MnNiSi-Fe 2 Ge system
journal, November 2015
- Zhang, C. L.; Shi, H. F.; Ye, E. J.
- Applied Physics Letters, Vol. 107, Issue 21
Giant magnetocaloric effect in isostructural MnNiGe-CoNiGe system by establishing a Curie-temperature window
journal, March 2013
- Liu, E. K.; Zhang, H. G.; Xu, G. Z.
- Applied Physics Letters, Vol. 102, Issue 12
Magnetocaloric effect: From materials research to refrigeration devices
journal, April 2018
- Franco, V.; Blázquez, J. S.; Ipus, J. J.
- Progress in Materials Science, Vol. 93
Recent progresses in exploring the rare earth based intermetallic compounds for cryogenic magnetic refrigeration
journal, May 2020
- Li, Lingwei; Yan, Mi
- Journal of Alloys and Compounds, Vol. 823
Realization of magnetostructural coupling by modifying structural transitions in MnNiSi-CoNiGe system with a wide Curie-temperature window
journal, March 2016
- Liu, Jun; Gong, Yuanyuan; Xu, Guizhou
- Scientific Reports, Vol. 6, Issue 1
Magnetostructural transition and magnetocaloric effect in a MnCoSi-based material system
journal, February 2018
- Zhao, J. Q.; Zhu, H. X.; Zhang, C. L.
- Journal of Alloys and Compounds, Vol. 735
Magnetocaloric effect and negative thermal expansion in hexagonal Fe doped MnNiGe compounds with a magnetoelastic AFM-FM-like transition
journal, January 2017
- Xu, Kun; Li, Zhe; Liu, Enke
- Scientific Reports, Vol. 7, Issue 1
The influence of hydrostatic pressure and annealing conditions on the magnetostructural transitions in MnCoGe
journal, June 2021
- Chen, Jing-Han; Poudel Chhetri, Tej; Chang, Chung-Kai
- Journal of Applied Physics, Vol. 129, Issue 21
Hydrostatic pressure effect on the magnetocaloric behavior of Ga-doped MnNiGe magnetic equiatomic alloy
journal, February 2016
- Dutta, P.; Das, D.; Chatterjee, S.
- Journal of Physics D: Applied Physics, Vol. 49, Issue 12
Pressure-tuned magnetocaloric effect in Mn Cr CoGe
journal, July 2011
- Caron, L.; Trung, N. T.; Brück, E.
- Physical Review B, Vol. 84, Issue 2
Effects of heat treatments on magneto-structural phase transitions in MnNiSi-FeCoGe alloys
journal, September 2019
- Chen, Jing-Han; Poudel Chhetri, Tej; Us Saleheen, Ahmad
- Intermetallics, Vol. 112
Crystal and magnetic structure of the CoMn1−xTixSi system
journal, August 1983
- Szytuła, A.; Bażla, W.; Radenković, S.
- Journal of Magnetism and Magnetic Materials, Vol. 38, Issue 1
The tunable magnetostructural transition in MnNiSi-FeNiGe system
journal, September 2013
- Zhang, C. L.; Wang, D. H.; Han, Z. D.
- Applied Physics Letters, Vol. 103, Issue 13
Crystal and magnetic structure of CoxNi1-xMnGe system
journal, June 1982
- Nizioł, S.; Bombik, A.; Baz̊ela, W.
- Journal of Magnetism and Magnetic Materials, Vol. 27, Issue 3
Magnetocaloric effect and magnetic refrigeration
journal, October 1999
- Pecharsky, Vitalij K.; Gschneidner Jr, Karl A.
- Journal of Magnetism and Magnetic Materials, Vol. 200, Issue 1-3
On the crystal structure and magnetic properties of MnNiGe
journal, July 1985
- Fjellvåg, H.; Andresen, A. F.
- Journal of Magnetism and Magnetic Materials, Vol. 50, Issue 3
Large inverse magnetic entropy changes and magnetoresistance in the vicinity of a field-induced martensitic transformation in Ni50−xCoxMn32−yFeyGa18
journal, August 2010
- Pathak, Arjun K.; Dubenko, Igor; Karaca, Haluk E.
- Applied Physics Letters, Vol. 97, Issue 6
Giant magnetocaloric effects near room temperature in Mn 1 − x Cu x CoGe
journal, December 2012
- Samanta, Tapas; Dubenko, Igor; Quetz, Abdiel
- Applied Physics Letters, Vol. 101, Issue 24
Designed materials with the giant magnetocaloric effect near room temperature
journal, November 2019
- Biswas, Anis; Pathak, Arjun K.; Zarkevich, Nikolai A.
- Acta Materialia, Vol. 180
Giant magnetocaloric effect near room temperature in the off-stoichiometric Mn–Co–Ge alloy
journal, November 2016
- Sharma, V. K.; Manekar, M. A.; Srivastava, Himanshu
- Journal of Physics D: Applied Physics, Vol. 49, Issue 50
Crystal and magnetic structure of NiMnGe
journal, December 1976
- Bazela, W.; Szytuła, A.; Todorović, J.
- Physica Status Solidi (a), Vol. 38, Issue 2
Influence of magnetic field, chemical pressure and hydrostatic pressure on the structural and magnetocaloric properties of the Mn–Ni–Ge system
journal, October 2017
- Taubel, Andreas; Gottschall, Tino; Fries, Maximilian
- Journal of Physics D: Applied Physics, Vol. 50, Issue 46
On the determination of the magnetic entropy change in materials with first-order transitions
journal, November 2009
- Caron, L.; Ou, Z. Q.; Nguyen, T. T.
- Journal of Magnetism and Magnetic Materials, Vol. 321, Issue 21
Ambient pressure colossal magnetocaloric effect tuned by composition in Mn1−xFe x As
journal, September 2006
- de Campos, Ariana; Rocco, Daniel L.; Carvalho, Alexandre Magnus G.
- Nature Materials, Vol. 5, Issue 10
Enhancement of magnetocaloric effect by external hydrostatic pressure in MnNi0.75Fe0.25Ge alloy
journal, May 2018
- Mandal, K.; Dutta, P.; Dasgupta, P.
- Journal of Physics D: Applied Physics, Vol. 51, Issue 22
The magnetostructural transformation and magnetocaloric effect in Co-doped MnNiGe 1.05 alloys
journal, May 2010
- Zhang, Chengliang; Wang, Dunhui; Cao, Qingqi
- Journal of Physics D: Applied Physics, Vol. 43, Issue 20
EXPGUI , a graphical user interface for GSAS
journal, April 2001
- Toby, Brian H.
- Journal of Applied Crystallography, Vol. 34, Issue 2
Magnetic properties of the CoxNi1−xMnGe system
journal, September 1981
- Nizioł, S.; Wesełucha, A.; Bażela, W.
- Solid State Communications, Vol. 39, Issue 10
Effects of hydrostatic pressure on magnetostructural transitions and magnetocaloric properties in (MnNiSi)1−x(FeCoGe)x
journal, March 2015
- Samanta, Tapas; Lepkowski, Daniel L.; Saleheen, Ahmad Us
- Journal of Applied Physics, Vol. 117, Issue 12
The influence of Au substitution and hydrostatic pressure on the phase transitions and magnetocaloric properties of MnCoGe alloys
journal, June 2020
- Chen, Jing-Han; Trigg, Aaron; Poudel Chhetri, Tej
- Journal of Applied Physics, Vol. 127, Issue 21
Magnetostructural phase transition and magnetocaloric effect in off-stoichiometric Mn1.9−xNixGe alloys
journal, September 2008
- Zhang, C. L.; Wang, D. H.; Cao, Q. Q.
- Applied Physics Letters, Vol. 93, Issue 12
Phase diagram and magnetocaloric effects in aluminum doped MnNiGe alloys
journal, October 2013
- Quetz, Abdiel; Samanta, Tapas; Dubenko, Igor
- Journal of Applied Physics, Vol. 114, Issue 15
Giant Magnetocaloric Effect in
journal, June 1997
- Pecharsky, V. K.; Gschneidner, Jr., K. A.
- Physical Review Letters, Vol. 78, Issue 23, p. 4494-4497
Coupled nature of magnetic and structural transition in MnNiGe under pressure
journal, September 1978
- Anzai, S.; Ozawa, K.
- Physical Review B, Vol. 18, Issue 5
Stable magnetostructural coupling with tunable magnetoresponsive effects in hexagonal ferromagnets
journal, January 2012
- Liu, Enke; Wang, Wenhong; Feng, Lin
- Nature Communications, Vol. 3, Issue 1
A profile refinement method for nuclear and magnetic structures
journal, June 1969
- Rietveld, H. M.
- Journal of Applied Crystallography, Vol. 2, Issue 2, p. 65-71
Giant reversible magnetocaloric effect in MnNiGe-based materials: Minimizing thermal hysteresis via crystallographic compatibility modulation
journal, August 2019
- Liu, Jun; Gong, Yuanyuan; You, Yurong
- Acta Materialia, Vol. 174
Giant low field magnetocaloric effect near room temperature in isostructurally alloyed MnNiGe-FeCoGe systems
journal, July 2020
- Kuang, Yafei; Yang, Bo; Hao, Xiaowen
- Journal of Magnetism and Magnetic Materials, Vol. 506
On entropy determination from magnetic and calorimetric experiments in conventional giant magnetocaloric materials
journal, April 2018
- Chen, Jing-Han; Us Saleheen, Ahmad; Adams, Philip W.
- Journal of Applied Physics, Vol. 123, Issue 14
Effects of doping, hydrostatic pressure, and thermal quenching on the phase transitions and magnetocaloric properties in Mn1−xCoxNiGe
journal, July 2022
- Poudel Chhetri, Tej; Chen, Jing-Han; Grant, Anthony T.
- Journal of Applied Physics, Vol. 132, Issue 4
Low-pressure-induced large reversible barocaloric effect near room temperature in (MnNiGe)-(FeCoGe) alloys
journal, July 2021
- Kuang, Yafei; Qi, Ji; Xu, Haijian
- Scripta Materialia, Vol. 200
Recent Progress in Exploring Magnetocaloric Materials
journal, December 2009
- Shen, B. G.; Sun, J. R.; Hu, F. X.
- Advanced Materials, Vol. 21, Issue 45
Pressure-Induced Colossal Magnetocaloric Effect in MnAs
journal, November 2004
- Gama, Sergio; Coelho, Adelino A.; de Campos, Ariana
- Physical Review Letters, Vol. 93, Issue 23
Diffusionless orthorhombic to hexagonal transitions in ternary silicides and germanides
journal, May 1975
- Johnson, V.
- Inorganic Chemistry, Vol. 14, Issue 5
Magnetostructural phase transitions and magnetocaloric effects in MnNiGe 1−x Al x
journal, January 2012
- Samanta, Tapas; Dubenko, Igor; Quetz, Abdiel
- Applied Physics Letters, Vol. 100, Issue 5
Enhanced magnetic refrigeration performance in metamagnetic MnCoSi alloy by high-pressure annealing
journal, April 2017
- Liu, Jun; Si, Yu; Gong, Yuanyuan
- Journal of Alloys and Compounds, Vol. 701