Effects of doping, hydrostatic pressure, and thermal quenching on the phase transitions and magnetocaloric properties in Mn1–xCoxNiGe
Abstract
The effects of doping, hydrostatic pressure, and thermal quenching on the phase transitions and magnetocaloric properties of the Mn1–xCoxNiGe system have been investigated. Cobalt doping on the Mn site shifted the martensitic structural transition toward lower temperature until it was ultimately absent, leaving only a magnetic transition from a ferromagnetic (FM) to a paramagnetic (PM) state in the high-temperature hexagonal phase. Co-occurrence of the magnetic and structural transitions to form a first-order magnetostructural transition (MST) from the FM orthorhombic to the PM hexagonal phase was observed in samples with 0.05 < x < 0.20. An additional antiferromagnetic–ferromagnetic-like transition was observed in the martensite phase for 0.05 < x < 0.10, which gradually vanished with increasing Co concentration (x > 0.10) or magnetic field (H > 0.5 T). The application of external hydrostatic pressure shifted the structural transition to lower temperature until an MST was formed in samples with x = 0.03 and 0.05, inducing large magnetic entropy changes up to –80.3 J kg–1 K–1 (x = 0.03) for a 7-T field change under 10.6-kbar pressure. Similar to the effects of the application of hydrostatic pressure, an MST was formed near room temperature in the sample with x = 0.03 bymore »
- Authors:
-
- Louisiana State University, Baton Rouge, LA (United States)
- Southern Illinois University, Carbondale, IL (United States)
- Publication Date:
- Research Org.:
- Louisiana State Univ., Baton Rouge, LA (United States); Southern Illinois Univ., Carbondale, IL (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1975225
- Alternate Identifier(s):
- OSTI ID: 1878255
- Grant/Contract Number:
- FG02-13ER46946; SC0010521
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of Applied Physics
- Additional Journal Information:
- Journal Volume: 132; Journal Issue: 4; Journal ID: ISSN 0021-8979
- Publisher:
- American Institute of Physics (AIP)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; 75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; 32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATION; magnetocaloric; barocaloric; magnetic refrigeration; phase transitions; magnetism; alloys; materials heat treatment
Citation Formats
Chhetri, Tej Poudel, Chen, Jing-Han, Grant, Anthony T., Young, David P., Dubenko, Igor, Talapatra, Saikat, Ali, Naushad, and Stadler, Shane. Effects of doping, hydrostatic pressure, and thermal quenching on the phase transitions and magnetocaloric properties in Mn1–xCoxNiGe. United States: N. p., 2022.
Web. doi:10.1063/5.0100987.
Chhetri, Tej Poudel, Chen, Jing-Han, Grant, Anthony T., Young, David P., Dubenko, Igor, Talapatra, Saikat, Ali, Naushad, & Stadler, Shane. Effects of doping, hydrostatic pressure, and thermal quenching on the phase transitions and magnetocaloric properties in Mn1–xCoxNiGe. United States. https://doi.org/10.1063/5.0100987
Chhetri, Tej Poudel, Chen, Jing-Han, Grant, Anthony T., Young, David P., Dubenko, Igor, Talapatra, Saikat, Ali, Naushad, and Stadler, Shane. Wed .
"Effects of doping, hydrostatic pressure, and thermal quenching on the phase transitions and magnetocaloric properties in Mn1–xCoxNiGe". United States. https://doi.org/10.1063/5.0100987. https://www.osti.gov/servlets/purl/1975225.
@article{osti_1975225,
title = {Effects of doping, hydrostatic pressure, and thermal quenching on the phase transitions and magnetocaloric properties in Mn1–xCoxNiGe},
author = {Chhetri, Tej Poudel and Chen, Jing-Han and Grant, Anthony T. and Young, David P. and Dubenko, Igor and Talapatra, Saikat and Ali, Naushad and Stadler, Shane},
abstractNote = {The effects of doping, hydrostatic pressure, and thermal quenching on the phase transitions and magnetocaloric properties of the Mn1–xCoxNiGe system have been investigated. Cobalt doping on the Mn site shifted the martensitic structural transition toward lower temperature until it was ultimately absent, leaving only a magnetic transition from a ferromagnetic (FM) to a paramagnetic (PM) state in the high-temperature hexagonal phase. Co-occurrence of the magnetic and structural transitions to form a first-order magnetostructural transition (MST) from the FM orthorhombic to the PM hexagonal phase was observed in samples with 0.05 < x < 0.20. An additional antiferromagnetic–ferromagnetic-like transition was observed in the martensite phase for 0.05 < x < 0.10, which gradually vanished with increasing Co concentration (x > 0.10) or magnetic field (H > 0.5 T). The application of external hydrostatic pressure shifted the structural transition to lower temperature until an MST was formed in samples with x = 0.03 and 0.05, inducing large magnetic entropy changes up to –80.3 J kg–1 K–1 (x = 0.03) for a 7-T field change under 10.6-kbar pressure. Similar to the effects of the application of hydrostatic pressure, an MST was formed near room temperature in the sample with x = 0.03 by annealing at high temperature (1200 °C) followed by quenching, resulting in a large magnetic entropy change of –56.2 J kg–1 K–1. Furthermore, these experimental results show that the application of pressure and thermal quenching, in addition to compositional variations, are effective methods to create magnetostructural transitions in the MnNiGe system, resulting in large magnetocaloric effects.},
doi = {10.1063/5.0100987},
journal = {Journal of Applied Physics},
number = 4,
volume = 132,
place = {United States},
year = {Wed Jul 27 00:00:00 EDT 2022},
month = {Wed Jul 27 00:00:00 EDT 2022}
}
Works referenced in this record:
Giant magnetocaloric effect of MnAs1−xSbx
journal, November 2001
- Wada, H.; Tanabe, Y.
- Applied Physics Letters, Vol. 79, Issue 20
Giant barocaloric effect in hexagonal Ni2In-type Mn-Co-Ge-In compounds around room temperature
journal, December 2015
- Wu, Rong-Rong; Bao, Li-Fu; Hu, Feng-Xia
- Scientific Reports, Vol. 5, Issue 1
Giant magnetocaloric effect driven by structural transitions
journal, May 2012
- Liu, Jian; Gottschall, Tino; Skokov, Konstantin P.
- Nature Materials, Vol. 11, Issue 7
Giant magnetocaloric effects by tailoring the phase transitions
journal, April 2010
- Trung, N. T.; Zhang, L.; Caron, L.
- Applied Physics Letters, Vol. 96, Issue 17
Large negative magnetoresistance in a ferromagnetic shape memory alloy: Ni2+xMn1−xGa
journal, May 2005
- Biswas, C.; Rawat, R.; Barman, S. R.
- Applied Physics Letters, Vol. 86, Issue 20
Transition-metal-based magnetic refrigerants for room-temperature applications
journal, January 2002
- Tegus, O.; Brück, E.; Buschow, K. H. J.
- Nature, Vol. 415, Issue 6868
Giant magnetocaloric effect in isostructural MnNiGe-CoNiGe system by establishing a Curie-temperature window
journal, March 2013
- Liu, E. K.; Zhang, H. G.; Xu, G. Z.
- Applied Physics Letters, Vol. 102, Issue 12
Realization of magnetostructural coupling by modifying structural transitions in MnNiSi-CoNiGe system with a wide Curie-temperature window
journal, March 2016
- Liu, Jun; Gong, Yuanyuan; Xu, Guizhou
- Scientific Reports, Vol. 6, Issue 1
Tuning martensitic transitions in (MnNiSi) 0.65 (Fe 2 Ge) 0.35 through heat treatment and hydrostatic pressure
journal, November 2018
- Chen, Jing-Han; Us Saleheen, Ahmad; Karna, Sunil K.
- Journal of Applied Physics, Vol. 124, Issue 20
Magnetocaloric effect and negative thermal expansion in hexagonal Fe doped MnNiGe compounds with a magnetoelastic AFM-FM-like transition
journal, January 2017
- Xu, Kun; Li, Zhe; Liu, Enke
- Scientific Reports, Vol. 7, Issue 1
Inverse magnetocaloric effect in ferromagnetic Ni50Mn37+xSb13−x Heusler alloys
journal, March 2007
- Khan, Mahmud; Ali, Naushad; Stadler, Shane
- Journal of Applied Physics, Vol. 101, Issue 5
The influence of hydrostatic pressure and annealing conditions on the magnetostructural transitions in MnCoGe
journal, June 2021
- Chen, Jing-Han; Poudel Chhetri, Tej; Chang, Chung-Kai
- Journal of Applied Physics, Vol. 129, Issue 21
Effects of heat treatments on magneto-structural phase transitions in MnNiSi-FeCoGe alloys
journal, September 2019
- Chen, Jing-Han; Poudel Chhetri, Tej; Us Saleheen, Ahmad
- Intermetallics, Vol. 112
Itinerant-electron metamagnetic transition and large magnetocaloric effects in compounds and their hydrides
journal, March 2003
- Fujita, A.; Fujieda, S.; Hasegawa, Y.
- Physical Review B, Vol. 67, Issue 10
Large magnetic‐field‐induced strains in Ni 2 MnGa single crystals
journal, September 1996
- Ullakko, K.; Huang, J. K.; Kantner, C.
- Applied Physics Letters, Vol. 69, Issue 13
Crystal and magnetic structure of CoxNi1-xMnGe system
journal, June 1982
- Nizioł, S.; Bombik, A.; Baz̊ela, W.
- Journal of Magnetism and Magnetic Materials, Vol. 27, Issue 3
On the crystal structure and magnetic properties of MnNiGe
journal, July 1985
- Fjellvåg, H.; Andresen, A. F.
- Journal of Magnetism and Magnetic Materials, Vol. 50, Issue 3
An efficient scheme to tailor the magnetostructural transitions by staged quenching and cyclical ageing in hexagonal martensitic alloys
journal, August 2019
- Li, Yong; Zeng, Qingqi; Wei, Zhiyang
- Acta Materialia, Vol. 174
Magnetostrictive and magnetocaloric effects in Mn 0.89 Cr 0.11 NiGe
journal, December 2013
- Sivachenko, A. P.; Mityuk, V. I.; Kamenev, V. I.
- Low Temperature Physics, Vol. 39, Issue 12
Giant magnetocaloric effects near room temperature in Mn 1 − x Cu x CoGe
journal, December 2012
- Samanta, Tapas; Dubenko, Igor; Quetz, Abdiel
- Applied Physics Letters, Vol. 101, Issue 24
Designed materials with the giant magnetocaloric effect near room temperature
journal, November 2019
- Biswas, Anis; Pathak, Arjun K.; Zarkevich, Nikolai A.
- Acta Materialia, Vol. 180
Taming the First-Order Transition in Giant Magnetocaloric Materials
journal, February 2014
- Guillou, François; Porcari, Giacomo; Yibole, Hargen
- Advanced Materials, Vol. 26, Issue 17
Crystal and magnetic structure of NiMnGe
journal, December 1976
- Bazela, W.; Szytuła, A.; Todorović, J.
- Physica Status Solidi (a), Vol. 38, Issue 2
Magnetic and martensitic transformations of NiMnX(X=In,Sn,Sb) ferromagnetic shape memory alloys
journal, January 2004
- Sutou, Y.; Imano, Y.; Koeda, N.
- Applied Physics Letters, Vol. 85, Issue 19
Influence of magnetic field, chemical pressure and hydrostatic pressure on the structural and magnetocaloric properties of the Mn–Ni–Ge system
journal, October 2017
- Taubel, Andreas; Gottschall, Tino; Fries, Maximilian
- Journal of Physics D: Applied Physics, Vol. 50, Issue 46
On the determination of the magnetic entropy change in materials with first-order transitions
journal, November 2009
- Caron, L.; Ou, Z. Q.; Nguyen, T. T.
- Journal of Magnetism and Magnetic Materials, Vol. 321, Issue 21
The magnetostructural transformation and magnetocaloric effect in Co-doped MnNiGe 1.05 alloys
journal, May 2010
- Zhang, Chengliang; Wang, Dunhui; Cao, Qingqi
- Journal of Physics D: Applied Physics, Vol. 43, Issue 20
La(Fe,Si)13-based magnetic refrigerants obtained by novel processing routes
journal, September 2008
- Lyubina, Julia; Gutfleisch, Oliver; Kuz’min, Michael D.
- Journal of Magnetism and Magnetic Materials, Vol. 320, Issue 18
A coupling of martensitic and metamagnetic transitions with collective magneto-volume and table-like magnetocaloric effects
journal, August 2014
- Liu, E. K.; Wei, Z. Y.; Li, Y.
- Applied Physics Letters, Vol. 105, Issue 6
Magnetostructural transformation and magnetocaloric effect in MnNiGe 1-x Ga x alloys
journal, October 2013
- Zhang, C. L.; Han, Z. D.; Qian, B.
- Journal of Applied Physics, Vol. 114, Issue 15
EXPGUI , a graphical user interface for GSAS
journal, April 2001
- Toby, Brian H.
- Journal of Applied Crystallography, Vol. 34, Issue 2
Large reversible magnetocaloric effect in Ni-Mn-In-Co
journal, January 2015
- Gottschall, Tino; Skokov, Konstantin P.; Frincu, Bianca
- Applied Physics Letters, Vol. 106, Issue 2
Magnetic properties of the CoxNi1−xMnGe system
journal, September 1981
- Nizioł, S.; Wesełucha, A.; Bażela, W.
- Solid State Communications, Vol. 39, Issue 10
Influence of negative lattice expansion and metamagnetic transition on magnetic entropy change in the compound LaFe11.4Si1.6
journal, June 2001
- Hu, Feng-xia; Shen, Bao-gen; Sun, Ji-rong
- Applied Physics Letters, Vol. 78, Issue 23
The influence of Au substitution and hydrostatic pressure on the phase transitions and magnetocaloric properties of MnCoGe alloys
journal, June 2020
- Chen, Jing-Han; Trigg, Aaron; Poudel Chhetri, Tej
- Journal of Applied Physics, Vol. 127, Issue 21
Magnetostructural phase transition and magnetocaloric effect in off-stoichiometric Mn1.9−xNixGe alloys
journal, September 2008
- Zhang, C. L.; Wang, D. H.; Cao, Q. Q.
- Applied Physics Letters, Vol. 93, Issue 12
Phase diagram and magnetocaloric effects in aluminum doped MnNiGe alloys
journal, October 2013
- Quetz, Abdiel; Samanta, Tapas; Dubenko, Igor
- Journal of Applied Physics, Vol. 114, Issue 15
Heat treatment effect on the magnetic properties and martensitic transformations of MnCoGe
journal, April 2020
- Noguchi, Kohei; Kobayashi, Ryota; Mitsui, Yoshifuru
- Journal of Magnetism and Magnetic Materials, Vol. 499
Giant Magnetocaloric Effect in
journal, June 1997
- Pecharsky, V. K.; Gschneidner, Jr., K. A.
- Physical Review Letters, Vol. 78, Issue 23, p. 4494-4497
Magnetic superelasticity and inverse magnetocaloric effect in Ni-Mn-In
journal, March 2007
- Krenke, Thorsten; Duman, Eyüp; Acet, Mehmet
- Physical Review B, Vol. 75, Issue 10
Magnetocaloric effect in Ni-Mn-X (X = Ga, In, Sn, Sb) Heusler alloys
journal, December 2011
- Buchelnikov, V. D.; Sokolovskiy, V. V.
- The Physics of Metals and Metallography, Vol. 112, Issue 7
Magnetocaloric properties of Ni2Mn1−xCuxGa
journal, May 2006
- Stadler, Shane; Khan, Mahmud; Mitchell, Joseph
- Applied Physics Letters, Vol. 88, Issue 19
Coupled nature of magnetic and structural transition in MnNiGe under pressure
journal, September 1978
- Anzai, S.; Ozawa, K.
- Physical Review B, Vol. 18, Issue 5
Large magnetoresistance in single-crystalline Ni50Mn50−xInx alloys (x=14–16) upon martensitic transformation
journal, October 2006
- Yu, S. Y.; Liu, Z. H.; Liu, G. D.
- Applied Physics Letters, Vol. 89, Issue 16
Stable magnetostructural coupling with tunable magnetoresponsive effects in hexagonal ferromagnets
journal, January 2012
- Liu, Enke; Wang, Wenhong; Feng, Lin
- Nature Communications, Vol. 3, Issue 1
Large magnetic entropy change in Ni50Mn50−xInx Heusler alloys
journal, June 2007
- Pathak, Arjun Kumar; Khan, Mahmud; Dubenko, Igor
- Applied Physics Letters, Vol. 90, Issue 26
A profile refinement method for nuclear and magnetic structures
journal, June 1969
- Rietveld, H. M.
- Journal of Applied Crystallography, Vol. 2, Issue 2, p. 65-71
Giant reversible magnetocaloric effect in MnNiGe-based materials: Minimizing thermal hysteresis via crystallographic compatibility modulation
journal, August 2019
- Liu, Jun; Gong, Yuanyuan; You, Yurong
- Acta Materialia, Vol. 174
Giant low field magnetocaloric effect near room temperature in isostructurally alloyed MnNiGe-FeCoGe systems
journal, July 2020
- Kuang, Yafei; Yang, Bo; Hao, Xiaowen
- Journal of Magnetism and Magnetic Materials, Vol. 506
On entropy determination from magnetic and calorimetric experiments in conventional giant magnetocaloric materials
journal, April 2018
- Chen, Jing-Han; Us Saleheen, Ahmad; Adams, Philip W.
- Journal of Applied Physics, Vol. 123, Issue 14
Low-pressure-induced large reversible barocaloric effect near room temperature in (MnNiGe)-(FeCoGe) alloys
journal, July 2021
- Kuang, Yafei; Qi, Ji; Xu, Haijian
- Scripta Materialia, Vol. 200
Magnetic-field-induced shape recovery by reverse phase transformation
journal, February 2006
- Kainuma, R.; Imano, Y.; Ito, W.
- Nature, Vol. 439, Issue 7079
Diffusionless orthorhombic to hexagonal transitions in ternary silicides and germanides
journal, May 1975
- Johnson, V.
- Inorganic Chemistry, Vol. 14, Issue 5
Magnetostructural phase transitions and magnetocaloric effects in MnNiGe 1−x Al x
journal, January 2012
- Samanta, Tapas; Dubenko, Igor; Quetz, Abdiel
- Applied Physics Letters, Vol. 100, Issue 5
Tuning magnetostructural transition and the associated giant magnetocaloric effect via thermal treatment in MnCoGe-based alloys
journal, January 2019
- Zhang, C. L.; Nie, Y. G.; Shi, H. F.
- Journal of Magnetism and Magnetic Materials, Vol. 469