Barocaloric and magnetocaloric effects in (MnNiSi)1-x(FeCoGe)x

Samanta, Tapas; Lloveras, Pol; Us Saleheen, Ahmad; Lepkowski, Daniel L.; Kramer, Emily; Dubenko, Igor; Adams, Philip W.; Young, David P.; Barrio, Maria; Tamarit, Josep Ll.; Ali, Naushad; Stadler, Shane

doi:10.1063/1.5011743

Title: Barocaloric and magnetocaloric effects in (MnNiSi)_1-x(FeCoGe)_x

Journal Article · 11 January 2018 · Applied Physics Letters

DOI: https://doi.org/10.1063/1.5011743 · OSTI ID:1510947

Samanta, Tapas ^[1];

^[2]; Us Saleheen, Ahmad ^[1]; Lepkowski, Daniel L. ^[1]; Kramer, Emily ^[1]; Dubenko, Igor ^[3]; Adams, Philip W. ^[1]; Young, David P. ^[1];

^[2];

^[2]; Ali, Naushad ^[3]; Stadler, Shane ^[1]

Louisiana State Univ., Baton Rouge, LA (United States). Dept. of Physics and Astronomy
Polytechnic Univ. of Catalonia, Barcelona (Spain). Dept. of Physics. Barcelona Research Center in Multiscale Science and Engineering
Southern Illinois Univ., Carbondale, IL (United States). Dept. of Physics

(MnNiSi)_1-x(FeCoGe)_x undergoes a magnetostructural phase transition near room temperature that is acutely sensitive to applied hydrostatic pressure, which presents as a marked shift in the martensitic transition temperature (T_M) by about –7.5 K/kbar. The magnetostructural transition can therefore be induced by applied hydrostatic pressure or by magnetic field. The barocaloric and magnetocaloric effects were measured across T_M (for the sample with x = 0.38), and the corresponding entropy changes were +74 J/kg K (P = 2.7 kbar) and –58 J/kg K (μ₀ H = 5 T), respectively. It was observed here that the transition entropy change increases with pressure, which results in an enhancement of the barocaloric effect. Our measurements show that the transformed phase fraction associated with magnetostructural transition does not depend on pressure and, therefore, this enhancement cannot be attributed to a pressure-assisted completion of the phase transformation.

View Accepted Manuscript (DOE)

View Accepted Manuscript (Publisher)

Cite

Export

Save

Research Organization:: Southern Illinois Univ., Carbondale, IL (United States); Louisiana State Univ., Baton Rouge, LA (United States); Polytechnic Univ. of Catalonia, Barcelona (Spain)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation (NSF); Interministerial Commission of Science and Technology (CICYT) (Spain); Catalan Government; USDOE

Grant/Contract Number:: FG02-06ER46291; FG02-13ER46946; FG02-07ER46420; SC0010521; 1306392; FIS2014-54734-P; 2014SGR-00581

OSTI ID:: 1510947

Alternate ID(s):: OSTI ID: 1416647; OSTI ID: 1872898

Journal Information:: Applied Physics Letters, Vol. 112, Issue 2; ISSN 0003-6951

Publisher:: American Institute of Physics (AIP)Copyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 62 works

Citation information provided by
Web of Science

References (38)

Crystal and magnetic structure of NiMnGe Bazela, W.; Szytuła, A.; Todorović, J. Physica Status Solidi (a), Vol. 38, Issue 2 https://doi.org/10.1002/pssa.2210380235	journal	December 1976
Giant barocaloric effect in hexagonal Ni2In-type Mn-Co-Ge-In compounds around room temperature Wu, Rong-Rong; Bao, Li-Fu; Hu, Feng-Xia Scientific Reports, Vol. 5, Issue 1 https://doi.org/10.1038/srep18027	journal	December 2015
Magnetic method of magnetocaloric effect determination in high pulsed magnetic fields Levitin, R. Z.; Snegirev, V. V.; Kopylov, A. V. Journal of Magnetism and Magnetic Materials, Vol. 170, Issue 1-2 https://doi.org/10.1016/S0304-8853(96)00688-9	journal	June 1997
Effects of hydrostatic pressure on the magnetism and martensitic transition of Ni–Mn–In magnetic superelastic alloys Mañosa, Lluís; Moya, Xavier; Planes, Antoni Applied Physics Letters, Vol. 92, Issue 1 https://doi.org/10.1063/1.2830999	journal	January 2008
Crystal and magnetic structure of CoMnGe, CoFeGe, FeMnGe and NiFeGe SzytuŁa, A.; Pȩdziwiatr, A. T.; Tomkowicz, Z. Journal of Magnetism and Magnetic Materials, Vol. 25, Issue 2 https://doi.org/10.1016/0304-8853(81)90116-5	journal	December 1981
Entropy change upon magnetic field and pressure variations de Oliveira, N. A. Applied Physics Letters, Vol. 90, Issue 5 https://doi.org/10.1063/1.2434154	journal	January 2007
Giant magnetocaloric effect driven by structural transitions Liu, Jian; Gottschall, Tino; Skokov, Konstantin P. Nature Materials, Vol. 11, Issue 7 https://doi.org/10.1038/nmat3334	journal	May 2012
Giant magnetocaloric effects by tailoring the phase transitions Trung, N. T.; Zhang, L.; Caron, L. Applied Physics Letters, Vol. 96, Issue 17 https://doi.org/10.1063/1.3399773	journal	April 2010
Caloric materials near ferroic phase transitions Moya, X.; Kar-Narayan, S.; Mathur, N. D. Nature Materials, Vol. 13, Issue 5 https://doi.org/10.1038/nmat3951	journal	April 2014
Giant barocaloric effects at low pressure in ferrielectric ammonium sulphate Lloveras, P.; Stern-Taulats, E.; Barrio, M. Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms9801	journal	November 2015
Pressure and temperature dependence of electrical resistivity of Pb and Sn from 1-300K and 0-10 GPa-use as continuous resistive pressure monitor accurate over wide temperature range; superconductivity under pressure in Pb, Sn and In Eiling, A.; Schilling, J. S. Journal of Physics F: Metal Physics, Vol. 11, Issue 3 https://doi.org/10.1088/0305-4608/11/3/010	journal	March 1981
Transition-metal-based magnetic refrigerants for room-temperature applications Tegus, O.; Brück, E.; Buschow, K. H. J. Nature, Vol. 415, Issue 6868 https://doi.org/10.1038/415150a	journal	January 2002
Barocaloric effect in the magnetocaloric prototype Gd5Si2Ge2 Yuce, Suheyla; Barrio, Maria; Emre, Baris Applied Physics Letters, Vol. 101, Issue 7 https://doi.org/10.1063/1.4745920	journal	August 2012
Effects of hydrostatic pressure on magnetostructural transitions and magnetocaloric properties in (MnNiSi)1−x(FeCoGe)x Samanta, Tapas; Lepkowski, Daniel L.; Saleheen, Ahmad Us Journal of Applied Physics, Vol. 117, Issue 12 https://doi.org/10.1063/1.4916339	journal	March 2015
Vacancy-tuned paramagnetic/ferromagnetic martensitic transformation in Mn-poor Mn _1-x CoGe alloys Liu, E. K.; Zhu, W.; Feng, L. EPL (Europhysics Letters), Vol. 91, Issue 1 https://doi.org/10.1209/0295-5075/91/17003	journal	July 2010
Materials with Giant Mechanocaloric Effects: Cooling by Strength Mañosa, Lluís; Planes, Antoni Advanced Materials, Vol. 29, Issue 11 https://doi.org/10.1002/adma.201603607	journal	December 2016
Pressure dependence of the magnetic transition temperature of the CoMnGe 1-x Si x system NizioŁ, S.; Zach, R.; Senateur, J. P. Journal of Magnetism and Magnetic Materials, Vol. 79, Issue 3 https://doi.org/10.1016/0304-8853(89)90188-1	journal	July 1989
Hydrostatic pressure-induced modifications of structural transitions lead to large enhancements of magnetocaloric effects in MnNiSi-based systems Samanta, Tapas; Lepkowski, Daniel L.; Saleheen, Ahmad Us Physical Review B, Vol. 91, Issue 2 https://doi.org/10.1103/PhysRevB.91.020401	journal	January 2015
New developments in caloric materials for cooling applications Crossley, S.; Mathur, N. D.; Moya, X. AIP Advances, Vol. 5, Issue 6 https://doi.org/10.1063/1.4922871	journal	June 2015
Giant Magnetocaloric Effect in Gd5(Si2Ge2) Pecharsky, V. K.; Gschneidner, Jr., K. A. Physical Review Letters, Vol. 78, Issue 23, p. 4494-4497 https://doi.org/10.1103/PhysRevLett.78.4494	journal	June 1997
Giant solid-state barocaloric effect in the Ni–Mn–In magnetic shape-memory alloy Mañosa, Lluís; González-Alonso, David; Planes, Antoni Nature Materials, Vol. 9, Issue 6 https://doi.org/10.1038/nmat2731	journal	April 2010
Giant barocaloric effect enhanced by the frustration of the antiferromagnetic phase in Mn3GaN Matsunami, Daichi; Fujita, Asaya; Takenaka, Koshi Nature Materials, Vol. 14, Issue 1 https://doi.org/10.1038/nmat4117	journal	October 2014
Reversible adiabatic temperature changes at the magnetocaloric and barocaloric effects in Fe ₄₉ Rh ₅₁ Stern-Taulats, Enric; Gràcia-Condal, Adrià; Planes, Antoni Applied Physics Letters, Vol. 107, Issue 15 https://doi.org/10.1063/1.4933409	journal	October 2015
Coupled nature of magnetic and structural transition in MnNiGe under pressure Anzai, S.; Ozawa, K. Physical Review B, Vol. 18, Issue 5 https://doi.org/10.1103/PhysRevB.18.2173	journal	September 1978
Large reversible entropy change at the inverse magnetocaloric effect in Ni-Co-Mn-Ga-In magnetic shape memory alloys Emre, Baris; Yüce, Süheyla; Stern-Taulats, Enric Journal of Applied Physics, Vol. 113, Issue 21 https://doi.org/10.1063/1.4808340	journal	June 2013
Stable magnetostructural coupling with tunable magnetoresponsive effects in hexagonal ferromagnets Liu, Enke; Wang, Wenhong; Feng, Lin Nature Communications, Vol. 3, Issue 1 https://doi.org/10.1038/ncomms1868	journal	January 2012
The tunable magnetostructural transition in MnNiSi-FeNiGe system Zhang, C. L.; Wang, D. H.; Han, Z. D. Applied Physics Letters, Vol. 103, Issue 13 https://doi.org/10.1063/1.4823510	journal	September 2013
Inverse barocaloric effect in the giant magnetocaloric La–Fe–Si–Co compound Mañosa, Lluís; González-Alonso, David; Planes, Antoni Nature Communications, Vol. 2, Issue 1 https://doi.org/10.1038/ncomms1606	journal	September 2011
Barocaloric and magnetocaloric effects in Fe 49 Rh 51 Stern-Taulats, Enric; Planes, Antoni; Lloveras, Pol Physical Review B, Vol. 89, Issue 21 https://doi.org/10.1103/PhysRevB.89.214105	journal	June 2014
Giant barocaloric effect in the ferroic organic-inorganic hybrid [TPrA][Mn(dca)3] perovskite under easily accessible pressures Bermúdez-García, Juan M.; Sánchez-Andújar, Manuel; Castro-García, Socorro Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/ncomms15715	journal	June 2017
Magnetic properties of CoMnSi and CoMnSi0.85Ge0.15 Nizioł, S.; Fruchart, R.; Senateur, J. P. Physica Status Solidi (a), Vol. 51, Issue 1 https://doi.org/10.1002/pssa.2210510142	journal	January 1979
Caloric materials near ferroic phase transitions Moya, X.; Kar-Narayan, S.; Mathur, Nd Springer Nature https://doi.org/10.17863/cam.13209	journalarticle	January 2014
Vacancy-tuned paramagnetic/ferromagnetic martensitic transformation in Mn-poor Mn_{1-x}CoGe alloys Liu, E. K.; Zhu, W.; Feng, L. arXiv https://doi.org/10.48550/arxiv.1003.0489	text	January 2010
Pressure enhancement of the giant magnetocaloric effect in LaFe11.6Si1.4 Sun, Young; Arnold, Z.; Kamarad, J. Applied Physics Letters, Vol. 89, Issue 17 https://doi.org/10.1063/1.2372584	journal	October 2006
Magnetic-field-induced shape recovery by reverse phase transformation Kainuma, R.; Imano, Y.; Ito, W. Nature, Vol. 439, Issue 7079 https://doi.org/10.1038/nature04493	journal	February 2006
Inverse magnetocaloric effect in ferromagnetic Ni–Mn–Sn alloys Krenke, Thorsten; Duman, Eyüp; Acet, Mehmet Nature Materials, Vol. 4, Issue 6 https://doi.org/10.1038/nmat1395	journal	May 2005
Recent developments in magnetocaloric materials Gschneidner, K. A.; Pecharsky, V. K.; Tsokol, A. O. Reports on Progress in Physics, Vol. 68, Issue 6, p. 1479-1539 https://doi.org/10.1088/0034-4885/68/6/R04	journal	May 2005
Stress modulated martensitic transition and magnetocaloric effect in hexagonal Ni2In-type MnCoGe1−xInx alloys Liu, Y.; Shen, F. R.; Zhang, M. Journal of Alloys and Compounds, Vol. 649 https://doi.org/10.1016/j.jallcom.2015.07.234	journal	November 2015

Cited By (8)

Giant reversible barocaloric response of (MnNiSi) _{1− x} (FeCoGe) _x ( x = 0.39, 0.40, 0.41) Lloveras, Pol; Samanta, Tapas; Barrio, María APL Materials, Vol. 7, Issue 6 https://doi.org/10.1063/1.5097959	journal	June 2019
Magnetic and lattice contributions to the magnetocaloric effect in Sm _1-x Sr _x MnO ₃ manganites Aliev, A. M.; Batdalov, A. B.; Khanov, L. N. Applied Physics Letters, Vol. 112, Issue 14 https://doi.org/10.1063/1.5023867	journal	April 2018
Colossal barocaloric effects near room temperature in plastic crystals of neopentylglycol Lloveras, P.; Aznar, A.; Barrio, M. Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-09730-9	journal	April 2019
Colossal barocaloric effects near room temperature in plastic crystals of neopentylglycol. Lloveras, P.; Aznar, A.; Barrio, M. Apollo - University of Cambridge Repository https://doi.org/10.17863/cam.38470	text	January 2019
Giant and Reversible Inverse Barocaloric Effects near Room Temperature in Ferromagnetic MnCoGeB0.03. Aznar, Araceli; Lloveras, Pol; Kim, Ji-Yeob Apollo - University of Cambridge Repository https://doi.org/10.17863/cam.42244	text	January 2019
Reversible and irreversible colossal barocaloric effects in plastic crystals Aznar, A.; Lloveras, P.; Barrio, M. Apollo - University of Cambridge Repository https://doi.org/10.17863/cam.48384	text	January 2020
Giant and Reversible Inverse Barocaloric Effects near Room Temperature in Ferromagnetic MnCoGeB _0.03 Aznar, Araceli; Lloveras, Pol; Kim, Ji‐Yeob Advanced Materials, Vol. 31, Issue 37 https://doi.org/10.1002/adma.201903577	journal	July 2019
A Novel Option for Waste Tire Rubber Reutilization: Refrigerant in Solid-State Cooling Devices Bom, Nicolau Molina; Usuda, Érik Oda; Gigliotti, Mariana da Silva arXiv https://doi.org/10.48550/arxiv.1907.02113	preprint	January 2019

Figures / Tables (5)

Similar Records

Giant reversible barocaloric response of (MnNiSi)_1-x (FeCoGe)_x (x = 0.39, 0.40, 0.41)

Journal Article · 2019 · APL Materials · OSTI ID:1609723

Lloveras, Pol; Samanta, Tapas; Barrio, María; +4 more

Effects of heat treatments on magneto-structural phase transitions in MnNiSi-FeCoGe alloys

Journal Article · 2019 · Intermetallics · OSTI ID:1872461

Chen, Jing-Han; Chhetri, Tej Poudel; Saleheen, Ahmad Us; +4 more

Tuning martensitic transitions in (MnNiSi)_0.65(Fe₂Ge)_0.35 through heat treatment and hydrostatic pressure

Journal Article · 2018 · Journal of Applied Physics · OSTI ID:1484787

Chen, Jing-Han; Us Saleheen, Ahmad; Karna, Sunil K.; +4 more

Related Subjects

36 MATERIALS SCIENCE
71 CLASSICAL AND QUANTUM MECHANICS
GENERAL PHYSICS
magnetism
hydrostatics
chemical elements
thermodynamic measurements and instrumentation
phase transitions
thermodynamic properties
entropy
ferromagnetic materials
thermodynamic states and processes
thermal instruments
75 CONDENSED MATTER PHYSICS
SUPERCONDUCTIVITY AND SUPERFLUIDITY
32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATION
barocaloric effect
magnetocaloric effect

Title: Barocaloric and magnetocaloric effects in (MnNiSi)1-x(FeCoGe)x

Citation Formats