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Title: Proton radiation effects on electronic defect states in MOCVD-grown (010) β-Ga2O3

Abstract

The impact of 1.8 MeV proton irradiation on metalorganic chemical vapor deposition grown (010) β-Ga2O3 Schottky diodes is presented. It is found that after a 10.8 × 1013 cm–2 proton fluence the Schottky barrier height of (1.40 ± 0.05 eV) and the ideality factor of (1.05 ± 0.05 ) are unaffected. Capacitance–voltage extracted net ionized doping curves indicate a carrier removal rate of 268 ± 10 cm–1. The defect states responsible for the observed carrier removal are studied through a combination of deep level transient and optical spectroscopies (DLTS/DLOS) as well as lighted capacitance–voltage (LCV) measurements. The dominating effect on the defect spectrum is due to the Ec-2.0 eV defect state observed in DLOS and LCV. This state accounts for ~75 % of the total trap introduction rate and is the primary source of carrier removal from proton irradiation. Of the DLTS detected states, the Ec-0.72 eV state dominated but had a comparably smaller contribution to the trap introduction. These two traps have previously been correlated with acceptor-like gallium vacancy-related defects. Several other trap states at EC-0.36, EC-0.63, and EC-1.09 eV were newly detected after proton irradiation, and two pre-existing states at EC-1.2 and EC-4.4 eV showed a slight increasemore » in concentration after irradiation, together accounting for the remainder of trap introduction. However, a pre-existing trap at Ec-0.40 eV was found to be insensitive to proton irradiation and, therefore, is likely of extrinsic origin. Furthermore, the comprehensive defect characterization of 1.8 MeV proton irradiation damage can aid the modeling and design for a range of radiation tolerant devices.« less

Authors:
ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [2]; ORCiD logo [2];  [1]; ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [1]
  1. The Ohio State Univ., Columbus, OH (United States)
  2. Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
Publication Date:
Research Org.:
Georgia Institute of Technology, Atlanta, GA (United States); Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
Sponsoring Org.:
USDOE National Nuclear Security Administration (NNSA); Department of the Defense, Defense Threat Reduction Agency; US Air Force Office of Scientific Research (AFOSR)
OSTI Identifier:
1971636
Alternate Identifier(s):
OSTI ID: 1916513; OSTI ID: 2311671
Report Number(s):
SAND-2023-00299J
Journal ID: ISSN 0021-8979; TRN: US2313584
Grant/Contract Number:  
NA0003921; HDTRA11710034; DGE-1343012; FA9550-22-1-0012; NA0003525; Award Number DE-NA0003921
Resource Type:
Accepted Manuscript
Journal Name:
Journal of Applied Physics
Additional Journal Information:
Journal Volume: 133; Journal Issue: 4; Journal ID: ISSN 0021-8979
Publisher:
American Institute of Physics (AIP)
Country of Publication:
United States
Language:
English
Subject:
42 ENGINEERING; Electrical properties and parameters; Schottky diodes; Current-voltage characteristic; Semiconductor device defects; Deep level transient spectroscopy; Optical spectroscopy; Radiation damage; Schottky barriers; Chemical vapor deposition; Oxides; electrical properties and parameters; current-voltage characteristic; semiconductor device defects; deep level transient spectroscopy; optical spectroscopy; radiation damage; chemical vapor deposition; oxides

Citation Formats

McGlone, Joe F., Ghadi, Hemant, Cornuelle, Evan, Armstrong, Andrew, Burns, George, Feng, Zixuan, Uddin Bhuiyan, A. F. M. Anhar, Zhao, Hongping, Arehart, Aaron R., and Ringel, Steven A. Proton radiation effects on electronic defect states in MOCVD-grown (010) β-Ga2O3. United States: N. p., 2023. Web. doi:10.1063/5.0121416.
McGlone, Joe F., Ghadi, Hemant, Cornuelle, Evan, Armstrong, Andrew, Burns, George, Feng, Zixuan, Uddin Bhuiyan, A. F. M. Anhar, Zhao, Hongping, Arehart, Aaron R., & Ringel, Steven A. Proton radiation effects on electronic defect states in MOCVD-grown (010) β-Ga2O3. United States. https://doi.org/10.1063/5.0121416
McGlone, Joe F., Ghadi, Hemant, Cornuelle, Evan, Armstrong, Andrew, Burns, George, Feng, Zixuan, Uddin Bhuiyan, A. F. M. Anhar, Zhao, Hongping, Arehart, Aaron R., and Ringel, Steven A. Wed . "Proton radiation effects on electronic defect states in MOCVD-grown (010) β-Ga2O3". United States. https://doi.org/10.1063/5.0121416. https://www.osti.gov/servlets/purl/1971636.
@article{osti_1971636,
title = {Proton radiation effects on electronic defect states in MOCVD-grown (010) β-Ga2O3},
author = {McGlone, Joe F. and Ghadi, Hemant and Cornuelle, Evan and Armstrong, Andrew and Burns, George and Feng, Zixuan and Uddin Bhuiyan, A. F. M. Anhar and Zhao, Hongping and Arehart, Aaron R. and Ringel, Steven A.},
abstractNote = {The impact of 1.8 MeV proton irradiation on metalorganic chemical vapor deposition grown (010) β-Ga2O3 Schottky diodes is presented. It is found that after a 10.8 × 1013 cm–2 proton fluence the Schottky barrier height of (1.40 ± 0.05 eV) and the ideality factor of (1.05 ± 0.05 ) are unaffected. Capacitance–voltage extracted net ionized doping curves indicate a carrier removal rate of 268 ± 10 cm–1. The defect states responsible for the observed carrier removal are studied through a combination of deep level transient and optical spectroscopies (DLTS/DLOS) as well as lighted capacitance–voltage (LCV) measurements. The dominating effect on the defect spectrum is due to the Ec-2.0 eV defect state observed in DLOS and LCV. This state accounts for ~75 % of the total trap introduction rate and is the primary source of carrier removal from proton irradiation. Of the DLTS detected states, the Ec-0.72 eV state dominated but had a comparably smaller contribution to the trap introduction. These two traps have previously been correlated with acceptor-like gallium vacancy-related defects. Several other trap states at EC-0.36, EC-0.63, and EC-1.09 eV were newly detected after proton irradiation, and two pre-existing states at EC-1.2 and EC-4.4 eV showed a slight increase in concentration after irradiation, together accounting for the remainder of trap introduction. However, a pre-existing trap at Ec-0.40 eV was found to be insensitive to proton irradiation and, therefore, is likely of extrinsic origin. Furthermore, the comprehensive defect characterization of 1.8 MeV proton irradiation damage can aid the modeling and design for a range of radiation tolerant devices.},
doi = {10.1063/5.0121416},
journal = {Journal of Applied Physics},
number = 4,
volume = 133,
place = {United States},
year = {Wed Jan 25 00:00:00 EST 2023},
month = {Wed Jan 25 00:00:00 EST 2023}
}

Works referenced in this record:

Split Ga vacancies in n -type and semi-insulating β-Ga 2 O 3 single crystals
journal, February 2021

  • Karjalainen, A.; Makkonen, I.; Etula, J.
  • Applied Physics Letters, Vol. 118, Issue 7
  • DOI: 10.1063/5.0033930

Iron and intrinsic deep level states in Ga 2 O 3
journal, January 2018

  • Ingebrigtsen, M. E.; Varley, J. B.; Kuznetsov, A. Yu.
  • Applied Physics Letters, Vol. 112, Issue 4
  • DOI: 10.1063/1.5020134

Hydrogenated cation vacancies in semiconducting oxides
journal, August 2011


Influence of neutron irradiation on deep levels in Ge-doped (010) β-Ga 2 O 3 layers grown by plasma-assisted molecular beam epitaxy
journal, December 2019

  • Farzana, Esmat; Mauze, Akhil; Varley, Joel B.
  • APL Materials, Vol. 7, Issue 12
  • DOI: 10.1063/1.5126463

Impact of proton irradiation on conductivity and deep level defects in β-Ga 2 O 3
journal, February 2019

  • Ingebrigtsen, M. E.; Kuznetsov, A. Yu.; Svensson, B. G.
  • APL Materials, Vol. 7, Issue 2
  • DOI: 10.1063/1.5054826

Impact of deep level defects induced by high energy neutron radiation in β-Ga 2 O 3
journal, February 2019

  • Farzana, Esmat; Chaiken, Max F.; Blue, Thomas E.
  • APL Materials, Vol. 7, Issue 2
  • DOI: 10.1063/1.5054606

Correlation of proton irradiation induced threshold voltage shifts to deep level traps in AlGaN/GaN heterostructures
journal, April 2016

  • Zhang, Z.; Cardwell, D.; Sasikumar, A.
  • Journal of Applied Physics, Vol. 119, Issue 16
  • DOI: 10.1063/1.4948298

Structure and vibrational properties of the dominant O-H center in β-Ga 2 O 3
journal, June 2018

  • Weiser, Philip; Stavola, Michael; Fowler, W. Beall
  • Applied Physics Letters, Vol. 112, Issue 23
  • DOI: 10.1063/1.5029921

Deep‐level transient spectroscopy: A new method to characterize traps in semiconductors
journal, July 1974


Electrical conductivity and carrier concentration control in β-Ga2O3 by Si doping
journal, May 2008

  • Víllora, Encarnación G.; Shimamura, Kiyoshi; Yoshikawa, Yukio
  • Applied Physics Letters, Vol. 92, Issue 20
  • DOI: 10.1063/1.2919728

Defects responsible for charge carrier removal and correlation with deep level introduction in irradiated β-Ga 2 O 3
journal, August 2018

  • Polyakov, A. Y.; Smirnov, N. B.; Shchemerov, I. V.
  • Applied Physics Letters, Vol. 113, Issue 9
  • DOI: 10.1063/1.5049130

Deep level defects in Ge-doped (010) β-Ga 2 O 3 layers grown by plasma-assisted molecular beam epitaxy
journal, April 2018

  • Farzana, Esmat; Ahmadi, Elaheh; Speck, James S.
  • Journal of Applied Physics, Vol. 123, Issue 16
  • DOI: 10.1063/1.5010608

Optical Absorption and Photoconductivity in the Band Edge of β Ga 2 O 3
journal, October 1965


Radiation hardness of gallium nitride
journal, December 2002

  • Ionascut-Nedelcescu, A.; Carlone, C.; Houdayer, A.
  • IEEE Transactions on Nuclear Science, Vol. 49, Issue 6
  • DOI: 10.1109/TNS.2002.805363

Low-pressure CVD-grown β-Ga 2 O 3 bevel-field-plated Schottky barrier diodes
journal, February 2018

  • Joishi, Chandan; Rafique, Subrina; Xia, Zhanbo
  • Applied Physics Express, Vol. 11, Issue 3
  • DOI: 10.7567/APEX.11.031101

Effect of 1.5 MeV electron irradiation on β-Ga2O3 carrier lifetime and diffusion length
journal, February 2018

  • Lee, Jonathan; Flitsiyan, Elena; Chernyak, Leonid
  • Applied Physics Letters, Vol. 112, Issue 8
  • DOI: 10.1063/1.5011971

A unified thermionic and thermionic-field emission (TE–TFE) model for ideal Schottky reverse-bias leakage current
journal, January 2022

  • Li, W.; Jena, D.; Xing, H. G.
  • Journal of Applied Physics, Vol. 131, Issue 1
  • DOI: 10.1063/5.0070668

Pulsed fast reactor neutron irradiation effects in Si doped n-type β-Ga 2 O 3
journal, May 2020

  • Polyakov, A. Y.; Smirnov, N. B.; Shchemerov, I. V.
  • Journal of Physics D: Applied Physics, Vol. 53, Issue 27
  • DOI: 10.1088/1361-6463/ab83c4

Trapping Effects in Si -Doped -Ga 2 O 3 MESFETs on an Fe-Doped -Ga 2 O 3 Substrate
journal, July 2018

  • Mcglone, Joe F.; Xia, Zhanbo; Zhang, Yuewei
  • IEEE Electron Device Letters, Vol. 39, Issue 7
  • DOI: 10.1109/LED.2018.2843344

Gallium oxide (Ga 2 O 3 ) metal-semiconductor field-effect transistors on single-crystal β-Ga 2 O 3 (010) substrates
journal, January 2012

  • Higashiwaki, Masataka; Sasaki, Kohei; Kuramata, Akito
  • Applied Physics Letters, Vol. 100, Issue 1
  • DOI: 10.1063/1.3674287

1.5 MeV electron irradiation damage in β-Ga 2 O 3 vertical rectifiers
journal, May 2017

  • Yang, Jiancheng; Ren, Fan; Pearton, Stephen J.
  • Journal of Vacuum Science & Technology B, Nanotechnology and Microelectronics: Materials, Processing, Measurement, and Phenomena, Vol. 35, Issue 3
  • DOI: 10.1116/1.4983377

Probing Charge Transport and Background Doping in Metal‐Organic Chemical Vapor Deposition‐Grown (010) β‐Ga 2 O 3
journal, June 2020

  • Feng, Zixuan; Bhuiyan, A. F. M. Anhar Uddin; Xia, Zhanbo
  • physica status solidi (RRL) – Rapid Research Letters, Vol. 14, Issue 8
  • DOI: 10.1002/pssr.202000145

MOCVD homoepitaxy of Si-doped (010) β-Ga 2 O 3 thin films with superior transport properties
journal, June 2019

  • Feng, Zixuan; Anhar Uddin Bhuiyan, A. F. M.; Karim, Md Rezaul
  • Applied Physics Letters, Vol. 114, Issue 25
  • DOI: 10.1063/1.5109678

Identification of critical buffer traps in Si δ-doped β-Ga 2 O 3 MESFETs
journal, October 2019

  • McGlone, Joe F.; Xia, Zhanbo; Joishi, Chandan
  • Applied Physics Letters, Vol. 115, Issue 15
  • DOI: 10.1063/1.5118250

Unusual Formation of Point-Defect Complexes in the Ultrawide-Band-Gap Semiconductor β Ga 2 O 3
journal, November 2019


SRIM – The stopping and range of ions in matter (2010)
journal, June 2010

  • Ziegler, James F.; Ziegler, M. D.; Biersack, J. P.
  • Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, Vol. 268, Issue 11-12
  • DOI: 10.1016/j.nimb.2010.02.091

On the bulk β-Ga2O3 single crystals grown by the Czochralski method
journal, October 2014


Choosing the correct hybrid for defect calculations: A case study on intrinsic carrier trapping in β G a 2 O 3
journal, February 2017


Effect of 5 MeV proton irradiation damage on performance of β-Ga 2 O 3 photodetectors
journal, July 2016

  • Ahn, Shihyun; Lin, Yi-Hsuan; Ren, Fan
  • Journal of Vacuum Science & Technology B, Nanotechnology and Microelectronics: Materials, Processing, Measurement, and Phenomena, Vol. 34, Issue 4
  • DOI: 10.1116/1.4950872

Enhancement-Mode Ga 2 O 3 Vertical Transistors With Breakdown Voltage >1 kV
journal, June 2018

  • Hu, Zongyang; Nomoto, Kazuki; Li, Wenshen
  • IEEE Electron Device Letters, Vol. 39, Issue 6
  • DOI: 10.1109/LED.2018.2830184

Interplay of vacancies, hydrogen, and electrical compensation in irradiated and annealed n-type β-Ga2O3
journal, April 2021

  • Karjalainen, A.; Weiser, P. M.; Makkonen, I.
  • Journal of Applied Physics, Vol. 129, Issue 16
  • DOI: 10.1063/5.0042518

Growth of β-Ga 2 O 3 Single Crystals by the Edge-Defined, Film Fed Growth Method
journal, November 2008

  • Aida, Hideo; Nishiguchi, Kengo; Takeda, Hidetoshi
  • Japanese Journal of Applied Physics, Vol. 47, Issue 11
  • DOI: 10.1143/JJAP.47.8506

Synthesis and control of conductivity of ultraviolet transmitting β-Ga2O3 single crystals
journal, June 1997

  • Ueda, Naoyuki; Hosono, Hideo; Waseda, Ryuta
  • Applied Physics Letters, Vol. 70, Issue 26
  • DOI: 10.1063/1.119233

A method to determine deep level profiles in highly compensated, wide band gap semiconductors
journal, April 2005

  • Armstrong, A.; Arehart, A. R.; Ringel, S. A.
  • Journal of Applied Physics, Vol. 97, Issue 8
  • DOI: 10.1063/1.1862321

Full bandgap defect state characterization of β -Ga 2 O 3 grown by metal organic chemical vapor deposition
journal, February 2020

  • Ghadi, Hemant; McGlone, Joe F.; Jackson, Christine M.
  • APL Materials, Vol. 8, Issue 2
  • DOI: 10.1063/1.5142313

3.8-MV/cm Breakdown Strength of MOVPE-Grown Sn-Doped $\beta $ -Ga 2 O 3 MOSFETs
journal, July 2016

  • Green, Andrew J.; Chabak, Kelson D.; Heller, Eric R.
  • IEEE Electron Device Letters, Vol. 37, Issue 7
  • DOI: 10.1109/LED.2016.2568139

Point defect induced degradation of electrical properties of Ga 2 O 3 by 10 MeV proton damage
journal, January 2018

  • Polyakov, A. Y.; Smirnov, N. B.; Shchemerov, I. V.
  • Applied Physics Letters, Vol. 112, Issue 3
  • DOI: 10.1063/1.5012993

Deep level defects throughout the bandgap of (010) β-Ga 2 O 3 detected by optically and thermally stimulated defect spectroscopy
journal, February 2016

  • Zhang, Z.; Farzana, E.; Arehart, A. R.
  • Applied Physics Letters, Vol. 108, Issue 5
  • DOI: 10.1063/1.4941429

10 MeV proton damage in β-Ga2O3 Schottky rectifiers
journal, January 2018

  • Yang, Jiancheng; Chen, Zhiting; Ren, Fan
  • Journal of Vacuum Science & Technology B, Nanotechnology and Microelectronics: Materials, Processing, Measurement, and Phenomena, Vol. 36, Issue 1
  • DOI: 10.1116/1.5013155

Influence of growth temperature on defect states throughout the bandgap of MOCVD-grown β-Ga2O3
journal, October 2020

  • Ghadi, Hemant; McGlone, Joe F.; Feng, Zixuan
  • Applied Physics Letters, Vol. 117, Issue 17
  • DOI: 10.1063/5.0025970

Isothermal DLTS method using sampling time scanning
journal, May 1986

  • Turchanikov, V. I.; Lysenko, V. S.; Gusev, V. A.
  • physica status solidi (a), Vol. 95, Issue 1
  • DOI: 10.1002/pssa.2210950136

Some electrical properties of the semiconductor βGa2O3
journal, March 1967

  • Lorenz, M. R.; Woods, J. F.; Gambino, R. J.
  • Journal of Physics and Chemistry of Solids, Vol. 28, Issue 3
  • DOI: 10.1016/0022-3697(67)90305-8

Multistability of isolated and hydrogenated Ga–O divacancies in β Ga 2 O 3
journal, February 2021