The Design and Optimization of Plasmonic Crystals for Surface Enhanced Raman Spectroscopy Using the Finite Difference Time Domain Method

Bigness, Alec; Montgomery, Jason

doi:10.3390/ma11050672

Title: The Design and Optimization of Plasmonic Crystals for Surface Enhanced Raman Spectroscopy Using the Finite Difference Time Domain Method

Abstract

We present computational studies of quasi three-dimensional nanowell (NW) and nanopost (NP) plasmonic crystals for applications in surface enhanced Raman spectroscopy (SERS). The NW and NP plasmonic crystals are metal coated arrays of cylindrical voids or posts, respectively, in a dielectric substrate characterized by a well/post diameter (D), relief depth (RD), periodicity (P), and metal thickness (MT). Each plasmonic crystal is modeled using the three-dimensional finite-difference time-domain (FDTD) method with periodic boundary conditions in the x- and y-directions applied to a computational unit cell to simulate the effect of a periodic array.

Authors:

Bigness, Alec ^[1];

^[1]

Florida Southern College, Lakeland, FL (United States)

Publication Date:: Thu Apr 26 00:00:00 EDT 2018

Research Org.:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States). National Energy Research Scientific Computing Center (NERSC); Univ. of California, Oakland, CA (United States)

Sponsoring Org.:: USDOE Office of Science (SC)

OSTI Identifier:: 1544041

Grant/Contract Number:: AC02-05CH11231

Resource Type:: Accepted Manuscript

Journal Name:: Materials

Additional Journal Information:: Journal Volume: 11; Journal Issue: 5; Journal ID: ISSN 1996-1944

Publisher:: MDPI

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE; Materials Science; finite-difference time-domain; FDTD; surface plasmons; surface enhanced Raman spectroscopy; soft nanolithography

Citation Formats


                    Bigness, Alec, and Montgomery, Jason. The Design and Optimization of Plasmonic Crystals for Surface Enhanced Raman Spectroscopy Using the Finite Difference Time Domain Method.  United States: N. p., 2018. 
Web.  doi:10.3390/ma11050672.

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                    Bigness, Alec, & Montgomery, Jason. The Design and Optimization of Plasmonic Crystals for Surface Enhanced Raman Spectroscopy Using the Finite Difference Time Domain Method.  United States.  https://doi.org/10.3390/ma11050672

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                    Bigness, Alec, and Montgomery, Jason. Thu .  
"The Design and Optimization of Plasmonic Crystals for Surface Enhanced Raman Spectroscopy Using the Finite Difference Time Domain Method".  United States.  https://doi.org/10.3390/ma11050672.  https://www.osti.gov/servlets/purl/1544041.

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@article{osti_1544041,

  title        = {The Design and Optimization of Plasmonic Crystals for Surface Enhanced Raman Spectroscopy Using the Finite Difference Time Domain Method},

  author       = {Bigness, Alec and Montgomery, Jason},

  abstractNote = {We present computational studies of quasi three-dimensional nanowell (NW) and nanopost (NP) plasmonic crystals for applications in surface enhanced Raman spectroscopy (SERS). The NW and NP plasmonic crystals are metal coated arrays of cylindrical voids or posts, respectively, in a dielectric substrate characterized by a well/post diameter (D), relief depth (RD), periodicity (P), and metal thickness (MT). Each plasmonic crystal is modeled using the three-dimensional finite-difference time-domain (FDTD) method with periodic boundary conditions in the x- and y-directions applied to a computational unit cell to simulate the effect of a periodic array.},

  doi          = {10.3390/ma11050672},

  journal      = {Materials},

  number       = 5,

  volume       = 11,

  place        = {United States},

  year         = {Thu Apr 26 00:00:00 EDT 2018},

  month        = {Thu Apr 26 00:00:00 EDT 2018}

}

Copy to clipboard

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https://doi.org/10.3390/ma11050672

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Works referenced in this record:

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Seeded Growth Synthesis of Uniform Gold Nanoparticles with Diameters of 15−300 nm
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Ziegler, Christoph; Eychmüller, Alexander
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Modeling of regular gold nanostructures arrays for SERS applications using a 3D FDTD method
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Grimault, A. -S.; Vial, A.; Lamy de la Chapelle, M.
Applied Physics B, Vol. 84, Issue 1-2
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Distinguishing correct from incorrect PML proposals and a corrected unsplit PML for anisotropic, dispersive media
journal, April 2011

Oskooi, Ardavan; Johnson, Steven G.
Journal of Computational Physics, Vol. 230, Issue 7
DOI: 10.1016/j.jcp.2011.01.006

Multispectral Thin Film Biosensing and Quantitative Imaging Using 3D Plasmonic Crystals
journal, August 2009

Stewart, Matthew E.; Yao, Jimin; Maria, Joana
Analytical Chemistry, Vol. 81, Issue 15
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Mosaic-like Silver Nanobowl Plasmonic Crystals as Highly Active Surface-Enhanced Raman Scattering Substrates
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Baca, Alfred J.; Baca, Joshua; Montgomery, Jason M.
The Journal of Physical Chemistry C, Vol. 119, Issue 31
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Nanostructured Plasmonic Sensors
journal, February 2008

Stewart, Matthew E.; Anderton, Christopher R.; Thompson, Lucas B.
Chemical Reviews, Vol. 108, Issue 2
DOI: 10.1021/cr068126n

Localized Surface Plasmon Resonance Sensors
journal, June 2011

Mayer, Kathryn M.; Hafner, Jason H.
Chemical Reviews, Vol. 111, Issue 6
DOI: 10.1021/cr100313v

Plasmon-Sampled Surface-Enhanced Raman Excitation Spectroscopy ^†
journal, July 2003

Haynes, Christy L.; Van Duyne, Richard P.
The Journal of Physical Chemistry B, Vol. 107, Issue 30
DOI: 10.1021/jp027749b

Finite-difference Time-domain Studies of the Optical Properties of Nanoshell Dimers
journal, May 2005

Oubre, C.; Nordlander, P.
The Journal of Physical Chemistry B, Vol. 109, Issue 20
DOI: 10.1021/jp044382x

Optimization of Nanopost Plasmonic Crystals for Surface Enhanced Raman Scattering
journal, March 2011

Baca, Alfred J.; Montgomery, Jason M.; Cambrea, Lee R.
The Journal of Physical Chemistry C, Vol. 115, Issue 15
DOI: 10.1021/jp109066c

Flexibly tunable high-quality-factor induced transparency in plasmonic systems
journal, January 2018

Lu, Hua; Gan, Xuetao; Mao, Dong
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Eustis, Susie; El-Sayed, Mostafa A.
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Atomic force microscopy and surface‐enhanced Raman spectroscopy. I. Ag island films and Ag film over polymer nanosphere surfaces supported on glass
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The Journal of Chemical Physics, Vol. 99, Issue 3
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Yang, Wen‐hui; Hulteen, John; Schatz, George C.
The Journal of Chemical Physics, Vol. 104, Issue 11
DOI: 10.1063/1.471241

Quantitative multispectral biosensing and 1D imaging using quasi-3D plasmonic crystals
journal, November 2006

Stewart, M. E.; Mack, N. H.; Malyarchuk, V.
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Refractive index sensing and surface-enhanced Raman spectroscopy using silver–gold layered bimetallic plasmonic crystals
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Kang, Somi; Lehman, Sean E.; Schulmerich, Matthew V.
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Works referencing / citing this record:

Plasmonic Au Array SERS Substrate with Optimized Thin Film Oxide Substrate Layer
journal, June 2018

Brawley, Zachary; Bauman, Stephen; Darweesh, Ahmad
Materials, Vol. 11, Issue 6
DOI: 10.3390/ma11060942

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Similar Records

Title: The Design and Optimization of Plasmonic Crystals for Surface Enhanced Raman Spectroscopy Using the Finite Difference Time Domain Method

Abstract

Citation Formats

The Optical Properties of Metal Nanoparticles: The Influence of Size, Shape, and Dielectric Environment journal, January 2003

Quantitative multispectral biosensing and 1D imaging using quasi-3D plasmonic crystals journal, November 2006

Raman spectra of pyridine adsorbed at a silver electrode journal, May 1974

Atomic force microscopy and surface‐enhanced Raman spectroscopy. I. Ag island films and Ag film over polymer nanosphere surfaces supported on glass journal, August 1993

Distinguishing correct from incorrect PML proposals and a corrected unsplit PML for anisotropic, dispersive media journal, April 2011

Optimization of Nanopost Plasmonic Crystals for Surface Enhanced Raman Scattering journal, March 2011

Nanostructured Plasmonic Sensors journal, February 2008

Molded plasmonic crystals for detecting and spatially imaging surface bound species by surface-enhanced Raman scattering journal, June 2009

Review of Recent Progress of Plasmonic Materials and Nano-Structures for Surface-Enhanced Raman Scattering journal, May 2015

Modeling of regular gold nanostructures arrays for SERS applications using a 3D FDTD method journal, April 2006

Localized Surface Plasmon Resonance Sensors journal, June 2011

Beiträge zur Optik trüber Medien, speziell kolloidaler Metallösungen journal, January 1908

Flexibly tunable high-quality-factor induced transparency in plasmonic systems journal, January 2018

Theoretical Simulation and Focused Ion Beam Fabrication of Gold Nanostructures for Surface-Enhanced Raman Scattering (SERS) journal, December 2007

Refractive index sensing and surface-enhanced Raman spectroscopy using silver–gold layered bimetallic plasmonic crystals journal, January 2017

Tailoring plasmonic substrates for surface enhanced spectroscopies journal, January 2008

Mosaic-like Silver Nanobowl Plasmonic Crystals as Highly Active Surface-Enhanced Raman Scattering Substrates journal, July 2015

Finite-difference Time-domain Studies of the Optical Properties of Nanoshell Dimers journal, May 2005

Meep: A flexible free-software package for electromagnetic simulations by the FDTD method journal, March 2010

Anomalously intense Raman spectra of pyridine at a silver electrode journal, June 1977

Soft Embossing of Nanoscale Optical and Plasmonic Structures in Glass journal, June 2011

All-optical manipulation of micrometer-sized metallic particles journal, January 2018

A surface‐enhanced hyper‐Raman and surface‐enhanced Raman scattering study of trans ‐1,2‐bis(4‐pyridyl)ethylene adsorbed onto silver film over nanosphere electrodes. Vibrational assignments: Experiment and theory journal, March 1996

Optical Constants of the Noble Metals journal, December 1972

Plasmon-Sampled Surface-Enhanced Raman Excitation Spectroscopy † journal, July 2003

Multispectral Thin Film Biosensing and Quantitative Imaging Using 3D Plasmonic Crystals journal, August 2009

Seeded Growth Synthesis of Uniform Gold Nanoparticles with Diameters of 15−300 nm journal, February 2011

One-step synthesis of gold and silver non-spherical nanoparticles mediated by Eosin Methylene Blue agar journal, December 2019

Why Gold Nanoparticles Are More Precious than Pretty Gold: Noble Metal Surface Plasmon Resonance and Its Enhancement of the Radiative and Nonradiative Properties of Nanocrystals of Different Shapes journal, June 2006

Meep: A flexible free-software package for electromagnetic simulations by the FDTD method dataset, January 2019

The Optical Properties of Metal Nanoparticles: The Influence of Size, Shape, and Dielectric Environment journal, April 2003

Meep: A flexible free-software package for electromagnetic simulations by the FDTD method dataset, January 2019

The Optical Properties of Metal Nanoparticles: The Influence of Size, Shape, and Dielectric Environment journal, April 2003

Modeling of regular gold nanostructures arrays for SERS applications using a 3D FDTD method journal, April 2006

Distinguishing correct from incorrect PML proposals and a corrected unsplit PML for anisotropic, dispersive media journal, April 2011

Multispectral Thin Film Biosensing and Quantitative Imaging Using 3D Plasmonic Crystals journal, August 2009

Mosaic-like Silver Nanobowl Plasmonic Crystals as Highly Active Surface-Enhanced Raman Scattering Substrates journal, July 2015

Nanostructured Plasmonic Sensors journal, February 2008

Localized Surface Plasmon Resonance Sensors journal, June 2011

Plasmon-Sampled Surface-Enhanced Raman Excitation Spectroscopy † journal, July 2003

Finite-difference Time-domain Studies of the Optical Properties of Nanoshell Dimers journal, May 2005

Optimization of Nanopost Plasmonic Crystals for Surface Enhanced Raman Scattering journal, March 2011

Flexibly tunable high-quality-factor induced transparency in plasmonic systems journal, January 2018

Lighting system bioinspired by Haworthia obtusa journal, July 2020

Why gold nanoparticles are more precious than pretty gold: Noble metal surface plasmon resonance and its enhancement of the radiative and nonradiative properties of nanocrystals of different shapes journal, January 2006

Tailoring plasmonic substrates for surface enhanced spectroscopies journal, January 2008

Atomic force microscopy and surface‐enhanced Raman spectroscopy. I. Ag island films and Ag film over polymer nanosphere surfaces supported on glass journal, August 1993

A surface‐enhanced hyper‐Raman and surface‐enhanced Raman scattering study of trans ‐1,2‐bis(4‐pyridyl)ethylene adsorbed onto silver film over nanosphere electrodes. Vibrational assignments: Experiment and theory journal, March 1996

Quantitative multispectral biosensing and 1D imaging using quasi-3D plasmonic crystals journal, November 2006

Subwavelength Optical Imaging through a Metallic Nanorod Array journal, December 2005

Graded-index structures for high-efficiency solar thermophotovoltaic emitting surfaces journal, January 2014

Review of Recent Progress of Plasmonic Materials and Nano-Structures for Surface-Enhanced Raman Scattering journal, May 2015

Refractive index sensing and surface-enhanced Raman spectroscopy using silver–gold layered bimetallic plasmonic crystals journal, January 2017

Plasmonic Au Array SERS Substrate with Optimized Thin Film Oxide Substrate Layer journal, June 2018

The Optical Properties of Metal Nanoparticles: The Influence of Size, Shape, and Dielectric Environment
journal, January 2003

Quantitative multispectral biosensing and 1D imaging using quasi-3D plasmonic crystals
journal, November 2006

Raman spectra of pyridine adsorbed at a silver electrode
journal, May 1974

Atomic force microscopy and surface‐enhanced Raman spectroscopy. I. Ag island films and Ag film over polymer nanosphere surfaces supported on glass
journal, August 1993

Distinguishing correct from incorrect PML proposals and a corrected unsplit PML for anisotropic, dispersive media
journal, April 2011

Optimization of Nanopost Plasmonic Crystals for Surface Enhanced Raman Scattering
journal, March 2011

Nanostructured Plasmonic Sensors
journal, February 2008

Molded plasmonic crystals for detecting and spatially imaging surface bound species by surface-enhanced Raman scattering
journal, June 2009

Review of Recent Progress of Plasmonic Materials and Nano-Structures for Surface-Enhanced Raman Scattering
journal, May 2015

Modeling of regular gold nanostructures arrays for SERS applications using a 3D FDTD method
journal, April 2006

Localized Surface Plasmon Resonance Sensors
journal, June 2011

Beiträge zur Optik trüber Medien, speziell kolloidaler Metallösungen
journal, January 1908

Flexibly tunable high-quality-factor induced transparency in plasmonic systems
journal, January 2018

Theoretical Simulation and Focused Ion Beam Fabrication of Gold Nanostructures for Surface-Enhanced Raman Scattering (SERS)
journal, December 2007

Refractive index sensing and surface-enhanced Raman spectroscopy using silver–gold layered bimetallic plasmonic crystals
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Tailoring plasmonic substrates for surface enhanced spectroscopies
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Mosaic-like Silver Nanobowl Plasmonic Crystals as Highly Active Surface-Enhanced Raman Scattering Substrates
journal, July 2015

Finite-difference Time-domain Studies of the Optical Properties of Nanoshell Dimers
journal, May 2005

Meep: A flexible free-software package for electromagnetic simulations by the FDTD method
journal, March 2010

Anomalously intense Raman spectra of pyridine at a silver electrode
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Soft Embossing of Nanoscale Optical and Plasmonic Structures in Glass
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All-optical manipulation of micrometer-sized metallic particles
journal, January 2018

A surface‐enhanced hyper‐Raman and surface‐enhanced Raman scattering study of trans ‐1,2‐bis(4‐pyridyl)ethylene adsorbed onto silver film over nanosphere electrodes. Vibrational assignments: Experiment and theory
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Optical Constants of the Noble Metals
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Plasmon-Sampled Surface-Enhanced Raman Excitation Spectroscopy ^†
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Multispectral Thin Film Biosensing and Quantitative Imaging Using 3D Plasmonic Crystals
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Seeded Growth Synthesis of Uniform Gold Nanoparticles with Diameters of 15−300 nm
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One-step synthesis of gold and silver non-spherical nanoparticles mediated by Eosin Methylene Blue agar
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Why Gold Nanoparticles Are More Precious than Pretty Gold: Noble Metal Surface Plasmon Resonance and Its Enhancement of the Radiative and Nonradiative Properties of Nanocrystals of Different Shapes
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Meep: A flexible free-software package for electromagnetic simulations by the FDTD method
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The Optical Properties of Metal Nanoparticles: The Influence of Size, Shape, and Dielectric Environment
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Meep: A flexible free-software package for electromagnetic simulations by the FDTD method
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The Optical Properties of Metal Nanoparticles: The Influence of Size, Shape, and Dielectric Environment
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Modeling of regular gold nanostructures arrays for SERS applications using a 3D FDTD method
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Distinguishing correct from incorrect PML proposals and a corrected unsplit PML for anisotropic, dispersive media
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Multispectral Thin Film Biosensing and Quantitative Imaging Using 3D Plasmonic Crystals
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Mosaic-like Silver Nanobowl Plasmonic Crystals as Highly Active Surface-Enhanced Raman Scattering Substrates
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Nanostructured Plasmonic Sensors
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Localized Surface Plasmon Resonance Sensors
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Plasmon-Sampled Surface-Enhanced Raman Excitation Spectroscopy ^†
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Finite-difference Time-domain Studies of the Optical Properties of Nanoshell Dimers
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Optimization of Nanopost Plasmonic Crystals for Surface Enhanced Raman Scattering
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Flexibly tunable high-quality-factor induced transparency in plasmonic systems
journal, January 2018

Lighting system bioinspired by Haworthia obtusa
journal, July 2020

Why gold nanoparticles are more precious than pretty gold: Noble metal surface plasmon resonance and its enhancement of the radiative and nonradiative properties of nanocrystals of different shapes
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Tailoring plasmonic substrates for surface enhanced spectroscopies
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Atomic force microscopy and surface‐enhanced Raman spectroscopy. I. Ag island films and Ag film over polymer nanosphere surfaces supported on glass
journal, August 1993

A surface‐enhanced hyper‐Raman and surface‐enhanced Raman scattering study of trans ‐1,2‐bis(4‐pyridyl)ethylene adsorbed onto silver film over nanosphere electrodes. Vibrational assignments: Experiment and theory
journal, March 1996

Quantitative multispectral biosensing and 1D imaging using quasi-3D plasmonic crystals
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Subwavelength Optical Imaging through a Metallic Nanorod Array
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Graded-index structures for high-efficiency solar thermophotovoltaic emitting surfaces
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Review of Recent Progress of Plasmonic Materials and Nano-Structures for Surface-Enhanced Raman Scattering
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Refractive index sensing and surface-enhanced Raman spectroscopy using silver–gold layered bimetallic plasmonic crystals
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Plasmonic Au Array SERS Substrate with Optimized Thin Film Oxide Substrate Layer
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