Molded plasmonic crystals for detecting and spatially imaging surface bound species by surface-enhanced Raman scattering.

Baca, A J; Truong, T T; Cambrea, L R; Montgomery, J M; Abdula, D; Banks, T R; Yao, J; Nuzzo, R G; Gray, S K; Rogers, J A

doi:10.1063/1.3155198

Title: Molded plasmonic crystals for detecting and spatially imaging surface bound species by surface-enhanced Raman scattering.

Journal Article · Wed Jun 24 00:00:00 EDT 2009 · Applied Physics Letters

DOI:https://doi.org/10.1063/1.3155198· OSTI ID:1016462

Baca, A J; Truong, T T; Cambrea, L R; Montgomery, J M; Abdula, D; Banks, T R; Yao, J; Nuzzo, R G; Gray, S K; Rogers, J A ^[1]

Center for Nanoscale Materials

This report introduces a type of plasmonic crystal that consists of metal coated nanostructures of relief molded on a polymer film as a substrate for surface-enhanced Raman scattering (SERS). Such crystals exhibit SERS enhancement factors of {approx} 10{sup 5}, over large areas and with sufficiently high levels of uniformity for precise two-dimensional Raman mapping of surface bound monolayers. The ease of fabrication together with the high sensitivities and spatial resolution that can be achieved suggests an attractive route to SERS substrates for portable chemical warfare agent detection, environmental monitors, noninvasive imaging of biomolecules, and other applications.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC); DP; ONR

DOE Contract Number:: DE-AC02-06CH11357

OSTI ID:: 1016462

Report Number(s):: ANL/CNM/JA-64388; TRN: US201112%%344

Journal Information:: Applied Physics Letters, Vol. 94, Issue Jun. 24, 2009

Country of Publication:: United States

Language:: ENGLISH

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Cited By (5)

Plasmonic nanostructures for surface enhanced spectroscopic methods Jahn, Martin; Patze, Sophie; Hidi, Izabella J. The Analyst, Vol. 141, Issue 3 https://doi.org/10.1039/c5an02057c	journal	January 2016
Functional Nanostructured Plasmonic Materials Yao, Jimin; Le, An-Phong; Gray, Stephen K. Advanced Materials, Vol. 22, Issue 10, p. 1102-1110 https://doi.org/10.1002/adma.200904097	journal	January 2010
The Design and Optimization of Plasmonic Crystals for Surface Enhanced Raman Spectroscopy Using the Finite Difference Time Domain Method Bigness, Alec; Montgomery, Jason Materials, Vol. 11, Issue 5 https://doi.org/10.3390/ma11050672	journal	April 2018
Coupling of plasmonic and optical cavity modes in quasi-three-dimensional plasmonic crystals Chanda, Debashis; Shigeta, Kazuki; Truong, Tu Nature Communications, Vol. 2, Issue 1 https://doi.org/10.1038/ncomms1487	journal	September 2011
Remote grating-assisted excitation of  narrow-band surface plasmons Lee, Tae-Woo; Gray, Stephen K. Optics Express, Vol. 18, Issue 23 https://doi.org/10.1364/oe.18.023857	journal	October 2010

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