3D Plasmon Coupling Assisted Sers on Nanoparticle-Nanocup Array Hybrids
Abstract
Unique colorimetric optical properties of nanomaterials can effectively influence the light absorption or emission of molecules. Here, we design plasmonic substrate for surface-enhanced Raman scattering (SERS) by inducing three-dimensional (3D) hot spots on the sensing surface. The 3D hot spots are formed by the self-assembly of plasmonic nanoparticles (NPs) on a 3D plasmonic nanocup array structure. This 3D hot spot formation on the periodic nanocup arrays achieves much higher SERS enhancement factor than the 2D NP arrays, which have been conventionally sought SERS substrates. We also utilize the colorimetric properties of the nanocup arrays for an additional degree of SERS enhancement. Colorimetry, achieved by tunable plasmon resonance wavelength by controlling dielectric property on the nanocup array surface, eases the modulation of the plasmonic resonance condition without modifying the nanostructure design. By continuously monitoring the shifts of the plasmon resonance condition and its effect on the light absorption and emission of the nearby molecules, we verify that larger SERS enhancement is achieved when the plasmon resonance wavelength is matched with the Raman excitation wavelength. In conclusion, the ease of plasmon resonance tuning of this nanocup array-nanoparticle hybrid structure allows versatile SERS enhancement for a variety of different Raman measurement conditions.
- Authors:
-
- Univ. of Illinois at Urbana-Champaign, Urbana, IL (United States)
- Publication Date:
- Research Org.:
- Univ. of Illinois at Urbana-Champaign, IL (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1500106
- Grant/Contract Number:
- FG02-07ER46453; FG02-07ER46471
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Scientific Reports
- Additional Journal Information:
- Journal Volume: 8; Journal Issue: 1; Journal ID: ISSN 2045-2322
- Publisher:
- Nature Publishing Group
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE
Citation Formats
Seo, Sujin, Chang, Te -Wei, and Liu, Gang Logan. 3D Plasmon Coupling Assisted Sers on Nanoparticle-Nanocup Array Hybrids. United States: N. p., 2018.
Web. doi:10.1038/s41598-018-19256-7.
Seo, Sujin, Chang, Te -Wei, & Liu, Gang Logan. 3D Plasmon Coupling Assisted Sers on Nanoparticle-Nanocup Array Hybrids. United States. https://doi.org/10.1038/s41598-018-19256-7
Seo, Sujin, Chang, Te -Wei, and Liu, Gang Logan. Wed .
"3D Plasmon Coupling Assisted Sers on Nanoparticle-Nanocup Array Hybrids". United States. https://doi.org/10.1038/s41598-018-19256-7. https://www.osti.gov/servlets/purl/1500106.
@article{osti_1500106,
title = {3D Plasmon Coupling Assisted Sers on Nanoparticle-Nanocup Array Hybrids},
author = {Seo, Sujin and Chang, Te -Wei and Liu, Gang Logan},
abstractNote = {Unique colorimetric optical properties of nanomaterials can effectively influence the light absorption or emission of molecules. Here, we design plasmonic substrate for surface-enhanced Raman scattering (SERS) by inducing three-dimensional (3D) hot spots on the sensing surface. The 3D hot spots are formed by the self-assembly of plasmonic nanoparticles (NPs) on a 3D plasmonic nanocup array structure. This 3D hot spot formation on the periodic nanocup arrays achieves much higher SERS enhancement factor than the 2D NP arrays, which have been conventionally sought SERS substrates. We also utilize the colorimetric properties of the nanocup arrays for an additional degree of SERS enhancement. Colorimetry, achieved by tunable plasmon resonance wavelength by controlling dielectric property on the nanocup array surface, eases the modulation of the plasmonic resonance condition without modifying the nanostructure design. By continuously monitoring the shifts of the plasmon resonance condition and its effect on the light absorption and emission of the nearby molecules, we verify that larger SERS enhancement is achieved when the plasmon resonance wavelength is matched with the Raman excitation wavelength. In conclusion, the ease of plasmon resonance tuning of this nanocup array-nanoparticle hybrid structure allows versatile SERS enhancement for a variety of different Raman measurement conditions.},
doi = {10.1038/s41598-018-19256-7},
journal = {Scientific Reports},
number = 1,
volume = 8,
place = {United States},
year = {Wed Feb 14 00:00:00 EST 2018},
month = {Wed Feb 14 00:00:00 EST 2018}
}
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Works referenced in this record:
Absorbance Amplification Using Chromophore–Nanoplasmon Coupling for Ultrasensitive Protein Quantification
journal, September 2015
- Seo, Sujin; Edwards, Lonna; Logan Liu, Gang
- Analytical Chemistry, Vol. 87, Issue 19
Different Plasmon Sensing Behavior of Silver and Gold Nanorods
journal, April 2013
- Mahmoud, Mahmoud A.; El-Sayed, Mostafa A.
- The Journal of Physical Chemistry Letters, Vol. 4, Issue 9
Sensitivity Tuning through Additive Heterogeneous Plasmon Coupling between 3D Assembled Plasmonic Nanoparticle and Nanocup Arrays
journal, May 2016
- Seo, Sujin; Zhou, Xiangfei; Liu, Gang Logan
- Small, Vol. 12, Issue 25
Intracellular SERS Nanoprobes For Distinction Of Different Neuronal Cell Types
journal, May 2013
- Huefner, Anna; Kuan, Wei-Li; Barker, Roger A.
- Nano Letters, Vol. 13, Issue 6
SERS Encoded Silver Pyramids for Attomolar Detection of Multiplexed Disease Biomarkers
journal, January 2015
- Xu, Liguang; Yan, Wenjing; Ma, Wei
- Advanced Materials, Vol. 27, Issue 10
Effect of Moisture on the Aggregation of Methylene Blue and Rhodamine 6G in Poly(N-vinylpyrrolidone) Film
journal, June 1995
- Otsuki, Soichi; Adachi, Kimihiro
- Polymer Journal, Vol. 27, Issue 6
Metallic Nanoparticle Arrays: A Common Substrate for Both Surface-Enhanced Raman Scattering and Surface-Enhanced Infrared Absorption
journal, March 2008
- Le, Fei; Brandl, Daniel W.; Urzhumov, Yaroslav A.
- ACS Nano, Vol. 2, Issue 4
Surface-Enhanced Raman Spectroscopy on Two-Dimensional Networks of Gold Nanoparticle−Nanocavity Dual Structures Supported on Dielectric Nanosieves
journal, May 2010
- Li, Yingshun; Su, Huimin; Wong, Kam Sing
- The Journal of Physical Chemistry C, Vol. 114, Issue 23
Self-Assembling Nanoparticles at Surfaces and Interfaces
journal, January 2008
- Kinge, Sachin; Crego-Calama, Mercedes; Reinhoudt, David N.
- ChemPhysChem, Vol. 9, Issue 1
Nanoimprinted SERS-Active Substrates with Tunable Surface Plasmon Resonances
journal, May 2007
- Alvarez-Puebla, Ramon; Cui, Bo; Bravo-Vasquez, Juan-Pablo
- The Journal of Physical Chemistry C, Vol. 111, Issue 18
Tunable SERS from aluminium nanohole arrays in the ultraviolet region
journal, January 2011
- Yang, Zhi-Lin; Li, Qian-Hong; Ren, Bin
- Chemical Communications, Vol. 47, Issue 13
Photochemical Formation of Silver Nanoparticles in Poly( N -vinylpyrrolidone)
journal, January 1996
- Huang, H. H.; Ni, X. P.; Loy, G. L.
- Langmuir, Vol. 12, Issue 4
Time-dependent SERS of pseudoisocyanine on silver particles generated in silver bromide sol by laser illumination
journal, February 1993
- Kneipp, K.; Kneipp, H.
- Spectrochimica Acta Part A: Molecular Spectroscopy, Vol. 49, Issue 2
Bifunctional Nano Lycurgus Cup Array Plasmonic Sensor for Colorimetric Sensing and Surface-Enhanced Raman Spectroscopy
journal, July 2015
- Chang, Te-Wei; Wang, Xinhao; Hsiao, Austin
- Advanced Optical Materials, Vol. 3, Issue 10
‘Fairy Chimney’-Shaped Tandem Metamaterials as Double Resonance SERS Substrates
journal, October 2012
- Cinel, Neval A.; Bütün, Serkan; Ertaş, Gülay
- Small, Vol. 9, Issue 4
Ligand-assisted etching: the stability of silver nanoparticles and the generation of luminescent silver nanodots
journal, January 2014
- Choi, Sungmoon; Park, Soonyoung; Yu, Junhua
- Chem. Commun., Vol. 50, Issue 95
How To Light Special Hot Spots in Multiparticle–Film Configurations
journal, November 2015
- Chen, Shu; Meng, Ling-Yan; Shan, Hang-Yong
- ACS Nano, Vol. 10, Issue 1
Nanogap-engineerable Raman-active nanodumbbells for single-molecule detection
journal, December 2009
- Lim, Dong-Kwon; Jeon, Ki-Seok; Kim, Hyung Min
- Nature Materials, Vol. 9, Issue 1
Bimetallic structure fabricated by laser interference lithography for tuning surface plasmon resonance
journal, January 2008
- Liu, C. H.; Hong, M. H.; Cheung, H. W.
- Optics Express, Vol. 16, Issue 14
Large-area, lithography-free, low-cost SERS sensor with good flexibility and high performance
journal, August 2016
- Jiang, Jing; Xu, Zhida; Ameen, Abid
- Nanotechnology, Vol. 27, Issue 38
Toward a Glucose Biosensor Based on Surface-Enhanced Raman Scattering
journal, January 2003
- Shafer-Peltier, Karen E.; Haynes, Christy L.; Glucksberg, Matthew R.
- Journal of the American Chemical Society, Vol. 125, Issue 2
Surface-enhanced Raman spectroscopy: a brief retrospective
journal, January 2005
- Moskovits, Martin
- Journal of Raman Spectroscopy, Vol. 36, Issue 6-7
Colorimetric Plasmon Resonance Imaging Using Nano Lycurgus Cup Arrays
journal, January 2013
- Gartia, Manas Ranjan; Hsiao, Austin; Pokhriyal, Anusha
- Advanced Optical Materials, Vol. 1, Issue 1
Colorimetric Effect of Gold Nanocup Arrays on Fluorescence Amplification
journal, August 2015
- Seo, Sujin; Ameen, Abid; Liu, Gang Logan
- The Journal of Physical Chemistry C, Vol. 119, Issue 32
Facile Fabrication of High-Density Sub-1-nm Gaps from Au Nanoparticle Monolayers as Reproducible SERS Substrates
journal, October 2016
- Si, Shaorong; Liang, Wenkai; Sun, Yinghui
- Advanced Functional Materials, Vol. 26, Issue 44
Shell-isolated nanoparticle-enhanced Raman spectroscopy
journal, March 2010
- Li, Jian Feng; Huang, Yi Fan; Ding, Yong
- Nature, Vol. 464, Issue 7287, p. 392-395
Monitoring the electrochemical responses of neurotransmitters through localized surface plasmon resonance using nanohole array
journal, July 2017
- Li, Nantao; Lu, Yanli; Li, Shuang
- Biosensors and Bioelectronics, Vol. 93
Rapid Detection of an Anthrax Biomarker by Surface-Enhanced Raman Spectroscopy
journal, March 2005
- Zhang, Xiaoyu; Young, Matthew A.; Lyandres, Olga
- Journal of the American Chemical Society, Vol. 127, Issue 12
Hot Spot-Localized Artificial Antibodies for Label-Free Plasmonic Biosensing
journal, November 2012
- Abbas, Abdennour; Tian, Limei; Morrissey, Jeremiah J.
- Advanced Functional Materials, Vol. 23, Issue 14
Surface-Enhanced Raman Scattering (SERS) and Surface-Enhanced Resonance Raman Scattering (SERRS): A Review of Applications
journal, August 2011
- McNay, Graeme; Eustace, David; Smith, W. Ewen
- Applied Spectroscopy, Vol. 65, Issue 8
Surface-Enhanced Raman Spectroscopy on Liquid Interfacial Nanoparticle Arrays for Multiplex Detecting Drugs in Urine
journal, July 2016
- Ma, Yongmei; Liu, Honglin; Mao, Mei
- Analytical Chemistry, Vol. 88, Issue 16
A reproducible gold SERS substrate assisted by silver nanoparticles without using extra aggregation agents
journal, January 2016
- Liu, Yuping; Lu, Zhiwei; Lin, Xiang
- RSC Advances, Vol. 6, Issue 63
Panchromatic plasmonic color patterns: from embedded Ag nanohole arrays to elevated Ag nanohole arrays
journal, January 2013
- Zhang, Xuemin; Ye, Shunsheng; Zhang, Xun
- J. Mater. Chem. C, Vol. 1, Issue 5
Plasmonic Nanogap-Enhanced Raman Scattering Using a Resonant Nanodome Array
journal, July 2012
- Wu, Hsin-Yu; Choi, Charles J.; Cunningham, Brian T.
- Small, Vol. 8, Issue 18
A wafer-scale backplane-assisted resonating nanoantenna array SERS device created by tunable thermal dewetting nanofabrication
journal, March 2014
- Chang, Te-Wei; Gartia, Manas Ranjan; Seo, Sujin
- Nanotechnology, Vol. 25, Issue 14
Engineered SERS Substrates with Multiscale Signal Enhancement: Nanoparticle Cluster Arrays
journal, April 2009
- Yan, Bo; Thubagere, Anupama; Premasiri, W. Ranjith
- ACS Nano, Vol. 3, Issue 5
Towards high quality triangular silver nanoprisms: improved synthesis, six-tip based hot spots and ultra-high local surface plasmon resonance sensitivity
journal, January 2015
- Xue, Bin; Wang, Dan; Zuo, Jing
- Nanoscale, Vol. 7, Issue 17
Near-field Raman imaging of organic molecules by an apertureless metallic probe scanning optical microscope
journal, July 2002
- Hayazawa, Norikiko; Inouye, Yasushi; Sekkat, Zouheir
- The Journal of Chemical Physics, Vol. 117, Issue 3
Ordered arrays of Au-nanobowls loaded with Ag-nanoparticles as effective SERS substrates for rapid detection of PCBs
journal, March 2014
- Chen, Bensong; Meng, Guowen; Zhou, Fei
- Nanotechnology, Vol. 25, Issue 14
Actively Targeted In Vivo Multiplex Detection of Intrinsic Cancer Biomarkers Using Biocompatible SERS Nanotags
journal, February 2014
- Dinish, U. S.; Balasundaram, Ghayathri; Chang, Young-Tae
- Scientific Reports, Vol. 4, Issue 1
Plasmonic Nanogap-enhanced Raman Scattering Using a Resonant Nanodome Array
conference, January 2012
- Wu, Hsin-Yu; Choi, Charles J.; Cunningham, Brian T.
- CLEO: Science and Innovations, Conference on Lasers and Electro-Optics 2012
Intracellular SERS nanoprobes for distinction of different neuronal cell types.
text, January 2013
- Huefner, Anna; Kuan, William; Barker, Roger
- Apollo - University of Cambridge Repository
Hot Spot-Localized Artificial Antibodies for Label-Free Plasmonic Biosensing
journal, November 2012
- Abbas, Abdennour; Tian, Limei; Morrissey, Jeremiah J.
- Advanced Functional Materials, Vol. 23, Issue 14
Facile Fabrication of High-Density Sub-1-nm Gaps from Au Nanoparticle Monolayers as Reproducible SERS Substrates
journal, October 2016
- Si, Shaorong; Liang, Wenkai; Sun, Yinghui
- Advanced Functional Materials, Vol. 26, Issue 44
SERS Encoded Silver Pyramids for Attomolar Detection of Multiplexed Disease Biomarkers
journal, January 2015
- Xu, Liguang; Yan, Wenjing; Ma, Wei
- Advanced Materials, Vol. 27, Issue 10
Self-Assembling Nanoparticles at Surfaces and Interfaces
journal, January 2008
- Kinge, Sachin; Crego-Calama, Mercedes; Reinhoudt, David N.
- ChemPhysChem, Vol. 9, Issue 1
‘Fairy Chimney’-Shaped Tandem Metamaterials as Double Resonance SERS Substrates
journal, October 2012
- Cinel, Neval A.; Bütün, Serkan; Ertaş, Gülay
- Small, Vol. 9, Issue 4
Sensitivity Tuning through Additive Heterogeneous Plasmon Coupling between 3D Assembled Plasmonic Nanoparticle and Nanocup Arrays
journal, May 2016
- Seo, Sujin; Zhou, Xiangfei; Liu, Gang Logan
- Small, Vol. 12, Issue 25
Time-dependent SERS of pseudoisocyanine on silver particles generated in silver bromide sol by laser illumination
journal, February 1993
- Kneipp, K.; Kneipp, H.
- Spectrochimica Acta Part A: Molecular Spectroscopy, Vol. 49, Issue 2
Surface-Enhanced Raman Spectroscopy on Liquid Interfacial Nanoparticle Arrays for Multiplex Detecting Drugs in Urine
journal, July 2016
- Ma, Yongmei; Liu, Honglin; Mao, Mei
- Analytical Chemistry, Vol. 88, Issue 16
Carbon-Dot/Silver-Nanoparticle Flexible SERS-Active Films
journal, September 2016
- Bhunia, Susanta Kumar; Zeiri, Leila; Manna, Joydeb
- ACS Applied Materials & Interfaces, Vol. 8, Issue 38
Toward a Glucose Biosensor Based on Surface-Enhanced Raman Scattering
journal, January 2003
- Shafer-Peltier, Karen E.; Haynes, Christy L.; Glucksberg, Matthew R.
- Journal of the American Chemical Society, Vol. 125, Issue 2
Rapid Detection of an Anthrax Biomarker by Surface-Enhanced Raman Spectroscopy
journal, March 2005
- Zhang, Xiaoyu; Young, Matthew A.; Lyandres, Olga
- Journal of the American Chemical Society, Vol. 127, Issue 12
Nanoimprinted SERS-Active Substrates with Tunable Surface Plasmon Resonances
journal, May 2007
- Alvarez-Puebla, Ramon; Cui, Bo; Bravo-Vasquez, Juan-Pablo
- The Journal of Physical Chemistry C, Vol. 111, Issue 18
Different Plasmon Sensing Behavior of Silver and Gold Nanorods
journal, April 2013
- Mahmoud, Mahmoud A.; El-Sayed, Mostafa A.
- The Journal of Physical Chemistry Letters, Vol. 4, Issue 9
Intracellular SERS Nanoprobes For Distinction Of Different Neuronal Cell Types
journal, May 2013
- Huefner, Anna; Kuan, Wei-Li; Barker, Roger A.
- Nano Letters, Vol. 13, Issue 6
Metallic Nanoparticle Arrays: A Common Substrate for Both Surface-Enhanced Raman Scattering and Surface-Enhanced Infrared Absorption
journal, March 2008
- Le, Fei; Brandl, Daniel W.; Urzhumov, Yaroslav A.
- ACS Nano, Vol. 2, Issue 4
Engineered SERS Substrates with Multiscale Signal Enhancement: Nanoparticle Cluster Arrays
journal, April 2009
- Yan, Bo; Thubagere, Anupama; Premasiri, W. Ranjith
- ACS Nano, Vol. 3, Issue 5
Shell-isolated nanoparticle-enhanced Raman spectroscopy
journal, March 2010
- Li, Jian Feng; Huang, Yi Fan; Ding, Yong
- Nature, Vol. 464, Issue 7287, p. 392-395
Nanogap-engineerable Raman-active nanodumbbells for single-molecule detection
journal, December 2009
- Lim, Dong-Kwon; Jeon, Ki-Seok; Kim, Hyung Min
- Nature Materials, Vol. 9, Issue 1
Actively Targeted In Vivo Multiplex Detection of Intrinsic Cancer Biomarkers Using Biocompatible SERS Nanotags
journal, February 2014
- Dinish, U. S.; Balasundaram, Ghayathri; Chang, Young-Tae
- Scientific Reports, Vol. 4, Issue 1
Near-field Raman imaging of organic molecules by an apertureless metallic probe scanning optical microscope
journal, July 2002
- Hayazawa, Norikiko; Inouye, Yasushi; Sekkat, Zouheir
- The Journal of Chemical Physics, Vol. 117, Issue 3
A wafer-scale backplane-assisted resonating nanoantenna array SERS device created by tunable thermal dewetting nanofabrication
journal, March 2014
- Chang, Te-Wei; Gartia, Manas Ranjan; Seo, Sujin
- Nanotechnology, Vol. 25, Issue 14
Ordered arrays of Au-nanobowls loaded with Ag-nanoparticles as effective SERS substrates for rapid detection of PCBs
journal, March 2014
- Chen, Bensong; Meng, Guowen; Zhou, Fei
- Nanotechnology, Vol. 25, Issue 14
Large-area, lithography-free, low-cost SERS sensor with good flexibility and high performance
journal, August 2016
- Jiang, Jing; Xu, Zhida; Ameen, Abid
- Nanotechnology, Vol. 27, Issue 38
Effect of Moisture on the Aggregation of Methylene Blue and Rhodamine 6G in Poly(N-vinylpyrrolidone) Film
journal, June 1995
- Otsuki, Soichi; Adachi, Kimihiro
- Polymer Journal, Vol. 27, Issue 6
Plasmonic Nanogap-enhanced Raman Scattering Using a Resonant Nanodome Array
conference, January 2012
- Wu, Hsin-Yu; Choi, Charles J.; Cunningham, Brian T.
- CLEO: Science and Innovations, Conference on Lasers and Electro-Optics 2012
Surface-Enhanced Raman Scattering (SERS) and Surface-Enhanced Resonance Raman Scattering (SERRS): A Review of Applications
journal, August 2011
- McNay, Graeme; Eustace, David; Smith, W. Ewen
- Applied Spectroscopy, Vol. 65, Issue 8
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