Epoxy resin reinforced with nanothin polydopamine-coated carbon nanotubes: a study of the interfacial polymer layer thickness
Abstract
Carbon nanotubes (CNTs) functionalized by a nanothin poly(dopamine) (PDA) layer were produced by a one-pot, nondestructive approach, with direct polymerization of dopamine on the CNT surface. The thickness of the PDA layer can be well-controlled by the reaction time and the proportion of dopamine, and this thickness is found to be the key factor in controlling the dispersion of CNTs and the extent of the interfacial interactions between the CNT@PDA and epoxy resin. SEM results indicated that the dispersion of CNTs in epoxy was improved significantly by coating a nanothin PDA layer onto the CNT surface. In agreeme nt with this finding, the CNTs functionalized with the thinnest PDA layer provided the best mechanical and thermal properties. This result confirmed that a thinner PDA layer could provide optimized interfacial interactions between the CNT@PDA and epoxy matrix and weaken the self-agglomeration of CNTs, which led to an improved effective stress and heat transfer between the CNTs and the polymer matrix.
- Authors:
-
- Shanghai Univ. of Engineering Science, Shanghai (China)
- Shanghai Univ. of Engineering Science, Shanghai (China); Fudan Univ., Shanghai (China)
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
- Publication Date:
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1378768
- Grant/Contract Number:
- AC02-05CH11231
- Resource Type:
- Accepted Manuscript
- Journal Name:
- RSC Advances
- Additional Journal Information:
- Journal Volume: 6; Journal Issue: 37; Journal ID: ISSN 2046-2069
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; epoxy resin; polydopamine; carbon nanotubes; core-shell structure; surface functionalization
Citation Formats
Ling, Yang, Li, Weizhen, Wang, Baoyu, Gan, Wenjun, Zhu, Chenhui, Brady, Michael A., and Wang, Cheng. Epoxy resin reinforced with nanothin polydopamine-coated carbon nanotubes: a study of the interfacial polymer layer thickness. United States: N. p., 2016.
Web. doi:10.1039/c5ra26539h.
Ling, Yang, Li, Weizhen, Wang, Baoyu, Gan, Wenjun, Zhu, Chenhui, Brady, Michael A., & Wang, Cheng. Epoxy resin reinforced with nanothin polydopamine-coated carbon nanotubes: a study of the interfacial polymer layer thickness. United States. https://doi.org/10.1039/c5ra26539h
Ling, Yang, Li, Weizhen, Wang, Baoyu, Gan, Wenjun, Zhu, Chenhui, Brady, Michael A., and Wang, Cheng. Tue .
"Epoxy resin reinforced with nanothin polydopamine-coated carbon nanotubes: a study of the interfacial polymer layer thickness". United States. https://doi.org/10.1039/c5ra26539h. https://www.osti.gov/servlets/purl/1378768.
@article{osti_1378768,
title = {Epoxy resin reinforced with nanothin polydopamine-coated carbon nanotubes: a study of the interfacial polymer layer thickness},
author = {Ling, Yang and Li, Weizhen and Wang, Baoyu and Gan, Wenjun and Zhu, Chenhui and Brady, Michael A. and Wang, Cheng},
abstractNote = {Carbon nanotubes (CNTs) functionalized by a nanothin poly(dopamine) (PDA) layer were produced by a one-pot, nondestructive approach, with direct polymerization of dopamine on the CNT surface. The thickness of the PDA layer can be well-controlled by the reaction time and the proportion of dopamine, and this thickness is found to be the key factor in controlling the dispersion of CNTs and the extent of the interfacial interactions between the CNT@PDA and epoxy resin. SEM results indicated that the dispersion of CNTs in epoxy was improved significantly by coating a nanothin PDA layer onto the CNT surface. In agreeme nt with this finding, the CNTs functionalized with the thinnest PDA layer provided the best mechanical and thermal properties. This result confirmed that a thinner PDA layer could provide optimized interfacial interactions between the CNT@PDA and epoxy matrix and weaken the self-agglomeration of CNTs, which led to an improved effective stress and heat transfer between the CNTs and the polymer matrix.},
doi = {10.1039/c5ra26539h},
journal = {RSC Advances},
number = 37,
volume = 6,
place = {United States},
year = {Tue Mar 29 00:00:00 EDT 2016},
month = {Tue Mar 29 00:00:00 EDT 2016}
}
Web of Science
Works referenced in this record:
Reinforcement of Polymers with Carbon Nanotubes: The Role of Nanotube Surface Area
journal, February 2004
- Cadek, M.; Coleman, J. N.; Ryan, K. P.
- Nano Letters, Vol. 4, Issue 2
Effect of Carbon Nanotube Functionalization on Mechanical and Thermal Properties of Cross-Linked Epoxy–Carbon Nanotube Nanocomposites: Role of Strengthening the Interfacial Interactions
journal, March 2014
- Khare, Ketan S.; Khabaz, Fardin; Khare, Rajesh
- ACS Applied Materials & Interfaces, Vol. 6, Issue 9
Human endothelial cell growth on mussel-inspired nanofiber scaffold for vascular tissue engineering
journal, December 2010
- Ku, Sook Hee; Park, Chan Beum
- Biomaterials, Vol. 31, Issue 36, p. 9431-9437
Oxidant-induced dopamine polymerization for multifunctional coatings
journal, January 2010
- Wei, Qiang; Zhang, Fulong; Li, Jie
- Polymer Chemistry, Vol. 1, Issue 9
Elastomers with chain-end mussel-mimetic modification for nanocomposites: Strong modifications to reinforcement and viscoelastic properties
journal, July 2010
- Pan, Xiao-Dong; Qin, Zengquan; Yan, Yuan-Yong
- Polymer, Vol. 51, Issue 15
Chemical Engineering of the Single-Walled Carbon Nanotube−Nylon 6 Interface
journal, June 2006
- Gao, Junbo; Zhao, Bin; Itkis, Mikhail E.
- Journal of the American Chemical Society, Vol. 128, Issue 23
Position-selective growth of vertically aligned carbon nanotubes for application of electronic-measuring nanoprobes
journal, March 2007
- Okuyama, Hiroki; Iwata, Nobuyuki; Yamamoto, Hiroshi
- Physica E: Low-dimensional Systems and Nanostructures, Vol. 37, Issue 1-2
The interface effect of carbon nanotube suspension on the thermal performance of a two-phase closed thermosyphon
journal, November 2006
- Xue, H. S.; Fan, J. R.; Hu, Y. C.
- Journal of Applied Physics, Vol. 100, Issue 10
Reduction and Functionalization of Graphene Oxide Sheets Using Biomimetic Dopamine Derivatives in One Step
journal, February 2012
- Kaminska, Izabela; Das, Manash R.; Coffinier, Yannick
- ACS Applied Materials & Interfaces, Vol. 4, Issue 2
Noncovalent Functionalization as an Alternative to Oxidative Acid Treatment of Single Wall Carbon Nanotubes with Applications for Polymer Composites
journal, March 2009
- Simmons, Trevor J.; Bult, Justin; Hashim, Daniel P.
- ACS Nano, Vol. 3, Issue 4
Reinforcement of Polyether Polyurethane with Dopamine-Modified Clay: The Role of Interfacial Hydrogen Bonding
journal, August 2012
- Phua, Si Lei; Yang, Liping; Toh, Cher Ling
- ACS Applied Materials & Interfaces, Vol. 4, Issue 9
Effect of functionalized carbon nanotubes on the thermal conductivity of epoxy composites
journal, March 2010
- Yang, Shin-Yi; Ma, Chen-Chi M.; Teng, Chih-Chun
- Carbon, Vol. 48, Issue 3
Are cured epoxy resins inhomogeneous?
journal, April 1978
- Dušek, K.; Pleštil, J.; Lednický, F.
- Polymer, Vol. 19, Issue 4
Simultaneous Enhancements of UV Resistance and Mechanical Properties of Polypropylene by Incorporation of Dopamine-Modified Clay
journal, February 2013
- Phua, Si Lei; Yang, Liping; Toh, Cher Ling
- ACS Applied Materials & Interfaces, Vol. 5, Issue 4
Chemical treatment of carbon nanotubes
journal, January 1996
- Esumi, K.; Ishigami, M.; Nakajima, A.
- Carbon, Vol. 34, Issue 2
Nanotubes as nanoprobes in scanning probe microscopy
journal, November 1996
- Dai, Hongjie; Hafner, Jason H.; Rinzler, Andrew G.
- Nature, Vol. 384, Issue 6605
Mussel-inspired surface modification of poly(l-lactide) electrospun fibers for modulation of osteogenic differentiation of human mesenchymal stem cells
journal, March 2012
- Rim, Nae Gyune; Kim, Seok Joo; Shin, Young Min
- Colloids and Surfaces B: Biointerfaces, Vol. 91
Effect of Nanoconfinement on Kinetics of Cross-Linking Reactions: A Molecular Simulation Study
journal, November 2011
- Lin, Po-Han; Kohale, Swapnil C.; Khare, Rajesh
- The Journal of Physical Chemistry B, Vol. 115, Issue 43
Dopamine-Induced Reduction and Functionalization of Graphene Oxide Nanosheets
journal, October 2010
- Xu, Li Qun; Yang, Wen Jing; Neoh, Koon-Gee
- Macromolecules, Vol. 43, Issue 20
Bioinspired Templating Synthesis of Metal–Polymer Hybrid Nanostructures within 3D Electrospun Nanofibers
journal, June 2013
- Son, Ho Yeon; Ryu, Ji Hyun; Lee, Haeshin
- ACS Applied Materials & Interfaces, Vol. 5, Issue 13
Realizing Ultrahigh Modulus and High Strength of Macroscopic Graphene Oxide Papers Through Crosslinking of Mussel-Inspired Polymers
journal, May 2013
- Tian, Ye; Cao, Yewen; Wang, Yu
- Advanced Materials, Vol. 25, Issue 21
Surface Modification of Aramid Fibers by Bio-Inspired Poly(dopamine) and Epoxy Functionalized Silane Grafting
journal, November 2014
- Sa, Rina; Yan, Yan; Wei, Zhenhai
- ACS Applied Materials & Interfaces, Vol. 6, Issue 23
Antibacterial and biocompatible surfaces based on dopamine autooxidized silver nanoparticles
journal, November 2012
- Sureshkumar, Manthiriyappan; Siswanto, Dessy Yovita; Chen, Yong-Cin
- Journal of Polymer Science Part B: Polymer Physics, Vol. 51, Issue 4
A Biomimetic Approach to Enhancing Interfacial Interactions: Polydopamine-Coated Clay as Reinforcement for Epoxy Resin
journal, June 2011
- Yang, Liping; Phua, Si Lei; Teo, Jun Kai Herman
- ACS Applied Materials & Interfaces, Vol. 3, Issue 8
Resonance Raman and infrared spectroscopy of carbon nanotubes
journal, April 1994
- Kastner, J.; Pichler, T.; Kuzmany, H.
- Chemical Physics Letters, Vol. 221, Issue 1-2
Polydopamine As an Efficient and Robust Platform to Functionalize Carbon Fiber for High-Performance Polymer Composites
journal, November 2013
- Chen, Shusheng; Cao, Yewen; Feng, Jiachun
- ACS Applied Materials & Interfaces, Vol. 6, Issue 1
Characterization methods of carbon nanotubes: a review
journal, May 2005
- Belin, T.; Epron, F.
- Materials Science and Engineering: B, Vol. 119, Issue 2
Silver-Polydopamine Hybrid Coatings of Electrospun Poly(vinyl alcohol) Nanofibers
journal, January 2013
- Son, Ho Yeon; Ryu, Ji Hyun; Lee, Haeshin
- Macromolecular Materials and Engineering, Vol. 298, Issue 5
Coating carbon nanotubes by spontaneous oxidative polymerization of dopamine
journal, November 2008
- Fei, Bin; Qian, Baitai; Yang, Zongyue
- Carbon, Vol. 46, Issue 13
Nanofibrous scaffold-mediated REST knockdown to enhance neuronal differentiation of stem cells
journal, May 2013
- Low, Wei Ching; Rujitanaroj, Pim-On; Lee, Dong-Keun
- Biomaterials, Vol. 34, Issue 14
Fluorination of single-wall carbon nanotubes
journal, October 1998
- Mickelson, E. T.; Huffman, C. B.; Rinzler, A. G.
- Chemical Physics Letters, Vol. 296, Issue 1-2
Polymer-Grafted Multiwalled Carbon Nanotubes through Surface-Initiated Polymerization
journal, April 2004
- Baskaran, D.; Mays, Jimmy W.; Bratcher, Matthew S.
- Angewandte Chemie International Edition, Vol. 43, Issue 16
Reinforcing Epoxy Polymer Composites Through Covalent Integration of Functionalized Nanotubes
journal, July 2004
- Zhu, J.; Peng, H.; Rodriguez-Macias, F.
- Advanced Functional Materials, Vol. 14, Issue 7
Improving the mechanical properties of single-walled carbon nanotube sheets by intercalation of polymeric adhesives
journal, March 2003
- Coleman, Jonathan N.; Blau, Werner J.; Dalton, Alan B.
- Applied Physics Letters, Vol. 82, Issue 11
Mussel-Inspired Surface Chemistry for Multifunctional Coatings
journal, October 2007
- Lee, H.; Dellatore, S. M.; Miller, W. M.
- Science, Vol. 318, Issue 5849
Mussel-Inspired Synthesis of Polydopamine-Functionalized Graphene Hydrogel as Reusable Adsorbents for Water Purification
journal, December 2012
- Gao, Hongcai; Sun, Yimin; Zhou, Jiajing
- ACS Applied Materials & Interfaces, Vol. 5, Issue 2
Elastic and mechanical properties of carbon nanotubes
journal, June 1999
- Goze, C.; Vaccarini, L.; Henrard, L.
- Synthetic Metals, Vol. 103, Issue 1-3
Intercalation and exfoliation of clay nanoplatelets in epoxy-based nanocomposites: TEM and XRD observations
journal, January 2006
- Miyagawa, Hiroaki; Drzal, Lawrence T.; Carsello, Jerrold A.
- Polymer Engineering & Science, Vol. 46, Issue 4
Carbon nanotube networks on different platforms
journal, November 2014
- Saha, Avishek; Jiang, Chengmin; Martí, Angel A.
- Carbon, Vol. 79
Carbon nanotubides: an alternative for dispersion, functionalization and composites fabrication
journal, January 2015
- Jiang, C.; Saha, A.; Martí, A. A.
- Nanoscale, Vol. 7, Issue 37
Surface-initiated polymerization from carbon nanotubes: strategies and perspectives
journal, January 2013
- Sakellariou, Georgios; Priftis, Dimitrios; Baskaran, Durairaj
- Chem. Soc. Rev., Vol. 42, Issue 2
Influence of carbon nanotube suspension on the thermal performance of a miniature thermosyphon
journal, April 2010
- Liu, Zhen-hua; Yang, Xue-fei; Wang, Guo-san
- International Journal of Heat and Mass Transfer, Vol. 53, Issue 9-10
Bioinspired fabrication of high performance composite membranes with ultrathin defect-free skin layer
journal, September 2009
- Pan, Fusheng; Jia, Huiping; Qiao, Shizhang
- Journal of Membrane Science, Vol. 341, Issue 1-2, p. 279-285
Functionalization of Multiwalled Carbon Nanotubes with Poly(styrene- b -(ethylene- co -butylene)- b -styrene) by Click Coupling
journal, June 2010
- Yadav, Santosh Kumar; Mahapatra, Sibdas Singha; Cho, Jae Whan
- The Journal of Physical Chemistry C, Vol. 114, Issue 26
Multi-walled carbon nanotubes coated by multi-layer silica for improving thermal conductivity of polymer composites
journal, January 2013
- Guo, Jiaxi; Saha, Purnatosh; Liang, Junfeng
- Journal of Thermal Analysis and Calorimetry, Vol. 113, Issue 2
Enabling Graphene Oxide Nanosheets as Water Separation Membranes
journal, April 2013
- Hu, Meng; Mi, Baoxia
- Environmental Science & Technology, Vol. 47, Issue 8
Mechanical properties of carbon nanotubes: theoretical predictions and experimental measurements
journal, November 2003
- Ruoff, Rodney S.; Qian, Dong; Liu, Wing Kam
- Comptes Rendus Physique, Vol. 4, Issue 9
Polymer-Grafted Multiwalled Carbon Nanotubes through Surface-Initiated Polymerization
journal, April 2004
- Baskaran, D.; Mays, Jimmy W.; Bratcher, Matthew S.
- Angewandte Chemie, Vol. 116, Issue 16
Works referencing / citing this record:
Versatile Surface Modification Using Polydopamine and Related Polycatecholamines: Chemistry, Structure, and Applications
journal, September 2017
- Barclay, Thomas G.; Hegab, Hanaa M.; Clarke, Stephen R.
- Advanced Materials Interfaces, Vol. 4, Issue 19
Application of polydopamine in biomedical microfluidic devices
journal, February 2018
- Kanitthamniyom, Pojchanun; Zhang, Yi
- Microfluidics and Nanofluidics, Vol. 22, Issue 3
Low effective content of reduced graphene oxide/silver nanowire hybrids in epoxy composites with enhanced conductive properties
journal, March 2019
- Zhang, Zhao; Li, Weizhen; Wang, Xue
- Journal of Materials Science: Materials in Electronics, Vol. 30, Issue 8