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Title: Engineering Tunneling Selector to Achieve High Non-linearity for 1S1R Integration

Abstract

Memristor devices have been extensively studied as one of the most promising technologies for next-generation non-volatile memory. However, for the memristor devices to have a real technological impact, they must be densely packed in a large crossbar array (CBA) exceeding Gigabytes in size. Devising a selector device that is CMOS compatible, 3D stackable, and has a high non-linearity (NL) and great endurance is a crucial enabling ingredient to reach this goal. Tunneling based selectors are very promising in these aspects, but the mediocre NL value limits their applications in large passive crossbar arrays. In this work, we demonstrated a trilayer tunneling selector based on the Ge/Pt/TaN1+x/Ta2O5/TaN1+x/Pd layers that could achieve a NL of 3 × 105, which is the highest NL achieved using a tunnel selector so far. The record-high tunneling NL is partially attributed to the bottom electrode's ultra-smoothness (BE) induced by a Ge/Pt layer. We further demonstrated the feasibility of 1S1R (1-selector 1-resistor) integration by vertically integrating a Pd/Ta2O5/Ru based memristor on top of the proposed selector.

Authors:
 [1];  [2]; ORCiD logo [2]; ORCiD logo [2];  [3];  [3]; ORCiD logo [2]; ORCiD logo [2];  [4];  [5]
  1. Univ. of Massachusetts, Amherst, MA (United States); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
  2. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
  3. Western Digital, San Jose, CA (United States)
  4. Univ. of Massachusetts, Amherst, MA (United States)
  5. Univ. of Massachusetts, Amherst, MA (United States); Univ. of Southern California, Los Angeles, CA (United States)
Publication Date:
Research Org.:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1817406
Grant/Contract Number:  
AC05-00OR22725
Resource Type:
Accepted Manuscript
Journal Name:
Frontiers in Nanotechnology
Additional Journal Information:
Journal Volume: 3; Journal Issue: 656026; Journal ID: ISSN 2673-3013
Publisher:
Frontiers Media S.A.
Country of Publication:
United States
Language:
English
Subject:
77 NANOSCIENCE AND NANOTECHNOLOGY; selectors; high non-linearity; vertically integrated 1S1R; crossbar arrays; memristor

Citation Formats

Upadhyay, Navnidhi K., Blum, Thomas, Maksymovych, Petro, Lavrik, Nickolay V., Davila, Noraica, Katine, Jordan A., Ievlev, A. V., Chi, Miaofang, Xia, Qiangfei, and Yang, J. Joshua. Engineering Tunneling Selector to Achieve High Non-linearity for 1S1R Integration. United States: N. p., 2021. Web. doi:10.3389/fnano.2021.656026.
Upadhyay, Navnidhi K., Blum, Thomas, Maksymovych, Petro, Lavrik, Nickolay V., Davila, Noraica, Katine, Jordan A., Ievlev, A. V., Chi, Miaofang, Xia, Qiangfei, & Yang, J. Joshua. Engineering Tunneling Selector to Achieve High Non-linearity for 1S1R Integration. United States. https://doi.org/10.3389/fnano.2021.656026
Upadhyay, Navnidhi K., Blum, Thomas, Maksymovych, Petro, Lavrik, Nickolay V., Davila, Noraica, Katine, Jordan A., Ievlev, A. V., Chi, Miaofang, Xia, Qiangfei, and Yang, J. Joshua. Thu . "Engineering Tunneling Selector to Achieve High Non-linearity for 1S1R Integration". United States. https://doi.org/10.3389/fnano.2021.656026. https://www.osti.gov/servlets/purl/1817406.
@article{osti_1817406,
title = {Engineering Tunneling Selector to Achieve High Non-linearity for 1S1R Integration},
author = {Upadhyay, Navnidhi K. and Blum, Thomas and Maksymovych, Petro and Lavrik, Nickolay V. and Davila, Noraica and Katine, Jordan A. and Ievlev, A. V. and Chi, Miaofang and Xia, Qiangfei and Yang, J. Joshua},
abstractNote = {Memristor devices have been extensively studied as one of the most promising technologies for next-generation non-volatile memory. However, for the memristor devices to have a real technological impact, they must be densely packed in a large crossbar array (CBA) exceeding Gigabytes in size. Devising a selector device that is CMOS compatible, 3D stackable, and has a high non-linearity (NL) and great endurance is a crucial enabling ingredient to reach this goal. Tunneling based selectors are very promising in these aspects, but the mediocre NL value limits their applications in large passive crossbar arrays. In this work, we demonstrated a trilayer tunneling selector based on the Ge/Pt/TaN1+x/Ta2O5/TaN1+x/Pd layers that could achieve a NL of 3 × 105, which is the highest NL achieved using a tunnel selector so far. The record-high tunneling NL is partially attributed to the bottom electrode's ultra-smoothness (BE) induced by a Ge/Pt layer. We further demonstrated the feasibility of 1S1R (1-selector 1-resistor) integration by vertically integrating a Pd/Ta2O5/Ru based memristor on top of the proposed selector.},
doi = {10.3389/fnano.2021.656026},
journal = {Frontiers in Nanotechnology},
number = 656026,
volume = 3,
place = {United States},
year = {Thu Apr 15 00:00:00 EDT 2021},
month = {Thu Apr 15 00:00:00 EDT 2021}
}

Works referenced in this record:

Low-power, low-pressure reactive-ion etching process for silicon etching with vertical and smooth walls for mechanobiology application
journal, July 2017

  • Ashraf, Mohammed; Sundararajan, Sree V.; Grenci, Gianluca
  • Journal of Micro/Nanolithography, MEMS, and MOEMS, Vol. 16, Issue 3
  • DOI: 10.1117/1.jmm.16.3.034501

Three-dimensional memristor circuits as complex neural networks
journal, April 2020


Tunnel Barrier Engineering for Non-Volatile Memory
journal, March 2008

  • Jung, Jong-Wan; Cho, Won-Ju
  • JSTS:Journal of Semiconductor Technology and Science, Vol. 8, Issue 1
  • DOI: 10.5573/jsts.2008.8.1.032

A Memristor with Low Switching Current and Voltage for 1S1R Integration and Array Operation
journal, March 2020

  • Upadhyay, Navnidhi K.; Sun, Wen; Lin, Peng
  • Advanced Electronic Materials, Vol. 6, Issue 5
  • DOI: 10.1002/aelm.201901411

3D resistive RAM cell design for high-density storage class memory—a review
journal, March 2016

  • Hudec, Boris; Hsu, Chung-Wei; Wang, I-Ting
  • Science China Information Sciences, Vol. 59, Issue 6
  • DOI: 10.1007/s11432-016-5566-0

Synaptic electronics and neuromorphic computing
journal, May 2016

  • Upadhyay, Navnidhi K.; Joshi, Saumil; Yang, J. Joshua
  • Science China Information Sciences, Vol. 59, Issue 6
  • DOI: 10.1007/s11432-016-5565-1

Memristive crossbar arrays for brain-inspired computing
journal, March 2019


A 130.7-$\hbox{mm}^{2}$ 2-Layer 32-Gb ReRAM Memory Device in 24-nm Technology
journal, January 2014

  • Liu, Tz-yi; Yan, Tian Hong; Scheuerlein, Roy
  • IEEE Journal of Solid-State Circuits, Vol. 49, Issue 1
  • DOI: 10.1109/JSSC.2013.2280296

A Low‐Current and Analog Memristor with Ru as Mobile Species
journal, January 2020


Emerging Memory Devices for Neuromorphic Computing
journal, January 2019

  • Upadhyay, Navnidhi K.; Jiang, Hao; Wang, Zhongrui
  • Advanced Materials Technologies, Vol. 4, Issue 4
  • DOI: 10.1002/admt.201800589

One-step regression and classification with cross-point resistive memory arrays
journal, January 2020

  • Sun, Zhong; Pedretti, Giacomo; Bricalli, Alessandro
  • Science Advances, Vol. 6, Issue 5
  • DOI: 10.1126/sciadv.aay2378

Solving matrix equations in one step with cross-point resistive arrays
journal, February 2019

  • Sun, Zhong; Pedretti, Giacomo; Ambrosi, Elia
  • Proceedings of the National Academy of Sciences, Vol. 116, Issue 10
  • DOI: 10.1073/pnas.1815682116

Layered tunnel barriers for nonvolatile memory devices
journal, October 1998

  • Likharev, Konstantin K.
  • Applied Physics Letters, Vol. 73, Issue 15
  • DOI: 10.1063/1.122402

A copper ReRAM cell for Storage Class Memory applications
conference, June 2014

  • Sills, Scott; Yasuda, Shuichiro; Strand, Jonathan
  • 2014 IEEE Symposium on VLSI Technology, 2014 Symposium on VLSI Technology (VLSI-Technology): Digest of Technical Papers
  • DOI: 10.1109/VLSIT.2014.6894368

An 8 Mb Multi-Layered Cross-Point ReRAM Macro With 443 MB/s Write Throughput
journal, January 2013

  • Kawahara, Akifumi; Azuma, Ryotaro; Ikeda, Yuuichirou
  • IEEE Journal of Solid-State Circuits, Vol. 48, Issue 1
  • DOI: 10.1109/JSSC.2012.2215121

Multi-layer cross-point binary oxide resistive memory (OxRRAM) for post-NAND storage application
conference, January 2005

  • Baek, I. G.; Kim, D. C.; Lee, M. J.
  • IEEE InternationalElectron Devices Meeting, 2005. IEDM Technical Digest.
  • DOI: 10.1109/IEDM.2005.1609462

Reversible electroresistance at the Ag∕La0.67Sr0.33MnO3 interface
journal, August 2006

  • Xie, Y. W.; Sun, J. R.; Wang, D. J.
  • Journal of Applied Physics, Vol. 100, Issue 3
  • DOI: 10.1063/1.2222069

Crossbar Dial Telephone Switching System*
journal, January 1939


Trilayer Tunnel Selectors for Memristor Memory Cells
journal, November 2015

  • Choi, Byung Joon; Zhang, Jiaming; Norris, Kate
  • Advanced Materials, Vol. 28, Issue 2
  • DOI: 10.1002/adma.201503604

Ionic conductivity of tantalum oxide by rf sputtering
journal, July 1993


Dependence of Read Margin on Pull-Up Schemes in High-Density One Selector–One Resistor Crossbar Array
journal, January 2013

  • Lo, Chun-Li; Hou, Tuo-Hung; Chen, Mei-Chin
  • IEEE Transactions on Electron Devices, Vol. 60, Issue 1
  • DOI: 10.1109/TED.2012.2225147

Nanoscale molecular-switch crossbar circuits
journal, March 2003


Ultrasmooth Silver Thin Films Deposited with a Germanium Nucleation Layer
journal, January 2009

  • Logeeswaran VJ, ; Kobayashi, Nobuhiko P.; Islam, M. Saif
  • Nano Letters, Vol. 9, Issue 1
  • DOI: 10.1021/nl8027476

Mechanism and control of the metal-to-insulator transition in rocksalt tantalum nitride
journal, June 2002


Memristive devices for computing
journal, January 2013

  • Yang, J. Joshua; Strukov, Dmitri B.; Stewart, Duncan R.
  • Nature Nanotechnology, Vol. 8, Issue 1, p. 13-24
  • DOI: 10.1038/nnano.2012.240

Low-Temperature-Grown Transition Metal Oxide Based Storage Materials and Oxide Transistors for High-Density Non-volatile Memory
journal, May 2009

  • Lee, Myoung-Jae; Kim, Sun I.; Lee, Chang B.
  • Advanced Functional Materials, Vol. 19, Issue 10
  • DOI: 10.1002/adfm.200801032

Resistive switching materials for information processing
journal, January 2020


Engineering nonlinearity into memristors for passive crossbar applications
journal, March 2012

  • Joshua Yang, J.; Zhang, M.-X.; Pickett, Matthew D.
  • Applied Physics Letters, Vol. 100, Issue 11, Article No. 113501
  • DOI: 10.1063/1.3693392