Effect of overcharge on Li(Ni0.5Mn0.3Co0.2)O2/Graphite lithium ion cells with poly(vinylidene fluoride) binder. I - Microstructural changes in the anode
Abstract
Cells based on NMC/graphite, containing poly(vinylidene difluoride) (PVDF) binders in the positive and negative electrodes, were systematically overcharged to 100, 120, 140, 160, 180, and 250% state-of-charge (SOC). At 250% SOC the cell vented. Scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS) of the anodes showed several state-of-overcharge-dependent trends. Starting at 120% SOC, dendrites appeared and increased in concentration as the SOC increased. Dendrite morphology appeared to be dependent on whether the active material was on the "dull" or "shiny" side of the copper collector. Significantly more delamination of the active material from the collector was seen on the "shiny" side of the collector particularly at 180 and 250% SOC. Transition metals were detected at 120% SOC and increased in concentration as the SOC increased. There was considerable spatial heterogeneity in the microstructures across each laminate with several regions displaying complex layered structures.
- Authors:
-
- Argonne National Lab. (ANL), Argonne, IL (United States). Chemical Sciences and Engineering Division
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Energy and Transportation Science Division
- Sandia National Lab. (SNL-NM), Albuquerque, NM (United States). Power Sources Technology Group
- Publication Date:
- Research Org.:
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Argonne National Lab. (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V); USDOE National Nuclear Security Administration (NNSA); USDOE Office of Energy Efficiency and Renewable Energy (EERE)
- OSTI Identifier:
- 1439931
- Alternate Identifier(s):
- OSTI ID: 1460965; OSTI ID: 1548542
- Grant/Contract Number:
- AC05-00OR22725; AC02-06CH11357; NA0003525
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of Power Sources
- Additional Journal Information:
- Journal Volume: 385; Journal Issue: C; Journal ID: ISSN 0378-7753
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; Lithium-ion battery; Overcharge; Scanning electron microscopy; Microstructure; SEI; Anode; scanning electron microscopy; anode; microstructure; overcharge
Citation Formats
Dietz Rago, Nancy, Bareno, Javier, Li, Jianlin, Du, Zhijia, Wood, David L., Steele, Leigh Anna, Lamb, Joshua, Spangler, Scott, Grosso, Christopher, Fenton, Kyle, and Bloom, Ira. Effect of overcharge on Li(Ni0.5Mn0.3Co0.2)O2/Graphite lithium ion cells with poly(vinylidene fluoride) binder. I - Microstructural changes in the anode. United States: N. p., 2018.
Web. doi:10.1016/j.jpowsour.2018.01.009.
Dietz Rago, Nancy, Bareno, Javier, Li, Jianlin, Du, Zhijia, Wood, David L., Steele, Leigh Anna, Lamb, Joshua, Spangler, Scott, Grosso, Christopher, Fenton, Kyle, & Bloom, Ira. Effect of overcharge on Li(Ni0.5Mn0.3Co0.2)O2/Graphite lithium ion cells with poly(vinylidene fluoride) binder. I - Microstructural changes in the anode. United States. https://doi.org/10.1016/j.jpowsour.2018.01.009
Dietz Rago, Nancy, Bareno, Javier, Li, Jianlin, Du, Zhijia, Wood, David L., Steele, Leigh Anna, Lamb, Joshua, Spangler, Scott, Grosso, Christopher, Fenton, Kyle, and Bloom, Ira. Sat .
"Effect of overcharge on Li(Ni0.5Mn0.3Co0.2)O2/Graphite lithium ion cells with poly(vinylidene fluoride) binder. I - Microstructural changes in the anode". United States. https://doi.org/10.1016/j.jpowsour.2018.01.009. https://www.osti.gov/servlets/purl/1439931.
@article{osti_1439931,
title = {Effect of overcharge on Li(Ni0.5Mn0.3Co0.2)O2/Graphite lithium ion cells with poly(vinylidene fluoride) binder. I - Microstructural changes in the anode},
author = {Dietz Rago, Nancy and Bareno, Javier and Li, Jianlin and Du, Zhijia and Wood, David L. and Steele, Leigh Anna and Lamb, Joshua and Spangler, Scott and Grosso, Christopher and Fenton, Kyle and Bloom, Ira},
abstractNote = {Cells based on NMC/graphite, containing poly(vinylidene difluoride) (PVDF) binders in the positive and negative electrodes, were systematically overcharged to 100, 120, 140, 160, 180, and 250% state-of-charge (SOC). At 250% SOC the cell vented. Scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS) of the anodes showed several state-of-overcharge-dependent trends. Starting at 120% SOC, dendrites appeared and increased in concentration as the SOC increased. Dendrite morphology appeared to be dependent on whether the active material was on the "dull" or "shiny" side of the copper collector. Significantly more delamination of the active material from the collector was seen on the "shiny" side of the collector particularly at 180 and 250% SOC. Transition metals were detected at 120% SOC and increased in concentration as the SOC increased. There was considerable spatial heterogeneity in the microstructures across each laminate with several regions displaying complex layered structures.},
doi = {10.1016/j.jpowsour.2018.01.009},
journal = {Journal of Power Sources},
number = C,
volume = 385,
place = {United States},
year = {Sat Mar 17 00:00:00 EDT 2018},
month = {Sat Mar 17 00:00:00 EDT 2018}
}
Web of Science
Figures / Tables:
Works referenced in this record:
Comparison of the structural and electrochemical properties of layered Li[NixCoyMnz]O2 (x = 1/3, 0.5, 0.6, 0.7, 0.8 and 0.85) cathode material for lithium-ion batteries
journal, July 2013
- Noh, Hyung-Joo; Youn, Sungjune; Yoon, Chong Seung
- Journal of Power Sources, Vol. 233
Overcharge-induced capacity fading analysis for large format lithium-ion batteries with Li Ni1/3Co1/3Mn1/3O2+ Li Mn2O4 composite cathode
journal, April 2015
- Ouyang, Minggao; Ren, Dongsheng; Lu, Languang
- Journal of Power Sources, Vol. 279
A Review on Lithium-Ion Batteries Safety Issues: Existing Problems and Possible Solutions
journal, September 2012
- Wen, Jianwu; Yu, Yan; Chen, Chunhua
- Materials Express, Vol. 2, Issue 3
Cathodes with intrinsic redox overcharge protection: A new strategy towards safer Li-ion batteries
journal, October 2014
- Wen, Jian-Wu; Zhang, Da-Wei; Chen, Chun-Hua
- Journal of Power Sources, Vol. 264
Thermal and overcharge abuse analysis of a redox shuttle for overcharge protection of LiFePO 4
journal, February 2014
- Lamb, Joshua; Orendorff, Christopher J.; Amine, Khalil
- Journal of Power Sources, Vol. 247
N -Substituted Phenothiazine Derivatives: How the Stability of the Neutral and Radical Cation Forms Affects Overcharge Performance in Lithium-Ion Batteries
journal, December 2014
- Narayana, Kishore Anand; Casselman, Matthew D.; Elliott, Corrine F.
- ChemPhysChem, Vol. 16, Issue 6
Overcharge failure investigation of lithium-ion batteries
journal, October 2015
- Yuan, QingFeng; Zhao, Fenggang; Wang, Weidong
- Electrochimica Acta, Vol. 178
Studying the Charging Process of a Lithium-Ion Battery toward 10 V by In Situ X-ray Absorption and Diffraction: Lithium Insertion/Extraction with Side Reactions at Positive and Negative Electrodes
journal, January 2016
- Makimura, Yoshinari; Sasaki, Tsuyoshi; Oka, Hideaki
- Journal of The Electrochemical Society, Vol. 163, Issue 7
Improvement of overcharge performance using Li4Ti5O12 as negative electrode for LiFePO4 power battery
journal, February 2011
- Cui, Wei; He, Yan-Bing; Tang, Zhi-Yuan
- Journal of Solid State Electrochemistry, Vol. 16, Issue 1
Thermal runaway of commercial 18650 Li-ion batteries with LFP and NCA cathodes – impact of state of charge and overcharge
journal, January 2015
- Golubkov, Andrey W.; Scheikl, Sebastian; Planteu, René
- RSC Advances, Vol. 5, Issue 70
Abuse Testing of Lithium-Ion Batteries: Characterization of the Overcharge Reaction of LiCoO[sub 2]/Graphite Cells
journal, January 2001
- Leising, Randolph A.; Palazzo, Marcus J.; Takeuchi, Esther Sans
- Journal of The Electrochemical Society, Vol. 148, Issue 8
Failure Investigation of LiFePO 4 Cells under Overcharge Conditions
journal, January 2012
- Xu, Fan; He, Hao; Liu, YaDong
- Journal of The Electrochemical Society, Vol. 159, Issue 5
Abuse by External Heating, Overcharge and Short Circuiting of Commercial Lithium-Ion Battery Cells
journal, January 2014
- Larsson, Fredrik; Mellander, Bengt-Erik
- Journal of The Electrochemical Society, Vol. 161, Issue 10
Failure Study of Commercial LiFePO 4 Cells in Overcharge Conditions Using Electrochemical Impedance Spectroscopy
journal, January 2015
- Liu, Yadong; Xie, Jian
- Journal of The Electrochemical Society, Vol. 162, Issue 10
Overcharge Effect on Morphology and Structure of Carbon Electrodes for Lithium-Ion Batteries
journal, January 2012
- Lu, Wenquan; López, Carmen M.; Liu, Nathan
- Journal of The Electrochemical Society, Vol. 159, Issue 5
In Situ Solid State 7 Li NMR Observations of Lithium Metal Deposition during Overcharge in Lithium Ion Batteries
journal, January 2015
- Arai, J.; Okada, Y.; Sugiyama, T.
- Journal of The Electrochemical Society, Vol. 162, Issue 6
Overcharge Study in Li 4 Ti 5 O 12 Based Lithium-Ion Pouch Cell: I. Quantitative Diagnosis of Degradation Modes
journal, January 2015
- Devie, Arnaud; Dubarry, Matthieu; Liaw, Bor Yann
- Journal of The Electrochemical Society, Vol. 162, Issue 6
Evaluation Residual Moisture in Lithium-Ion Battery Electrodes and Its Effect on Electrode Performance
journal, January 2016
- Li, Jianlin; Daniel, Claus; An, Seong Jin
- MRS Advances, Vol. 1, Issue 15
Vacuum-tight sample transfer stage for a scanning electron microscopic study of stabilized lithium metal particles
journal, October 2011
- Howe, Jane Y.; Boatner, Lynn A.; Kolopus, James A.
- Journal of Materials Science, Vol. 47, Issue 3
In situ Scanning Electron Microscopy (SEM) observation of interfaces within plastic lithium batteries
journal, November 1998
- Orsini, F.; Du Pasquier, A.; Beaudoin, B.
- Journal of Power Sources, Vol. 76, Issue 1
Mechanisms of dendritic growth investigated by in situ light microscopy during electrodeposition and dissolution of lithium
journal, September 2014
- Steiger, Jens; Kramer, Dominik; Mönig, Reiner
- Journal of Power Sources, Vol. 261
A stable lithium metal interface
journal, July 2014
- Bouchet, Renaud
- Nature Nanotechnology, Vol. 9, Issue 8
Failure mechanism of Li-ion battery at overcharge conditions
journal, November 2007
- Belov, D.; Yang, Mo-Hua
- Journal of Solid State Electrochemistry, Vol. 12, Issue 7-8
Contribution of the Structural Changes of LiNi[sub 0.8]Co[sub 0.15]Al[sub 0.05]O[sub 2] Cathodes on the Exothermic Reactions in Li-Ion Cells
journal, January 2006
- Bang, Hyun Joo; Joachin, Humberto; Yang, Hui
- Journal of The Electrochemical Society, Vol. 153, Issue 4
A short review of failure mechanisms of lithium metal and lithiated graphite anodes in liquid electrolyte solutions
journal, June 2002
- Aurbach, D.
- Solid State Ionics, Vol. 148, Issue 3-4
Review of selected electrode–solution interactions which determine the performance of Li and Li ion batteries
journal, August 2000
- Aurbach, Doron
- Journal of Power Sources, Vol. 89, Issue 2
A morphological study of SEI film on graphite electrodes
journal, July 2001
- Zane, D.; Antonini, A.; Pasquali, M.
- Journal of Power Sources, Vol. 97-98
The state of understanding of the lithium-ion-battery graphite solid electrolyte interphase (SEI) and its relationship to formation cycling
journal, August 2016
- An, Seong Jin; Li, Jianlin; Daniel, Claus
- Carbon, Vol. 105
Failure Mechanism for Fast-Charged Lithium Metal Batteries with Liquid Electrolytes
journal, September 2014
- Lu, Dongping; Shao, Yuyan; Lozano, Terence
- Advanced Energy Materials, Vol. 5, Issue 3
Abuse behavior of high-power, lithium-ion cells
journal, January 2003
- Spotnitz, R.; Franklin, J.
- Journal of Power Sources, Vol. 113, Issue 1
A review of the features and analyses of the solid electrolyte interphase in Li-ion batteries
journal, September 2010
- Verma, Pallavi; Maire, Pascal; Novák, Petr
- Electrochimica Acta, Vol. 55, Issue 22, p. 6332-6341
Works referencing / citing this record:
Overcharge Cycling Effect on the Surface Layers and Crystalline Structure of LiFePO4 Cathodes of Li-Ion Batteries
journal, December 2019
- Beletskii, Evgenii V.; Alekseeva, Elena V.; Spiridonova, Dar’ya V.
- Energies, Vol. 12, Issue 24
Experimental investigation on the essential cause of the degrading performances for an overcharging ternary battery
journal, December 2019
- Zhang, Jiangyun; Li, Xinxi; Zhang, Guoqing
- International Journal of Energy Research, Vol. 44, Issue 4