Effect of overcharge on Li(Ni0.5Mn0.3Co0.2)O2/Graphite cells–effect of binder

Dietz Rago, Nancy; Graczyk, Donald G.; Tsai, Yifen; Naik, Seema R.; Li, Jianlin; Du, Zhijia; Wood III, David L.; Steele, Leigh Anna; Lamb, Joshua; Spangler, Scott; Grosso, Christopher; Fenton, Kyle; Bloom, Ira

doi:10.1016/j.jpowsour.2019.227414

Title: Effect of overcharge on Li(Ni_0.5Mn_0.3Co_0.2)O₂/Graphite cells–effect of binder

Journal Article · 31 January 2020 · Journal of Power Sources

DOI: https://doi.org/10.1016/j.jpowsour.2019.227414 · OSTI ID:1606410

Dietz Rago, Nancy ^[1]; Graczyk, Donald G. ^[2]; Tsai, Yifen ^[2]; Naik, Seema R. ^[2];

^[3];

^[3]; Steele, Leigh Anna ^[4]; Lamb, Joshua ^[4]; Spangler, Scott ^[4]; Grosso, Christopher ^[4]; Fenton, Kyle ^[4];

^[1]

Argonne National Lab. (ANL), Argonne, IL (United States). Chemical Sciences and Engineering Division
Argonne National Lab. (ANL), Argonne, IL (United States). Analytical Chemistry Lab., Chemical and Fuel Cycle Technologies Division
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

Cells based on NMC/graphite, containing styrene-butadiene rubber/carboxymethylcellulose binder in the anodes and pVdF latex/carboxymethykellulose in the cathodes, were systematically overcharged to 100, 120, 140, 160, 180, 250% and 270% state-of-charge. The impact of the binder was characterized by elemental analysis, SEM, and HPLC. These results were compared to similar cells just using the poly (vinylidene difluoride) binder. Not only did the binder impact the rate of transition metal transport from the cathode to the anode, it also had a marked effect on the microstructure and composition of the materials on the anode surface.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States); Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE)

Grant/Contract Number:: AC02-06CH11357; AC05-00OR22725

OSTI ID:: 1606410

Journal Information:: Journal of Power Sources, Journal Name: Journal of Power Sources Journal Issue: C Vol. 448; ISSN 0378-7753

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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microstructure
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Title: Effect of overcharge on Li(Ni0.5Mn0.3Co0.2)O2/Graphite cells–effect of binder

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Title: Effect of overcharge on Li(Ni_0.5Mn_0.3Co_0.2)O₂/Graphite cells–effect of binder