skip to main content

DOE PAGESDOE PAGES

This content will become publicly available on February 13, 2019

Title: Effect of overcharge on Li(Ni 0.5Mn 0.3Co 0.2)O 2 cathodes: NMP-soluble binder. II — Chemical changes in the anode

For this study, cells based on nickel manganese cobalt oxide (NMC)/graphite electrodes, which contained polyvinylidene difluoride (PVDF) binders in the electrodes, were systematically charged to 100, 120, 140, 160, 180, and 250% state of charge (SOC). Characterization of the anodes by inductively-coupled-plasma mass spectrometry (ICP-MS), X-ray photoelectron spectroscopy (XPS), and high-performance liquid chromatography coupled with electrospray ionization mass spectrometry (HPLC-ESI-MS) showed several extent-of-overcharge-dependent trends. The concentrations (by wt) of nickel, manganese, and cobalt in the negative electrode increased with SOC, but the metals remained in the same ratio as that of the positive. Electrolyte reaction products, such as LiF:LiPO 3, increased with overcharge, as expected. Three organic products were found by HPLC-ESI-MS. From an analysis of the mass spectra, two of these compounds seem to be organophosphates, which were formed by the reaction of polymerized electrolyte decomposition products and PF 3 or O=PF 3. Their concentration tended to reach a constant ratio. The third was seen at 250% SOC only.
Authors:
 [1] ;  [1] ;  [1] ;  [1] ;  [2] ;  [2] ;  [2] ;  [1] ;  [1] ; ORCiD logo [3] ; ORCiD logo [3] ; ORCiD logo [3] ; ORCiD logo [3] ;  [4] ;  [4] ;  [4] ;  [4] ;  [4]
  1. Argonne National Lab. (ANL), Argonne, IL (United States). Chemical Sciences and Engineering Division
  2. Argonne National Lab. (ANL), Argonne, IL (United States). Analytical Chemistry Lab. and Nuclear Engineering Division
  3. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Energy and Transportation Science Division
  4. Sandia National Lab. (SNL-NM), Albuquerque, NM (United States). Power Sources Technology Group
Publication Date:
Grant/Contract Number:
AC05-00OR22725; AC02-06CH11357; NA0003525
Type:
Accepted Manuscript
Journal Name:
Journal of Power Sources
Additional Journal Information:
Journal Volume: 385; Journal Issue: C; Journal ID: ISSN 0378-7753
Publisher:
Elsevier
Research Org:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Argonne National Lab. (ANL), Argonne, IL (United States); Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
Sponsoring Org:
USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V); USDOE National Nuclear Security Administration (NNSA)
Country of Publication:
United States
Language:
English
Subject:
25 ENERGY STORAGE; 36 MATERIALS SCIENCE; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; Lithium-ion battery; Overcharge; SEI layer; lithium-ion battery; overcharge
OSTI Identifier:
1437886
Alternate Identifier(s):
OSTI ID: 1474299

Bloom, Ira, Bareno, Javier, Dietz Rago, Nancy, Dogan, Fulya, Graczyk, Donald G., Tsai, Yifen, Naik, Seema R., Han, Sang-Don, Lee, Eungje, Du, Zhijia, Sheng, Yangping, Li, Jianlin, Wood, David L., Steele, Leigh Anna, Lamb, Joshua, Spangler, Scott, Grosso, Christopher, and Fenton, Kyle. Effect of overcharge on Li(Ni0.5Mn0.3Co0.2)O2 cathodes: NMP-soluble binder. II — Chemical changes in the anode. United States: N. p., Web. doi:10.1016/j.jpowsour.2017.12.015.
Bloom, Ira, Bareno, Javier, Dietz Rago, Nancy, Dogan, Fulya, Graczyk, Donald G., Tsai, Yifen, Naik, Seema R., Han, Sang-Don, Lee, Eungje, Du, Zhijia, Sheng, Yangping, Li, Jianlin, Wood, David L., Steele, Leigh Anna, Lamb, Joshua, Spangler, Scott, Grosso, Christopher, & Fenton, Kyle. Effect of overcharge on Li(Ni0.5Mn0.3Co0.2)O2 cathodes: NMP-soluble binder. II — Chemical changes in the anode. United States. doi:10.1016/j.jpowsour.2017.12.015.
Bloom, Ira, Bareno, Javier, Dietz Rago, Nancy, Dogan, Fulya, Graczyk, Donald G., Tsai, Yifen, Naik, Seema R., Han, Sang-Don, Lee, Eungje, Du, Zhijia, Sheng, Yangping, Li, Jianlin, Wood, David L., Steele, Leigh Anna, Lamb, Joshua, Spangler, Scott, Grosso, Christopher, and Fenton, Kyle. 2018. "Effect of overcharge on Li(Ni0.5Mn0.3Co0.2)O2 cathodes: NMP-soluble binder. II — Chemical changes in the anode". United States. doi:10.1016/j.jpowsour.2017.12.015.
@article{osti_1437886,
title = {Effect of overcharge on Li(Ni0.5Mn0.3Co0.2)O2 cathodes: NMP-soluble binder. II — Chemical changes in the anode},
author = {Bloom, Ira and Bareno, Javier and Dietz Rago, Nancy and Dogan, Fulya and Graczyk, Donald G. and Tsai, Yifen and Naik, Seema R. and Han, Sang-Don and Lee, Eungje and Du, Zhijia and Sheng, Yangping and Li, Jianlin and Wood, David L. and Steele, Leigh Anna and Lamb, Joshua and Spangler, Scott and Grosso, Christopher and Fenton, Kyle},
abstractNote = {For this study, cells based on nickel manganese cobalt oxide (NMC)/graphite electrodes, which contained polyvinylidene difluoride (PVDF) binders in the electrodes, were systematically charged to 100, 120, 140, 160, 180, and 250% state of charge (SOC). Characterization of the anodes by inductively-coupled-plasma mass spectrometry (ICP-MS), X-ray photoelectron spectroscopy (XPS), and high-performance liquid chromatography coupled with electrospray ionization mass spectrometry (HPLC-ESI-MS) showed several extent-of-overcharge-dependent trends. The concentrations (by wt) of nickel, manganese, and cobalt in the negative electrode increased with SOC, but the metals remained in the same ratio as that of the positive. Electrolyte reaction products, such as LiF:LiPO3, increased with overcharge, as expected. Three organic products were found by HPLC-ESI-MS. From an analysis of the mass spectra, two of these compounds seem to be organophosphates, which were formed by the reaction of polymerized electrolyte decomposition products and PF3 or O=PF3. Their concentration tended to reach a constant ratio. The third was seen at 250% SOC only.},
doi = {10.1016/j.jpowsour.2017.12.015},
journal = {Journal of Power Sources},
number = C,
volume = 385,
place = {United States},
year = {2018},
month = {2}
}