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Title: Effect of overcharge on Li(Ni0.5Mn0.3Co0.2)O2/Graphite cells–effect of binder

Abstract

Cells based on NMC/graphite, containing styrene-butadiene rubber/carboxymethylcellulose binder in the anodes and pVdF latex/carboxymethylcellulose in the cathodes, were systematically overcharged to 100, 120, 140, 160, 180, 250% and 270% state-of-charge. The impact of the binder was characterized by elemental analysis, SEM, and HPLC. These results were compared to similar cells just using the poly (vinylidene difluoride) binder. Not only did the binder impact the rate of transition metal transport from the cathode to the anode, it also had a marked effect on the microstructure and composition of the materials on the anode surface.

Authors:
 [1];  [2];  [2];  [2]; ORCiD logo [3]; ORCiD logo [3]; ORCiD logo [3];  [4];  [4];  [4];  [4];  [4]; ORCiD logo [1]
  1. Argonne National Lab. (ANL), Argonne, IL (United States). Chemical Sciences and Engineering Division
  2. Argonne National Lab. (ANL), Argonne, IL (United States). Analytical Chemistry Lab., Chemical and Fuel Cycle Technologies Division
  3. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
  4. Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Sponsoring Org.:
USDOE Office of Energy Efficiency and Renewable Energy (EERE)
OSTI Identifier:
1606410
Alternate Identifier(s):
OSTI ID: 1606737; OSTI ID: 1698143
Grant/Contract Number:  
AC02-06CH11357; AC05-00OR22725
Resource Type:
Accepted Manuscript
Journal Name:
Journal of Power Sources
Additional Journal Information:
Journal Volume: 448; Journal Issue: C; Journal ID: ISSN 0378-7753
Publisher:
Elsevier
Country of Publication:
United States
Language:
English
Subject:
25 ENERGY STORAGE; PVDF; SBR/CMC; SEI; anode; binder; lithium-ion battery; microstructure; overcharge

Citation Formats

Dietz Rago, Nancy, Graczyk, Donald G., Tsai, Yifen, Naik, Seema R., Li, Jianlin, Du, Zhijia, Wood III, David L., Steele, Leigh Anna, Lamb, Joshua, Spangler, Scott, Grosso, Christopher, Fenton, Kyle, and Bloom, Ira. Effect of overcharge on Li(Ni0.5Mn0.3Co0.2)O2/Graphite cells–effect of binder. United States: N. p., 2020. Web. doi:10.1016/j.jpowsour.2019.227414.
Dietz Rago, Nancy, Graczyk, Donald G., Tsai, Yifen, Naik, Seema R., Li, Jianlin, Du, Zhijia, Wood III, David L., Steele, Leigh Anna, Lamb, Joshua, Spangler, Scott, Grosso, Christopher, Fenton, Kyle, & Bloom, Ira. Effect of overcharge on Li(Ni0.5Mn0.3Co0.2)O2/Graphite cells–effect of binder. United States. https://doi.org/10.1016/j.jpowsour.2019.227414
Dietz Rago, Nancy, Graczyk, Donald G., Tsai, Yifen, Naik, Seema R., Li, Jianlin, Du, Zhijia, Wood III, David L., Steele, Leigh Anna, Lamb, Joshua, Spangler, Scott, Grosso, Christopher, Fenton, Kyle, and Bloom, Ira. Sat . "Effect of overcharge on Li(Ni0.5Mn0.3Co0.2)O2/Graphite cells–effect of binder". United States. https://doi.org/10.1016/j.jpowsour.2019.227414. https://www.osti.gov/servlets/purl/1606410.
@article{osti_1606410,
title = {Effect of overcharge on Li(Ni0.5Mn0.3Co0.2)O2/Graphite cells–effect of binder},
author = {Dietz Rago, Nancy and Graczyk, Donald G. and Tsai, Yifen and Naik, Seema R. and Li, Jianlin and Du, Zhijia and Wood III, David L. and Steele, Leigh Anna and Lamb, Joshua and Spangler, Scott and Grosso, Christopher and Fenton, Kyle and Bloom, Ira},
abstractNote = {Cells based on NMC/graphite, containing styrene-butadiene rubber/carboxymethylcellulose binder in the anodes and pVdF latex/carboxymethylcellulose in the cathodes, were systematically overcharged to 100, 120, 140, 160, 180, 250% and 270% state-of-charge. The impact of the binder was characterized by elemental analysis, SEM, and HPLC. These results were compared to similar cells just using the poly (vinylidene difluoride) binder. Not only did the binder impact the rate of transition metal transport from the cathode to the anode, it also had a marked effect on the microstructure and composition of the materials on the anode surface.},
doi = {10.1016/j.jpowsour.2019.227414},
journal = {Journal of Power Sources},
number = C,
volume = 448,
place = {United States},
year = {Sat Feb 01 00:00:00 EST 2020},
month = {Sat Feb 01 00:00:00 EST 2020}
}

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Cited by: 5 works
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