Periodic nanostructures from self assembled wedge-type block-copolymers
Abstract
The invention provides a class of wedge-type block copolymers having a plurality of chemically different blocks, at least a portion of which incorporates a wedge group-containing block providing useful properties. For example, use of one or more wedge group-containing blocks in some block copolymers of the invention significantly inhibits chain entanglement and, thus, the present block copolymers materials provide a class of polymer materials capable of efficient molecular self-assembly to generate a range of structures, such as periodic nanostructures and microstructures. Materials of the present invention include copolymers having one or more wedge group-containing blocks, and optionally for some applications copolymers also incorporating one or more polymer side group-containing blocks. The present invention also provides useful methods of making and using wedge-type block copolymers.
- Inventors:
- Issue Date:
- Research Org.:
- California Institute of Technology (CalTech), Pasadena, CA (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1183455
- Patent Number(s):
- 9045579
- Application Number:
- 13/801,710
- Assignee:
- California Institute of Technology (Pasadena, CA)
- Patent Classifications (CPCs):
-
B - PERFORMING OPERATIONS B81 - MICROSTRUCTURAL TECHNOLOGY B81C - PROCESSES OR APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OR TREATMENT OF MICROSTRUCTURAL DEVICES OR SYSTEMS
B - PERFORMING OPERATIONS B82 - NANOTECHNOLOGY B82Y - SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES
- DOE Contract Number:
- FG02-05ER46218
- Resource Type:
- Patent
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 77 NANOSCIENCE AND NANOTECHNOLOGY
Citation Formats
Xia, Yan, Sveinbjornsson, Benjamin R., Grubbs, Robert H., Weitekamp, Raymond, Miyake, Garret M., Piunova, Victoria, and Daeffler, Christopher Scot. Periodic nanostructures from self assembled wedge-type block-copolymers. United States: N. p., 2015.
Web.
Xia, Yan, Sveinbjornsson, Benjamin R., Grubbs, Robert H., Weitekamp, Raymond, Miyake, Garret M., Piunova, Victoria, & Daeffler, Christopher Scot. Periodic nanostructures from self assembled wedge-type block-copolymers. United States.
Xia, Yan, Sveinbjornsson, Benjamin R., Grubbs, Robert H., Weitekamp, Raymond, Miyake, Garret M., Piunova, Victoria, and Daeffler, Christopher Scot. Tue .
"Periodic nanostructures from self assembled wedge-type block-copolymers". United States. https://www.osti.gov/servlets/purl/1183455.
@article{osti_1183455,
title = {Periodic nanostructures from self assembled wedge-type block-copolymers},
author = {Xia, Yan and Sveinbjornsson, Benjamin R. and Grubbs, Robert H. and Weitekamp, Raymond and Miyake, Garret M. and Piunova, Victoria and Daeffler, Christopher Scot},
abstractNote = {The invention provides a class of wedge-type block copolymers having a plurality of chemically different blocks, at least a portion of which incorporates a wedge group-containing block providing useful properties. For example, use of one or more wedge group-containing blocks in some block copolymers of the invention significantly inhibits chain entanglement and, thus, the present block copolymers materials provide a class of polymer materials capable of efficient molecular self-assembly to generate a range of structures, such as periodic nanostructures and microstructures. Materials of the present invention include copolymers having one or more wedge group-containing blocks, and optionally for some applications copolymers also incorporating one or more polymer side group-containing blocks. The present invention also provides useful methods of making and using wedge-type block copolymers.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Jun 02 00:00:00 EDT 2015},
month = {Tue Jun 02 00:00:00 EDT 2015}
}
Works referenced in this record:
Multifunctional organic polymers
patent, October 1995
- Hubbell, Jeffrey A.; Elbert, Donald; Hill-West, Jennifer L.
- US Patent Document 5,462,990
Nanoparticles and microparticles of non-linear hydrophilic-hydrophobic multiblock copolymers
patent, December 1999
- Domb, Abraham J.; Gref, Ruxandra; Minamitake, Yoshiharu
- US Patent Document 6,007,845
Particles comprising amphiphilic copolymers, having a crosslinked shell domain and an interior core domain, useful for pharmaceutical and other applications
patent, May 2002
- Wooley, Karen L.; Thurmond, K. Bruce; Huang, Haiyong Hugh
- US Patent Document 6,383,500
(Co)polymers and a novel polymerization process based on atom (or group) transfer radical polymerization
patent, June 2002
- Matyjaszewski, Krzysztof; Wang, Jin-Shan
- US Patent Document 6,407,187
Polymeric photonic band gap materials
patent, August 2002
- Fink, Yoel; Thomas, Edwin L.
- US Patent Document 6,433,931
Preparation of nanocomposite structures by controlled polymerization
patent, September 2003
- Matyjaszewski, Krzysztof; Pyun, Jeffrey
- US Patent Document 6,627,314
Polymeric photonic band gap materials
patent, December 2003
- Fink, Yoel; Thomas, Edwin L.
- US Patent Document 6,671,097
Polymer brushes for immobilizing molecules to a surface or substrate, where the polymers have water-soluble or water-dispersible segments and probes bonded thereto
patent, February 2004
- Klaerner, Gerrit; Nielsen, Ralph B.; Mansky, Paul
- US Patent Document 6,692,914
Dendritic based macromolecules
patent, September 2006
- Frechet, Jean M. J.; Hawker, Craig J.; Wooley, Karen L.
- US Patent Document 7,101,937
Preparation of functional polymers
patent, September 2010
- Matyjaszewski, Krzyszlof; Sumerlin, Brent S.; Tsarevsky, Nicolay
- US Patent Document 7,795,355
Brush copolymers
patent, June 2011
- Cheng, Chong; Khoshdel, Ezat; Wooley, Karen L.
- US Patent Document 7,960,479
Polymer particles having polymer brush and method of preparing the same
patent, April 2013
- Han, Bo-ryeong; Chun, Moon Seok; Park, Dong-Seek
- US Patent Document 8,415,436
Brush copolymers
patent, April 2013
- Vanderbilt, David P.; Valint, Jr., Paul L.
- US Patent Document 8,419,792
Brush copolymers
patent, June 2013
- Vanderbilt, David P.; Valint, Jr., Paul L.
- US Patent Document 8,454,689
Polymeric photonic band gap materials
patent-application, September 2002
- Fink, Yoel; Thomas, Edwin L.
- US Patent Application 10/146775; 20020135880
Polymers of polycyclic olefins having a polyhedral oligosilsesquioxane pendant group and uses thereof
patent-application, September 2005
- Rhodes, Larry F.; Seger, Larry; Ravikiran, Ramakrishna
- US Patent Application 11/054963; 20050192409
Inorganic block co-polymers and other similar materials as ceramic precursors for nanoscale ordered high-temperature ceramics
patent-application, May 2007
- Wan, Julin; Malenfant, Patrick Roland Lucien; Manoharan, Mohan
- US Patent Application 11/488521; 20070099791
Rapid self-assembly of block copolymers to photonic crystals
patent-application, December 2013
- Xia, Yan; Sveinbjornsson, Benjamin R.; Grubbs, Robert H.
- US Patent Application 13/800646; 20130324666
Photonic structures from self assembly of brush block copolymers and polymer blends
patent-application, January 2014
- Miyake, Garret M.; Weitekamp, Raymond; Grubbs, Robert H.
- US Patent Application 13/930400; 20140011958
Synthesis, characterization and modification of azide-containing dendronized diblock copolymers
journal, March 2009
- Fiset, Erika; Morin, Jean-François
- Polymer, Vol. 50, Issue 6, p. 1369-1377
Tunable Colors in Opals and Inverse Opal Photonic Crystals
journal, July 2010
- Aguirre, Carlos I.; Reguera, Edilso; Stein, Andreas
- Advanced Functional Materials, Vol. 20, Issue 16
Cool surfaces and shade trees to reduce energy use and improve air quality in urban areas
journal, January 2001
- Akbari, H.; Pomerantz, M.; Taha, H.
- Solar Energy, Vol. 70, Issue 3
Self-assembly of block copolymer thin films
journal, June 2010
- Albert, Julie N. L.; Epps, Thomas H.
- Materials Today, Vol. 13, Issue 6, p. 24-33
Rigid Backbone Polymers. 2. Polyisocyanates and Their Liquid-Crystal Behavior
journal, January 1979
- Aharoni, Shaul M.
- Macromolecules, Vol. 12, Issue 1
Plasmonics for improved photovoltaic devices
journal, February 2010
- Atwater, Harry A.; Polman, Albert
- Nature Materials, Vol. 9, Issue 3, p. 205-213
Polymer brushes here, there, and everywhere: Recent advances in their practical applications and emerging opportunities in multiple research fields
journal, May 2012
- Azzaroni, Omar
- Journal of Polymer Science Part A: Polymer Chemistry, Vol. 50, Issue 16
Block Copolymer Nanolithography: Translation of Molecular Level Control to Nanoscale Patterns
journal, July 2009
- Bang, Joona; Jeong, Unyong; Ryu, Du Yeol
- Advanced Materials, Vol. 21, Issue 47, p. 4769-4792
Dual Templating Synthesis of Mesoporous Titanium Nitride Microspheres
journal, August 2009
- Bang, Jin Ho; Suslick, Kenneth S.
- Advanced Materials, Vol. 21, Issue 31, p. 3186-3190
Block Copolymer Thermodynamics: Theory and Experiment
journal, October 1990
- Bates, Frank S.; Fredrickson, Glenn H.
- Annual Review of Physical Chemistry, Vol. 41, Issue 1
Block Copolymers—Designer Soft Materials
journal, February 1999
- Bates, Frank S.; Fredrickson, Glenn H.
- Physics Today, Vol. 52, Issue 2
Multiblock Polymers: Panacea or Pandora's Box?
journal, April 2012
- Bates, F. S.; Hillmyer, M. A.; Lodge, T. P.
- Science, Vol. 336, Issue 6080
Responsive polymers in controlled drug delivery
journal, November 2008
- Bajpai, A. K.; Shukla, Sandeep K.; Bhanu, Smitha
- Progress in Polymer Science, Vol. 33, Issue 11, p. 1088-1118
Organization of Rigid Wedge−Flexible Coil Block Copolymers into Liquid Crystalline Assembly
journal, May 2005
- Bae, Jinyoung; Kim, Jung-Keun; Oh, Nam-Keun
- Macromolecules, Vol. 38, Issue 10
Modelling of the urban heat island and of its interaction with pollutant dispersal
journal, January 1982
- Bennett, M.; Saab, A. E.
- Atmospheric Environment (1967), Vol. 16, Issue 8, p. 1797-1822
Thickness Dependence of the Optical Properties of Ordered Silica-Air and Air-Polymer Photonic Crystals
journal, July 1999
- Bertone, Jane F.; Jiang, Peng; Hwang, Kevin S.
- Physical Review Letters, Vol. 83, Issue 2
Living ring-opening metathesis polymerization
journal, January 2007
- Bielawski, Christopher W.; Grubbs, Robert H.
- Progress in Polymer Science, Vol. 32, Issue 1, p. 1-29
Integration of self-assembled diblock copolymers for semiconductor capacitor fabrication
journal, July 2001
- Black, C. T.; Guarini, K. W.; Milkove, K. R.
- Applied Physics Letters, Vol. 79, Issue 3, p. 409-411
Microporous materials: Electrochemically grown photonic crystals
journal, December 1999
- Braun, Paul V.; Wiltzius, Pierre
- Nature, Vol. 402, Issue 6762, p. 603-604
Fabrication of photonic crystals for the visible spectrum by holographic lithography
journal, March 2000
- Campbell, M.; Sharp, D. N.; Harrison, M. T.
- Nature, Vol. 404, Issue 6773, p. 53-56
Static and dynamic properties of two-dimensional polymer melts
journal, January 1990
- Carmesin, I.; Kremer, Kurt
- Journal de Physique, Vol. 51, Issue 10
Intramolecular Hydroamination of Aminoalkynes with Silver−Phenanthroline Catalysts
journal, September 2008
- Carney, Jeffrey M.; Donoghue, Patrick J.; Wuest, William M.
- Organic Letters, Vol. 10, Issue 17
New Directions: The growing urban heat and pollution ?island? effect?impact on chemistry and climate*1
journal, July 2004
- Crutzen, P.
- Atmospheric Environment, Vol. 38, Issue 21
Formation of a Cobalt Magnetic Dot Array via Block Copolymer Lithography
journal, August 2001
- Cheng, J.Y.; Ross, C.A.; Chan, V.Z.-H.
- Advanced Materials, Vol. 13, Issue 15, p. 1174-1178
Templated Self-Assembly of Block Copolymers: Top-Down Helps Bottom-Up
journal, October 2006
- Cheng, J. Y.; Ross, C. A.; Smith, H. I.
- Advanced Materials, Vol. 18, Issue 19, p. 2505-2521
Oligosaccharide/Silicon-Containing Block Copolymers with 5 nm Features for Lithographic Applications
journal, March 2012
- Cushen, Julia D.; Otsuka, Issei; Bates, Christopher M.
- ACS Nano, Vol. 6, Issue 4
Interdiffusion and self‐diffusion in polymer mixtures: A Monte Carlo study
journal, February 1991
- Deutsch, H. P.; Binder, K.
- The Journal of Chemical Physics, Vol. 94, Issue 3
Polymer-Based Photonic Crystals
journal, March 2001
- Edrington, A. C.; Urbas, A. M.; DeRege, P.
- Advanced Materials, Vol. 13, Issue 6, p. 421-425
Design Considerations for Plasmonic Photovoltaics
journal, September 2010
- Ferry, Vivian E.; Munday, Jeremy N.; Atwater, Harry A.
- Advanced Materials, Vol. 22, Issue 43, p. 4794-4808
Block copolymers as photonic bandgap materials
journal, November 1999
- Fink, Y.; Urbas, A. M.; Bawendi, M. G.
- Journal of Lightwave Technology, Vol. 17, Issue 11, p. 1963-1969
Dynamics of Block Copolymers: Theory and Experiment
journal, August 1996
- Fredrickson, G. H.; Bates, F. S.
- Annual Review of Materials Science, Vol. 26, Issue 1
Self-Assembled Photonic Structures
journal, September 2010
- Galisteo-López, Juan F.; Ibisate, Marta; Sapienza, Riccardo
- Advanced Materials, Vol. 23, Issue 1, p. 30-69
Synthesis of Molecular Brushes by “Grafting onto” Method: Combination of ATRP and Click Reactions
journal, May 2007
- Gao, Haifeng; Matyjaszewski, Krzysztof
- Journal of the American Chemical Society, Vol. 129, Issue 20
Responsive Photonic Crystals
journal, January 2011
- Ge, Jianping; Yin, Yadong
- Angewandte Chemie International Edition, Vol. 50, Issue 7, p. 1492-1522
The packing of soft materials: Molecular asymmetry, geometric frustration and optimal lattices in block copolymer melts
journal, October 2006
- Grason, G.
- Physics Reports, Vol. 433, Issue 1
The Macromolecular Route to Chiral Amplification
journal, November 1999
- Green, Mark M.; Park, Ji-Woong; Sato, Takahiro
- Angewandte Chemie International Edition, Vol. 38, Issue 21, p. 3138-3154
Macromolecular stereochemistry: the out-of-proportion influence of optically active comonomers on the conformational characteristics of polyisocyanates. The sergeants and soldiers experiment
journal, August 1989
- Green, Mark M.; Reidy, Michael P.; Johnson, Robert D.
- Journal of the American Chemical Society, Vol. 111, Issue 16, p. 6452-6454
Global Change and the Ecology of Cities
journal, February 2008
- Grimm, N. B.; Faeth, S. H.; Golubiewski, N. E.
- Science, Vol. 319, Issue 5864
Self-Assembly of Symmetric Brush Diblock Copolymers
journal, February 2013
- Gu, Weiyin; Huh, June; Hong, Sung Woo
- ACS Nano, Vol. 7, Issue 3
Polymers with Complex Architecture by Living Anionic Polymerization
journal, December 2001
- Hadjichristidis, Nikos; Pitsikalis, Marinos; Pispas, Stergios
- Chemical Reviews, Vol. 101, Issue 12
The Strength of the Macromonomer Strategy for Complex Macromolecular Architecture: Molecular Characterization, Properties and Applications of Polymacromonomers
journal, November 2003
- Hadjichristidis, Nikos; Pitsikalis, Marinos; Iatrou, Hermis
- Macromolecular Rapid Communications, Vol. 24, Issue 17
Nanostructure fabrication using block copolymers
journal, September 2003
- Hamley, I. W.
- Nanotechnology, Vol. 14, Issue 10
Ordered structure in blends of block copolymers. 1. Miscibility criterion for lamellar block copolymers
journal, May 1993
- Hashimoto, Takeji; Yamasaki, Komei; Koizumi, Satoshi
- Macromolecules, Vol. 26, Issue 11
Block Copolymer Lithography: Merging “Bottom-Up” with “Top-Down” Processes
journal, December 2005
- Hawker, Craig J.; Russell, Thomas P.
- MRS Bulletin, Vol. 30, Issue 12, p. 952-966
Synthesis of α-Norbornenylpoly(ethylene oxide) Macromonomers and Their Ring-Opening Metathesis Polymerization
journal, January 1996
- Heroguez, Valérie; Breunig, Stefan; Gnanou, Yves
- Macromolecules, Vol. 29, Issue 13
Linear Rheological Response of a Series of Densely Branched Brush Polymers
journal, September 2011
- Hu, Miao; Xia, Yan; McKenna, Gregory B.
- Macromolecules, Vol. 44, Issue 17, p. 6935-6943
Photonic Polyethylene from Self-Assembled Mesophases of Polydisperse Olefin Block Copolymers
journal, June 2009
- Hustad, Phillip D.; Marchand, Gary R.; Garcia-Meitin, Eddy I.
- Macromolecules, Vol. 42, Issue 11
Fabricating complex three-dimensional nanostructures with high-resolution conformable phase masks
journal, August 2004
- Jeon, S.; Park, J.-U.; Cirelli, R.
- Proceedings of the National Academy of Sciences, Vol. 101, Issue 34, p. 12428-12433
Patterned polymer growth on silicon surfaces using microcontact printing and surface-initiated polymerization
journal, December 1999
- Jeon, Noo Li; Choi, Insung S.; Whitesides, George M.
- Applied Physics Letters, Vol. 75, Issue 26
Drug-Loaded, Bivalent-Bottle-Brush Polymers by Graft-through ROMP
journal, December 2010
- Johnson, Jeremiah A.; Lu, Ying Y.; Burts, Alan O.
- Macromolecules, Vol. 43, Issue 24
Core-Clickable PEG- Branch -Azide Bivalent-Bottle-Brush Polymers by ROMP: Grafting-Through and Clicking-To
journal, January 2011
- Johnson, Jeremiah A.; Lu, Ying Y.; Burts, Alan O.
- Journal of the American Chemical Society, Vol. 133, Issue 3
Impact of urbanization and land-use change on climate
journal, May 2003
- Kalnay, Eugenia; Cai, Ming
- Nature, Vol. 423, Issue 6939
Phase Behavior and Morphological Characteristics of Compositionally Symmetric Diblock Copolymer Blends
journal, January 1996
- Kane, Lisaleigh; Satkowski, Michael M.; Smith, Steven D.
- Macromolecules, Vol. 29, Issue 27
Broad-wavelength-range chemically tunable block-copolymer photonic gels
journal, October 2007
- Kang, Youngjong; Walish, Joseph J.; Gorishnyy, Taras
- Nature Materials, Vol. 6, Issue 12
Full Color Stop Bands in Hybrid Organic/Inorganic Block Copolymer Photonic Gels by Swelling−Freezing
journal, June 2009
- Kang, Changjoon; Kim, Eunjoo; Baek, Heeyoel
- Journal of the American Chemical Society, Vol. 131, Issue 22
Ultrafast Cyclopolymerization for Polyene Synthesis: Living Polymerization to Dendronized Polymers
journal, August 2011
- Kang, Eun-Hye; Lee, In Sun; Choi, Tae-Lim
- Journal of the American Chemical Society, Vol. 133, Issue 31
Conformational Properties of Cylindrical Rod Brushes Consisting of a Polystyrene Main Chain and Poly( n -hexyl isocyanate) Side Chains
journal, September 2008
- Kikuchi, Moriya; Lien, Le Thi Ngoc; Narumi, Atsushi
- Macromolecules, Vol. 41, Issue 17
A Route to Nanoscopic SiO2 Posts via Block Copolymer Templates
journal, June 2001
- Kim, H. -C.; Jia, X.; Stafford, C. M.
- Advanced Materials, Vol. 13, Issue 11
Simple Synthesis of Poly(acetylene) Latex Particles in Aqueous Media
journal, December 2003
- Krause, Jens O.; Zarka, M. Tobias; Anders, Udo
- Angewandte Chemie International Edition, Vol. 42, Issue 48, p. 5965-5969
Factors Relevant for the Regioselective Cyclopolymerization of 1,6-Heptadiynes, N , N -Dipropargylamines, N , N -Dipropargylammonium Salts, and Dipropargyl Ethers by Ru IV −Alkylidene-Based Metathesis Initiators
journal, January 2009
- Kumar, P. Santhosh; Wurst, K.; Buchmeiser, Michael R.
- Journal of the American Chemical Society, Vol. 131, Issue 1
Poly(styrene)comb- b -Poly(ethylene oxide)comb Copolymers: Synthesis and AFM Investigation of Intra- and Supramolecular Organization as Thin Deposits
journal, December 2007
- Lanson, David; Schappacher, Michel; Borsali, Redouane
- Macromolecules, Vol. 40, Issue 26
Synthesis of (Poly(chloroethyl vinyl ether)- g -polystyrene)comb- b -(poly(chloropyran ethoxy vinyl ether)- g -polyisoprene)comb Copolymers and Study of Hyper-Branched Micelle Formation in Dilute Solutions
journal, July 2007
- Lanson, David; Schappacher, Michel; Borsali, Redouane
- Macromolecules, Vol. 40, Issue 15
Hetero-Grafted Block Brushes with PCL and PBA Side Chains
journal, August 2008
- Lee, Hyung-il; Matyjaszewski, Krzysztof; Yu-Su, Sherryl
- Macromolecules, Vol. 41, Issue 16
Quasi-Amorphous Colloidal Structures for Electrically Tunable Full-Color Photonic Pixels with Angle-Independency
journal, August 2010
- Lee, Insook; Kim, Daihyun; Kal, Jinha
- Advanced Materials, Vol. 22, Issue 44, p. 4973-4977
Theory of Microphase Separation in Block Copolymers
journal, November 1980
- Leibler, Ludwik
- Macromolecules, Vol. 13, Issue 6
The ROMP toolbox upgraded
journal, June 2010
- Leitgeb, Anita; Wappel, Julia; Slugovc, Christian
- Polymer, Vol. 51, Issue 14, p. 2927-2946
Dense arrays of ordered GaAs nanostructures by selective area growth on substrates patterned by block copolymer lithography
journal, March 2000
- Li, R. R.; Dapkus, P. D.; Thompson, M. E.
- Applied Physics Letters, Vol. 76, Issue 13, p. 1689-1691
A three-dimensional photonic crystal operating at infrared wavelengths
journal, July 1998
- Lin, S. Y.; Fleming, J. G.; Hetherington, D. L.
- Nature, Vol. 394, Issue 6690, p. 251-253
Plasmonic nanocavity arrays for enhanced efficiency in organic photovoltaic cells
journal, September 2008
- Lindquist, Nathan C.; Luhman, Wade A.; Oh, Sang-Hyun
- Applied Physics Letters, Vol. 93, Issue 12
Hierarchical self-assembly of metal nanostructures on diblock copolymer scaffolds
journal, December 2001
- Lopes, Ward A.; Jaeger, Heinrich M.
- Nature, Vol. 414, Issue 6865, p. 735-738
A Practical and Highly Active Ruthenium-Based Catalyst that Effects the Cross Metathesis of Acrylonitrile
journal, November 2002
- Love, Jennifer A.; Morgan, John P.; Trnka, Tina M.
- Angewandte Chemie International Edition, Vol. 41, Issue 21
Massively parallel fabrication of repetitive nanostructures: nanolithography for nanoarrays
journal, June 2009
- Luttge, Regina
- Journal of Physics D: Applied Physics, Vol. 42, Issue 12
Controlling Order in Block Copolymer Thin Films for Nanopatterning Applications
journal, June 2010
- Marencic, Andrew P.; Register, Richard A.
- Annual Review of Chemical and Biomolecular Engineering, Vol. 1, Issue 1
Helical polymer brushes with a preferred-handed helix-sense triggered by a terminal optically active group in the pendant
journal, January 2012
- Maeda, Katsuhiro; Wakasone, Shiho; Shimomura, Kouhei
- Chemical Communications, Vol. 48, Issue 27
Photonic Crystal Using Anodic Porous Alumina
journal, December 1999
- Masuda, Hideki; Ohya, Masayuki; Asoh, Hidetaka
- Japanese Journal of Applied Physics, Vol. 38, Issue Part 2, No. 12A
Conformationally asymmetric block copolymers
journal, April 1997
- Matsen, M. W.; Bates, F. S.
- Journal of Polymer Science Part B: Polymer Physics, Vol. 35, Issue 6, p. 945-952
Synthesis of Fluorine-18 Functionalized Nanoparticles for use as in vivo Molecular Imaging Agents
journal, May 2008
- Matson, John B.; Grubbs, Robert H.
- Journal of the American Chemical Society, Vol. 130, Issue 21
Chiral polyisocyanates, a special class of helical polymers
journal, December 2001
- Mayer, Sabine; Zentel, Rudolf
- Progress in Polymer Science, Vol. 26, Issue 10, p. 1973-2013
Structure−Property Relations in Cholesteric Networks from Chiral Polyisocyanates
journal, September 1999
- Maxein, Georg; Mayer, Sabine; Zentel, Rudolf
- Macromolecules, Vol. 32, Issue 18
Opalescent Cholesteric Networks from Chiral Polyisocyanates in Polystyrene
journal, March 1998
- Maxein, Georg; Keller, Harald; Novak, Bruce M.
- Advanced Materials, Vol. 10, Issue 4, p. 341-345
Bi- and Trinuclear Ruthenium Alkylidene Triggered Cyclopolymerization of 1,6-Heptadiynes: Access to A n −X−A n Block and (A n ) 3 X Tristar Copolymers
journal, May 2006
- Mayershofer, Martin G.; Nuyken, Oskar; Buchmeiser, Michael R.
- Macromolecules, Vol. 39, Issue 10
Theory of the grafted polymer brush
journal, August 1988
- Milner, S. T.; Witten, T. A.; Cates, M. E.
- Macromolecules, Vol. 21, Issue 8
Synthesis of Isocyanate-Based Brush Block Copolymers and Their Rapid Self-Assembly to Infrared-Reflecting Photonic Crystals
journal, August 2012
- Miyake, Garret M.; Weitekamp, Raymond A.; Piunova, Victoria A.
- Journal of the American Chemical Society, Vol. 134, Issue 34
Precisely Tunable Photonic Crystals From Rapidly Self-Assembling Brush Block Copolymer Blends
journal, September 2012
- Miyake, Garret M.; Piunova, Victoria A.; Weitekamp, Raymond A.
- Angewandte Chemie International Edition, Vol. 51, Issue 45, p. 11246-11248
Stereospecific Polymerization of Chiral Oxazolidinone-Functionalized Alkenes
journal, September 2010
- Miyake, Garret M.; DiRocco, Daniel A.; Liu, Qin
- Macromolecules, Vol. 43, Issue 18
Chemical Aspects of Three-Dimensional Photonic Crystals
journal, January 2010
- Moon, Jun Hyuk; Yang, Shu
- Chemical Reviews, Vol. 110, Issue 1
Polymerization of Macromonomers to Cylindrical Brushes Initiated by Organolanthanides
journal, June 2003
- Neiser, Michael W.; Okuda, Jun; Schmidt, Manfred
- Macromolecules, Vol. 36, Issue 15
How dense are cylindrical brushes grafted from a multifunctional macroinitiator?
journal, November 2004
- Neugebauer, Dorota; Sumerlin, Brent S.; Matyjaszewski, Krzysztof
- Polymer, Vol. 45, Issue 24, p. 8173-8179
⅔ -Power Law for Copolymer Lamellar Thickness Implies a ⅓ -Power Law for Spinodal Decomposition
journal, August 1988
- Oono, Y.; Bahiana, M.
- Physical Review Letters, Vol. 61, Issue 9
Safe and Convenient Procedure for Solvent Purification
journal, January 1996
- Pangborn, Amy B.; Giardello, Michael A.; Grubbs, Robert H.
- Organometallics, Vol. 15, Issue 5, p. 1518-1520
Nanostructured polymers for photonics
journal, April 2008
- Paquet, Chantal; Kumacheva, Eugenia
- Materials Today, Vol. 11, Issue 4, p. 48-56
Block Copolymer Lithography: Periodic Arrays of 1011 Holes in 1 Square Centimeter
journal, May 1997
- Park, Miri; Harrison, Christopher; Chaikin, Paul M.
- Science, Vol. 276, Issue 5317, p. 1401-1404
Enabling nanotechnology with self assembled block copolymer patterns
journal, October 2003
- Park, Cheolmin; Yoon, Jongseung; Thomas, Edwin L.
- Polymer, Vol. 44, Issue 22, p. 6725-6760
Macroscopic 10-Terabit-per-Square-Inch Arrays from Block Copolymers with Lateral Order
journal, February 2009
- Park, Soojin; Lee, Dong Hyun; Xu, Ji
- Science, Vol. 323, Issue 5917, p. 1030-1033
Continuously tuneable optical filters from self-assembled block copolymer blends
journal, January 2011
- Parnell, Andrew J.; Pryke, Andrew; Mykhaylyk, Oleksandr O.
- Soft Matter, Vol. 7, Issue 8
"Living" titanium(IV) catalyzed coordination polymerizations of isocyanates
journal, June 1991
- Patten, Timothy E.; Novak, Bruce M.
- Journal of the American Chemical Society, Vol. 113, Issue 13, p. 5065-5066
Living Organotitanium(IV)-Catalyzed Polymerizations of Isocyanates
journal, January 1996
- Patten, Timothy E.; Novak, Bruce M.
- Journal of the American Chemical Society, Vol. 118, Issue 8
Impact of regional climate change on human health
journal, November 2005
- Patz, Jonathan A.; Campbell-Lendrum, Diarmid; Holloway, Tracey
- Nature, Vol. 438, Issue 7066
Aluminum nanowire polarizing grids: Fabrication and analysis
journal, May 2006
- Pelletier, Vincent; Asakawa, Koji; Wu, Mingshaw
- Applied Physics Letters, Vol. 88, Issue 21, Article No. 211114
Surface Urban Heat Island Across 419 Global Big Cities
journal, December 2011
- Peng, Shushi; Piao, Shilong; Ciais, Philippe
- Environmental Science & Technology, Vol. 46, Issue 2
Cyclic Block Copolymers for Controlling Feature Sizes in Block Copolymer Lithography
journal, November 2012
- Poelma, Justin E.; Ono, Kosuke; Miyajima, Daigo
- ACS Nano, Vol. 6, Issue 12
A review on the generation, determination and mitigation of Urban Heat Island
journal, January 2008
- Rizwan, Ahmed Memon; Dennis, Leung Y. C.; Liu, Chunho
- Journal of Environmental Sciences, Vol. 20, Issue 1, p. 120-128
Synthesis of High Molecular Weight Comb Block Copolymers and Their Assembly into Ordered Morphologies in the Solid State
journal, August 2007
- Runge, M. Brett; Bowden, Ned B.
- Journal of the American Chemical Society, Vol. 129, Issue 34
Investigation of the Assembly of Comb Block Copolymers in the Solid State
journal, October 2008
- Runge, M. Brett; Lipscomb, Corinne E.; Ditzler, Lindsay R.
- Macromolecules, Vol. 41, Issue 20
Synthesis of Polymer Dielectric Layers for Organic Thin Film Transistors via Surface-Initiated Ring-Opening Metathesis Polymerization
journal, April 2004
- Rutenberg, Isaac M.; Scherman, Oren A.; Grubbs, Robert H.
- Journal of the American Chemical Society, Vol. 126, Issue 13
Synthesis of Polystyrene−Polylactide Bottlebrush Block Copolymers and Their Melt Self-Assembly into Large Domain Nanostructures
journal, March 2009
- Rzayev, Javid
- Macromolecules, Vol. 42, Issue 6
From Combs to Comb- g -Comb Centipedes
journal, August 2005
- Schappacher, Michel; Deffieux, Alain
- Macromolecules, Vol. 38, Issue 17
Patterning with block copolymer thin films
journal, February 2005
- Segalman, Rachel A.
- Materials Science and Engineering: R: Reports, Vol. 48, Issue 6, p. 191-226
Chiroptical Properties of Graft Copolymers Containing Chiral Poly( n -hexyl isocyanate) as a Side Chain
journal, October 2011
- Shah, Priyank N.; Min, Joonkeun; Kim, Hyung-Jin
- Macromolecules, Vol. 44, Issue 20
Visualization of MacromoleculesA First Step to Manipulation and Controlled Response
journal, December 2001
- Sheiko, Sergei S.; Möller, Martin
- Chemical Reviews, Vol. 101, Issue 12
The Ring Opening Metathesis Polymerisation Toolbox
journal, July 2004
- Slugovc, Christian
- Macromolecular Rapid Communications, Vol. 25, Issue 14
Modular and Dynamic Functionalization of Polymeric Scaffolds
journal, January 2007
- South, Clinton R.; Burd, Caroline; Weck, Marcus
- Accounts of Chemical Research, Vol. 40, Issue 1
Block copolymers and conventional lithography
journal, September 2006
- Stoykovich, Mark P.; Nealey, Paul F.
- Materials Today, Vol. 9, Issue 9, p. 20-29
Initiation Efficiency in the Synthesis of Molecular Brushes by Grafting from via Atom Transfer Radical Polymerization
journal, February 2005
- Sumerlin, Brent S.; Neugebauer, Dorota; Matyjaszewski, Krzysztof
- Macromolecules, Vol. 38, Issue 3
Rapid self-assembly of brush block copolymers to photonic crystals
journal, August 2012
- Sveinbjornsson, B. R.; Weitekamp, R. A.; Miyake, G. M.
- Proceedings of the National Academy of Sciences, Vol. 109, Issue 36, p. 14332-14336
Solvent Accelerated Polymer Diffusion in Thin Films
journal, May 2005
- Thompson, Richard L.; McDonald, Martin T.; Lenthall, Joseph T.
- Macromolecules, Vol. 38, Issue 10
Ultrahigh-Density Nanowire Arrays Grown in Self-Assembled Diblock Copolymer Templates
journal, December 2000
- Thurn-Albrecht, T.; Schotter, J.; Kastle, G. A.
- Science, Vol. 290, Issue 5499, p. 2126-2129
Transfer-matrix formalism for the calculation of optical response in multilayer systems: from coherent to incoherent interference
journal, January 2010
- Troparevsky, M. Claudia; Sabau, Adrian S.; Lupini, Andrew R.
- Optics Express, Vol. 18, Issue 24
Block Copolymer Nanostructures for Technology
journal, October 2010
- Tseng, Yu-Chih; Darling, Seth B.
- Polymers, Vol. 2, Issue 4
Tunable Block Copolymer/Homopolymer Photonic Crystals
journal, June 2000
- Urbas, A.; Sharp, R.; Fink, Y.
- Advanced Materials, Vol. 12, Issue 11, p. 812-814
One-Dimensionally Periodic Dielectric Reflectors from Self-Assembled Block Copolymer−Homopolymer Blends
journal, July 1999
- Urbas, Augustine; Fink, Yoel; Thomas, Edwin L.
- Macromolecules, Vol. 32, Issue 14
Self-assembled polymeric solid films with temperature-induced large and reversible photonic-bandgap switching
journal, November 2004
- Valkama, Sami; Kosonen, Harri; Ruokolainen, Janne
- Nature Materials, Vol. 3, Issue 12
Perpendicular orientation of cylindrical domains upon solvent annealing thin films of polystyrene-b-polylactide
journal, May 2010
- Vayer, Marylène; Hillmyer, Marc A.; Dirany, Mohammed
- Thin Solid Films, Vol. 518, Issue 14, p. 3710-3715
Ruthenium-Based Heterocyclic Carbene-Coordinated Olefin Metathesis Catalysts †
journal, March 2010
- Vougioukalakis, Georgios C.; Grubbs, Robert H.
- Chemical Reviews, Vol. 110, Issue 3
Cyclopolymerization of N , N -Dipropargylamines and N , N -Dipropargyl Ammonium Salts
journal, March 2008
- Vygodskii, Yakov S.; Shaplov, Alexander S.; Lozinskaya, Elena I.
- Macromolecules, Vol. 41, Issue 6
Thermodynamic Properties of Block Copolymer Electrolytes Containing Imidazolium and Lithium Salts
journal, October 2010
- Wanakule, Nisita S.; Virgili, Justin M.; Teran, Alexander A.
- Macromolecules, Vol. 43, Issue 19
Bioinspired Colloidal Photonic Crystals with Controllable Wettability
journal, June 2011
- Wang, Jingxia; Zhang, Youzhuan; Wang, Shutao
- Accounts of Chemical Research, Vol. 44, Issue 6
Metal cluster enhanced organic solar cells
journal, February 2000
- Westphalen, M.; Kreibig, U.; Rostalski, J.
- Solar Energy Materials and Solar Cells, Vol. 61, Issue 1, p. 97-105
Efficient Synthesis of Narrowly Dispersed Brush Copolymers and Study of Their Assemblies: The Importance of Side Chain Arrangement
journal, December 2009
- Xia, Yan; Olsen, Bradley D.; Kornfield, Julia A.
- Journal of the American Chemical Society, Vol. 131, Issue 51, p. 18525-18532
Efficient Synthesis of Narrowly Dispersed Brush Polymers via Living Ring-Opening Metathesis Polymerization of Macromonomers
journal, June 2009
- Xia, Yan; Kornfield, Julia A.; Grubbs, Robert H.
- Macromolecules, Vol. 42, Issue 11, p. 3761-3766
Fabrication of Silicon Oxide Nanodots with an Areal Density Beyond 1 Teradots Inch−2
journal, November 2011
- Xu, Ji; Hong, Sung Woo; Gu, Weiyin
- Advanced Materials, Vol. 23, Issue 48, p. 5755-5761
Supramolecular ABC Triblock Copolymers via One-Pot, Orthogonal Self-Assembly
journal, February 2010
- Yang, Si Kyung; Ambade, Ashootosh V.; Weck, Marcus
- Journal of the American Chemical Society, Vol. 132, Issue 5
A Phase Diagram for the Binary Blends of Nearly Symmetric Diblock Copolymers. 1. Parameter Space of Molecular Weight Ratio and Blend Composition †
journal, August 2001
- Yamaguchi, Daisuke; Hashimoto, Takeji
- Macromolecules, Vol. 34, Issue 18
Helical Polymers: Synthesis, Structures, and Functions
journal, November 2009
- Yashima, Eiji; Maeda, Katsuhiro; Iida, Hiroki
- Chemical Reviews, Vol. 109, Issue 11
Self-Assembly of Block Copolymers for Photonic-Bandgap Materials
journal, October 2005
- Yoon, Jongseung; Lee, Wonmok; Thomas, Edwin L.
- MRS Bulletin, Vol. 30, Issue 10
Optically Transparent and High Molecular Weight Polyolefin Block Copolymers toward Self-Assembled Photonic Band Gap Materials
journal, March 2006
- Yoon, Jongseung; Mathers, Robert T.; Coates, Geoffrey W.
- Macromolecules, Vol. 39, Issue 5
Thermochromic Block Copolymer Photonic Gel
journal, July 2008
- Yoon, Jongseung; Lee, Wonmok; Thomas, Edwin L.
- Macromolecules, Vol. 41, Issue 13
Ordered Nanoporous Polymers from Polystyrene−Polylactide Block Copolymers
journal, October 2002
- Zalusky, Andrew S.; Olayo-Valles, Roberto; Wolf, Johanna H.
- Journal of the American Chemical Society, Vol. 124, Issue 43
Cylindrical polymer brushes
journal, January 2005
- Zhang, Mingfu; Müller, Axel H. E.
- Journal of Polymer Science Part A: Polymer Chemistry, Vol. 43, Issue 16, p. 3461-3481
Works referencing / citing this record:
Periodic nanostructures from self assembled wedge-type block-copolymers
patent, June 2015
- Xia, Yan; Sveinbjornsson, Benjamin R.; Grubbs, Robert H.
- US Patent Document 9,045,579