Rapid self-assembly of block copolymers to photonic crystals
Abstract
The invention provides a class of copolymers having useful properties, including brush block copolymers, wedge-type block copolymers and hybrid wedge and polymer block copolymers. In an embodiment, for example, block copolymers of the invention incorporate chemically different blocks comprising polymer size chain groups and/or wedge groups that significantly inhibit chain entanglement, thereby enhancing molecular self-assembly processes for generating a range of supramolecular structures, such as periodic nanostructures and microstructures. The present invention also provides useful methods of making and using copolymers, including block copolymers.
- Inventors:
- Issue Date:
- Research Org.:
- California Institute of Technology (CalTech), Pasadena, CA (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1260251
- Patent Number(s):
- 9382387
- Application Number:
- 13/800,646
- Assignee:
- CALIFORNIA INSTITUTE OF TECHNOLOGY (Pasadena, CA)
- Patent Classifications (CPCs):
-
C - CHEMISTRY C08 - ORGANIC MACROMOLECULAR COMPOUNDS C08G - MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- DOE Contract Number:
- FG02-05ER46218
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 2013 Mar 13
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Xia, Yan, Sveinbjornsson, Benjamin R, Grubbs, Robert H, Weitekamp, Raymond, Miyake, Garret M, Atwater, Harry A, Piunova, Victoria, Daeffler, Christopher Scot, Hong, Sung Woo, Gu, Weiyin, and Russell, Thomas P. Rapid self-assembly of block copolymers to photonic crystals. United States: N. p., 2016.
Web.
Xia, Yan, Sveinbjornsson, Benjamin R, Grubbs, Robert H, Weitekamp, Raymond, Miyake, Garret M, Atwater, Harry A, Piunova, Victoria, Daeffler, Christopher Scot, Hong, Sung Woo, Gu, Weiyin, & Russell, Thomas P. Rapid self-assembly of block copolymers to photonic crystals. United States.
Xia, Yan, Sveinbjornsson, Benjamin R, Grubbs, Robert H, Weitekamp, Raymond, Miyake, Garret M, Atwater, Harry A, Piunova, Victoria, Daeffler, Christopher Scot, Hong, Sung Woo, Gu, Weiyin, and Russell, Thomas P. Tue .
"Rapid self-assembly of block copolymers to photonic crystals". United States. https://www.osti.gov/servlets/purl/1260251.
@article{osti_1260251,
title = {Rapid self-assembly of block copolymers to photonic crystals},
author = {Xia, Yan and Sveinbjornsson, Benjamin R and Grubbs, Robert H and Weitekamp, Raymond and Miyake, Garret M and Atwater, Harry A and Piunova, Victoria and Daeffler, Christopher Scot and Hong, Sung Woo and Gu, Weiyin and Russell, Thomas P.},
abstractNote = {The invention provides a class of copolymers having useful properties, including brush block copolymers, wedge-type block copolymers and hybrid wedge and polymer block copolymers. In an embodiment, for example, block copolymers of the invention incorporate chemically different blocks comprising polymer size chain groups and/or wedge groups that significantly inhibit chain entanglement, thereby enhancing molecular self-assembly processes for generating a range of supramolecular structures, such as periodic nanostructures and microstructures. The present invention also provides useful methods of making and using copolymers, including block copolymers.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Jul 05 00:00:00 EDT 2016},
month = {Tue Jul 05 00:00:00 EDT 2016}
}
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Works referenced in this record:
Tunable Colors in Opals and Inverse Opal Photonic Crystals
journal, July 2010
- Aguirre, Carlos I.; Reguera, Edilso; Stein, Andreas
- Advanced Functional Materials, Vol. 20, Issue 16
Cool surfaces and shade trees to reduce energy use and improve air quality in urban areas
journal, January 2001
- Akbari, H.; Pomerantz, M.; Taha, H.
- Solar Energy, Vol. 70, Issue 3
Self-assembly of block copolymer thin films
journal, June 2010
- Albert, Julie N. L.; Epps, Thomas H.
- Materials Today, Vol. 13, Issue 6, p. 24-33
Rigid Backbone Polymers. 2. Polyisocyanates and Their Liquid-Crystal Behavior
journal, January 1979
- Aharoni, Shaul M.
- Macromolecules, Vol. 12, Issue 1
Plasmonics for improved photovoltaic devices
journal, February 2010
- Atwater, Harry A.; Polman, Albert
- Nature Materials, Vol. 9, Issue 3, p. 205-213
Polymer brushes here, there, and everywhere: Recent advances in their practical applications and emerging opportunities in multiple research fields
journal, May 2012
- Azzaroni, Omar
- Journal of Polymer Science Part A: Polymer Chemistry, Vol. 50, Issue 16
Block Copolymer Nanolithography: Translation of Molecular Level Control to Nanoscale Patterns
journal, July 2009
- Bang, Joona; Jeong, Unyong; Ryu, Du Yeol
- Advanced Materials, Vol. 21, Issue 47, p. 4769-4792
Dual Templating Synthesis of Mesoporous Titanium Nitride Microspheres
journal, August 2009
- Bang, Jin Ho; Suslick, Kenneth S.
- Advanced Materials, Vol. 21, Issue 31, p. 3186-3190
Responsive polymers in controlled drug delivery
journal, November 2008
- Bajpai, A. K.; Shukla, Sandeep K.; Bhanu, Smitha
- Progress in Polymer Science, Vol. 33, Issue 11, p. 1088-1118
Organization of Rigid Wedge−Flexible Coil Block Copolymers into Liquid Crystalline Assembly
journal, May 2005
- Bae, Jinyoung; Kim, Jung-Keun; Oh, Nam-Keun
- Macromolecules, Vol. 38, Issue 10
Modelling of the urban heat island and of its interaction with pollutant dispersal
journal, January 1982
- Bennett, M.; Saab, A. E.
- Atmospheric Environment (1967), Vol. 16, Issue 8, p. 1797-1822
Thickness Dependence of the Optical Properties of Ordered Silica-Air and Air-Polymer Photonic Crystals
journal, July 1999
- Bertone, Jane F.; Jiang, Peng; Hwang, Kevin S.
- Physical Review Letters, Vol. 83, Issue 2
Living ring-opening metathesis polymerization
journal, January 2007
- Bielawski, Christopher W.; Grubbs, Robert H.
- Progress in Polymer Science, Vol. 32, Issue 1, p. 1-29
Self-aligned self assembly of multi-nanowire silicon field effect transistors
journal, October 2005
- Black, C. T.
- Applied Physics Letters, Vol. 87, Issue 16
Integration of self-assembled diblock copolymers for semiconductor capacitor fabrication
journal, July 2001
- Black, C. T.; Guarini, K. W.; Milkove, K. R.
- Applied Physics Letters, Vol. 79, Issue 3, p. 409-411
Microporous materials: Electrochemically grown photonic crystals
journal, December 1999
- Braun, Paul V.; Wiltzius, Pierre
- Nature, Vol. 402, Issue 6762, p. 603-604
Fabrication of photonic crystals for the visible spectrum by holographic lithography
journal, March 2000
- Campbell, M.; Sharp, D. N.; Harrison, M. T.
- Nature, Vol. 404, Issue 6773, p. 53-56
Static and dynamic properties of two-dimensional polymer melts
journal, January 1990
- Carmesin, I.; Kremer, Kurt
- Journal de Physique, Vol. 51, Issue 10
Intramolecular Hydroamination of Aminoalkynes with Silver−Phenanthroline Catalysts
journal, September 2008
- Carney, Jeffrey M.; Donoghue, Patrick J.; Wuest, William M.
- Organic Letters, Vol. 10, Issue 17
Formation of a Cobalt Magnetic Dot Array via Block Copolymer Lithography
journal, August 2001
- Cheng, J.Y.; Ross, C.A.; Chan, V.Z.-H.
- Advanced Materials, Vol. 13, Issue 15, p. 1174-1178
Templated Self-Assembly of Block Copolymers: Top-Down Helps Bottom-Up
journal, October 2006
- Cheng, J. Y.; Ross, C. A.; Smith, H. I.
- Advanced Materials, Vol. 18, Issue 19, p. 2505-2521
Oligosaccharide/Silicon-Containing Block Copolymers with 5 nm Features for Lithographic Applications
journal, March 2012
- Cushen, Julia D.; Otsuka, Issei; Bates, Christopher M.
- ACS Nano, Vol. 6, Issue 4
Interdiffusion and self‐diffusion in polymer mixtures: A Monte Carlo study
journal, February 1991
- Deutsch, H. P.; Binder, K.
- The Journal of Chemical Physics, Vol. 94, Issue 3
Polymer-based photonic crystals
conference, January 2003
- Torres, C. S.; Chigrin, D.; Vivas, J.
- 2003 International Conference on Transparent Optical Networks - ICTON 2003, Proceedings of 2003 5th International Conference on Transparent Optical Networks, 2003.
Design Considerations for Plasmonic Photovoltaics
journal, September 2010
- Ferry, Vivian E.; Munday, Jeremy N.; Atwater, Harry A.
- Advanced Materials, Vol. 22, Issue 43, p. 4794-4808
Block copolymers as photonic bandgap materials
journal, November 1999
- Fink, Y.; Urbas, A. M.; Bawendi, M. G.
- Journal of Lightwave Technology, Vol. 17, Issue 11, p. 1963-1969
Self-Assembled Photonic Structures
journal, September 2010
- Galisteo-López, Juan F.; Ibisate, Marta; Sapienza, Riccardo
- Advanced Materials, Vol. 23, Issue 1, p. 30-69
Synthesis of Molecular Brushes by “Grafting onto” Method: Combination of ATRP and Click Reactions
journal, May 2007
- Gao, Haifeng; Matyjaszewski, Krzysztof
- Journal of the American Chemical Society, Vol. 129, Issue 20
Responsive Photonic Crystals
journal, January 2011
- Ge, Jianping; Yin, Yadong
- Angewandte Chemie International Edition, Vol. 50, Issue 7, p. 1492-1522
The packing of soft materials: Molecular asymmetry, geometric frustration and optimal lattices in block copolymer melts
journal, October 2006
- Grason, G.
- Physics Reports, Vol. 433, Issue 1
The Macromolecular Route to Chiral Amplification
journal, November 1999
- Green, Mark M.; Park, Ji-Woong; Sato, Takahiro
- Angewandte Chemie International Edition, Vol. 38, Issue 21, p. 3138-3154
Macromolecular stereochemistry: the out-of-proportion influence of optically active comonomers on the conformational characteristics of polyisocyanates. The sergeants and soldiers experiment
journal, August 1989
- Green, Mark M.; Reidy, Michael P.; Johnson, Robert D.
- Journal of the American Chemical Society, Vol. 111, Issue 16, p. 6452-6454
Global Change and the Ecology of Cities
journal, February 2008
- Grimm, N. B.; Faeth, S. H.; Golubiewski, N. E.
- Science, Vol. 319, Issue 5864
The Strength of the Macromonomer Strategy for Complex Macromolecular Architecture: Molecular Characterization, Properties and Applications of Polymacromonomers
journal, November 2003
- Hadjichristidis, Nikos; Pitsikalis, Marinos; Iatrou, Hermis
- Macromolecular Rapid Communications, Vol. 24, Issue 17
Ordered structure in blends of block copolymers. 1. Miscibility criterion for lamellar block copolymers
journal, May 1993
- Hashimoto, Takeji; Yamasaki, Komei; Koizumi, Satoshi
- Macromolecules, Vol. 26, Issue 11
Block Copolymer Lithography: Merging “Bottom-Up” with “Top-Down” Processes
journal, December 2005
- Hawker, Craig J.; Russell, Thomas P.
- MRS Bulletin, Vol. 30, Issue 12, p. 952-966
Synthesis of α-Norbornenylpoly(ethylene oxide) Macromonomers and Their Ring-Opening Metathesis Polymerization
journal, January 1996
- Heroguez, Valérie; Breunig, Stefan; Gnanou, Yves
- Macromolecules, Vol. 29, Issue 13
Linear Rheological Response of a Series of Densely Branched Brush Polymers
journal, September 2011
- Hu, Miao; Xia, Yan; McKenna, Gregory B.
- Macromolecules, Vol. 44, Issue 17, p. 6935-6943
Photonic Polyethylene from Self-Assembled Mesophases of Polydisperse Olefin Block Copolymers
journal, June 2009
- Hustad, Phillip D.; Marchand, Gary R.; Garcia-Meitin, Eddy I.
- Macromolecules, Vol. 42, Issue 11
Fabricating complex three-dimensional nanostructures with high-resolution conformable phase masks
journal, August 2004
- Jeon, S.; Park, J.-U.; Cirelli, R.
- Proceedings of the National Academy of Sciences, Vol. 101, Issue 34, p. 12428-12433
Patterned polymer growth on silicon surfaces using microcontact printing and surface-initiated polymerization
journal, December 1999
- Jeon, Noo Li; Choi, Insung S.; Whitesides, George M.
- Applied Physics Letters, Vol. 75, Issue 26
Drug-Loaded, Bivalent-Bottle-Brush Polymers by Graft-through ROMP
journal, December 2010
- Johnson, Jeremiah A.; Lu, Ying Y.; Burts, Alan O.
- Macromolecules, Vol. 43, Issue 24
Core-Clickable PEG- Branch -Azide Bivalent-Bottle-Brush Polymers by ROMP: Grafting-Through and Clicking-To
journal, January 2011
- Johnson, Jeremiah A.; Lu, Ying Y.; Burts, Alan O.
- Journal of the American Chemical Society, Vol. 133, Issue 3
Phase Behavior and Morphological Characteristics of Compositionally Symmetric Diblock Copolymer Blends
journal, January 1996
- Kane, Lisaleigh; Satkowski, Michael M.; Smith, Steven D.
- Macromolecules, Vol. 29, Issue 27
Broad-wavelength-range chemically tunable block-copolymer photonic gels
journal, October 2007
- Kang, Youngjong; Walish, Joseph J.; Gorishnyy, Taras
- Nature Materials, Vol. 6, Issue 12
Full Color Stop Bands in Hybrid Organic/Inorganic Block Copolymer Photonic Gels by Swelling−Freezing
journal, June 2009
- Kang, Changjoon; Kim, Eunjoo; Baek, Heeyoel
- Journal of the American Chemical Society, Vol. 131, Issue 22
Ultrafast Cyclopolymerization for Polyene Synthesis: Living Polymerization to Dendronized Polymers
journal, August 2011
- Kang, Eun-Hye; Lee, In Sun; Choi, Tae-Lim
- Journal of the American Chemical Society, Vol. 133, Issue 31
Conformational Properties of Cylindrical Rod Brushes Consisting of a Polystyrene Main Chain and Poly( n -hexyl isocyanate) Side Chains
journal, September 2008
- Kikuchi, Moriya; Lien, Le Thi Ngoc; Narumi, Atsushi
- Macromolecules, Vol. 41, Issue 17
Simple Synthesis of Poly(acetylene) Latex Particles in Aqueous Media
journal, December 2003
- Krause, Jens O.; Zarka, M. Tobias; Anders, Udo
- Angewandte Chemie International Edition, Vol. 42, Issue 48, p. 5965-5969
Hetero-Grafted Block Brushes with PCL and PBA Side Chains
journal, August 2008
- Lee, Hyung-il; Matyjaszewski, Krzysztof; Yu-Su, Sherryl
- Macromolecules, Vol. 41, Issue 16
Synthesis of (Poly(chloroethyl vinyl ether)- g -polystyrene)comb- b -(poly(chloropyran ethoxy vinyl ether)- g -polyisoprene)comb Copolymers and Study of Hyper-Branched Micelle Formation in Dilute Solutions
journal, July 2007
- Lanson, David; Schappacher, Michel; Borsali, Redouane
- Macromolecules, Vol. 40, Issue 15
Poly(styrene)comb- b -Poly(ethylene oxide)comb Copolymers: Synthesis and AFM Investigation of Intra- and Supramolecular Organization as Thin Deposits
journal, December 2007
- Lanson, David; Schappacher, Michel; Borsali, Redouane
- Macromolecules, Vol. 40, Issue 26
Quasi-Amorphous Colloidal Structures for Electrically Tunable Full-Color Photonic Pixels with Angle-Independency
journal, August 2010
- Lee, Insook; Kim, Daihyun; Kal, Jinha
- Advanced Materials, Vol. 22, Issue 44, p. 4973-4977
Theory of Microphase Separation in Block Copolymers
journal, November 1980
- Leibler, Ludwik
- Macromolecules, Vol. 13, Issue 6
A three-dimensional photonic crystal operating at infrared wavelengths
journal, July 1998
- Lin, S. Y.; Fleming, J. G.; Hetherington, D. L.
- Nature, Vol. 394, Issue 6690, p. 251-253
Plasmonic nanocavity arrays for enhanced efficiency in organic photovoltaic cells
journal, September 2008
- Lindquist, Nathan C.; Luhman, Wade A.; Oh, Sang-Hyun
- Applied Physics Letters, Vol. 93, Issue 12
Hierarchical self-assembly of metal nanostructures on diblock copolymer scaffolds
journal, December 2001
- Lopes, Ward A.; Jaeger, Heinrich M.
- Nature, Vol. 414, Issue 6865, p. 735-738
A Practical and Highly Active Ruthenium-Based Catalyst that Effects the Cross Metathesis of Acrylonitrile
journal, November 2002
- Love, Jennifer A.; Morgan, John P.; Trnka, Tina M.
- Angewandte Chemie International Edition, Vol. 41, Issue 21
Synthesis of Fluorine-18 Functionalized Nanoparticles for use as in vivo Molecular Imaging Agents
journal, May 2008
- Matson, John B.; Grubbs, Robert H.
- Journal of the American Chemical Society, Vol. 130, Issue 21
Chiral polyisocyanates, a special class of helical polymers
journal, December 2001
- Mayer, Sabine; Zentel, Rudolf
- Progress in Polymer Science, Vol. 26, Issue 10, p. 1973-2013
Structure−Property Relations in Cholesteric Networks from Chiral Polyisocyanates
journal, September 1999
- Maxein, Georg; Mayer, Sabine; Zentel, Rudolf
- Macromolecules, Vol. 32, Issue 18
Opalescent Cholesteric Networks from Chiral Polyisocyanates in Polystyrene
journal, March 1998
- Maxein, Georg; Keller, Harald; Novak, Bruce M.
- Advanced Materials, Vol. 10, Issue 4, p. 341-345
Theory of the grafted polymer brush
journal, August 1988
- Milner, S. T.; Witten, T. A.; Cates, M. E.
- Macromolecules, Vol. 21, Issue 8
Synthesis of Isocyanate-Based Brush Block Copolymers and Their Rapid Self-Assembly to Infrared-Reflecting Photonic Crystals
journal, August 2012
- Miyake, Garret M.; Weitekamp, Raymond A.; Piunova, Victoria A.
- Journal of the American Chemical Society, Vol. 134, Issue 34
Precisely Tunable Photonic Crystals From Rapidly Self-Assembling Brush Block Copolymer Blends
journal, September 2012
- Miyake, Garret M.; Piunova, Victoria A.; Weitekamp, Raymond A.
- Angewandte Chemie International Edition, Vol. 51, Issue 45, p. 11246-11248
Stereospecific Polymerization of Chiral Oxazolidinone-Functionalized Alkenes
journal, September 2010
- Miyake, Garret M.; DiRocco, Daniel A.; Liu, Qin
- Macromolecules, Vol. 43, Issue 18
Chemical Aspects of Three-Dimensional Photonic Crystals
journal, January 2010
- Moon, Jun Hyuk; Yang, Shu
- Chemical Reviews, Vol. 110, Issue 1
Polymerization of Macromonomers to Cylindrical Brushes Initiated by Organolanthanides
journal, June 2003
- Neiser, Michael W.; Okuda, Jun; Schmidt, Manfred
- Macromolecules, Vol. 36, Issue 15
How dense are cylindrical brushes grafted from a multifunctional macroinitiator?
journal, November 2004
- Neugebauer, Dorota; Sumerlin, Brent S.; Matyjaszewski, Krzysztof
- Polymer, Vol. 45, Issue 24, p. 8173-8179
Modeling the Dynamic Behavior of Diblock Copolymer/Particle Composites
journal, August 2000
- Ginzburg, Valeriy V.; Gibbons, Corey; Qiu, Feng
- Macromolecules, Vol. 33, Issue 16
Safe and Convenient Procedure for Solvent Purification
journal, January 1996
- Pangborn, Amy B.; Giardello, Michael A.; Grubbs, Robert H.
- Organometallics, Vol. 15, Issue 5, p. 1518-1520
Nanostructured polymers for photonics
journal, April 2008
- Paquet, Chantal; Kumacheva, Eugenia
- Materials Today, Vol. 11, Issue 4, p. 48-56
Enabling nanotechnology with self assembled block copolymer patterns
journal, October 2003
- Park, Cheolmin; Yoon, Jongseung; Thomas, Edwin L.
- Polymer, Vol. 44, Issue 22, p. 6725-6760
Macroscopic 10-Terabit-per-Square-Inch Arrays from Block Copolymers with Lateral Order
journal, February 2009
- Park, Soojin; Lee, Dong Hyun; Xu, Ji
- Science, Vol. 323, Issue 5917, p. 1030-1033
"Living" titanium(IV) catalyzed coordination polymerizations of isocyanates
journal, June 1991
- Patten, Timothy E.; Novak, Bruce M.
- Journal of the American Chemical Society, Vol. 113, Issue 13, p. 5065-5066
Living Organotitanium(IV)-Catalyzed Polymerizations of Isocyanates
journal, January 1996
- Patten, Timothy E.; Novak, Bruce M.
- Journal of the American Chemical Society, Vol. 118, Issue 8
Impact of regional climate change on human health
journal, November 2005
- Patz, Jonathan A.; Campbell-Lendrum, Diarmid; Holloway, Tracey
- Nature, Vol. 438, Issue 7066
Aluminum nanowire polarizing grids: Fabrication and analysis
journal, May 2006
- Pelletier, Vincent; Asakawa, Koji; Wu, Mingshaw
- Applied Physics Letters, Vol. 88, Issue 21, Article No. 211114
Surface Urban Heat Island Across 419 Global Big Cities
journal, December 2011
- Peng, Shushi; Piao, Shilong; Ciais, Philippe
- Environmental Science & Technology, Vol. 46, Issue 2
Cyclic Block Copolymers for Controlling Feature Sizes in Block Copolymer Lithography
journal, November 2012
- Poelma, Justin E.; Ono, Kosuke; Miyajima, Daigo
- ACS Nano, Vol. 6, Issue 12
A review on the generation, determination and mitigation of Urban Heat Island
journal, January 2008
- Rizwan, Ahmed Memon; Dennis, Leung Y. C.; Liu, Chunho
- Journal of Environmental Sciences, Vol. 20, Issue 1, p. 120-128
Synthesis of High Molecular Weight Comb Block Copolymers and Their Assembly into Ordered Morphologies in the Solid State
journal, August 2007
- Runge, M. Brett; Bowden, Ned B.
- Journal of the American Chemical Society, Vol. 129, Issue 34
Investigation of the Assembly of Comb Block Copolymers in the Solid State
journal, October 2008
- Runge, M. Brett; Lipscomb, Corinne E.; Ditzler, Lindsay R.
- Macromolecules, Vol. 41, Issue 20
Synthesis of Polymer Dielectric Layers for Organic Thin Film Transistors via Surface-Initiated Ring-Opening Metathesis Polymerization
journal, April 2004
- Rutenberg, Isaac M.; Scherman, Oren A.; Grubbs, Robert H.
- Journal of the American Chemical Society, Vol. 126, Issue 13
Synthesis of Polystyrene−Polylactide Bottlebrush Block Copolymers and Their Melt Self-Assembly into Large Domain Nanostructures
journal, March 2009
- Rzayev, Javid
- Macromolecules, Vol. 42, Issue 6
Patterning with block copolymer thin films
journal, February 2005
- Segalman, Rachel A.
- Materials Science and Engineering: R: Reports, Vol. 48, Issue 6, p. 191-226
Chiroptical Properties of Graft Copolymers Containing Chiral Poly( n -hexyl isocyanate) as a Side Chain
journal, October 2011
- Shah, Priyank N.; Min, Joonkeun; Kim, Hyung-Jin
- Macromolecules, Vol. 44, Issue 20
Visualization of MacromoleculesA First Step to Manipulation and Controlled Response
journal, December 2001
- Sheiko, Sergei S.; Möller, Martin
- Chemical Reviews, Vol. 101, Issue 12
The Ring Opening Metathesis Polymerisation Toolbox
journal, July 2004
- Slugovc, Christian
- Macromolecular Rapid Communications, Vol. 25, Issue 14
Modular and Dynamic Functionalization of Polymeric Scaffolds
journal, January 2007
- South, Clinton R.; Burd, Caroline; Weck, Marcus
- Accounts of Chemical Research, Vol. 40, Issue 1
Block copolymers and conventional lithography
journal, September 2006
- Stoykovich, Mark P.; Nealey, Paul F.
- Materials Today, Vol. 9, Issue 9, p. 20-29
Initiation Efficiency in the Synthesis of Molecular Brushes by Grafting from via Atom Transfer Radical Polymerization
journal, February 2005
- Sumerlin, Brent S.; Neugebauer, Dorota; Matyjaszewski, Krzysztof
- Macromolecules, Vol. 38, Issue 3
Rapid self-assembly of brush block copolymers to photonic crystals
journal, August 2012
- Sveinbjornsson, B. R.; Weitekamp, R. A.; Miyake, G. M.
- Proceedings of the National Academy of Sciences, Vol. 109, Issue 36, p. 14332-14336
Solvent Accelerated Polymer Diffusion in Thin Films
journal, May 2005
- Thompson, Richard L.; McDonald, Martin T.; Lenthall, Joseph T.
- Macromolecules, Vol. 38, Issue 10
Ultrahigh-Density Nanowire Arrays Grown in Self-Assembled Diblock Copolymer Templates
journal, December 2000
- Thurn-Albrecht, T.; Schotter, J.; Kastle, G. A.
- Science, Vol. 290, Issue 5499, p. 2126-2129
Transfer-matrix formalism for the calculation of optical response in multilayer systems: from coherent to incoherent interference
journal, January 2010
- Troparevsky, M. Claudia; Sabau, Adrian S.; Lupini, Andrew R.
- Optics Express, Vol. 18, Issue 24
Block Copolymer Nanostructures for Technology
journal, October 2010
- Tseng, Yu-Chih; Darling, Seth B.
- Polymers, Vol. 2, Issue 4
Self-assembled polymeric solid films with temperature-induced large and reversible photonic-bandgap switching
journal, November 2004
- Valkama, Sami; Kosonen, Harri; Ruokolainen, Janne
- Nature Materials, Vol. 3, Issue 12
Perpendicular orientation of cylindrical domains upon solvent annealing thin films of polystyrene-b-polylactide
journal, May 2010
- Vayer, Marylène; Hillmyer, Marc A.; Dirany, Mohammed
- Thin Solid Films, Vol. 518, Issue 14, p. 3710-3715
Ruthenium-Based Heterocyclic Carbene-Coordinated Olefin Metathesis Catalysts †
journal, March 2010
- Vougioukalakis, Georgios C.; Grubbs, Robert H.
- Chemical Reviews, Vol. 110, Issue 3
Cyclopolymerization of N , N -Dipropargylamines and N , N -Dipropargyl Ammonium Salts
journal, March 2008
- Vygodskii, Yakov S.; Shaplov, Alexander S.; Lozinskaya, Elena I.
- Macromolecules, Vol. 41, Issue 6
Thermodynamic Properties of Block Copolymer Electrolytes Containing Imidazolium and Lithium Salts
journal, October 2010
- Wanakule, Nisita S.; Virgili, Justin M.; Teran, Alexander A.
- Macromolecules, Vol. 43, Issue 19
Bioinspired Colloidal Photonic Crystals with Controllable Wettability
journal, June 2011
- Wang, Jingxia; Zhang, Youzhuan; Wang, Shutao
- Accounts of Chemical Research, Vol. 44, Issue 6
Metal cluster enhanced organic solar cells
journal, February 2000
- Westphalen, M.; Kreibig, U.; Rostalski, J.
- Solar Energy Materials and Solar Cells, Vol. 61, Issue 1, p. 97-105
Efficient Synthesis of Narrowly Dispersed Brush Copolymers and Study of Their Assemblies: The Importance of Side Chain Arrangement
journal, December 2009
- Xia, Yan; Olsen, Bradley D.; Kornfield, Julia A.
- Journal of the American Chemical Society, Vol. 131, Issue 51, p. 18525-18532
Efficient Synthesis of Narrowly Dispersed Brush Polymers via Living Ring-Opening Metathesis Polymerization of Macromonomers
journal, June 2009
- Xia, Yan; Kornfield, Julia A.; Grubbs, Robert H.
- Macromolecules, Vol. 42, Issue 11, p. 3761-3766
Fabrication of Silicon Oxide Nanodots with an Areal Density Beyond 1 Teradots Inch−2
journal, November 2011
- Xu, Ji; Hong, Sung Woo; Gu, Weiyin
- Advanced Materials, Vol. 23, Issue 48, p. 5755-5761
Supramolecular ABC Triblock Copolymers via One-Pot, Orthogonal Self-Assembly
journal, February 2010
- Yang, Si Kyung; Ambade, Ashootosh V.; Weck, Marcus
- Journal of the American Chemical Society, Vol. 132, Issue 5
A Phase Diagram for the Binary Blends of Nearly Symmetric Diblock Copolymers. 1. Parameter Space of Molecular Weight Ratio and Blend Composition †
journal, August 2001
- Yamaguchi, Daisuke; Hashimoto, Takeji
- Macromolecules, Vol. 34, Issue 18
Helical Polymers: Synthesis, Structures, and Functions
journal, November 2009
- Yashima, Eiji; Maeda, Katsuhiro; Iida, Hiroki
- Chemical Reviews, Vol. 109, Issue 11
Self-Assembly of Block Copolymers for Photonic-Bandgap Materials
journal, October 2005
- Yoon, Jongseung; Lee, Wonmok; Thomas, Edwin L.
- MRS Bulletin, Vol. 30, Issue 10
Optically Transparent and High Molecular Weight Polyolefin Block Copolymers toward Self-Assembled Photonic Band Gap Materials
journal, March 2006
- Yoon, Jongseung; Mathers, Robert T.; Coates, Geoffrey W.
- Macromolecules, Vol. 39, Issue 5
Ordered Nanoporous Polymers from Polystyrene−Polylactide Block Copolymers
journal, October 2002
- Zalusky, Andrew S.; Olayo-Valles, Roberto; Wolf, Johanna H.
- Journal of the American Chemical Society, Vol. 124, Issue 43
Cylindrical polymer brushes
journal, January 2005
- Zhang, Mingfu; Müller, Axel H. E.
- Journal of Polymer Science Part A: Polymer Chemistry, Vol. 43, Issue 16, p. 3461-3481
Multifunctional organic polymers
patent, October 1995
- Hubbell, Jeffrey A.; Elbert, Donald; Hill-West, Jennifer L.
- US Patent Document 5,462,990
Nanoparticles and microparticles of non-linear hydrophilic-hydrophobic multiblock copolymers
patent, December 1999
- Domb, Abraham J.; Gref, Ruxandra; Minamitake, Yoshiharu
- US Patent Document 6,007,845
Particles comprising amphiphilic copolymers, having a crosslinked shell domain and an interior core domain, useful for pharmaceutical and other applications
patent, May 2002
- Wooley, Karen L.; Thurmond, K. Bruce; Huang, Haiyong Hugh
- US Patent Document 6,383,500
(Co)polymers and a novel polymerization process based on atom (or group) transfer radical polymerization
patent, June 2002
- Matyjaszewski, Krzysztof; Wang, Jin-Shan
- US Patent Document 6,407,187
Polymeric photonic band gap materials
patent, August 2002
- Fink, Yoel; Thomas, Edwin L.
- US Patent Document 6,433,931
Preparation of nanocomposite structures by controlled polymerization
patent, September 2003
- Matyjaszewski, Krzysztof; Pyun, Jeffrey
- US Patent Document 6,627,314
Polymeric photonic band gap materials
patent, December 2003
- Fink, Yoel; Thomas, Edwin L.
- US Patent Document 6,671,097
Polymer brushes for immobilizing molecules to a surface or substrate, where the polymers have water-soluble or water-dispersible segments and probes bonded thereto
patent, February 2004
- Klaerner, Gerrit; Nielsen, Ralph B.; Mansky, Paul
- US Patent Document 6,692,914
Dendritic based macromolecules
patent, September 2006
- Frechet, Jean M. J.; Hawker, Craig J.; Wooley, Karen L.
- US Patent Document 7,101,937
Preparation of functional polymers
patent, September 2010
- Matyjaszewski, Krzyszlof; Sumerlin, Brent S.; Tsarevsky, Nicolay
- US Patent Document 7,795,355
Brush copolymers
patent, June 2011
- Cheng, Chong; Khoshdel, Ezat; Wooley, Karen L.
- US Patent Document 7,960,479
Polymer particles having polymer brush and method of preparing the same
patent, April 2013
- Han, Bo-ryeong; Chun, Moon Seok; Park, Dong-Seek
- US Patent Document 8,415,436
Brush copolymers
patent, April 2013
- Vanderbilt, David P.; Valint, Jr., Paul L.
- US Patent Document 8,419,792
Brush copolymers
patent, June 2013
- Vanderbilt, David P.; Valint, Jr., Paul L.
- US Patent Document 8,454,689
Polymeric photonic band gap materials
patent-application, September 2002
- Fink, Yoel; Thomas, Edwin L.
- US Patent Application 10/146775; 20020135880
Inorganic block co-polymers and other similar materials as ceramic precursors for nanoscale ordered high-temperature ceramics
patent-application, May 2007
- Wan, Julin; Malenfant, Patrick Roland Lucien; Manoharan, Mohan
- US Patent Application 11/488521; 20070099791
Periodic Nanostructures From Self Assembled Wedge-Type Block-Copolymers
patent-application, November 2013
- Xia, Yan; Sveinbjornsson, Benjamin R.; Grubbs, Robert H.
- US Patent Application 13/801710; 20130296491
Photonic structures from self assembly of brush block copolymers and polymer blends
patent-application, January 2014
- Miyake, Garret M.; Weitekamp, Raymond; Grubbs, Robert H.
- US Patent Application 13/930400; 20140011958