Photobiomolecular deposition of metallic particles and films
Abstract
The method of the invention is based on the unique electron-carrying function of a photocatalytic unit such as the photosynthesis system I (PSI) reaction center of the protein-chlorophyll complex isolated from chloroplasts. The method employs a photo-biomolecular metal deposition technique for precisely controlled nucleation and growth of metallic clusters/particles, e.g., platinum, palladium, and their alloys, etc., as well as for thin-film formation above the surface of a solid substrate. The photochemically mediated technique offers numerous advantages over traditional deposition methods including quantitative atom deposition control, high energy efficiency, and mild operating condition requirements.
- Inventors:
- Issue Date:
- Research Org.:
- Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1175232
- Patent Number(s):
- 6852425
- Application Number:
- 10/369,818
- Assignee:
- Ut-Battelle, LLC (Oak Ridge, TN)
- Patent Classifications (CPCs):
-
B - PERFORMING OPERATIONS B82 - NANOTECHNOLOGY B82Y - SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES
C - CHEMISTRY C23 - COATING METALLIC MATERIAL C23C - COATING METALLIC MATERIAL
- Resource Type:
- Patent
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 59 BASIC BIOLOGICAL SCIENCES
Citation Formats
Hu, Zhong-Cheng. Photobiomolecular deposition of metallic particles and films. United States: N. p., 2005.
Web.
Hu, Zhong-Cheng. Photobiomolecular deposition of metallic particles and films. United States.
Hu, Zhong-Cheng. Tue .
"Photobiomolecular deposition of metallic particles and films". United States. https://www.osti.gov/servlets/purl/1175232.
@article{osti_1175232,
title = {Photobiomolecular deposition of metallic particles and films},
author = {Hu, Zhong-Cheng},
abstractNote = {The method of the invention is based on the unique electron-carrying function of a photocatalytic unit such as the photosynthesis system I (PSI) reaction center of the protein-chlorophyll complex isolated from chloroplasts. The method employs a photo-biomolecular metal deposition technique for precisely controlled nucleation and growth of metallic clusters/particles, e.g., platinum, palladium, and their alloys, etc., as well as for thin-film formation above the surface of a solid substrate. The photochemically mediated technique offers numerous advantages over traditional deposition methods including quantitative atom deposition control, high energy efficiency, and mild operating condition requirements.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2005},
month = {2}
}
Works referenced in this record:
[26] Subchloroplast fragments: Digitonin method
book, January 1971
- Boardman, N. K.
- Methods in Enzymology
Contribution to the structural characterization of eucaryotic PSI reaction centre ? II. Characterization of a highly purified photoactive SDS-CP1 complex
journal, January 1980
- Setif, Pierre; Acker, Suzanne; Lagoutte, Bernard
- Photosynthesis Research, Vol. 1, Issue 1
Biomolecular electronics: observation of oriented photocurrents by entrapped platinized chloroplasts
journal, April 1989
- Greenbaum, E.
- Bioelectrochemistry and Bioenergetics, Vol. 21, Issue 2
Molecular electronics of a single photosystem I reaction center: studies with scanning tunneling microscopy and spectroscopy.
journal, March 1995
- Lee, I.; Lee, J. W.; Warmack, R. J.
- Proceedings of the National Academy of Sciences, Vol. 92, Issue 6
Photosynthetic Water Splitting: In situ Photoprecipitation of Metallocatalysts for Photoevolution of Hydrogen and Oxygen
journal, May 1994
- Lee, James W.; Tevault, Carol V.; Blankinship, Steve L.
- Energy & Fuels, Vol. 8, Issue 3
Vectorial photocurrents and photoconductivity in metalized chloroplasts
journal, August 1990
- Greenbaum, Elias.
- The Journal of Physical Chemistry, Vol. 94, Issue 16
[8] Higher plant chloroplasts and grana: General preparative procedures (excluding high carbon dioxide fixation ability chloroplasts)
book, January 1980
- Reeves, S. G.; Hall, D. O.
- Methods in Enzymology
Kinetic studies of interfacial photocurrents in platinized chloroplasts
journal, January 1992
- Greenbaum, Elias
- The Journal of Physical Chemistry, Vol. 96, Issue 2
Interfacial photoreactions at the photosynthetic membrane interface: an upper limit for the number of platinum atoms required to form a hydrogen-evolving platinum metal catalyst
journal, August 1988
- Greenbaum, E.
- The Journal of Physical Chemistry, Vol. 92, Issue 16
Platinized Chloroplasts: A Novel Photocatalytic Material
journal, December 1985
- Greenbaum, E.
- Science, Vol. 230, Issue 4732
Photobioelectronic studies with thylakoid membranes
journal, January 1989
- Greenbaum, E.
- Applied Biochemistry and Biotechnology, Vol. 20-21, Issue 1
Platinization: a novel technique to anchor photosystem I reaction centres onto a metal surface at biological temperature and pH
journal, January 1996
- Lee, James W.; Lee, Ida; Greenbaum, Elias
- Biosensors and Bioelectronics, Vol. 11, Issue 4
Bioelectronics and biometallocatalysis for production of fuels and chemicals by photosynthetic water splitting
journal, September 1995
- Lee, James Weifu; Greenbaum, Elias
- Applied Biochemistry and Biotechnology, Vol. 51-52, Issue 1