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Title: Compositions having reduced thermal conductivities and methods of making the same

Patent ·
OSTI ID:2293740

The present disclosure relates to a composition that includes a film having a network of randomly aligned carbon nanotubes, where the carbon nanotubes have an average diameter between about 0.6 nm and about 2.0 nm and the carbon nanotubes form bundles having an average diameter between about 3 nm and about 50 nm. In addition, the composition is characterized by a power factor α2σ between 1 μW/mK2 and about 3500 μW/mK2 and by ZT=α2σT/k between about 0.02 and about 2.0 over a temperature range between about 100 K and about 500 K.

Research Organization:
National Renewable Energy Laboratory (NREL), Golden, CO (United States); Univ. of Denver, CO (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
AC36-08GO28308
Assignee:
Alliance for Sustainable Energy, LLC (Golden, CO); University of Denver (Denver, CO)
Patent Number(s):
11,787,697
Application Number:
17/474,409
OSTI ID:
2293740
Resource Relation:
Patent File Date: 09/14/2021
Country of Publication:
United States
Language:
English

References (19)

Carbon-Nanotube-Based Thermoelectric Materials and Devices journal January 2018
Thermoelectric Properties of Carbon Nanotubes journal November 2019
Heat conduction in carbon nanotube materials: Strong effect of intrinsic thermal conductivity of carbon nanotubes journal July 2012
Diameter Enlargement of HiPco Single-Wall Carbon Nanotubes by Heat Treatment journal September 2001
Observation of extreme phase transition temperatures of water confined inside isolated carbon nanotubes journal November 2016
Intrinsic and Extrinsically Limited Thermoelectric Transport within Semiconducting Single‐Walled Carbon Nanotube Networks journal February 2019
Modulation of thermal and thermoelectric transport in individual carbon nanotubes by fullerene encapsulation journal July 2017
Turning Carbon Nanotubes from Exceptional Heat Conductors into Insulators journal March 2009
Customizing the Polarity of Single‐Walled Carbon‐Nanotube Field‐Effect Transistors Using Solution‐Based Additives journal November 2019
Thermal conductivity of micromachined low-stress silicon-nitride beams from 77 to 325 K journal February 2009
Tailored semiconducting carbon nanotube networks with enhanced thermoelectric properties journal April 2016
Polymer-Free Carbon Nanotube Thermoelectrics with Improved Charge Carrier Transport and Power Factor journal November 2016
Upper bound to the thermal conductivity of carbon nanotube pellets journal April 2009
CNT fibers p-doped with F4TCNQ (2,3,5,6-Tetrafluoro-7,7,8,8-tetracyanoquinodimethane) conference August 2017
Determining absolute Seebeck coefficients from relative thermopower measurements of thin films and nanostructures journal February 2020
Phonons in carbon nanotubes journal September 2000
Large n- and p-type thermoelectric power factors from doped semiconducting single-walled carbon nanotube thin films journal January 2017
Thermal and electrical conductivity of approximately 100-nm permalloy, Ni, Co, Al, and Cu films and examination of the Wiedemann-Franz Law journal December 2015
Heat transport by long mean free path vibrations in amorphous silicon nitride near room temperature journal June 2013

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