External-Field-Induced Phase Transformation and Associated Properties in a Ni50Mn34Fe3In13 Metamagnetic Shape Memory Wire

Chen, Zhen; Cong, Daoyong; Li, Shilei; Zhang, Yin; Li, Shaohui; Cao, Yuxian; Li, Shengwei; Song, Chao; Ren, Yang; Wang, Yandong

doi:10.3390/met11020309

Title: External-Field-Induced Phase Transformation and Associated Properties in a Ni₅₀Mn₃₄Fe₃In₁₃ Metamagnetic Shape Memory Wire

Journal Article · Wed Feb 10 00:00:00 EST 2021 · Metals

DOI:https://doi.org/10.3390/met11020309· OSTI ID:1797818

^[1]; Cong, Daoyong ^[1];

^[1]; Zhang, Yin ^[1]; Li, Shaohui ^[1]; Cao, Yuxian ^[1]; Li, Shengwei ^[1]; Song, Chao ^[1];

^[2]; Wang, Yandong ^[1]

Univ. of Science and Technology, Beijing (China)
Argonne National Lab. (ANL), Argonne, IL (United States)

Metamagnetic shape memory alloys exhibit a series of intriguing multifunctional properties and have great potential for applications in magnetic actuation, sensing and magnetic refrigeration. However, the poor mechanical properties of these alloys with hardly any tensile deformability seriously limit their practical application. In the present work, we developed a Ni-Fe-Mn-In microwire that exhibits both a giant, tensile superelasticity and a magnetic-field-induced first-order phase transformation. The recoverable strain of superelasticity is more than 20% in the temperature range of 233–283 K, which is the highest recoverable strain reported heretofore in Ni-Mn-based shape memory alloys (SMAs). Moreover, the present microwire exhibits a large shape memory effect with a recoverable strain of up to 13.9% under the constant tensile stress of 225 MPa. As a result of the magnetic-field-induced first-order phase transformation, a large reversible magnetocaloric effect with an isothermal entropy change ΔS_m of 15.1 J kg^–1 K^–1 for a field change from 0.2 T to 5 T was achieved in this microwire. The realization of both magnetic-field and tensile-stress-induced transformations confers on this microwire great potential for application in miniature multi-functional devices and provides an opportunity for multi-functional property optimization under coupled multiple fields.

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Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities Division; National Natural Science Foundation of China (NSFC); Fundamental Research Funds for the Central Universities; Funds for Creative Research Groups of China

Grant/Contract Number:: AC02-06CH11357; 51731005; 51822102; 52031005; 51831003; 51527801; 51921001; FRF-TP-18-008C1

OSTI ID:: 1797818

Journal Information:: Metals, Vol. 11, Issue 2; ISSN 2075-4701

Publisher:: MDPICopyright Statement

Country of Publication:: United States

Language:: English

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36 MATERIALS SCIENCE
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superelasticity

Title: External-Field-Induced Phase Transformation and Associated Properties in a Ni50Mn34Fe3In13 Metamagnetic Shape Memory Wire

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Title: External-Field-Induced Phase Transformation and Associated Properties in a Ni₅₀Mn₃₄Fe₃In₁₃ Metamagnetic Shape Memory Wire