Magnetic field-induced magnetostructural transition and huge tensile superelasticity in an oligocrystalline Ni–Cu–Co–Mn–In microwire

Chen, Zhen; Cong, Daoyong; Sun, Xiaoming; Zhang, Yin; Yan, Haile; Li, Shaohui; Li, Runguang; Nie, Zhihua; Ren, Yang; Wang, Yandong

doi:10.1107/s2052252519009102

Magnetic field-induced magnetostructural transition and huge tensile superelasticity in an oligocrystalline Ni–Cu–Co–Mn–In microwire

Journal Article · Thu Jul 11 00:00:00 EDT 2019 · IUCrJ

DOI:https://doi.org/10.1107/s2052252519009102· OSTI ID:1625825

Chen, Zhen ^[1]; Cong, Daoyong ^[2]; Sun, Xiaoming ^[2]; Zhang, Yin ^[2]; Yan, Haile ^[3]; ^[2]; Li, Runguang ^[2]; Nie, Zhihua ^[4]; Ren, Yang ^[5]; Wang, Yandong ^[2]

Beijing Advanced Innovation Center for Materials Genome Engineering, State Key Laboratory for Advanced Metals and Materials, University of Science and Technology Beijing, People’s Republic of China; DOE/OSTI
Beijing Advanced Innovation Center for Materials Genome Engineering, State Key Laboratory for Advanced Metals and Materials, University of Science and Technology Beijing, People’s Republic of China
Key Laboratory for Anisotropy and Texture of Materials (Ministry of Education), Northeastern University, Shenyang, People’s Republic of China
School of Materials Science and Engineering, Beijing Institute of Technology, Beijing, People’s Republic of China
Argonne National Lab. (ANL), Argonne, IL (United States). X-Ray Science Division

Meta-magnetic shape-memory alloys combine ferroelastic order with ferromagnetic order and exhibit attractive multifunctional properties, but they are extremely brittle, showing hardly any tensile deformability, which impedes their practical application. Here, for the first time, an Ni–Cu–Co–Mn–In microwire has been developed that simultaneously exhibits a magnetic field-induced first-order meta-magnetic phase transition and huge tensile superelasticity. A temperature-dependentin situsynchrotron high-energy X-ray diffraction investigation reveals that the martensite of this Ni_43.7Cu_1.5Co_5.1Mn_36.7In₁₃microwire shows a monoclinic six-layered modulated structure and the austenite shows a cubic structure. This microwire exhibits an oligocrystalline structure with bamboo grains, which remarkably reduces the strain incompatibility during deformation and martensitic transformation. As a result, huge tensile superelasticity with a recoverable strain of 13% is achieved in the microwire. This huge tensile superelasticity is in agreement with our theoretical calculations based on the crystal structure and lattice correspondence of austenite and martensite and the crystallographic orientation of the grains. Owing to the large magnetization difference between austenite and martensite, a pronounced magnetic field-induced magnetostructural transition is achieved in the microwire, which could give rise to a variety of magnetically driven functional properties. For example, a large magnetocaloric effect with an isothermal entropy change of 12.7 J kg^-1 K^-1(under 5 T) is obtained. The realization of magnetic-field- and tensile-stress-induced structural transformations in the microwire may pave the way for exploiting the multifunctional properties under the coupling of magnetic field and stress for applications in miniature multifunctional devices.

View Accepted Manuscript (DOE)

Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); National Natural Science Foundation of China; Fundamental Research Funds for the Central Universities

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1625825

Journal Information:: IUCrJ, Journal Name: IUCrJ Journal Issue: 5 Vol. 6; ISSN IUCRAJ; ISSN 2052-2525

Publisher:: International Union of CrystallographyCopyright Statement

Country of Publication:: United States

Language:: English

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Magnetic field-induced magnetostructural transition and huge tensile superelasticity in an oligocrystalline Ni–Cu–Co–Mn–In microwire

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