Gas Sensing Properties of Epitaxial LaBaCo2O5.5+δ Thin Films

Liu, M.; Ren, S. P.; Zhang, R. Y.; Xue, Z. Y.; Ma, C. R.; Yin, M. L.; Xu, X.; Bao, S. Y.; Chen, C. L.

doi:10.1038/srep10784

Title: Gas Sensing Properties of Epitaxial LaBaCo₂O_5.5+δ Thin Films

Journal Article · Mon Jul 06 00:00:00 EDT 2015 · Scientific Reports

DOI:https://doi.org/10.1038/srep10784· OSTI ID:1624772

Liu, M. ^[1]; Ren, S. P. ^[1]; Zhang, R. Y. ^[1]; Xue, Z. Y. ^[1]; Ma, C. R. ^[1]; Yin, M. L. ^[2]; Xu, X. ^[3]; Bao, S. Y. ^[3]; Chen, C. L. ^[4]

Xi’an Jiaotong Univ. (China)
Xi’an Technological Univ. (China)
Univ. of Texas at San Antonio, TX (United States)
Univ. of Texas at San Antonio, TX (United States); Univ. of Houston, TX (United States)

Chemical reactivity and stability of highly epitaxial mixed-conductive LaBaCo₂O_5.5+δ (LBCO) thin films on (001) LaAlO₃ (LAO) single-crystalline substrates, fabricated by using pulsed laser deposition system, were systematically investigated. Microstructure studies from x-ray diffraction indicate that the films are c-axis oriented with the interface relationship of [100]_LBCO//[100]_LAO and (001)_LBCO//(001)_LAO. LBCO thin films can detect the ethanol vapor concentration as low as 10ppm and the response of LBCO thin film to various ethanol vapor concentrations is very reliable and reproducible with the switch between air and ethanol vapor. Moreover, the fast response of the LBCO thin film, as the p-type gas sensor, is better than some n-type oxide semiconductor thin films and comparable with some nanorods and nanowires. These findings indicate that the LBCO thin films have great potential for the development of gas sensors in reducing/oxidizing environments.

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Research Organization:: Univ. of Texas at San Antonio, TX (United States)

Sponsoring Organization:: USDOE Office of Fossil Energy (FE); Natural Science Foundation of China; Fundamental Research Funds for the Central University; National Science Foundation (NSF); State of Texas; Foundation of Shaanxi Educational Committee

Grant/Contract Number:: FE0003780; 51202185; 51390472; 51471169; 11028409; NSF-NIRT-0709293; 14JK1331

OSTI ID:: 1624772

Journal Information:: Scientific Reports, Vol. 5, Issue 1; ISSN 2045-2322

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 28 works

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