Manipulation of Optical Transmittance by Ordered-Oxygen-Vacancy in Epitaxial LaBaCo2O5.5+δ Thin Films

Cheng, Sheng; Lu, Jiangbo; Han, Dong; Liu, Ming; Lu, Xiaoli; Ma, Chunrui; Zhang, Shengbai; Chen, Chonglin

doi:10.1038/srep37496

Title: Manipulation of Optical Transmittance by Ordered-Oxygen-Vacancy in Epitaxial LaBaCo₂O_5.5+δ Thin Films

Journal Article · Wed Nov 23 00:00:00 EST 2016 · Scientific Reports

DOI:https://doi.org/10.1038/srep37496· OSTI ID:1430215

Cheng, Sheng ^[1]; Lu, Jiangbo ^[1]; Han, Dong ^[2]; Liu, Ming ^[1]; Lu, Xiaoli ^[3]; Ma, Chunrui ^[4]; Zhang, Shengbai ^[5]; Chen, Chonglin ^[6]

Xi'an Jiaotong Univ., Xi'an (China). School of Electronic and Information Engineering
Chinese Academy of Sciences, Changchun (China). Changchun Inst. of Optics, Fine Mechanics and Physics and State Key Lab. of Luminescence and Applications
Xidian Univ., Xi'an (China). School of Microelectronics and State Key Discipline Lab. of Wide Band Gap Semiconductor Technology
Xi'an Jiaotong Univ., Xi'an (China). State Key Lab. for Mechanical Behavior of Materials
Rensselaer Polytechnic Inst., Troy, NY (United States). Dept. of Physics, Applied Physics, and Astronomy
Univ. of Texas, San Antonio, TX (United States). Dept. of Physics and Astronomy; Univ. of Houston, TX (United States). The Texas Center for Superconductivity

Giant optical transmittance changes of over 300% in wide wavelength range from 500 nm to 2500 nm were observed in LaBaCo₂O_5.5+δ thin films annealed in air and ethanol ambient, respectively. The reduction process induces high density of ordered oxygen vacancies and the formation of LaBaCo₂O_5.5 (δ = 0) structure evidenced by aberration-corrected transmission electron microscopy. Moreover, the first-principles calculations reveal the origin and mechanism of optical transmittance enhancement in LaBaCo₂O_5.5 (δ = 0), which exhibits quite different energy band structure compared to that of LaBaCo₂O₆ (δ = 0.5). The discrepancy of energy band structure was thought to be the direct reason for the enhancement of optical transmission in reducing ambient. Thus, LaBaCo₂O_5.5+δ thin films show great prospect for applications on optical gas sensors in reducing/oxidizing atmosphere.

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Research Organization:: Rensselaer Polytechnic Inst., Troy, NY (United States)

Sponsoring Organization:: USDOE; National Natural Science Foundation of China (NSFC); National Basic Research Program of China

Grant/Contract Number:: SC0002623; 51202185; 51390472; 51501143; 2015CB654903; 11504368; 51572211; 51202176

OSTI ID:: 1430215

Journal Information:: Scientific Reports, Vol. 6, Issue 1; ISSN 2045-2322

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 4 works

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Title: Manipulation of Optical Transmittance by Ordered-Oxygen-Vacancy in Epitaxial LaBaCo₂O_5.5+δ Thin Films