Lignin as a bioactive polymer and heavy metal absorber- an overview
Abstract
As a pulping and bio-refinery by-product with phenolic chemical structure, lignin indicated high potential as natural antioxidant activity, UV blocker, antibacterial and toxic material absorbent properties. Presence of phenolic hydroxyl groups in lignin structure plays the main role of its antioxidant activity. However, lignin antioxidant power can change depending on its other structural features and functional groups like ortho-methoxy groups, –OCH3 groups, the α-CH2 groups, the aliphatic carbonyl groups, and the size of π-conjugated systems. Lignin in mixture with synthetic polymers, improved their thermal stability. Lignin has high UV light absorbing potential in broad-spectrum (UVA, UVB). Adding 1–5% of lignin into hand cream indicated excellent range of sun protection factor (SPF) with more than 95% UV light absorption. Lignin also indicated strong UV light protection when applied in different transparent film and protect paint, oil, and varnish from UV degradation. Further, lignosulfonate and other modified lignin including chemically modification, nano-particles and lignin hydrogel indicated high potential as heavy metal absorber.
- Authors:
-
[1];
[2]
- Hollingsworth & Vose, Groton, MA (United States)
- Univ. of Tennessee, Knoxville, TN (United States); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Publication Date:
- Research Org.:
- Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1896978
- Grant/Contract Number:
- AC05-00OR22725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Chemosphere
- Additional Journal Information:
- Journal Volume: 309; Journal Issue: 1; Journal ID: ISSN 0045-6535
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; Lignin; Antioxidant; UV absorber; Heavy metal; Natural polymer; Bio-refinery
Citation Formats
Sadeghifar, Hasan, and Ragauskas, Arthur. Lignin as a bioactive polymer and heavy metal absorber- an overview. United States: N. p., 2022.
Web. doi:10.1016/j.chemosphere.2022.136564.
Sadeghifar, Hasan, & Ragauskas, Arthur. Lignin as a bioactive polymer and heavy metal absorber- an overview. United States. https://doi.org/10.1016/j.chemosphere.2022.136564
Sadeghifar, Hasan, and Ragauskas, Arthur. Thu .
"Lignin as a bioactive polymer and heavy metal absorber- an overview". United States. https://doi.org/10.1016/j.chemosphere.2022.136564. https://www.osti.gov/servlets/purl/1896978.
@article{osti_1896978,
title = {Lignin as a bioactive polymer and heavy metal absorber- an overview},
author = {Sadeghifar, Hasan and Ragauskas, Arthur},
abstractNote = {As a pulping and bio-refinery by-product with phenolic chemical structure, lignin indicated high potential as natural antioxidant activity, UV blocker, antibacterial and toxic material absorbent properties. Presence of phenolic hydroxyl groups in lignin structure plays the main role of its antioxidant activity. However, lignin antioxidant power can change depending on its other structural features and functional groups like ortho-methoxy groups, –OCH3 groups, the α-CH2 groups, the aliphatic carbonyl groups, and the size of π-conjugated systems. Lignin in mixture with synthetic polymers, improved their thermal stability. Lignin has high UV light absorbing potential in broad-spectrum (UVA, UVB). Adding 1–5% of lignin into hand cream indicated excellent range of sun protection factor (SPF) with more than 95% UV light absorption. Lignin also indicated strong UV light protection when applied in different transparent film and protect paint, oil, and varnish from UV degradation. Further, lignosulfonate and other modified lignin including chemically modification, nano-particles and lignin hydrogel indicated high potential as heavy metal absorber.},
doi = {10.1016/j.chemosphere.2022.136564},
journal = {Chemosphere},
number = 1,
volume = 309,
place = {United States},
year = {Thu Sep 22 00:00:00 EDT 2022},
month = {Thu Sep 22 00:00:00 EDT 2022}
}
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Antioxidant Activity of Lignin Phenolic Compounds Extracted from Kraft and Sulphite Black Liquors
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Influence of extraction methods on antimicrobial activities of lignin-based materials: A review
journal, December 2020
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Softwood kraft lignin: Raw material for the future
journal, December 2015
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Antioxidant PLA Composites Containing Lignin for 3D Printing Applications: A Potential Material for Healthcare Applications
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Investigation of the effects of different organosolv pulping methods on antioxidant capacity and extraction efficiency of lignin
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Poly (ethylene imine) anchored lignin composite for heavy metals capturing in water
journal, February 2017
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Antioxidant activities of lignin extracted from sugarcane bagasse via different chemical procedures
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Preparation and Application of Light-Colored Lignin Nanoparticles for Broad-Spectrum Sunscreens
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Sustainable and Antioxidant Lignin–Polyester Copolymers and Nanofibers for Potential Healthcare Applications
journal, June 2017
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Analytical Methods Used in Determining Antioxidant Activity: A Review
journal, March 2021
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Cellulose-Lignin Biodegradable and Flexible UV Protection Film
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Fabrication of a green porous lignin-based sphere for the removal of lead ions from aqueous media
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The heterogeneity of two Canadian kraft lignins
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Potential antioxidants for biodiesel from a softwood lignin pyrolyzate
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