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Title: Lignin as a UV Light Blocker—A Review

Abstract

Lignin is the by-product of pulp and paper industries and bio-refining operations. It is available as the leading natural phenolic biopolymer in the market. It has chromophore functional groups and can absorb a broad spectrum of UV light in range of 250–400 nm. Using lignin as a natural ingredient in sunscreen cream, transparent film, paints, varnishes and microorganism protection has been actively investigated. Both in non-modified and modified forms, lignin provides enhancing UV protection of commercial products with less than a 10% blend with other material. In mixtures with other synthetic UV blockers, lignin indicated synergic effects and increased final UV blocking potential in compare with using only synthetic UV blocker or lignin. However, using lignin as a UV blocker is also challenging due to its complex structure, polydispersity in molecular weight, brownish color and some impurities that require more research in order to make it an ideal bio-based UV blocker.

Authors:
 [1]; ORCiD logo [2]
  1. Hollingsworth & Vose (H&V) Company, West Groton, MA (United States)
  2. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Univ. of Tennessee, Knoxville, TN (United States)
Publication Date:
Research Org.:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1631220
Grant/Contract Number:  
AC05-00OR22725
Resource Type:
Accepted Manuscript
Journal Name:
Polymers
Additional Journal Information:
Journal Volume: 12; Journal Issue: 5; Journal ID: ISSN 2073-4360
Publisher:
MDPI
Country of Publication:
United States
Language:
English
Subject:
59 BASIC BIOLOGICAL SCIENCES

Citation Formats

Sadeghifar, Hasan, and Ragauskas, Arthur. Lignin as a UV Light Blocker—A Review. United States: N. p., 2020. Web. https://doi.org/10.3390/polym12051134.
Sadeghifar, Hasan, & Ragauskas, Arthur. Lignin as a UV Light Blocker—A Review. United States. https://doi.org/10.3390/polym12051134
Sadeghifar, Hasan, and Ragauskas, Arthur. Fri . "Lignin as a UV Light Blocker—A Review". United States. https://doi.org/10.3390/polym12051134. https://www.osti.gov/servlets/purl/1631220.
@article{osti_1631220,
title = {Lignin as a UV Light Blocker—A Review},
author = {Sadeghifar, Hasan and Ragauskas, Arthur},
abstractNote = {Lignin is the by-product of pulp and paper industries and bio-refining operations. It is available as the leading natural phenolic biopolymer in the market. It has chromophore functional groups and can absorb a broad spectrum of UV light in range of 250–400 nm. Using lignin as a natural ingredient in sunscreen cream, transparent film, paints, varnishes and microorganism protection has been actively investigated. Both in non-modified and modified forms, lignin provides enhancing UV protection of commercial products with less than a 10% blend with other material. In mixtures with other synthetic UV blockers, lignin indicated synergic effects and increased final UV blocking potential in compare with using only synthetic UV blocker or lignin. However, using lignin as a UV blocker is also challenging due to its complex structure, polydispersity in molecular weight, brownish color and some impurities that require more research in order to make it an ideal bio-based UV blocker.},
doi = {10.3390/polym12051134},
journal = {Polymers},
number = 5,
volume = 12,
place = {United States},
year = {2020},
month = {5}
}

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Works referenced in this record:

Lignin Valorization: Improving Lignin Processing in the Biorefinery
journal, May 2014

  • Ragauskas, A. J.; Beckham, G. T.; Biddy, M. J.
  • Science, Vol. 344, Issue 6185, p. 1246843-1246843
  • DOI: 10.1126/science.1246843

Quantitative Phosphorus-31 NMR Analysis of Lignins, a New Tool for the Lignin Chemist
journal, February 1994


Lignin−Quinone Interactions: Implications for Optical Properties of Lignin
journal, February 2003

  • Barsberg, S.; Elder, T.; Felby, C.
  • Chemistry of Materials, Vol. 15, Issue 3
  • DOI: 10.1021/cm021162s

Preparation of Highly Reactive Lignin by Ozone Oxidation: Application as Surfactants with Antioxidant and Anti-UV Properties
journal, December 2019


Thermal, antioxidant and swelling behaviour of transparent polyvinyl (alcohol) films in presence of hydrophobic citric acid-modified lignin nanoparticles
journal, April 2019


Ecofriendly UV-protective films based on poly(propylene carbonate) biocomposites filled with TiO2 decorated lignin
journal, April 2019


Preparation of organic acid lignin submicrometer particle as a natural broad-spectrum photo-protection agent
journal, July 2019


Towards better UV-blocking and antioxidant performance of varnish via additives based on lignin and its colloids
journal, May 2019


Preparation and characterisation of lignin nanoparticles: evaluation of their potential as antioxidants and UV protectants
journal, June 2015


Use of Agave tequilana-lignin and zinc oxide nanoparticles for skin photoprotection
journal, October 2016

  • Gutiérrez-Hernández, José Manuel; Escalante, Alfredo; Murillo-Vázquez, Raquel Nalleli
  • Journal of Photochemistry and Photobiology B: Biology, Vol. 163
  • DOI: 10.1016/j.jphotobiol.2016.08.027

Microporous titanate nanofibers for highly efficient UV-protective transparent coating
journal, January 2014

  • Hattori, H.; Ide, Y.; Sano, T.
  • J. Mater. Chem. A, Vol. 2, Issue 39
  • DOI: 10.1039/C4TA02975E

Preparation of Lignin-Based Superplasticizer by Graft Sulfonation and Investigation of the Dispersive Performance and Mechanism in a Cementitious System
journal, November 2013

  • Lou, Hongming; Lai, Huanran; Wang, Mengxia
  • Industrial & Engineering Chemistry Research, Vol. 52, Issue 46
  • DOI: 10.1021/ie402169g

Nanolignin Modified Linen Fabric as a Multifunctional Product
journal, April 2008

  • Zimniewska, M.; Kozłowski, R.; Batog, J.
  • Molecular Crystals and Liquid Crystals, Vol. 484, Issue 1
  • DOI: 10.1080/15421400801903395

Lignin: a nature-inspired sun blocker for broad-spectrum sunscreens
journal, January 2015

  • Qian, Yong; Qiu, Xueqing; Zhu, Shiping
  • Green Chemistry, Vol. 17, Issue 1
  • DOI: 10.1039/C4GC01333F

Review: Light-Induced Yellowing of Lignocellulosic Pulps – Mechanisms and Preventive Methods
journal, August 2012


Development of agri-biomass based lignin derived zinc oxide nanocomposites as promising UV protectant-cum-antimicrobial agents
journal, January 2020

  • Kaur, Ravneet; Thakur, Neeraj Singh; Chandna, Sanjam
  • Journal of Materials Chemistry B, Vol. 8, Issue 2
  • DOI: 10.1039/C9TB01569H

Structural characterization of Kraft lignins from different spent cooking liquors by 1D and 2D Nuclear Magnetic Resonance spectroscopy
journal, April 2014


Kinetic study of the photostabilisation of polypropylene films by an hydroxyphenylbenzotriazole
journal, April 1999


Non-flammable and moisture-permeable UV protection films only from plant polymers and clay minerals
journal, January 2019

  • Shikinaka, Kazuhiro; Nakamura, Masaya; Navarro, Ronald R.
  • Green Chemistry, Vol. 21, Issue 3
  • DOI: 10.1039/C8GC03765E

Skin photoprotection by natural polyphenols: anti-inflammatory, antioxidant and DNA repair mechanisms
journal, November 2009


Enhancing the Broad-Spectrum Adsorption of Lignin through Methoxyl Activation, Grafting Modification, and Reverse Self-Assembly
journal, August 2019


In vitro determination of sun protection factor and chemical stability of Rosa kordesii extract gel
journal, June 2013

  • Maske, Pratik P.; Lokapure, Sachin G.; Nimbalkar, Dhanashri
  • Journal of Pharmacy Research, Vol. 7, Issue 6
  • DOI: 10.1016/j.jopr.2013.05.021

All Biomass and UV Protective Composite Composed of Compatibilized Lignin and Poly (Lactic-acid)
journal, March 2017

  • Kim, Youngjun; Suhr, Jonghwan; Seo, Hee-Won
  • Scientific Reports, Vol. 7, Issue 1
  • DOI: 10.1038/srep43596

Biodegradable and High-Performance Poly(butylene adipate- co -terephthalate)–Lignin UV-Blocking Films
journal, September 2017


Crosslinking of lignin/poly(vinyl alcohol) nanocomposite fiber webs and their antimicrobial and ultraviolet-protective properties
journal, October 2017


Poly(methyl methacrylate) films reinforced with coconut shell lignin fractions to enhance their UV-blocking, antioxidant and thermo-mechanical properties
journal, March 2019

  • Avelino, Francisco; de Oliveira, Davi Rabelo; Mazzetto, Selma Elaine
  • International Journal of Biological Macromolecules, Vol. 125
  • DOI: 10.1016/j.ijbiomac.2018.12.043

Black Tea and Lignin as Ultraviolet Protectants for the Beet Armyworm Nucleopolyhedrovirus
journal, January 2009


Control of Apple Blue Mold by the Antagonistic Yeast Pichia anomala Strain K: Screening of UV Protectants for Preharvest Application
journal, March 2011

  • Lahlali, Rachid; Brostaux, Yves; Jijakli, M. Haissam
  • Plant Disease, Vol. 95, Issue 3
  • DOI: 10.1094/PDIS-04-10-0265

Sunscreen Performance of Lignin from Different Technical Resources and Their General Synergistic Effect with Synthetic Sunscreens
journal, May 2016


Review of current and future softwood kraft lignin process chemistry
journal, September 2004


Preparation and Application of Light-Colored Lignin Nanoparticles for Broad-Spectrum Sunscreens
journal, March 2020


High-value utilization of kraft lignin: Color reduction and evaluation as sunscreen ingredient
journal, July 2019


Cellulose-Lignin Biodegradable and Flexible UV Protection Film
journal, November 2016


Transparent and Homogenous Cellulose Nanocrystal/Lignin UV-Protection Films
journal, September 2018


Laccase-Catalyzed Synthesis of Low-Molecular-Weight Lignin-Like Oligomers and their Application as UV-Blocking Materials
journal, January 2018

  • Lim, Jieyan; Sana, Barindra; Krishnan, Ranganathan
  • Chemistry - An Asian Journal, Vol. 13, Issue 3
  • DOI: 10.1002/asia.201701573

Ionic Liquid Stabilized Gelatin-Lignin Films: A Potential UV-Shielding Material with Excellent Mechanical and Antimicrobial Properties
journal, December 2018


Binary and ternary sustainable composites of gellan gum, hydroxyethyl cellulose and lignin for food packaging applications: Biocompatibility, antioxidant activity, UV and water barrier properties
journal, June 2020

  • Rukmanikrishnan, Balasubramanian; Ramalingam, Srinivasan; Rajasekharan, Satish Kumar
  • International Journal of Biological Macromolecules, Vol. 153
  • DOI: 10.1016/j.ijbiomac.2020.03.016

Transparent UV-absorbers thin films of zinc oxide: Ceria system synthesized via sol–gel process
journal, November 2012

  • Lima, Juliana Fonseca de; Martins, Renata Figueredo; Serra, Osvaldo Antonio
  • Optical Materials, Vol. 35, Issue 1
  • DOI: 10.1016/j.optmat.2012.06.016

Assessment of extracts of Helichrysum arenarium, Crataegus monogyna, Sambucus nigra in photoprotective UVA and UVB; photostability in cosmetic emulsions
journal, November 2013


Facile and Green Preparation of High UV-Blocking Lignin/Titanium Dioxide Nanocomposites for Developing Natural Sunscreens
journal, October 2018

  • Yu, Jue; Li, Lan; Qian, Yong
  • Industrial & Engineering Chemistry Research, Vol. 57, Issue 46
  • DOI: 10.1021/acs.iecr.8b04101

Determination of active HALS in automotive paint systems II: HALS distribution in weathered clearcoat/basecoat paint systems
journal, January 2001