Robust perfluorinated porous organic networks: Succinct synthetic strategy and application in chlorofluorocarbons adsorption
Abstract
Fluorinated porous organic networks (F-PONs) have demonstrated unique properties and applications, but approaches capable of affording F-PONs with high fluorine content and robust nanoporous architecture under metal-free and easy handling conditions are still rarely reported. Herein, using polydivinylbenzene (PDVB) as an easily available precursor, a novel and straightforward approach was developed to afford F-PONs via a dehydrative Friedel-Crafts reaction using perfluorinated benzylic alcohols as the cross-linking agent promoted by Brønsted acid (trifluoromethanesulfonic acid. Furthermore, the afforded material (F-PDVB) featured high fluorine content (22 at.%), large surface area (771 m2∙g-1), and good chemical/thermal stability, rendering them as promising candidates for the adsorption of CO2, hydrocarbons, fluorocarbons, and chlorofluorocarbons, with weight capacities up to 520 wt% being achieved. This simple methodology can be extended to fabricate fluorinated hyper-crosslinked polymers (F-HCPs) from rigid aromatic monomers. The progress made in this work will open new opportunities to further expand the involvement of fluorinated materials in large scale applications.
- Authors:
-
[2];
[3];
[2];
[4]
- Nanjing Tech Univ. (China). Jiangsu Collaborative Innovation Center for Advanced Inorganic Function Composites, Jiangsu National Synergetic Innovation Center for Advanced Materials (SICAM)
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Univ. of Tennessee, Knoxville, TN (United States)
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Univ. of Tennessee, Knoxville, TN (United States)
- Publication Date:
- Research Org.:
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division
- OSTI Identifier:
- 1814319
- Grant/Contract Number:
- AC05-00OR22725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Nano Research
- Additional Journal Information:
- Journal Volume: 14; Journal Issue: 9; Journal ID: ISSN 1998-0124
- Publisher:
- Springer
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 77 NANOSCIENCE AND NANOTECHNOLOGY; fluorinated; porous organic networks; Friedel-Crafts reaction; hyper-crosslinked polymers; chlorofluorocarbons
Citation Formats
Luo, Yali, Yang, Zhenzhen, Suo, Xian, Chen, Hao, Wang, Tao, Wang, Ziqian, Liu, Yunfei, Lyu, Yinong, Popovs, Ilja, and Dai, Sheng. Robust perfluorinated porous organic networks: Succinct synthetic strategy and application in chlorofluorocarbons adsorption. United States: N. p., 2021.
Web. doi:10.1007/s12274-021-3339-6.
Luo, Yali, Yang, Zhenzhen, Suo, Xian, Chen, Hao, Wang, Tao, Wang, Ziqian, Liu, Yunfei, Lyu, Yinong, Popovs, Ilja, & Dai, Sheng. Robust perfluorinated porous organic networks: Succinct synthetic strategy and application in chlorofluorocarbons adsorption. United States. https://doi.org/10.1007/s12274-021-3339-6
Luo, Yali, Yang, Zhenzhen, Suo, Xian, Chen, Hao, Wang, Tao, Wang, Ziqian, Liu, Yunfei, Lyu, Yinong, Popovs, Ilja, and Dai, Sheng. Sat .
"Robust perfluorinated porous organic networks: Succinct synthetic strategy and application in chlorofluorocarbons adsorption". United States. https://doi.org/10.1007/s12274-021-3339-6. https://www.osti.gov/servlets/purl/1814319.
@article{osti_1814319,
title = {Robust perfluorinated porous organic networks: Succinct synthetic strategy and application in chlorofluorocarbons adsorption},
author = {Luo, Yali and Yang, Zhenzhen and Suo, Xian and Chen, Hao and Wang, Tao and Wang, Ziqian and Liu, Yunfei and Lyu, Yinong and Popovs, Ilja and Dai, Sheng},
abstractNote = {Fluorinated porous organic networks (F-PONs) have demonstrated unique properties and applications, but approaches capable of affording F-PONs with high fluorine content and robust nanoporous architecture under metal-free and easy handling conditions are still rarely reported. Herein, using polydivinylbenzene (PDVB) as an easily available precursor, a novel and straightforward approach was developed to afford F-PONs via a dehydrative Friedel-Crafts reaction using perfluorinated benzylic alcohols as the cross-linking agent promoted by Brønsted acid (trifluoromethanesulfonic acid. Furthermore, the afforded material (F-PDVB) featured high fluorine content (22 at.%), large surface area (771 m2∙g-1), and good chemical/thermal stability, rendering them as promising candidates for the adsorption of CO2, hydrocarbons, fluorocarbons, and chlorofluorocarbons, with weight capacities up to 520 wt% being achieved. This simple methodology can be extended to fabricate fluorinated hyper-crosslinked polymers (F-HCPs) from rigid aromatic monomers. The progress made in this work will open new opportunities to further expand the involvement of fluorinated materials in large scale applications.},
doi = {10.1007/s12274-021-3339-6},
journal = {Nano Research},
number = 9,
volume = 14,
place = {United States},
year = {Sat Feb 06 00:00:00 EST 2021},
month = {Sat Feb 06 00:00:00 EST 2021}
}
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