Hyper-crosslinked β-cyclodextrin porous polymer: an adsorption-facilitated molecular catalyst support for transformation of water-soluble aromatic molecules
Abstract
A hyper-crosslinked β-cyclodextrin porous polymer (BnCD-HCPP) was designed and synthesized facilely by β-cyclodextrin benzylation and subsequent crosslinking via a Friedel–Crafts alkylation route. The BnCD-HCPP shows an extremely high BET surface area, large pore volume, and high thermal stability, making it a highly efficient adsorbent for removal of aromatic pollutants from water. The adsorption efficiency in terms of distribution coefficient, defined as the ratio of adsorption capacity to equilibrium adsorbate concentration, ranged from 103 to 106 mL g-1 within a concentration of 0–100 ppm, one order of magnitude higher than that of other β-cyclodextrin-based adsorbents reported previously. The molar percentage of adsorbate to β-cyclodextrin exceeded 300%, suggesting that the adsorption occurred not only in the cyclodextrin cavities via a 1 : 1 complexation, but also in the nanopores of the BnCD-HCPP created during the hyper-crosslinking. The BnCD-HCPP can be further functionalized by incorporation of gold nanoparticles for catalytic transformation of adsorbed phenolic compounds such as 4-nitrophenol to 4-aminophenol.
- Authors:
-
[2];
- East China University of Science and Technology, Shanghai (China); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Univ. of Tennessee, Knoxville, TN (United States)
- East China University of Science and Technology, Shanghai (China)
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Univ. of Tennessee, Knoxville, TN (United States)
- Publication Date:
- Research Org.:
- Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES); National Basic Research Program of China; National Natural Science Foundation of China (NSFC); 111 Project of China; Fundamental Research Funds for the Central Universities of China; USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division
- OSTI Identifier:
- 1624929
- Grant/Contract Number:
- AC05-00OR22725; 2013CB733501; 913342903; B08021
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Chemical Science
- Additional Journal Information:
- Journal Volume: 7; Journal Issue: 2; Journal ID: ISSN 2041-6520
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; Chemistry
Citation Formats
Li, Haiying, Meng, Bo, Chai, Song-Hai, Liu, Honglai, and Dai, Sheng. Hyper-crosslinked β-cyclodextrin porous polymer: an adsorption-facilitated molecular catalyst support for transformation of water-soluble aromatic molecules. United States: N. p., 2015.
Web. doi:10.1039/c5sc04034e.
Li, Haiying, Meng, Bo, Chai, Song-Hai, Liu, Honglai, & Dai, Sheng. Hyper-crosslinked β-cyclodextrin porous polymer: an adsorption-facilitated molecular catalyst support for transformation of water-soluble aromatic molecules. United States. https://doi.org/10.1039/c5sc04034e
Li, Haiying, Meng, Bo, Chai, Song-Hai, Liu, Honglai, and Dai, Sheng. Fri .
"Hyper-crosslinked β-cyclodextrin porous polymer: an adsorption-facilitated molecular catalyst support for transformation of water-soluble aromatic molecules". United States. https://doi.org/10.1039/c5sc04034e. https://www.osti.gov/servlets/purl/1624929.
@article{osti_1624929,
title = {Hyper-crosslinked β-cyclodextrin porous polymer: an adsorption-facilitated molecular catalyst support for transformation of water-soluble aromatic molecules},
author = {Li, Haiying and Meng, Bo and Chai, Song-Hai and Liu, Honglai and Dai, Sheng},
abstractNote = {A hyper-crosslinked β-cyclodextrin porous polymer (BnCD-HCPP) was designed and synthesized facilely by β-cyclodextrin benzylation and subsequent crosslinking via a Friedel–Crafts alkylation route. The BnCD-HCPP shows an extremely high BET surface area, large pore volume, and high thermal stability, making it a highly efficient adsorbent for removal of aromatic pollutants from water. The adsorption efficiency in terms of distribution coefficient, defined as the ratio of adsorption capacity to equilibrium adsorbate concentration, ranged from 103 to 106 mL g-1 within a concentration of 0–100 ppm, one order of magnitude higher than that of other β-cyclodextrin-based adsorbents reported previously. The molar percentage of adsorbate to β-cyclodextrin exceeded 300%, suggesting that the adsorption occurred not only in the cyclodextrin cavities via a 1 : 1 complexation, but also in the nanopores of the BnCD-HCPP created during the hyper-crosslinking. The BnCD-HCPP can be further functionalized by incorporation of gold nanoparticles for catalytic transformation of adsorbed phenolic compounds such as 4-nitrophenol to 4-aminophenol.},
doi = {10.1039/c5sc04034e},
journal = {Chemical Science},
number = 2,
volume = 7,
place = {United States},
year = {Fri Nov 13 00:00:00 EST 2015},
month = {Fri Nov 13 00:00:00 EST 2015}
}
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