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Title: Hyper-crosslinked cyclodextrin porous polymer: An efficient CO 2 capturing material with tunable porosity

We designed and synthesized the cyclodextrin (CD)-based hyper-crosslinked porous polymers (HCPPs) for selective CO 2 adsorption and storage. We also explored the effect of monomer size on micropore formation, and determined a feasible way to tailor the porosity of the materials during the hyper-crosslinking process.
Authors:
 [1] ;  [2] ;  [3] ;  [2] ;  [4] ;  [2] ;  [5]
  1. Univ. of Tennessee, Knoxville, TN (United States)
  2. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
  3. (China)
  4. East China Univ. of Science and Technology, Shanghai (China)
  5. (United States)
Publication Date:
Grant/Contract Number:
AC05-00OR22725
Type:
Accepted Manuscript
Journal Name:
RSC Advances
Additional Journal Information:
Journal Volume: 6; Journal Issue: 111; Journal ID: ISSN 2046-2069
Publisher:
Royal Society of Chemistry
Research Org:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Sponsoring Org:
USDOE Office of Science (SC)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
OSTI Identifier:
1341581

Meng, Bo, Li, Haiyang, East China Univ. of Science and Technology, Shanghai, Mahurin, Shannon Mark, Liu, Honglai, Dai, Sheng, and Univ. of Tennessee, Knoxville, TN. Hyper-crosslinked cyclodextrin porous polymer: An efficient CO2 capturing material with tunable porosity. United States: N. p., Web. doi:10.1039/C6RA18307G.
Meng, Bo, Li, Haiyang, East China Univ. of Science and Technology, Shanghai, Mahurin, Shannon Mark, Liu, Honglai, Dai, Sheng, & Univ. of Tennessee, Knoxville, TN. Hyper-crosslinked cyclodextrin porous polymer: An efficient CO2 capturing material with tunable porosity. United States. doi:10.1039/C6RA18307G.
Meng, Bo, Li, Haiyang, East China Univ. of Science and Technology, Shanghai, Mahurin, Shannon Mark, Liu, Honglai, Dai, Sheng, and Univ. of Tennessee, Knoxville, TN. 2016. "Hyper-crosslinked cyclodextrin porous polymer: An efficient CO2 capturing material with tunable porosity". United States. doi:10.1039/C6RA18307G. https://www.osti.gov/servlets/purl/1341581.
@article{osti_1341581,
title = {Hyper-crosslinked cyclodextrin porous polymer: An efficient CO2 capturing material with tunable porosity},
author = {Meng, Bo and Li, Haiyang and East China Univ. of Science and Technology, Shanghai and Mahurin, Shannon Mark and Liu, Honglai and Dai, Sheng and Univ. of Tennessee, Knoxville, TN},
abstractNote = {We designed and synthesized the cyclodextrin (CD)-based hyper-crosslinked porous polymers (HCPPs) for selective CO2 adsorption and storage. We also explored the effect of monomer size on micropore formation, and determined a feasible way to tailor the porosity of the materials during the hyper-crosslinking process.},
doi = {10.1039/C6RA18307G},
journal = {RSC Advances},
number = 111,
volume = 6,
place = {United States},
year = {2016},
month = {11}
}

Works referenced in this record:

Strong and Reversible Binding of Carbon Dioxide in a Green Metal–Organic Framework
journal, October 2011
  • Gassensmith, Jeremiah J.; Furukawa, Hiroyasu; Smaldone, Ronald A.
  • Journal of the American Chemical Society, Vol. 133, Issue 39, p. 15312-15315
  • DOI: 10.1021/ja206525x

Nanoporous organic polymer networks
journal, April 2012

Conjugated Microporous Polymers
journal, March 2009