Designer interphases for the lithium-oxygen electrochemical cell
Abstract
An electrochemical cell based on the reversible oxygen reduction reaction: 2Li+ + 2e- + O2 ↔ Li2O2, provides among the most energy dense platforms for portable electrical energy storage. Such Lithium-Oxygen (Li-O2) cells offer specific energies competitive with fossil fuels and are considered promising for electrified transportation. Multiple, fundamental challenges with the cathode, anode, and electrolyte have limited practical interest in Li-O2 cells because these problems lead to as many practical shortcomings, including poor rechargeability, high overpotentials, and specific energies well below theoretical expectations. We create and study in-situ formation of solid-electrolyte interphases (SEIs) based on bromide ionomers tethered to a Li anode that take advantage of three powerful processes for overcoming the most stubborn of these challenges. The ionomer SEIs are shown to protect the Li anode against parasitic reactions and also stabilize Li electrodeposition during cell recharge. Bromine species liberated during the anchoring reaction also function as redox mediators at the cathode, reducing the charge overpotential. Finally, the ionomer SEI forms a stable interphase with Li, which protects the metal in high Gutmann donor number liquid electrolytes. Such electrolytes have been reported to exhibit rare stability against nucleophilic attack by Li2O2 and other cathode reaction intermediates, but alsomore »
- Authors:
-
[1];
[1];
[1];
[1];
[3];
[3];
- Cornell Univ., Ithaca, NY (United States). School of Chemical and Biomolecular Engineering
- Cornell Univ., Ithaca, NY (United States). Dept. of Materials Science and Engineering
- Cornell Univ., Ithaca, NY (United States). School of Applied and Engineering Physics; Cornell Univ., Ithaca, NY (United States). Kavli Inst. at Cornell for Nanoscale Science
- Publication Date:
- Research Org.:
- Cornell Univ., Ithaca, NY (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Engineering & Technology
- OSTI Identifier:
- 1625969
- Grant/Contract Number:
- SC0001086
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Science Advances
- Additional Journal Information:
- Journal Volume: 3; Journal Issue: 4; Journal ID: ISSN 2375-2548
- Publisher:
- AAAS
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; Science & Technology - Other Topics
Citation Formats
Choudhury, Snehashis, Wan, Charles Tai-Chieh, Al Sadat, Wajdi I., Tu, Zhengyuan, Lau, Sampson, Zachman, Michael J., Kourkoutis, Lena F., and Archer, Lynden A. Designer interphases for the lithium-oxygen electrochemical cell. United States: N. p., 2017.
Web. doi:10.1126/sciadv.1602809.
Choudhury, Snehashis, Wan, Charles Tai-Chieh, Al Sadat, Wajdi I., Tu, Zhengyuan, Lau, Sampson, Zachman, Michael J., Kourkoutis, Lena F., & Archer, Lynden A. Designer interphases for the lithium-oxygen electrochemical cell. United States. https://doi.org/10.1126/sciadv.1602809
Choudhury, Snehashis, Wan, Charles Tai-Chieh, Al Sadat, Wajdi I., Tu, Zhengyuan, Lau, Sampson, Zachman, Michael J., Kourkoutis, Lena F., and Archer, Lynden A. Sat .
"Designer interphases for the lithium-oxygen electrochemical cell". United States. https://doi.org/10.1126/sciadv.1602809. https://www.osti.gov/servlets/purl/1625969.
@article{osti_1625969,
title = {Designer interphases for the lithium-oxygen electrochemical cell},
author = {Choudhury, Snehashis and Wan, Charles Tai-Chieh and Al Sadat, Wajdi I. and Tu, Zhengyuan and Lau, Sampson and Zachman, Michael J. and Kourkoutis, Lena F. and Archer, Lynden A.},
abstractNote = {An electrochemical cell based on the reversible oxygen reduction reaction: 2Li+ + 2e- + O2 ↔ Li2O2, provides among the most energy dense platforms for portable electrical energy storage. Such Lithium-Oxygen (Li-O2) cells offer specific energies competitive with fossil fuels and are considered promising for electrified transportation. Multiple, fundamental challenges with the cathode, anode, and electrolyte have limited practical interest in Li-O2 cells because these problems lead to as many practical shortcomings, including poor rechargeability, high overpotentials, and specific energies well below theoretical expectations. We create and study in-situ formation of solid-electrolyte interphases (SEIs) based on bromide ionomers tethered to a Li anode that take advantage of three powerful processes for overcoming the most stubborn of these challenges. The ionomer SEIs are shown to protect the Li anode against parasitic reactions and also stabilize Li electrodeposition during cell recharge. Bromine species liberated during the anchoring reaction also function as redox mediators at the cathode, reducing the charge overpotential. Finally, the ionomer SEI forms a stable interphase with Li, which protects the metal in high Gutmann donor number liquid electrolytes. Such electrolytes have been reported to exhibit rare stability against nucleophilic attack by Li2O2 and other cathode reaction intermediates, but also react spontaneously with Li metal anodes. We conclude that rationally designed SEIs able to regulate transport of matter and ions at the electrolyte/anode interface provide a promising platform for addressing three major technical barriers to practical Li-O2 cells.},
doi = {10.1126/sciadv.1602809},
journal = {Science Advances},
number = 4,
volume = 3,
place = {United States},
year = {Sat Apr 01 00:00:00 EDT 2017},
month = {Sat Apr 01 00:00:00 EDT 2017}
}
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Design Principles of Functional Polymer Separators for High-Energy, Metal-Based Batteries
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A versatile functionalized ionic liquid to boost the solution-mediated performances of lithium-oxygen batteries
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3D-Printed Graphene Oxide Framework with Thermal Shock Synthesized Nanoparticles for Li-CO 2 Batteries
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Designing solid-liquid interphases for sodium batteries
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Upgrading traditional liquid electrolyte via in situ gelation for future lithium metal batteries
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Interfacial Super‐Assembled Porous CeO 2 /C Frameworks Featuring Efficient and Sensitive Decomposing Li 2 O 2 for Smart Li–O 2 Batteries
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PEEK‐WC/Nanosponge Membranes for Lithium‐Anode Protection in Rechargeable Li−O 2 Batteries
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Prevention of dendrite growth and volume expansion to give high-performance aprotic bimetallic Li-Na alloy–O2 batteries
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Highly efficient and stable solid-state Li–O 2 batteries using a perovskite solid electrolyte
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Graphene-based quasi-solid-state lithium–oxygen batteries with high energy efficiency and a long cycling lifetime
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Emerging Electron Microscopy Techniques for Probing Functional Interfaces in Energy Materials
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Dendrite‐Free Epitaxial Growth of Lithium Metal during Charging in Li–O 2 Batteries
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Functional and stability orientation synthesis of materials and structures in aprotic Li–O 2 batteries
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Electroless Formation of Hybrid Lithium Anodes for Fast Interfacial Ion Transport
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Taming Interfacial Instability in Lithium–Oxygen Batteries: A Polymeric Ionic Liquid Electrolyte Solution
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Can Hybrid Na–Air Batteries Outperform Nonaqueous Na–O 2 Batteries?
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Cryogenic specimens for nanoscale characterization of solid–liquid interfaces
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Designing solid-liquid interphases for sodium batteries
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An ion redistributor for dendrite-free lithium metal anodes
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