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Title: Advanced strategies for the development of porous carbon as a Li host/current collector for lithium metal batteries

Abstract

Lithium metal is considered a promising anode material for high-energy-density rechargeable batteries because of its high specific theoretical capacity (3860 mAh g-1, low mass density (0.534 g cm-3), and low electrochemical redox potential (-3.04 V vs. the standard hydrogen electrode). However, the high reactivity of Li with the electrolyte leads to the formation of an unstable solid electrolyte interphase (SEI) and continuous side reactions. Also, the non-uniform lithium-ion flux and infinite volume expansion of Li metal cause the growth of Li dendrites. These pose significant safety challenges and cause rapid capacity fading of the lithium metal batteries (LiMBs). To resolve these issues, a low-cost, easily processed, lightweight, high-performance carbon-based porous matrix is considered promising to host Li metal deposition. The three-dimensional (3D) porous nano/microstructured carbon provides sufficient space for Li accommodation during Li plating, buffers the volume changes during Li plating/stripping, and lowers the effective current density contributing to dendrite-free Li deposition. Besides, the outstanding electrochemical and mechanical stability, flexibility and the high electronic conductivity enable the nano/microstructured carbon to serve as both Li host and current collector. The development of 3D carbon/Li composite by mechanical roll-press techniques not only eliminates the complex and risky procedure of making carbon/Li compositemore » based on Li plating or molten Li infusion but also stabilizes the capacity at higher Li plating/stripping rates. Recently, there is an advancement in the lithiophilic decorations of 3D structure to introduce sufficient nucleation sites and the development of artificial SEI on top of the 3D matrix to suppress Li dendrite formation. Such 3D structural modifications create a uniform electric field, lower the Li nucleation overpotential, provide strong mechanical and chemical stability, and stabilize the interface thereby inhibiting the degradation of lithium and the electrolyte. Here we summarize the research progress on porous carbon/Li composites in terms of materials type, structure, fabrication technique, their electrochemical battery performance, and identify the critical challenges that need to be addressed for high-energy-density practical LiMBs.« less

Authors:
 [1];  [2];  [3];  [4];  [5];  [4];  [6];  [2]
+ Show Author Affiliations
  1. South Dakota State University, Brookings, SD (United States); Argonne National Laboratory (ANL), Argonne, IL (United States)
  2. South Dakota State University, Brookings, SD (United States)
  3. Huzhou University, Zhejiang (China)
  4. Argonne National Laboratory (ANL), Argonne, IL (United States)
  5. California Institute of Technology (CalTech), Pasadena, CA (United States). Jet Propulsion Laboratory (JPL)
  6. Syracuse University, NY (United States)
Publication Date:
Research Org.:
Argonne National Laboratory (ANL), Argonne, IL (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation (NSF); National Aeronautics and Space Administration (NASA); EDA University Center Program
OSTI Identifier:
1833531
Grant/Contract Number:  
AC02-06CH11357; 1428992; NNX15AM83A; ED18DEN3030025
Resource Type:
Accepted Manuscript
Journal Name:
Energy Storage Materials
Additional Journal Information:
Journal Volume: 41; Journal ID: ISSN 2405-8297
Publisher:
Elsevier
Country of Publication:
United States
Language:
English
Subject:
25 ENERGY STORAGE; lithium metal anode; lithium-host/current collector; porous carbon/li composite; solid-electrolyte-interphase; high-energy-density; lithium metal batteries

Citation Formats

Pathak, Rajesh, Chen, Ke, Wu, Fan, Mane, Anil U., Bugga, Ratnakumar V., Elam, Jeffrey W., Qiao, Quinn, and Zhou, Yue. Advanced strategies for the development of porous carbon as a Li host/current collector for lithium metal batteries. United States: N. p., 2021. Web. doi:10.1016/j.ensm.2021.06.015.
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Pathak, Rajesh, Chen, Ke, Wu, Fan, Mane, Anil U., Bugga, Ratnakumar V., Elam, Jeffrey W., Qiao, Quinn, & Zhou, Yue. Advanced strategies for the development of porous carbon as a Li host/current collector for lithium metal batteries. United States. https://doi.org/10.1016/j.ensm.2021.06.015
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Pathak, Rajesh, Chen, Ke, Wu, Fan, Mane, Anil U., Bugga, Ratnakumar V., Elam, Jeffrey W., Qiao, Quinn, and Zhou, Yue. Thu . "Advanced strategies for the development of porous carbon as a Li host/current collector for lithium metal batteries". United States. https://doi.org/10.1016/j.ensm.2021.06.015. https://www.osti.gov/servlets/purl/1833531.
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@article{osti_1833531,
title = {Advanced strategies for the development of porous carbon as a Li host/current collector for lithium metal batteries},
author = {Pathak, Rajesh and Chen, Ke and Wu, Fan and Mane, Anil U. and Bugga, Ratnakumar V. and Elam, Jeffrey W. and Qiao, Quinn and Zhou, Yue},
abstractNote = {Lithium metal is considered a promising anode material for high-energy-density rechargeable batteries because of its high specific theoretical capacity (3860 mAh g-1, low mass density (0.534 g cm-3), and low electrochemical redox potential (-3.04 V vs. the standard hydrogen electrode). However, the high reactivity of Li with the electrolyte leads to the formation of an unstable solid electrolyte interphase (SEI) and continuous side reactions. Also, the non-uniform lithium-ion flux and infinite volume expansion of Li metal cause the growth of Li dendrites. These pose significant safety challenges and cause rapid capacity fading of the lithium metal batteries (LiMBs). To resolve these issues, a low-cost, easily processed, lightweight, high-performance carbon-based porous matrix is considered promising to host Li metal deposition. The three-dimensional (3D) porous nano/microstructured carbon provides sufficient space for Li accommodation during Li plating, buffers the volume changes during Li plating/stripping, and lowers the effective current density contributing to dendrite-free Li deposition. Besides, the outstanding electrochemical and mechanical stability, flexibility and the high electronic conductivity enable the nano/microstructured carbon to serve as both Li host and current collector. The development of 3D carbon/Li composite by mechanical roll-press techniques not only eliminates the complex and risky procedure of making carbon/Li composite based on Li plating or molten Li infusion but also stabilizes the capacity at higher Li plating/stripping rates. Recently, there is an advancement in the lithiophilic decorations of 3D structure to introduce sufficient nucleation sites and the development of artificial SEI on top of the 3D matrix to suppress Li dendrite formation. Such 3D structural modifications create a uniform electric field, lower the Li nucleation overpotential, provide strong mechanical and chemical stability, and stabilize the interface thereby inhibiting the degradation of lithium and the electrolyte. Here we summarize the research progress on porous carbon/Li composites in terms of materials type, structure, fabrication technique, their electrochemical battery performance, and identify the critical challenges that need to be addressed for high-energy-density practical LiMBs.},
doi = {10.1016/j.ensm.2021.06.015},
journal = {Energy Storage Materials},
number = ,
volume = 41,
place = {United States},
year = {Thu Jun 17 00:00:00 EDT 2021},
month = {Thu Jun 17 00:00:00 EDT 2021}
}
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A Hierarchical Silver-Nanowire-Graphene Host Enabling Ultrahigh Rates and Superior Long-Term Cycling of Lithium-Metal Composite Anodes
journal, September 2018

3D Printed High‐Performance Lithium Metal Microbatteries Enabled by Nanocellulose
journal, February 2019

  • Cao, Daxian; Xing, Yingjie; Tantratian, Karnpiwat
  • Advanced Materials, Vol. 31, Issue 14
  • DOI: 10.1002/adma.201807313

A Scalable Approach to Dendrite-Free Lithium Anodes via Spontaneous Reduction of Spray-Coated Graphene Oxide Layers
journal, May 2018

Sulfiphilic FeP/rGO as a highly efficient sulfur host for propelling redox kinetics toward stable lithium-sulfur battery
journal, December 2020

Accommodating lithium into 3D current collectors with a submicron skeleton towards long-life lithium metal anodes
journal, August 2015

  • Yang, Chun-Peng; Yin, Ya-Xia; Zhang, Shuai-Feng
  • Nature Communications, Vol. 6, Issue 1
  • DOI: 10.1038/ncomms9058

Interlayer Lithium Plating in Au Nanoparticles Pillared Reduced Graphene Oxide for Lithium Metal Anodes
journal, August 2018

  • Pu, Jun; Li, Jiachen; Shen, Zihan
  • Advanced Functional Materials, Vol. 28, Issue 41
  • DOI: 10.1002/adfm.201804133

The Insights of Lithium Metal Plating/Stripping in Porous Hosts: Progress and Perspectives
journal, January 2021

Infiltrating lithium into carbon cloth decorated with zinc oxide arrays for dendrite-free lithium metal anode
journal, November 2018

Selective deposition and stable encapsulation of lithium through heterogeneous seeded growth
journal, February 2016

  • Yan, Kai; Lu, Zhenda; Lee, Hyun-Wook
  • Nature Energy, Vol. 1, Issue 3, Article No. 16010
  • DOI: 10.1038/nenergy.2016.10

VGCF 3D conducting host coating on glass fiber filters for lithium metal anodes
journal, January 2018

  • Yang, Yang; Xiong, Jian; Zeng, Jing
  • Chemical Communications, Vol. 54, Issue 10
  • DOI: 10.1039/C7CC07828E

In Situ Generation of Artificial Solid‐Electrolyte Interphases on 3D Conducting Scaffolds for High‐Performance Lithium‐Metal Anodes
journal, January 2020

Ultrafine Silver Nanoparticles for Seeded Lithium Deposition toward Stable Lithium Metal Anode
journal, August 2017

  • Yang, Chunpeng; Yao, Yonggang; He, Shuaiming
  • Advanced Materials, Vol. 29, Issue 38
  • DOI: 10.1002/adma.201702714

Lithium–matrix composite anode protected by a solid electrolyte layer for stable lithium metal batteries
journal, October 2019

A low ride on processing temperature for fast lithium conduction in garnet solid-state battery films
journal, May 2019

Lithiophilic Sites in Doped Graphene Guide Uniform Lithium Nucleation for Dendrite-Free Lithium Metal Anodes
journal, May 2017

Suppressing Lithium Dendrite Growth by Metallic Coating on a Separator
journal, October 2017

  • Lee, Hongkyung; Ren, Xiaodi; Niu, Chaojiang
  • Advanced Functional Materials, Vol. 27, Issue 45
  • DOI: 10.1002/adfm.201704391

Metal Organic Framework Derivative Improving Lithium Metal Anode Cycling
journal, January 2020

  • Zhong, Yiren; Lin, Fang; Wang, Maoyu
  • Advanced Functional Materials, Vol. 30, Issue 10
  • DOI: 10.1002/adfm.201907579

Stabilizing Lithium Metal Anodes by Uniform Li-Ion Flux Distribution in Nanochannel Confinement
journal, November 2016

  • Liu, Wei; Lin, Dingchang; Pei, Allen
  • Journal of the American Chemical Society, Vol. 138, Issue 47
  • DOI: 10.1021/jacs.6b08730

Realizing stable lithium deposition by in situ grown Cu 2 S nanowires inside commercial Cu foam for lithium metal anodes
journal, January 2019

  • Huang, Zhijia; Zhang, Chen; Lv, Wei
  • Journal of Materials Chemistry A, Vol. 7, Issue 2
  • DOI: 10.1039/C8TA10341K

Dendrite‐Free Lithium Plating Induced by In Situ Transferring Protection Layer from Separator
journal, November 2019

  • Hu, Zhiyu; Liu, Fengquan; Gao, Jian
  • Advanced Functional Materials, Vol. 30, Issue 5
  • DOI: 10.1002/adfm.201907020

Oxygen and nitrogen co-doped porous carbon granules enabling dendrite-free lithium metal anode
journal, March 2019

Porous Carbon Paper as Interlayer to Stabilize the Lithium Anode for Lithium–Sulfur Battery
journal, November 2016

  • Kong, Ling-Long; Zhang, Ze; Zhang, Ye-Zheng
  • ACS Applied Materials & Interfaces, Vol. 8, Issue 46
  • DOI: 10.1021/acsami.6b11188

High-power lithium batteries from functionalized carbon-nanotube electrodes
journal, June 2010

  • Lee, Seung Woo; Yabuuchi, Naoaki; Gallant, Betar M.
  • Nature Nanotechnology, Vol. 5, Issue 7
  • DOI: 10.1038/nnano.2010.116

High Areal Capacity and Lithium Utilization in Anodes Made of Covalently Connected Graphite Microtubes
journal, August 2017

Synergetic Coupling of Lithiophilic Sites and Conductive Scaffolds for Dendrite‐Free Lithium Metal Anodes
journal, April 2019

  • Chen, Xiao‐Ru; Li, Bo‐Quan; Zhao, Chang‐Xin
  • Small Methods, Vol. 4, Issue 6
  • DOI: 10.1002/smtd.201900177

Lithiophilic metallic nitrides modified nickel foam by plasma for stable lithium metal anode
journal, December 2019

Ultrafine Titanium Nitride Sheath Decorated Carbon Nanofiber Network Enabling Stable Lithium Metal Anodes
journal, September 2019

  • Lin, Kui; Qin, Xianying; Liu, Ming
  • Advanced Functional Materials, Vol. 29, Issue 46
  • DOI: 10.1002/adfm.201903229

Free-Standing Copper Nanowire Network Current Collector for Improving Lithium Anode Performance
journal, June 2016

Implantable Solid Electrolyte Interphase in Lithium-Metal Batteries
journal, February 2017

Wrinkled Graphene Cages as Hosts for High-Capacity Li Metal Anodes Shown by Cryogenic Electron Microscopy
journal, January 2019

3D TiC/C Core/Shell Nanowire Skeleton for Dendrite-Free and Long-Life Lithium Metal Anode
journal, December 2017

Popcorn Inspired Porous Macrocellular Carbon: Rapid Puffing Fabrication from Rice and Its Applications in Lithium-Sulfur Batteries
journal, September 2017

  • Zhong, Yu; Xia, Xinhui; Deng, Shengjue
  • Advanced Energy Materials, Vol. 8, Issue 1
  • DOI: 10.1002/aenm.201701110

Engineering Bifunctional Host Materials of Sulfur and Lithium‐Metal Based on Nitrogen‐Enriched Polyacrylonitrile for Li–S Batteries
journal, June 2020

  • Dai, Zudian; Wang, Mei; Zhang, Yin
  • Chemistry – A European Journal, Vol. 26, Issue 40
  • DOI: 10.1002/chem.202000467

Nanocrevasse-Rich Carbon Fibers for Stable Lithium and Sodium Metal Anodes
journal, November 2018

Vertically Aligned Lithiophilic CuO Nanosheets on a Cu Collector to Stabilize Lithium Deposition for Lithium Metal Batteries
journal, April 2018

  • Zhang, Chen; Lv, Wei; Zhou, Guangmin
  • Advanced Energy Materials, Vol. 8, Issue 21
  • DOI: 10.1002/aenm.201703404

Lithiated zinc oxide nanorod arrays on copper current collectors for robust Li metal anodes
journal, December 2019

Vacuum distillation derived 3D porous current collector for stable lithium–metal batteries
journal, May 2018

Structure Design and Composition Engineering of Carbon‐Based Nanomaterials for Lithium Energy Storage
journal, March 2020

  • Geng, Hongya; Peng, Yan; Qu, Liangti
  • Advanced Energy Materials, Vol. 10, Issue 10
  • DOI: 10.1002/aenm.201903030

Implanting CNT Forest onto Carbon Nanosheets as Multifunctional Hosts for High-Performance Lithium Metal Batteries
journal, February 2019

In Situ Preparation of Thin and Rigid COF Film on Li Anode as Artificial Solid Electrolyte Interphase Layer Resisting Li Dendrite Puncture
journal, December 2019

  • Chen, Dongdong; Huang, Sheng; Zhong, Lei
  • Advanced Functional Materials, Vol. 30, Issue 7
  • DOI: 10.1002/adfm.201907717

3D Porous Cu Current Collector/Li-Metal Composite Anode for Stable Lithium-Metal Batteries
journal, March 2017

  • Li, Qi; Zhu, Shoupu; Lu, Yingying
  • Advanced Functional Materials, Vol. 27, Issue 18
  • DOI: 10.1002/adfm.201606422

Multifunctional covalent organic frameworks for high capacity and dendrite-free lithium metal batteries
journal, March 2020

Real-time mass spectrometric characterization of the solid–electrolyte interphase of a lithium-ion battery
journal, January 2020

Coralloid Carbon Fiber-Based Composite Lithium Anode for Robust Lithium Metal Batteries
journal, April 2018

Controlled Lithium Dendrite Growth by a Synergistic Effect of Multilayered Graphene Coating and an Electrolyte Additive
journal, April 2015

  • Kim, Joo-Seong; Kim, Dae Woo; Jung, Hee Tae
  • Chemistry of Materials, Vol. 27, Issue 8
  • DOI: 10.1021/cm503447u

Uniform Lithium Deposition Assisted by Single‐Atom Doping toward High‐Performance Lithium Metal Anodes
journal, March 2019

  • Zhai, Pengbo; Wang, Tianshuai; Yang, Weiwei
  • Advanced Energy Materials, Vol. 9, Issue 18
  • DOI: 10.1002/aenm.201804019

Mesoporous carbon host material for stable lithium metal anode
journal, January 2020

  • Jeong, Jooyoung; Chun, Jinyoung; Lim, Won-Gwang
  • Nanoscale, Vol. 12, Issue 22
  • DOI: 10.1039/D0NR02258F

Lithium-coated polymeric matrix as a minimum volume-change and dendrite-free lithium metal anode
journal, March 2016

  • Liu, Yayuan; Lin, Dingchang; Liang, Zheng
  • Nature Communications, Vol. 7, Issue 1
  • DOI: 10.1038/ncomms10992

Composite lithium metal anode by melt infusion of lithium into a 3D conducting scaffold with lithiophilic coating
journal, February 2016

  • Liang, Zheng; Lin, Dingchang; Zhao, Jie
  • Proceedings of the National Academy of Sciences, Vol. 113, Issue 11
  • DOI: 10.1073/pnas.1518188113

Dendrite-Free Lithium Deposition Induced by Uniformly Distributed Lithium Ions for Efficient Lithium Metal Batteries
journal, February 2016

  • Cheng, Xin-Bing; Hou, Ting-Zheng; Zhang, Rui
  • Advanced Materials, Vol. 28, Issue 15
  • DOI: 10.1002/adma.201506124

Lithiophilic 3D Nanoporous Nitrogen-Doped Graphene for Dendrite-Free and Ultrahigh-Rate Lithium-Metal Anodes
journal, November 2018

Conductivity and lithiophilicity gradients guide lithium deposition to mitigate short circuits
journal, April 2019

Trapping Lithium into Hollow Silica Microspheres with a Carbon Nanotube Core for Dendrite-Free Lithium Metal Anodes
journal, December 2017

In situ confocal microscopic observation on inhibiting the dendrite formation of a-CN x /Li electrode
journal, January 2016

  • Zhang, Yi-jun; Bai, Wen-qi; Wang, Xiu-li
  • Journal of Materials Chemistry A, Vol. 4, Issue 40
  • DOI: 10.1039/C6TA06612G

Dendrite-Free Metallic Lithium in Lithiophilic Carbonized Metal-Organic Frameworks
journal, March 2018

Mixed Ionic and Electronic Conductor for Li-Metal Anode Protection
journal, January 2018

Stable Li Metal Anodes via Regulating Lithium Plating/Stripping in Vertically Aligned Microchannels
journal, September 2017

  • Wang, Shu-Hua; Yin, Ya-Xia; Zuo, Tong-Tong
  • Advanced Materials, Vol. 29, Issue 40
  • DOI: 10.1002/adma.201703729

2D Metal Carbides and Nitrides (MXenes) as High-Performance Electrode Materials for Lithium-Based Batteries
journal, September 2018

Vertically Grown Edge-Rich Graphene Nanosheets for Spatial Control of Li Nucleation
journal, May 2018

Fluorinated hybrid solid-electrolyte-interphase for dendrite-free lithium deposition
journal, January 2020

A high tap density secondary silicon particle anode fabricated by scalable mechanical pressing for lithium-ion batteries
journal, January 2015

  • Lin, Dingchang; Lu, Zhenda; Hsu, Po-Chun
  • Energy & Environmental Science, Vol. 8, Issue 8
  • DOI: 10.1039/C5EE01363A

Energy Storage: Advanced Micro/Nanostructures for Lithium Metal Anodes (Adv. Sci. 3/2017)
journal, March 2017

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