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Title: Unveiling the critical role of interfacial ionic conductivity in all-solid-state lithium batteries

Abstract

Advancement of all-solid-state lithium-ion (Li+) batteries (ASSLIBs) has been hindered by the large interfacial resistance mainly originating from interfacial reactions between oxide cathodes and solid-state sulfide electrolytes (SEs). To suppress the interfacial reactions, an interfacial coating layer between cathodes and SEs is indispensable. However, the kinetics of interfacial Li+ transport across the coating layer has not been well understood yet. Herein, we tune the interfacial ionic conductivity of the coating layer LiNb0.5Ta0.5O3 (LNTO) by manipulating post-annealing temperature. It is found that the interfacial ionic conductivity determines interfacial Li+ transport kinetics and enhancing the interfacial ionic conductivity can significantly boost the electrochemical performance of SE-based ASSLIBs. A representative cathode LiNi0.5Mn0.3Co0.2O2 coated by LNTO with the highest interfacial ionic conductivity exhibits a high initial capacity of 152 mAh.g-1 at 0.1 C and 107.5 mAh.g-1 at 1C. This work highlights the importance of increasing interfacial ionic conductivity for high-performance SE-based ASSLIBs.

Authors:
 [1];  [1];  [2];  [1];  [1];  [1];  [1];  [1];  [1];  [1];  [1];  [1];  [3];  [4];  [4];  [2]; ORCiD logo [1]
+ Show Author Affiliations
  1. Univ. of Western Ontario, London, ON (Canada)
  2. Brookhaven National Lab. (BNL), Upton, NY (United States)
  3. Glabat Solid-State Battery Inc., London, ON (Canada)
  4. China Automotive Battery Research Inst. Co. (China)
Publication Date:
Research Org.:
Brookhaven National Lab. (BNL), Upton, NY (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1605675
Alternate Identifier(s):
OSTI ID: 1703070
Report Number(s):
BNL-213737-2020-JAAM
Journal ID: ISSN 2211-2855
Grant/Contract Number:  
SC0012704
Resource Type:
Accepted Manuscript
Journal Name:
Nano Energy
Additional Journal Information:
Journal Volume: 72; Journal Issue: C; Journal ID: ISSN 2211-2855
Publisher:
Elsevier
Country of Publication:
United States
Language:
English
Subject:
25 ENERGY STORAGE; interfacial ionic conductivity; ion transport kinetics; all-solid-state batteries

Citation Formats

Wang, Changhong, Liang, Jianwen, Hwang, Sooyeon, Li, Xiaona, Zhao, Yang, Adair, Keegan, Zhao, Changtai, Li, Xia, Deng, Sixu, Lin, Xiaoting, Yang, Xiaofei, Li, Ruying, Huang, Huan, Zhang, Li, Lu, Shigang, Su, Dong, and Sun, Xueliang. Unveiling the critical role of interfacial ionic conductivity in all-solid-state lithium batteries. United States: N. p., 2020. Web. doi:10.1016/j.nanoen.2020.104686.
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Wang, Changhong, Liang, Jianwen, Hwang, Sooyeon, Li, Xiaona, Zhao, Yang, Adair, Keegan, Zhao, Changtai, Li, Xia, Deng, Sixu, Lin, Xiaoting, Yang, Xiaofei, Li, Ruying, Huang, Huan, Zhang, Li, Lu, Shigang, Su, Dong, & Sun, Xueliang. Unveiling the critical role of interfacial ionic conductivity in all-solid-state lithium batteries. United States. https://doi.org/10.1016/j.nanoen.2020.104686
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Wang, Changhong, Liang, Jianwen, Hwang, Sooyeon, Li, Xiaona, Zhao, Yang, Adair, Keegan, Zhao, Changtai, Li, Xia, Deng, Sixu, Lin, Xiaoting, Yang, Xiaofei, Li, Ruying, Huang, Huan, Zhang, Li, Lu, Shigang, Su, Dong, and Sun, Xueliang. Mon . "Unveiling the critical role of interfacial ionic conductivity in all-solid-state lithium batteries". United States. https://doi.org/10.1016/j.nanoen.2020.104686. https://www.osti.gov/servlets/purl/1605675.
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@article{osti_1605675,
title = {Unveiling the critical role of interfacial ionic conductivity in all-solid-state lithium batteries},
author = {Wang, Changhong and Liang, Jianwen and Hwang, Sooyeon and Li, Xiaona and Zhao, Yang and Adair, Keegan and Zhao, Changtai and Li, Xia and Deng, Sixu and Lin, Xiaoting and Yang, Xiaofei and Li, Ruying and Huang, Huan and Zhang, Li and Lu, Shigang and Su, Dong and Sun, Xueliang},
abstractNote = {Advancement of all-solid-state lithium-ion (Li+) batteries (ASSLIBs) has been hindered by the large interfacial resistance mainly originating from interfacial reactions between oxide cathodes and solid-state sulfide electrolytes (SEs). To suppress the interfacial reactions, an interfacial coating layer between cathodes and SEs is indispensable. However, the kinetics of interfacial Li+ transport across the coating layer has not been well understood yet. Herein, we tune the interfacial ionic conductivity of the coating layer LiNb0.5Ta0.5O3 (LNTO) by manipulating post-annealing temperature. It is found that the interfacial ionic conductivity determines interfacial Li+ transport kinetics and enhancing the interfacial ionic conductivity can significantly boost the electrochemical performance of SE-based ASSLIBs. A representative cathode LiNi0.5Mn0.3Co0.2O2 coated by LNTO with the highest interfacial ionic conductivity exhibits a high initial capacity of 152 mAh.g-1 at 0.1 C and 107.5 mAh.g-1 at 1C. This work highlights the importance of increasing interfacial ionic conductivity for high-performance SE-based ASSLIBs.},
doi = {10.1016/j.nanoen.2020.104686},
journal = {Nano Energy},
number = C,
volume = 72,
place = {United States},
year = {Mon Jun 01 00:00:00 EDT 2020},
month = {Mon Jun 01 00:00:00 EDT 2020}
}
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https://doi.org/10.1016/j.nanoen.2020.104686
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