Interfacial Chemistry Regulation via a Skin-Grafting Strategy Enables High-Performance Lithium-Metal Batteries
Abstract
The lithium (Li) metal anode suffers severe interfacial instability from its high reactivity toward liquid electrolytes, especially carbonate-based electrolytes, resulting in poor electrochemical performance of batteries that use 4 V high-capacity cathodes. In this paper, we report a new skin-grafting strategy that stabilizes the Li metal–liquid electrolyte interface by coating the Li metal surface with poly((N-2,2-dimethyl-1,3-dioxolane-4-methyl)-5-norbornene-exo-2,3-dicarboximide), a chemically and electrochemically active polymer layer. This layer, composed of cyclic ether groups with a stiff polycyclic main chain, serves as a grafted polymer skin on the Li metal anode not only to incorporate ether-based polymeric components into the solid-electrolyte interphase (SEI) but also to accommodate Li deposition/dissolution under the skin in a dendrite/moss-free manner. Consequently, a Li-metal battery employing a Li metal anode with the grafted skin paired with LiNi0.5Co0.2Mn0.3O2 cathode has a 90.0% capacity retention after 400 charge/discharge cycles and a capacity of 1.2 mAh/cm2 in a carbonate-based electrolyte. Finally, this proof-of-concept study provides a new direction for regulating the interfacial chemistry of Li metal anodes and for enabling high-performance Li-metal batteries.
- Authors:
-
[1];
[1];
[1];
[2]
- Pennsylvania State Univ., University Park, PA (United States). Dept. of Chemistry
- Pennsylvania State Univ., University Park, PA (United States). Dept. of Mechanical and Nuclear Engineering
- Publication Date:
- Research Org.:
- Pennsylvania State Univ., University Park, PA (United States)
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V); National Science Foundation (NSF)
- OSTI Identifier:
- 1435966
- Alternate Identifier(s):
- OSTI ID: 1430271
- Report Number(s):
- DOE-PENNSTATE-0007795
Journal ID: ISSN 0002-7863; PII:974
- Grant/Contract Number:
- EE0007795; DMR-1306938
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of the American Chemical Society
- Additional Journal Information:
- Journal Volume: 139; Journal Issue: 43; Journal ID: ISSN 0002-7863
- Publisher:
- American Chemical Society (ACS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; 36 MATERIALS SCIENCE; 77 NANOSCIENCE AND NANOTECHNOLOGY; 42 ENGINEERING; Li-metal batteries; Li metal anodes; solid-electrolyte interphase
Citation Formats
Gao, Yue, Zhao, Yuming, Li, Yuguang C., Huang, Qingquan, Mallouk, Thomas E., and Wang, Donghai. Interfacial Chemistry Regulation via a Skin-Grafting Strategy Enables High-Performance Lithium-Metal Batteries. United States: N. p., 2017.
Web. doi:10.1021/jacs.7b06437.
Gao, Yue, Zhao, Yuming, Li, Yuguang C., Huang, Qingquan, Mallouk, Thomas E., & Wang, Donghai. Interfacial Chemistry Regulation via a Skin-Grafting Strategy Enables High-Performance Lithium-Metal Batteries. United States. https://doi.org/10.1021/jacs.7b06437
Gao, Yue, Zhao, Yuming, Li, Yuguang C., Huang, Qingquan, Mallouk, Thomas E., and Wang, Donghai. Fri .
"Interfacial Chemistry Regulation via a Skin-Grafting Strategy Enables High-Performance Lithium-Metal Batteries". United States. https://doi.org/10.1021/jacs.7b06437. https://www.osti.gov/servlets/purl/1435966.
@article{osti_1435966,
title = {Interfacial Chemistry Regulation via a Skin-Grafting Strategy Enables High-Performance Lithium-Metal Batteries},
author = {Gao, Yue and Zhao, Yuming and Li, Yuguang C. and Huang, Qingquan and Mallouk, Thomas E. and Wang, Donghai},
abstractNote = {The lithium (Li) metal anode suffers severe interfacial instability from its high reactivity toward liquid electrolytes, especially carbonate-based electrolytes, resulting in poor electrochemical performance of batteries that use 4 V high-capacity cathodes. In this paper, we report a new skin-grafting strategy that stabilizes the Li metal–liquid electrolyte interface by coating the Li metal surface with poly((N-2,2-dimethyl-1,3-dioxolane-4-methyl)-5-norbornene-exo-2,3-dicarboximide), a chemically and electrochemically active polymer layer. This layer, composed of cyclic ether groups with a stiff polycyclic main chain, serves as a grafted polymer skin on the Li metal anode not only to incorporate ether-based polymeric components into the solid-electrolyte interphase (SEI) but also to accommodate Li deposition/dissolution under the skin in a dendrite/moss-free manner. Consequently, a Li-metal battery employing a Li metal anode with the grafted skin paired with LiNi0.5Co0.2Mn0.3O2 cathode has a 90.0% capacity retention after 400 charge/discharge cycles and a capacity of 1.2 mAh/cm2 in a carbonate-based electrolyte. Finally, this proof-of-concept study provides a new direction for regulating the interfacial chemistry of Li metal anodes and for enabling high-performance Li-metal batteries.},
doi = {10.1021/jacs.7b06437},
journal = {Journal of the American Chemical Society},
number = 43,
volume = 139,
place = {United States},
year = {Fri Oct 06 00:00:00 EDT 2017},
month = {Fri Oct 06 00:00:00 EDT 2017}
}
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Works referenced in this record:
The Li-Ion Rechargeable Battery: A Perspective
journal, January 2013
- Goodenough, John B.; Park, Kyu-Sung
- Journal of the American Chemical Society, Vol. 135, Issue 4
Issues and challenges facing rechargeable lithium batteries
journal, November 2001
- Tarascon, J.-M.; Armand, M.
- Nature, Vol. 414, Issue 6861, p. 359-367
Erratum: Li–O2 and Li–S batteries with high energy storage
journal, December 2011
- Bruce, Peter G.; Freunberger, Stefan A.; Hardwick, Laurence J.
- Nature Materials, Vol. 11, Issue 2
Lithium metal anodes for rechargeable batteries
journal, January 2014
- Xu, Wu; Wang, Jiulin; Ding, Fei
- Energy Environ. Sci., Vol. 7, Issue 2
Reviving the lithium metal anode for high-energy batteries
journal, March 2017
- Lin, Dingchang; Liu, Yayuan; Cui, Yi
- Nature Nanotechnology, Vol. 12, Issue 3
A Review of Solid Electrolyte Interphases on Lithium Metal Anode
journal, November 2015
- Cheng, Xin-Bing; Zhang, Rui; Zhao, Chen-Zi
- Advanced Science, Vol. 3, Issue 3
The Application of Atomic Force Microscopy for the Study of Li Deposition Processes
journal, January 1996
- Aurbach, Doron
- Journal of The Electrochemical Society, Vol. 143, Issue 11
Detection of subsurface structures underneath dendrites formed on cycled lithium metal electrodes
journal, November 2013
- Harry, Katherine J.; Hallinan, Daniel T.; Parkinson, Dilworth Y.
- Nature Materials, Vol. 13, Issue 1
Layered reduced graphene oxide with nanoscale interlayer gaps as a stable host for lithium metal anodes
journal, March 2016
- Lin, Dingchang; Liu, Yayuan; Liang, Zheng
- Nature Nanotechnology, Vol. 11, Issue 7
Stabilizing Lithium Metal Anodes by Uniform Li-Ion Flux Distribution in Nanochannel Confinement
journal, November 2016
- Liu, Wei; Lin, Dingchang; Pei, Allen
- Journal of the American Chemical Society, Vol. 138, Issue 47
Dendrite-Free Lithium Deposition via Self-Healing Electrostatic Shield Mechanism
journal, March 2013
- Ding, Fei; Xu, Wu; Graff, Gordon L.
- Journal of the American Chemical Society, Vol. 135, Issue 11, p. 4450-4456
Selective deposition and stable encapsulation of lithium through heterogeneous seeded growth
journal, February 2016
- Yan, Kai; Lu, Zhenda; Lee, Hyun-Wook
- Nature Energy, Vol. 1, Issue 3, Article No. 16010
Lithium Metal Anodes with an Adaptive “Solid-Liquid” Interfacial Protective Layer
journal, March 2017
- Liu, Kai; Pei, Allen; Lee, Hye Ryoung
- Journal of the American Chemical Society, Vol. 139, Issue 13
Graphitized Carbon Fibers as Multifunctional 3D Current Collectors for High Areal Capacity Li Anodes
journal, June 2017
- Zuo, Tong-Tong; Wu, Xiong-Wei; Yang, Chun-Peng
- Advanced Materials, Vol. 29, Issue 29
Accommodating lithium into 3D current collectors with a submicron skeleton towards long-life lithium metal anodes
journal, August 2015
- Yang, Chun-Peng; Yin, Ya-Xia; Zhang, Shuai-Feng
- Nature Communications, Vol. 6, Issue 1
Reshaping Lithium Plating/Stripping Behavior via Bifunctional Polymer Electrolyte for Room-Temperature Solid Li Metal Batteries
journal, December 2016
- Zeng, Xian-Xiang; Yin, Ya-Xia; Li, Nian-Wu
- Journal of the American Chemical Society, Vol. 138, Issue 49
An Artificial Solid Electrolyte Interphase Layer for Stable Lithium Metal Anodes
journal, December 2015
- Li, Nian-Wu; Yin, Ya-Xia; Yang, Chun-Peng
- Advanced Materials, Vol. 28, Issue 9
Stable Li Plating/Stripping Electrochemistry Realized by a Hybrid Li Reservoir in Spherical Carbon Granules with 3D Conducting Skeletons
journal, April 2017
- Ye, Huan; Xin, Sen; Yin, Ya-Xia
- Journal of the American Chemical Society, Vol. 139, Issue 16
Improved Cycling Performance of Lithium–Oxygen Cells by Use of a Lithium Electrode Protected with Conductive Polymer and Aluminum Fluoride
journal, November 2016
- Kim, Jae-Hong; Woo, Hyun-Sik; Kim, Won Keun
- ACS Applied Materials & Interfaces, Vol. 8, Issue 47
High-Performance Lithium Metal Negative Electrode with a Soft and Flowable Polymer Coating
journal, November 2016
- Zheng, Guangyuan; Wang, Chao; Pei, Allen
- ACS Energy Letters, Vol. 1, Issue 6
Regulating Li deposition at artificial solid electrolyte interphases
journal, January 2017
- Fan, Lei; Zhuang, Houlong L.; Gao, Lina
- Journal of Materials Chemistry A, Vol. 5, Issue 7
Cycling characteristics of lithium metal batteries assembled with a surface modified lithium electrode
journal, December 2013
- Choi, Sung Min; Kang, Ik Su; Sun, Yang-Kook
- Journal of Power Sources, Vol. 244
A facile surface chemistry route to a stabilized lithium metal anode
journal, July 2017
- Liang, Xiao; Pang, Quan; Kochetkov, Ivan R.
- Nature Energy, Vol. 2, Issue 9
Ionic-Liquid-Nanoparticle Hybrid Electrolytes: Applications in Lithium Metal Batteries
journal, November 2013
- Lu, Yingying; Korf, Kevin; Kambe, Yu
- Angewandte Chemie International Edition, Vol. 53, Issue 2
Stabilizing lithium metal using ionic liquids for long-lived batteries
journal, June 2016
- Basile, A.; Bhatt, A. I.; O’Mullane, A. P.
- Nature Communications, Vol. 7, Issue 1
Unusual Stability of Acetonitrile-Based Superconcentrated Electrolytes for Fast-Charging Lithium-Ion Batteries
journal, March 2014
- Yamada, Yuki; Furukawa, Keizo; Sodeyama, Keitaro
- Journal of the American Chemical Society, Vol. 136, Issue 13, p. 5039-5046
A new class of Solvent-in-Salt electrolyte for high-energy rechargeable metallic lithium batteries
journal, February 2013
- Suo, Liumin; Hu, Yong-Sheng; Li, Hong
- Nature Communications, Vol. 4, Issue 1
High rate and stable cycling of lithium metal anode
journal, February 2015
- Qian, Jiangfeng; Henderson, Wesley A.; Xu, Wu
- Nature Communications, Vol. 6, Issue 1
Stable lithium electrodeposition in liquid and nanoporous solid electrolytes
journal, August 2014
- Lu, Yingying; Tu, Zhengyuan; Archer, Lynden A.
- Nature Materials, Vol. 13, Issue 10
Effect of vinylene carbonate as additive to electrolyte for lithium metal anode
journal, February 2004
- Ota, Hitoshi; Shima, Kunihisa; Ue, Makoto
- Electrochimica Acta, Vol. 49, Issue 4
Role of LiNO3 in rechargeable lithium/sulfur battery
journal, May 2012
- Zhang, Sheng S.
- Electrochimica Acta, Vol. 70
The synergetic effect of lithium polysulfide and lithium nitrate to prevent lithium dendrite growth
journal, June 2015
- Li, Weiyang; Yao, Hongbin; Yan, Kai
- Nature Communications, Vol. 6, Issue 1
High capacity of lithium-sulfur batteries at low electrolyte/sulfur ratio enabled by an organosulfide containing electrolyte
journal, January 2017
- Chen, Shuru; Gao, Yue; Yu, Zhaoxin
- Nano Energy, Vol. 31
Synergism of Al-containing solid electrolyte interphase layer and Al-based colloidal particles for stable lithium anode
journal, June 2017
- Ye, Huan; Yin, Ya-Xia; Zhang, Shuai-Feng
- Nano Energy, Vol. 36
Fluoroethylene Carbonate as an Important Component for the Formation of an Effective Solid Electrolyte Interphase on Anodes and Cathodes for Advanced Li-Ion Batteries
journal, May 2017
- Markevich, Elena; Salitra, Gregory; Aurbach, Doron
- ACS Energy Letters, Vol. 2, Issue 6
Suppression of Lithium Dendrite Growth Using Cross-Linked Polyethylene/Poly(ethylene oxide) Electrolytes: A New Approach for Practical Lithium-Metal Polymer Batteries
journal, May 2014
- Khurana, Rachna; Schaefer, Jennifer L.; Archer, Lynden A.
- Journal of the American Chemical Society, Vol. 136, Issue 20
Control of Grafting Density and Distribution in Graft Polymers by Living Ring-Opening Metathesis Copolymerization
journal, March 2017
- Lin, Tzu-Pin; Chang, Alice B.; Chen, Hsiang-Yun
- Journal of the American Chemical Society, Vol. 139, Issue 10
A dendrite-suppressing composite ion conductor from aramid nanofibres
journal, January 2015
- Tung, Siu-On; Ho, Szushen; Yang, Ming
- Nature Communications, Vol. 6, Issue 1
Highly Stable Sodium Batteries Enabled by Functional Ionic Polymer Membranes
journal, January 2017
- Wei, Shuya; Choudhury, Snehashis; Xu, Jun
- Advanced Materials, Vol. 29, Issue 12
Performance Enhancing Electrolyte Additives for Lithium Ion Batteries with Silicon Anodes
journal, January 2012
- Dalavi, Swapnil; Guduru, Pradeep; Lucht, Brett L.
- Journal of The Electrochemical Society, Vol. 159, Issue 5
Electrolytes and Interphases in Li-Ion Batteries and Beyond
journal, October 2014
- Xu, Kang
- Chemical Reviews, Vol. 114, Issue 23
Works referencing / citing this record:
Highly [010]-oriented, gradient Co-doped LiMnPO4 with enhanced cycling stability as cathode for Li-ion batteries
journal, January 2020
- Wang, Ruijie; Zheng, Jinyun; Feng, Xiangming
- Journal of Solid State Electrochemistry, Vol. 24, Issue 3
Polymer Electrolytes for High Energy Density Ternary Cathode Material-Based Lithium Batteries
journal, February 2019
- Zhang, Huanrui; Zhang, Jianjun; Ma, Jun
- Electrochemical Energy Reviews, Vol. 2, Issue 1
Recent progress in carbon/lithium metal composite anode for safe lithium metal batteries
journal, May 2018
- Li, Tao; Liu, He; Shi, Peng
- Rare Metals, Vol. 37, Issue 6
Dendrite‐Free Lithium Plating Induced by In Situ Transferring Protection Layer from Separator
journal, November 2019
- Hu, Zhiyu; Liu, Fengquan; Gao, Jian
- Advanced Functional Materials, Vol. 30, Issue 5
Bulk Nanostructured Materials Design for Fracture‐Resistant Lithium Metal Anodes
journal, February 2019
- Liu, Shan; Deng, Lijun; Guo, Wenqing
- Advanced Materials, Vol. 31, Issue 15
Large‐Scale Modification of Commercial Copper Foil with Lithiophilic Metal Layer for Li Metal Battery
journal, January 2020
- Cui, Shiqiang; Zhai, Pengbo; Yang, Weiwei
- Small, Vol. 16, Issue 5
Free-standing 3D nitrogen–carbon anchored Cu nanorod arrays: in situ derivation from a metal–organic framework and strategy to stabilize lithium metal anodes
journal, January 2020
- Yin, Dongming; Huang, Gang; Wang, Shaohua
- Journal of Materials Chemistry A, Vol. 8, Issue 3
3D lithiophilic–lithiophobic–lithiophilic dual-gradient porous skeleton for highly stable lithium metal anode
journal, January 2020
- Zheng, Hongfei; Zhang, Qingfei; Chen, Qiulin
- Journal of Materials Chemistry A, Vol. 8, Issue 1
Suppressing Lithium Dendrite Growth via Sinusoidal Ripple Current Produced by Triboelectric Nanogenerators
journal, April 2019
- Zhang, Zailei; Wang, Zhong Lin; Lu, Xianmao
- Advanced Energy Materials, Vol. 9, Issue 20
Exploiting Lithium‐Depleted Cathode Materials for Solid‐State Li Metal Batteries
journal, June 2019
- Wang, Li‐Ping; Wang, Tai‐Shan; Yin, Ya‐Xia
- Advanced Energy Materials, Vol. 9, Issue 28
Highly Elastic Polyrotaxane Binders for Mechanically Stable Lithium Hosts in Lithium‐Metal Batteries
journal, May 2019
- Yoo, Dong‐Joo; Elabd, Ahmed; Choi, Sunghun
- Advanced Materials, Vol. 31, Issue 29
A borate decorated anion-immobilized solid polymer electrolyte for dendrite-free, long-life Li metal batteries
journal, January 2019
- Ma, Cheng; Feng, Yiming; Xing, Fangzhou
- Journal of Materials Chemistry A, Vol. 7, Issue 34
Bio‐Inspired Stable Lithium‐Metal Anodes by Co‐depositing Lithium with a 2D Vermiculite Shuttle
journal, May 2019
- Ma, Qingtao; Sun, Xiaowen; Liu, Ping
- Angewandte Chemie, Vol. 131, Issue 19
Solid/Solid Interfacial Architecturing of Solid Polymer Electrolyte–Based All‐Solid‐State Lithium–Sulfur Batteries by Atomic Layer Deposition
journal, September 2019
- Fan, Zengjie; Ding, Bing; Zhang, Tengfei
- Small, Vol. 15, Issue 46
High‐Rate and Large‐Capacity Lithium Metal Anode Enabled by Volume Conformal and Self‐Healable Composite Polymer Electrolyte
journal, March 2019
- Xia, Shuixin; Lopez, Jeffrey; Liang, Chao
- Advanced Science, Vol. 6, Issue 9
Visual Chemical Detection Mechanism by a Liquid Gating System with Dipole‐Induced Interfacial Molecular Reconfiguration
journal, March 2019
- Fan, Yi; Sheng, Zhizhi; Chen, Jun
- Angewandte Chemie International Edition, Vol. 58, Issue 12
Self‐Stabilized and Strongly Adhesive Supramolecular Polymer Protective Layer Enables Ultrahigh‐Rate and Large‐Capacity Lithium‐Metal Anode
journal, January 2020
- Wang, Gang; Chen, Chao; Chen, Yunhua
- Angewandte Chemie International Edition, Vol. 59, Issue 5
Polymer–inorganic solid–electrolyte interphase for stable lithium metal batteries under lean electrolyte conditions
journal, March 2019
- Gao, Yue; Yan, Zhifei; Gray, Jennifer L.
- Nature Materials, Vol. 18, Issue 4
Three‐Dimensional Graphene/Ag Aerogel for Durable and Stable Li Metal Anodes in Carbonate‐Based Electrolytes
journal, March 2019
- Yang, Yang; Zhao, Min; Geng, Hongbo
- Chemistry – A European Journal, Vol. 25, Issue 19
Salt-Based Organic-Inorganic Nanocomposites: Towards A Stable Lithium Metal/Li 10 GeP 2 S 12 Solid Electrolyte Interface
journal, September 2018
- Gao, Yue; Wang, Daiwei; Li, Yuguang C.
- Angewandte Chemie International Edition, Vol. 57, Issue 41
First principles studies of self-diffusion processes on metallic lithium surfaces
journal, January 2019
- Gaissmaier, Daniel; Fantauzzi, Donato; Jacob, Timo
- The Journal of Chemical Physics, Vol. 150, Issue 4
Highly Tough, Li‐Metal Compatible Organic–Inorganic Double‐Network Solvate Ionogel
journal, April 2019
- Yu, Le; Guo, Songtao; Lu, Yue
- Advanced Energy Materials, Vol. 9, Issue 22
An Interfacial Layer Based on Polymers of Intrinsic Microporosity to Suppress Dendrite Growth on Li Metal Anodes
journal, August 2019
- Qi, Liya; Shang, Luoran; Wu, Kai
- Chemistry – A European Journal, Vol. 25, Issue 52
A novel post-polymerizable polynorbornene prepared via ROMP: easy synthesis and conversion into a free-standing film with high T g and low dielectric constant
journal, January 2018
- Wang, Jiajia; Zhou, Junfeng; Fang, Linxuan
- Materials Chemistry Frontiers, Vol. 2, Issue 8
Fluorine-donating electrolytes enable highly reversible 5-V-class Li metal batteries
journal, January 2018
- Suo, Liumin; Xue, Weijiang; Gobet, Mallory
- Proceedings of the National Academy of Sciences, Vol. 115, Issue 6
Confinement effect and air tolerance of Li plating by lithiophilic poly(vinyl alcohol) coating for dendrite-free Li metal batteries
journal, January 2019
- Wu, Han; Yao, Zhenguo; Wu, Qingping
- Journal of Materials Chemistry A, Vol. 7, Issue 39
Lithiophilic CuO Nanoflowers on Ti‐Mesh Inducing Lithium Lateral Plating Enabling Stable Lithium‐Metal Anodes with Ultrahigh Rates and Ultralong Cycle Life
journal, June 2019
- Huang, Kai; Li, Zhi; Xu, Qunjie
- Advanced Energy Materials, Vol. 9, Issue 29
Elastic and Li-ion–percolating hybrid membrane stabilizes Li metal plating
journal, November 2018
- Pang, Quan; Zhou, Laidong; Nazar, Linda F.
- Proceedings of the National Academy of Sciences, Vol. 115, Issue 49
Two-dimensional molecular brush-functionalized porous bilayer composite separators toward ultrastable high-current density lithium metal anodes
journal, March 2019
- Li, Chuanfa; Liu, Shaohong; Shi, Chenguang
- Nature Communications, Vol. 10, Issue 1
Stable and Safe Lithium Metal Batteries with Ni-Rich Cathodes Enabled by a High Efficiency Flame Retardant Additive
journal, January 2019
- Li, Yuan; An, Yongling; Tian, Yuan
- Journal of The Electrochemical Society, Vol. 166, Issue 13
A self-healing interface on lithium metal with lithium difluoro (bisoxalato) phosphate for enhanced lithium electrochemistry
journal, January 2019
- Zhuang, Jingchun; Wang, Xianshu; Xu, Mengqing
- Journal of Materials Chemistry A, Vol. 7, Issue 45
Single-ion conducting artificial solid electrolyte interphase layers for dendrite-free and highly stable lithium metal anodes
journal, January 2019
- Deng, Kuirong; Han, Dongmei; Ren, Shan
- Journal of Materials Chemistry A, Vol. 7, Issue 21
Efficient Li‐Ion‐Conductive Layer for the Realization of Highly Stable High‐Voltage and High‐Capacity Lithium Metal Batteries
journal, February 2019
- Lee, Jung‐In; Shin, Myungsoo; Hong, Dongki
- Advanced Energy Materials, Vol. 9, Issue 13
2D Materials for Lithium/Sodium Metal Anodes
journal, October 2018
- Zhang, Chanyuan; Wang, Aoxuan; Zhang, Jiahua
- Advanced Energy Materials, Vol. 8, Issue 34
Lithium Silicide Surface Enrichment: A Solution to Lithium Metal Battery
journal, July 2018
- Tang, Wei; Yin, Xuesong; Kang, Sujin
- Advanced Materials, Vol. 30, Issue 34
Eliminating Tip Dendrite Growth by Lorentz Force for Stable Lithium Metal Anodes
journal, April 2019
- Wang, Aoxuan; Deng, Qibo; Deng, Lijun
- Advanced Functional Materials, Vol. 29, Issue 25
Emerging Functional Porous Polymeric and Carbonaceous Materials for Environmental Treatment and Energy Storage
journal, November 2019
- Zheng, Bingna; Lin, Xidong; Zhang, Xingcai
- Advanced Functional Materials, Vol. 30, Issue 41
Salt-Based Organic-Inorganic Nanocomposites: Towards A Stable Lithium Metal/Li 10 GeP 2 S 12 Solid Electrolyte Interface
journal, September 2018
- Gao, Yue; Wang, Daiwei; Li, Yuguang C.
- Angewandte Chemie, Vol. 130, Issue 41
Advances in Artificial Layers for Stable Lithium Metal Anodes
journal, April 2020
- Qi, Liya; Wu, Zhengwei; Zhao, Binglu
- Chemistry – A European Journal, Vol. 26, Issue 19
An ultrathin ionomer interphase for high efficiency lithium anode in carbonate based electrolyte
journal, December 2019
- Weng, Yu-Ting; Liu, Hao-Wen; Pei, Allen
- Nature Communications, Vol. 10, Issue 1
High Ion Conducting Solid Composite Electrolytes with Enhanced Interfacial Compatibility for Lithium Metal Batteries
journal, February 2019
- Feng, Haoyu; Ma, Cheng; Dai, Kuan
- ChemElectroChem, Vol. 6, Issue 3
Self‐Stabilized and Strongly Adhesive Supramolecular Polymer Protective Layer Enables Ultrahigh‐Rate and Large‐Capacity Lithium‐Metal Anode
journal, December 2019
- Wang, Gang; Chen, Chao; Chen, Yunhua
- Angewandte Chemie, Vol. 132, Issue 5
Low-volume-change, dendrite-free lithium metal anodes enabled by lithophilic 3D matrix with LiF-enriched surface
journal, January 2019
- Feng, Yangyang; Zhang, Chaofan; Li, Bing
- Journal of Materials Chemistry A, Vol. 7, Issue 11
Catalytic One‐Pot Conversion of Renewable Platform Chemicals to Hydrocarbon and Ether Biofuels through Tandem Hf(OTf) 4 +Pd/C Catalysis
journal, October 2019
- Liu, Dong‐Huang; Marks, Tobin J.; Li, Zhi
- ChemSusChem, Vol. 12, Issue 24
Boosting the Potassium Storage Performance of Alloy-Based Anode Materials via Electrolyte Salt Chemistry
journal, February 2018
- Zhang, Qing; Mao, Jianfeng; Pang, Wei Kong
- Advanced Energy Materials, Vol. 8, Issue 15
Designing polymers for advanced battery chemistries
journal, April 2019
- Lopez, Jeffrey; Mackanic, David G.; Cui, Yi
- Nature Reviews Materials, Vol. 4, Issue 5
Self‐Formed Protection Layer on a 3D Lithium Metal Anode for Ultrastable Lithium–Sulfur Batteries
journal, April 2019
- Yan, Xinxiu; Zhang, Huan; Huang, Meiling
- ChemSusChem, Vol. 12, Issue 10
Highly Improved Cycling Stability of Anion De-/Intercalation in the Graphite Cathode for Dual-Ion Batteries
journal, November 2018
- Li, Wen-Hao; Ning, Qiu-Li; Xi, Xiao-Tong
- Advanced Materials, Vol. 31, Issue 4
Advanced nanoporous separators for stable lithium metal electrodeposition at ultra-high current densities in liquid electrolytes
journal, January 2020
- Yang, Jingling; Wang, Chun-Yao; Wang, Chun-Chieh
- Journal of Materials Chemistry A, Vol. 8, Issue 10
High-capacity rechargeable batteries based on deeply cyclable lithium metal anodes
journal, May 2018
- Shi, Qiuwei; Zhong, Yiren; Wu, Min
- Proceedings of the National Academy of Sciences, Vol. 115, Issue 22
Boron additive passivated carbonate electrolytes for stable cycling of 5 V lithium–metal batteries
journal, January 2019
- Yue, Hongyun; Yang, Yange; Xiao, Yan
- Journal of Materials Chemistry A, Vol. 7, Issue 2
A fast and stable Li metal anode incorporating an Mo 6 S 8 artificial interphase with super Li-ion conductivity
journal, January 2019
- Lu, Ke; Gao, Siyuan; Dick, Robert J.
- Journal of Materials Chemistry A, Vol. 7, Issue 11
In situ formed polymer gel electrolytes for lithium batteries with inherent thermal shutdown safety features
journal, January 2019
- Zhou, Hongyao; Liu, Haodong; Li, Yejing
- Journal of Materials Chemistry A, Vol. 7, Issue 28
Bio‐Inspired Stable Lithium‐Metal Anodes by Co‐depositing Lithium with a 2D Vermiculite Shuttle
journal, May 2019
- Ma, Qingtao; Sun, Xiaowen; Liu, Ping
- Angewandte Chemie International Edition, Vol. 58, Issue 19
Dual‐Layered Film Protected Lithium Metal Anode to Enable Dendrite‐Free Lithium Deposition
journal, April 2018
- Yan, Chong; Cheng, Xin‐Bing; Tian, Yang
- Advanced Materials, Vol. 30, Issue 25
Infrared spectra, structure and bonding in the LiO 2 , LiO 2 Li, LiO and Li 2 O molecules in solid neon
journal, April 2009
- Wang, Xuefeng; Andrews, Lester
- Molecular Physics, Vol. 107, Issue 8-12
Visual Chemical Detection Mechanism by a Liquid Gating System with Dipole‐Induced Interfacial Molecular Reconfiguration
journal, February 2019
- Fan, Yi; Sheng, Zhizhi; Chen, Jun
- Angewandte Chemie, Vol. 131, Issue 12
High‐Rate and Large‐Capacity Lithium Metal Anode Enabled by Volume Conformal and Self‐Healable Composite Polymer Electrolyte
journal, March 2019
- Xia, Shuixin; Lopez, Jeffrey; Liang, Chao
- Advanced Science, Vol. 6, Issue 9
Robust Pinhole-free Li 3 N Solid Electrolyte Grown from Molten Lithium
journal, December 2017
- Li, Yanbin; Sun, Yongming; Pei, Allen
- ACS Central Science, Vol. 4, Issue 1
Two-dimensional molecular brush-functionalized porous bilayer composite separators toward ultrastable high-current density lithium metal anodes
journal, March 2019
- Li, Chuanfa; Liu, Shaohong; Shi, Chenguang
- Nature Communications, Vol. 10, Issue 1
An ultrathin ionomer interphase for high efficiency lithium anode in carbonate based electrolyte
journal, December 2019
- Weng, Yu-Ting; Liu, Hao-Wen; Pei, Allen
- Nature Communications, Vol. 10, Issue 1