A Fluorinated Ether Electrolyte Enabled High Performance Prelithiated Graphite/Sulfur Batteries
Abstract
Lithium/sulfur (Li/S) batteries have attracted great attention as a promising energy storage technology, but so far their practical applications are greatly hindered by issues of polysulfide shuttling and unstable lithium/electrolyte interface. To address these issues, a feasible strategy is to construct a rechargeable prelithiated graphite/sulfur batteries. In this study, a fluorinated ether of bis(2,2,2-trifluoroethyl) ether (BTFE) was reported to blend with 1,3-dioxolane (DOL) for making a multifunctional electrolyte of 1.0 M LiTFSI DOL/BTFE (1:1, v/v) to enable high performance prelithiated graphite/S batteries. First, the electrolyte significantly reduces polysulfide solubility to suppress the deleterious polysulfide shuttling and thus improves capacity retention of sulfur cathodes. Second, thanks to the low viscosity and good wettability, the fluorinated electrolyte dramatically enhances the reaction kinetics and sulfur utilization of high-areal-loading sulfur cathodes. More importantly, this electrolyte forms a stable solid-electrolyte interphase (SEI) layer on graphite surface and thus enables remarkable cyclability of graphite anodes. Lastly, by coupling prelithiated graphite anodes with sulfur cathodes with high areal capacity of ~3 mAh cm-2, we demonstrate prelithiated graphite/sulfur batteries that show high sulfur-specific capacity of ~1000 mAh g-1 and an excellent capacity retention of >65% after 450 cycles at C/10.
- Authors:
-
- Pennsylvania State Univ., University Park, PA (United States). Dept. of Mechanical and Nuclear Engineering
- Publication Date:
- Research Org.:
- Pennsylvania State Univ., University Park, PA (United States). Dept. of Mechanical and Nuclear Engineering; Pennsylvania State Univ., University Park, PA (United States). Department of Mechanical and Nuclear Engineering
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V)
- OSTI Identifier:
- 1435968
- Alternate Identifier(s):
- OSTI ID: 1430247
- Report Number(s):
- DOE-PENNSTATE-0007795; DOE-PENN STATE-0007795
Journal ID: ISSN 1944-8244; PII:974; TRN: US1900117
- Grant/Contract Number:
- EE0007795; EE0005475
- Resource Type:
- Accepted Manuscript
- Journal Name:
- ACS Applied Materials and Interfaces
- Additional Journal Information:
- Journal Volume: 9; Journal Issue: 8; Journal ID: ISSN 1944-8244
- Publisher:
- American Chemical Society (ACS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; 36 MATERIALS SCIENCE; 77 NANOSCIENCE AND NANOTECHNOLOGY; 42 ENGINEERING; batteries; fluorinated electrolytes; graphite; lithium/sulfur; prelithiated
Citation Formats
Chen, Shuru, Yu, Zhaoxin, Gordin, Mikhail L., Yi, Ran, Song, Jiangxuan, and Wang, Donghai. A Fluorinated Ether Electrolyte Enabled High Performance Prelithiated Graphite/Sulfur Batteries. United States: N. p., 2017.
Web. doi:10.1021/acsami.6b11008.
Chen, Shuru, Yu, Zhaoxin, Gordin, Mikhail L., Yi, Ran, Song, Jiangxuan, & Wang, Donghai. A Fluorinated Ether Electrolyte Enabled High Performance Prelithiated Graphite/Sulfur Batteries. United States. https://doi.org/10.1021/acsami.6b11008
Chen, Shuru, Yu, Zhaoxin, Gordin, Mikhail L., Yi, Ran, Song, Jiangxuan, and Wang, Donghai. Fri .
"A Fluorinated Ether Electrolyte Enabled High Performance Prelithiated Graphite/Sulfur Batteries". United States. https://doi.org/10.1021/acsami.6b11008. https://www.osti.gov/servlets/purl/1435968.
@article{osti_1435968,
title = {A Fluorinated Ether Electrolyte Enabled High Performance Prelithiated Graphite/Sulfur Batteries},
author = {Chen, Shuru and Yu, Zhaoxin and Gordin, Mikhail L. and Yi, Ran and Song, Jiangxuan and Wang, Donghai},
abstractNote = {Lithium/sulfur (Li/S) batteries have attracted great attention as a promising energy storage technology, but so far their practical applications are greatly hindered by issues of polysulfide shuttling and unstable lithium/electrolyte interface. To address these issues, a feasible strategy is to construct a rechargeable prelithiated graphite/sulfur batteries. In this study, a fluorinated ether of bis(2,2,2-trifluoroethyl) ether (BTFE) was reported to blend with 1,3-dioxolane (DOL) for making a multifunctional electrolyte of 1.0 M LiTFSI DOL/BTFE (1:1, v/v) to enable high performance prelithiated graphite/S batteries. First, the electrolyte significantly reduces polysulfide solubility to suppress the deleterious polysulfide shuttling and thus improves capacity retention of sulfur cathodes. Second, thanks to the low viscosity and good wettability, the fluorinated electrolyte dramatically enhances the reaction kinetics and sulfur utilization of high-areal-loading sulfur cathodes. More importantly, this electrolyte forms a stable solid-electrolyte interphase (SEI) layer on graphite surface and thus enables remarkable cyclability of graphite anodes. Lastly, by coupling prelithiated graphite anodes with sulfur cathodes with high areal capacity of ~3 mAh cm-2, we demonstrate prelithiated graphite/sulfur batteries that show high sulfur-specific capacity of ~1000 mAh g-1 and an excellent capacity retention of >65% after 450 cycles at C/10.},
doi = {10.1021/acsami.6b11008},
journal = {ACS Applied Materials and Interfaces},
number = 8,
volume = 9,
place = {United States},
year = {Fri Feb 03 00:00:00 EST 2017},
month = {Fri Feb 03 00:00:00 EST 2017}
}
Web of Science
Figures / Tables:
Works referenced in this record:
Li–O2 and Li–S batteries with high energy storage
journal, January 2012
- Bruce, Peter G.; Freunberger, Stefan A.; Hardwick, Laurence J.
- Nature Materials, Vol. 11, Issue 1, p. 19-29
Rechargeable Lithium–Sulfur Batteries
journal, July 2014
- Manthiram, Arumugam; Fu, Yongzhu; Chung, Sheng-Heng
- Chemical Reviews, Vol. 114, Issue 23
Electrochemistry of a nonaqueous lithium/sulfur cell
journal, January 1983
- Yamin, H.; Peled, E.
- Journal of Power Sources, Vol. 9, Issue 3
The Lithium/Sulfur Rechargeable Cell
journal, January 2002
- Shim, Joongpyo; Striebel, Kathryn A.; Cairns, Elton J.
- Journal of The Electrochemical Society, Vol. 149, Issue 10
Rechargeable Lithium Sulfur Battery
journal, May 2003
- Cheon, Sang-Eun; Ko, Ki-Seok; Cho, Ji-Hoon
- Journal of The Electrochemical Society, Vol. 150, Issue 6, p. A800-A805
Rechargeable Lithium Sulfur Battery
journal, January 2003
- Cheon, Sang-Eun; Ko, Ki-Seok; Cho, Ji-Hoon
- Journal of The Electrochemical Society, Vol. 150, Issue 6
Li/S fundamental chemistry and application to high-performance rechargeable batteries
journal, November 2004
- Akridge, J.
- Solid State Ionics, Vol. 175, Issue 1-4
Smaller Sulfur Molecules Promise Better Lithium–Sulfur Batteries
journal, October 2012
- Xin, Sen; Gu, Lin; Zhao, Na-Hong
- Journal of the American Chemical Society, Vol. 134, Issue 45
A highly ordered nanostructured carbon–sulphur cathode for lithium–sulphur batteries
journal, May 2009
- Ji, Xiulei; Lee, Kyu Tae; Nazar, Linda F.
- Nature Materials, Vol. 8, Issue 6, p. 500-506
Ordered mesoporous carbon/sulfur nanocomposite of high performances as cathode for lithium–sulfur battery
journal, November 2011
- Chen, Shu-Ru; Zhai, Yun-Pu; Xu, Gui-Liang
- Electrochimica Acta, Vol. 56, Issue 26, p. 9549-9555
Porous Hollow Carbon@Sulfur Composites for High-Power Lithium-Sulfur Batteries
journal, May 2011
- Jayaprakash, N.; Shen, J.; Moganty, Surya S.
- Angewandte Chemie International Edition, Vol. 50, Issue 26, p. 5904-5908
Facile synthesis of a interleaved expanded graphite-embedded sulphur nanocomposite as cathode of Li–S batteries with excellent lithium storage performance
journal, January 2012
- Wang, Yun-Xiao; Huang, Ling; Sun, Li-Chao
- Journal of Materials Chemistry, Vol. 22, Issue 11
Advanced Sulfur Cathode Enabled by Highly Crumpled Nitrogen-Doped Graphene Sheets for High-Energy-Density Lithium–Sulfur Batteries
journal, January 2016
- Song, Jiangxuan; Yu, Zhaoxin; Gordin, Mikhail L.
- Nano Letters, Vol. 16, Issue 2
Strong Lithium Polysulfide Chemisorption on Electroactive Sites of Nitrogen-Doped Carbon Composites For High-Performance Lithium-Sulfur Battery Cathodes
journal, February 2015
- Song, Jiangxuan; Gordin, Mikhail L.; Xu, Terrence
- Angewandte Chemie International Edition, Vol. 54, Issue 14
Nanostructured sulfur cathodes
journal, January 2013
- Yang, Yuan; Zheng, Guangyuan; Cui, Yi
- Chemical Society Reviews, Vol. 42, Issue 7, p. 3018-3032
Sulphur–TiO2 yolk–shell nanoarchitecture with internal void space for long-cycle lithium–sulphur batteries
journal, January 2013
- Wei Seh, Zhi; Li, Weiyang; Cha, Judy J.
- Nature Communications, Vol. 4, Article No. 1331
Insight into the Effect of Boron Doping on Sulfur/Carbon Cathode in Lithium–Sulfur Batteries
journal, April 2014
- Yang, Chun-Peng; Yin, Ya-Xia; Ye, Huan
- ACS Applied Materials & Interfaces, Vol. 6, Issue 11
Structural and chemical synergistic encapsulation of polysulfides enables ultralong-life lithium–sulfur batteries
journal, January 2016
- Wang, Xiaolei; Li, Ge; Li, Jingde
- Energy & Environmental Science, Vol. 9, Issue 8
Sulfur Nanogranular Film-Coated Three-Dimensional Graphene Sponge-Based High Power Lithium Sulfur Battery
journal, January 2016
- Ahn, Wook; Seo, Min Ho; Jun, Yun-Seok
- ACS Applied Materials & Interfaces, Vol. 8, Issue 3
A graphene foam electrode with high sulfur loading for flexible and high energy Li-S batteries
journal, January 2015
- Zhou, Guangmin; Li, Lu; Ma, Chaoqun
- Nano Energy, Vol. 11
High-Energy-Density Lithium–Sulfur Batteries Based on Blade-Cast Pure Sulfur Electrodes
journal, April 2016
- Qie, Long; Manthiram, Arumugam
- ACS Energy Letters, Vol. 1, Issue 1
High Energy Density Lithium-Sulfur Batteries: Challenges of Thick Sulfur Cathodes
journal, March 2015
- Lv, Dongping; Zheng, Jianming; Li, Qiuyan
- Advanced Energy Materials, Vol. 5, Issue 16, Article No. 1402290
Liquid electrolyte lithium/sulfur battery: Fundamental chemistry, problems, and solutions
journal, June 2013
- Zhang, Sheng S.
- Journal of Power Sources, Vol. 231, p. 153-162
New insights into the limiting parameters of the Li/S rechargeable cell
journal, February 2012
- Barchasz, Céline; Leprêtre, Jean-Claude; Alloin, Fannie
- Journal of Power Sources, Vol. 199, p. 322-330
Failure Mechanism for Fast-Charged Lithium Metal Batteries with Liquid Electrolytes
journal, September 2014
- Lu, Dongping; Shao, Yuyan; Lozano, Terence
- Advanced Energy Materials, Vol. 5, Issue 3
Lithium Sulfur Primary Battery with Super High Energy Density: Based on the Cauliflower-like Structured C/S Cathode
journal, October 2015
- Ma, Yiwen; Zhang, Hongzhang; Wu, Baoshan
- Scientific Reports, Vol. 5, Issue 1
Polysulfide dissolution control: the common ion effect
journal, January 2013
- Shin, Eon Sung; Kim, Keon; Oh, Si Hyoung
- Chem. Commun., Vol. 49, Issue 20
A new class of Solvent-in-Salt electrolyte for high-energy rechargeable metallic lithium batteries
journal, February 2013
- Suo, Liumin; Hu, Yong-Sheng; Li, Hong
- Nature Communications, Vol. 4, Issue 1
Review—Superconcentrated Electrolytes for Lithium Batteries
journal, January 2015
- Yamada, Yuki; Yamada, Atsuo
- Journal of The Electrochemical Society, Vol. 162, Issue 14
Solvate Ionic Liquid Electrolyte for Li–S Batteries
journal, January 2013
- Dokko, Kaoru; Tachikawa, Naoki; Yamauchi, Kento
- Journal of The Electrochemical Society, Vol. 160, Issue 8
Phosphorous Pentasulfide as a Novel Additive for High-Performance Lithium-Sulfur Batteries
journal, June 2012
- Lin, Zhan; Liu, Zengcai; Fu, Wujun
- Advanced Functional Materials, Vol. 23, Issue 8
Improved cycling performances of lithium sulfur batteries with LiNO3-modified electrolyte
journal, November 2011
- Liang, Xiao; Wen, Zhaoyin; Liu, Yu
- Journal of Power Sources, Vol. 196, Issue 22
Role of LiNO3 in rechargeable lithium/sulfur battery
journal, May 2012
- Zhang, Sheng S.
- Electrochimica Acta, Vol. 70
Fluorinated Electrolytes for Li-S Battery: Suppressing the Self-Discharge with an Electrolyte Containing Fluoroether Solvent
journal, November 2014
- Azimi, Nasim; Xue, Zheng; Rago, Nancy Dietz
- Journal of The Electrochemical Society, Vol. 162, Issue 1
Bis(2,2,2-trifluoroethyl) Ether As an Electrolyte Co-solvent for Mitigating Self-Discharge in Lithium–Sulfur Batteries
journal, May 2014
- Gordin, Mikhail L.; Dai, Fang; Chen, Shuru
- ACS Applied Materials & Interfaces, Vol. 6, Issue 11
High performance Li-ion sulfur batteries enabled by intercalation chemistry
journal, January 2015
- Lv, Dongping; Yan, Pengfei; Shao, Yuyan
- Chemical Communications, Vol. 51, Issue 70
A Graphite-Polysulfide Full Cell with DME-Based Electrolyte
journal, January 2016
- Bhargav, Amruth; Wu, Min; Fu, Yongzhu
- Journal of The Electrochemical Society, Vol. 163, Issue 8
Solvent Activity in Electrolyte Solutions Controls Electrochemical Reactions in Li-Ion and Li-Sulfur Batteries
journal, February 2015
- Moon, Heejoon; Mandai, Toshihiko; Tatara, Ryoichi
- The Journal of Physical Chemistry C, Vol. 119, Issue 8
Promising Cell Configuration for Next-Generation Energy Storage: Li 2 S/Graphite Battery Enabled by a Solvate Ionic Liquid Electrolyte
journal, June 2016
- Li, Zhe; Zhang, Shiguo; Terada, Shoshi
- ACS Applied Materials & Interfaces, Vol. 8, Issue 25
Carbon-Based Anodes for Lithium Sulfur Full Cells with High Cycle Stability
journal, August 2013
- Brückner, Jan; Thieme, Sören; Böttger-Hiller, Falko
- Advanced Functional Materials, Vol. 24, Issue 9
Prelithiated Silicon Nanowires as an Anode for Lithium Ion Batteries
journal, July 2011
- Liu, Nian; Hu, Liangbing; McDowell, Matthew T.
- ACS Nano, Vol. 5, Issue 8
A High-Performance Polymer Tin Sulfur Lithium Ion Battery
journal, February 2010
- Hassoun, Jusef; Scrosati, Bruno
- Angewandte Chemie International Edition, Vol. 49, Issue 13, p. 2371-2374
Recent studies on the correlation between surface chemistry, morphology, three-dimensional structures and performance of Li and Li-C intercalation anodes in several important electrolyte systems
journal, September 1997
- Aurbach, D.; Zaban, A.; Ein-Eli, Y.
- Journal of Power Sources, Vol. 68, Issue 1
The Effect of Interactions and Reduction Products of LiNO 3 , the Anti-Shuttle Agent, in Li-S Battery Systems
journal, December 2014
- Rosenman, Ariel; Elazari, Ran; Salitra, Gregory
- Journal of The Electrochemical Society, Vol. 162, Issue 3
Effect of Discharge Cutoff Voltage on Reversibility of Lithium/Sulfur Batteries with LiNO 3 -Contained Electrolyte
journal, January 2012
- Zhang, Sheng S.
- Journal of The Electrochemical Society, Vol. 159, Issue 7
Lithium-Sulfur Cells: The Gap between the State-of-the-Art and the Requirements for High Energy Battery Cells
journal, April 2015
- Hagen, Markus; Hanselmann, Dominik; Ahlbrecht, Katharina
- Advanced Energy Materials, Vol. 5, Issue 16, 1401986
Unique behaviour of nonsolvents for polysulphides in lithium–sulphur batteries
journal, January 2014
- Cuisinier, M.; Cabelguen, P. -E.; Adams, B. D.
- Energy Environ. Sci., Vol. 7, Issue 8
Anodes for Rechargeable Lithium-Sulfur Batteries
journal, April 2015
- Cao, Ruiguo; Xu, Wu; Lv, Dongping
- Advanced Energy Materials, Vol. 5, Issue 16
Improved performance of lithium–sulfur battery with fluorinated electrolyte
journal, December 2013
- Azimi, Nasim; Weng, Wei; Takoudis, Christos
- Electrochemistry Communications, Vol. 37
Insight into lithium–metal anodes in lithium–sulfur batteries with a fluorinated ether electrolyte
journal, January 2015
- Zu, Chenxi; Azimi, Nasim; Zhang, Zhengcheng
- Journal of Materials Chemistry A, Vol. 3, Issue 28
Works referencing / citing this record:
Anode Interface Engineering and Architecture Design for High‐Performance Lithium–Sulfur Batteries
journal, January 2019
- Zhao, Yuanyuan; Ye, Yusheng; Wu, Feng
- Advanced Materials, Vol. 31, Issue 12
A rechargeable metal-free full-liquid sulfur–bromine battery for sustainable energy storage
journal, January 2018
- Wang, Lina; Wang, Xiaofei; Liu, Jingyuan
- Journal of Materials Chemistry A, Vol. 6, Issue 42
High-Voltage LiNi 0.5 Mn 1.5 O 4 Cathode Stability of Fluorinated Ether Based on Enhanced Separator Wettability
journal, January 2019
- Zheng, Hao; Zhou, Xin; Cheng, Sheng
- Journal of The Electrochemical Society, Vol. 166, Issue 8
Toward High Performance Lithium-Sulfur Batteries Based on Li 2 S Cathodes and Beyond: Status, Challenges, and Perspectives
journal, March 2018
- Su, Dawei; Zhou, Dong; Wang, Chengyin
- Advanced Functional Materials, Vol. 28, Issue 38
Stable and Safe Lithium Metal Batteries with Ni-Rich Cathodes Enabled by a High Efficiency Flame Retardant Additive
journal, January 2019
- Li, Yuan; An, Yongling; Tian, Yuan
- Journal of The Electrochemical Society, Vol. 166, Issue 13
A hybrid ionic liquid-based electrolyte for high-performance lithium–sulfur batteries
journal, January 2020
- Lu, Hai; Zhu, Yan; Zheng, Bin
- New Journal of Chemistry, Vol. 44, Issue 2
Realizing High-Performance Li-Polysulfide Full Cells by using a Lithium Bis(trifluoromethanesulfonyl)imide Salt Electrolyte for Stable Cyclability
journal, August 2018
- Ahad, Syed Abdul; Pitchai, Ragupathy; Beyene, Anteneh Marelign
- ChemSusChem, Vol. 11, Issue 19
Toward Better Lithium–Sulfur Batteries: Functional Non-aqueous Liquid Electrolytes
journal, August 2018
- Xiong, Shizhao; Regula, Michael; Wang, Donghai
- Electrochemical Energy Reviews, Vol. 1, Issue 3
Lithium Molybdate (Li 2 MoO 3 )−Sulfur Battery
journal, January 2020
- Dharmasena, Ruchira R.; Martinez‐Garcia, Alejandro; Atla, Veerendra
- Batteries & Supercaps, Vol. 3, Issue 3
Revisiting the Role of Polysulfides in Lithium-Sulfur Batteries
journal, March 2018
- Li, Gaoran; Wang, Shun; Zhang, Yining
- Advanced Materials, Vol. 30, Issue 22
Pre-Lithiation Strategies for Rechargeable Energy Storage Technologies: Concepts, Promises and Challenges
journal, January 2018
- Holtstiege, Florian; Bärmann, Peer; Nölle, Roman
- Batteries, Vol. 4, Issue 1
Reduced Shuttle Effect of Lithium−sulfur Batteries by using a Simple Graphite-Modified Separator with a Preformed SEI Film
journal, November 2017
- Zeng, Pan; Huang, Liwu; Han, Yamiao
- ChemElectroChem, Vol. 5, Issue 2
Development and Challenges of Functional Electrolytes for High-Performance Lithium-Sulfur Batteries
journal, July 2018
- Wang, Lili; Ye, Yusheng; Chen, Nan
- Advanced Functional Materials, Vol. 28, Issue 38
Effect of soluble sulfur species on the electrochemical behavior of lithium–sulfur batteries with dual-phase electrolytes
journal, January 2019
- Zhao, Chengcheng; Yang, Hao; Wang, Xiaofei
- Sustainable Energy & Fuels, Vol. 3, Issue 8
Structure-Property Relationships of Organic Electrolytes and Their Effects on Li/S Battery Performance
journal, June 2017
- Kaiser, Mohammad Rejaul; Chou, Shulei; Liu, Hua-Kun
- Advanced Materials, Vol. 29, Issue 48
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