Polymer‐in‐“Quasi‐Ionic Liquid” Electrolytes for High‐Voltage Lithium Metal Batteries

Wu, Haiping; Xu, Yaobin; Ren, Xiaodi; Liu, Bin; Engelhard, Mark H.; Ding, Michael S.; El‐Khoury, Patrick Z.; Zhang, Linchao; Li, Qiuyan; Xu, Kang; Wang, Chongmin; Zhang, Ji‐Guang; Xu, Wu

doi:10.1002/aenm.201902108

Title: Polymer‐in‐“Quasi‐Ionic Liquid” Electrolytes for High‐Voltage Lithium Metal Batteries

Authors:

Wu, Haiping ^[1]; Xu, Yaobin ^[2]; Ren, Xiaodi ^[1]; Liu, Bin ^[1]; Engelhard, Mark H. ^[2]; Ding, Michael S. ^[3]; El‐Khoury, Patrick Z. ^[2]; Zhang, Linchao ^[4]; Li, Qiuyan ^[1]; Xu, Kang ^[3]; Wang, Chongmin ^[2]; Zhang, Ji‐Guang ^[1];

^[1]

Energy and Environment Directorate Pacific Northwest National Laboratory Richland WA 99354 USA
Environmental Molecular Sciences Laboratory Pacific Northwest National Laboratory Richland WA 99354 USA
Electrochemistry Branch U.S. Army Research Laboratory Adelphi MD 20783 USA
Energy and Environment Directorate Pacific Northwest National Laboratory Richland WA 99354 USA, Key Laboratory of Materials Physics Institute of Solid State Physics Chinese Academy of Sciences Hefei Anhui 230026 China

Publication Date:: 2019-09-18

Sponsoring Org.:: USDOE

OSTI Identifier:: 1562552

Grant/Contract Number:: DE‐AC02‐05CH11231; DE‐AC05‐76RLO1830

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Advanced Energy Materials

Additional Journal Information:: Journal Name: Advanced Energy Materials Journal Volume: 9 Journal Issue: 41; Journal ID: ISSN 1614-6832

Publisher:: Wiley Blackwell (John Wiley & Sons)

Country of Publication:: Germany

Language:: English

Citation Formats


                    Wu, Haiping, Xu, Yaobin, Ren, Xiaodi, Liu, Bin, Engelhard, Mark H., Ding, Michael S., El‐Khoury, Patrick Z., Zhang, Linchao, Li, Qiuyan, Xu, Kang, Wang, Chongmin, Zhang, Ji‐Guang, and Xu, Wu. Polymer‐in‐“Quasi‐Ionic Liquid” Electrolytes for High‐Voltage Lithium Metal Batteries.  Germany: N. p., 2019. 
Web.  doi:10.1002/aenm.201902108.

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                    Wu, Haiping, Xu, Yaobin, Ren, Xiaodi, Liu, Bin, Engelhard, Mark H., Ding, Michael S., El‐Khoury, Patrick Z., Zhang, Linchao, Li, Qiuyan, Xu, Kang, Wang, Chongmin, Zhang, Ji‐Guang, & Xu, Wu. Polymer‐in‐“Quasi‐Ionic Liquid” Electrolytes for High‐Voltage Lithium Metal Batteries.  Germany.  https://doi.org/10.1002/aenm.201902108

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                    Wu, Haiping, Xu, Yaobin, Ren, Xiaodi, Liu, Bin, Engelhard, Mark H., Ding, Michael S., El‐Khoury, Patrick Z., Zhang, Linchao, Li, Qiuyan, Xu, Kang, Wang, Chongmin, Zhang, Ji‐Guang, and Xu, Wu. Wed .  
"Polymer‐in‐“Quasi‐Ionic Liquid” Electrolytes for High‐Voltage Lithium Metal Batteries".  Germany.  https://doi.org/10.1002/aenm.201902108.

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@article{osti_1562552,

  title        = {Polymer‐in‐“Quasi‐Ionic Liquid” Electrolytes for High‐Voltage Lithium Metal Batteries},

  author       = {Wu, Haiping and Xu, Yaobin and Ren, Xiaodi and Liu, Bin and Engelhard, Mark H. and Ding, Michael S. and El‐Khoury, Patrick Z. and Zhang, Linchao and Li, Qiuyan and Xu, Kang and Wang, Chongmin and Zhang, Ji‐Guang and Xu, Wu},

  abstractNote = {},

  doi          = {10.1002/aenm.201902108},

  journal      = {Advanced Energy Materials},

  number       = 41,

  volume       = 9,

  place        = {Germany},

  year         = {2019},

  month        = {9}

}

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https://doi.org/10.1002/aenm.201902108

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Title: Polymer‐in‐“Quasi‐Ionic Liquid” Electrolytes for High‐Voltage Lithium Metal Batteries

Citation Formats

High-Voltage Lithium-Metal Batteries Enabled by Localized High-Concentration Electrolytes journal, March 2018

Supramolecular Self-Assembly of Methylated Rotaxanes for Solid Polymer Electrolyte Application journal, June 2018

Negating interfacial impedance in garnet-based solid-state Li metal batteries journal, December 2016

XPS and SIMS Analysis of Solid Electrolyte Interphases on Lithium Formed by Ether-Based Electrolytes journal, January 2017

In Situ Formation of Protective Coatings on Sulfur Cathodes in Lithium Batteries with LiFSI-Based Organic Electrolytes journal, December 2014

Superconcentrated electrolytes for a high-voltage lithium-ion battery journal, June 2016

Surface reconstruction and chemical evolution of stoichiometric layered cathode materials for lithium-ion batteries journal, March 2014

Ionic Liquids: Past, present and future journal, January 2012

Localized High-Concentration Sulfone Electrolytes for High-Efficiency Lithium-Metal Batteries journal, August 2018

Lithium Metal Stability in Batteries with Block Copolymer Electrolytes journal, January 2013

Suppressed oxygen extraction and degradation of LiNi x Mn y Co z O2 cathodes at high charge cut-off voltages journal, September 2017

Polymer–inorganic solid–electrolyte interphase for stable lithium metal batteries under lean electrolyte conditions journal, March 2019

Characterization of the Cathode Electrolyte Interface in Lithium Ion Batteries by Desorption Electrospray Ionization Mass Spectrometry journal, July 2016

Double-Layer Polymer Electrolyte for High-Voltage All-Solid-State Rechargeable Batteries journal, December 2018

Physicochemical Properties of Glyme–Li Salt Complexes as a New Family of Room-temperature Ionic Liquids journal, July 2010

Electrochemical measurement of transference numbers in polymer electrolytes journal, December 1987

Non-flammable electrolyte enables Li-metal batteries with aggressive cathode chemistries journal, July 2018

Accurate Determination of Coulombic Efficiency for Lithium Metal Anodes and Lithium Metal Batteries journal, October 2017

A Highly Reversible Lithium Metal Anode journal, January 2014

High-Concentration Ether Electrolytes for Stable High-Voltage Lithium Metal Batteries journal, March 2019

High-power all-solid-state batteries using sulfide superionic conductors journal, March 2016

Ultrahigh Performance All Solid-State Lithium Sulfur Batteries: Salt Anion’s Chemistry-Induced Anomalous Synergistic Effect journal, July 2018

Complexes of alkali metal ions with poly(ethylene oxide) journal, November 1973

Criteria for solvate ionic liquids journal, January 2014

Toward Safe Lithium Metal Anode in Rechargeable Batteries: A Review journal, July 2017

Nonaqueous Liquid Electrolytes for Lithium-Based Rechargeable Batteries journal, October 2004

In-Depth Interfacial Chemistry and Reactivity Focused Investigation of Lithium–Imide- and Lithium–Imidazole-Based Electrolytes journal, June 2016

Grafted polyrotaxanes as highly conductive electrolytes for lithium metal batteries journal, January 2019

Electrolytes and Interphases in Li-Ion Batteries and Beyond journal, October 2014

Identification of Surface Films Formed on Lithium in Dimethoxyethane and Tetrahydrofuran Solutions journal, January 1988

The Lithium-Oxygen Battery with Ether-Based Electrolytes journal, July 2011

Single lithium-ion conducting solid polymer electrolytes: advances and perspectives journal, January 2017

Lithium metal anodes for rechargeable batteries journal, January 2014

Stabilizing lithium metal using ionic liquids for long-lived batteries journal, June 2016

Stable cycling of high-voltage lithium metal batteries in ether electrolytes journal, July 2018

Fluorine-donating electrolytes enable highly reversible 5-V-class Li metal batteries journal, January 2018

A superconcentrated ether electrolyte for fast-charging Li-ion batteries journal, January 2013

Complexes of Lithium Imide Salts with Tetraglyme and Their Polyelectrolyte Composite Materials journal, January 2004

Electrolytes for solid-state lithium rechargeable batteries: recent advances and perspectives journal, January 2011

Extended Electrochemical Window of Solid Electrolytes via Heterogeneous Multilayered Structure for High‐Voltage Lithium Metal Batteries journal, January 2019

Ionic-Liquid-Based Polymer Electrolytes for Battery Applications journal, November 2015

Quantifying inactive lithium in lithium metal batteries journal, August 2019

High rate and stable cycling of lithium metal anode journal, February 2015

Oxidative-Stability Enhancement and Charge Transport Mechanism in Glyme–Lithium Salt Equimolar Complexes journal, August 2011

High-Voltage Lithium-Metal Batteries Enabled by Localized High-Concentration Electrolytes
journal, March 2018

Supramolecular Self-Assembly of Methylated Rotaxanes for Solid Polymer Electrolyte Application
journal, June 2018

Negating interfacial impedance in garnet-based solid-state Li metal batteries
journal, December 2016

XPS and SIMS Analysis of Solid Electrolyte Interphases on Lithium Formed by Ether-Based Electrolytes
journal, January 2017

In Situ Formation of Protective Coatings on Sulfur Cathodes in Lithium Batteries with LiFSI-Based Organic Electrolytes
journal, December 2014

Superconcentrated electrolytes for a high-voltage lithium-ion battery
journal, June 2016

Surface reconstruction and chemical evolution of stoichiometric layered cathode materials for lithium-ion batteries
journal, March 2014

Ionic Liquids: Past, present and future
journal, January 2012

Localized High-Concentration Sulfone Electrolytes for High-Efficiency Lithium-Metal Batteries
journal, August 2018

Lithium Metal Stability in Batteries with Block Copolymer Electrolytes
journal, January 2013

Suppressed oxygen extraction and degradation of LiNi x Mn y Co z O2 cathodes at high charge cut-off voltages
journal, September 2017

Polymer–inorganic solid–electrolyte interphase for stable lithium metal batteries under lean electrolyte conditions
journal, March 2019

Characterization of the Cathode Electrolyte Interface in Lithium Ion Batteries by Desorption Electrospray Ionization Mass Spectrometry
journal, July 2016

Double-Layer Polymer Electrolyte for High-Voltage All-Solid-State Rechargeable Batteries
journal, December 2018

Physicochemical Properties of Glyme–Li Salt Complexes as a New Family of Room-temperature Ionic Liquids
journal, July 2010

Electrochemical measurement of transference numbers in polymer electrolytes
journal, December 1987

Non-flammable electrolyte enables Li-metal batteries with aggressive cathode chemistries
journal, July 2018

Accurate Determination of Coulombic Efficiency for Lithium Metal Anodes and Lithium Metal Batteries
journal, October 2017

A Highly Reversible Lithium Metal Anode
journal, January 2014

High-Concentration Ether Electrolytes for Stable High-Voltage Lithium Metal Batteries
journal, March 2019

High-power all-solid-state batteries using sulfide superionic conductors
journal, March 2016

Ultrahigh Performance All Solid-State Lithium Sulfur Batteries: Salt Anion’s Chemistry-Induced Anomalous Synergistic Effect
journal, July 2018

Complexes of alkali metal ions with poly(ethylene oxide)
journal, November 1973

Criteria for solvate ionic liquids
journal, January 2014

Toward Safe Lithium Metal Anode in Rechargeable Batteries: A Review
journal, July 2017

Nonaqueous Liquid Electrolytes for Lithium-Based Rechargeable Batteries
journal, October 2004

In-Depth Interfacial Chemistry and Reactivity Focused Investigation of Lithium–Imide- and Lithium–Imidazole-Based Electrolytes
journal, June 2016

Grafted polyrotaxanes as highly conductive electrolytes for lithium metal batteries
journal, January 2019

Electrolytes and Interphases in Li-Ion Batteries and Beyond
journal, October 2014

Identification of Surface Films Formed on Lithium in Dimethoxyethane and Tetrahydrofuran Solutions
journal, January 1988

The Lithium-Oxygen Battery with Ether-Based Electrolytes
journal, July 2011

Single lithium-ion conducting solid polymer electrolytes: advances and perspectives
journal, January 2017

Lithium metal anodes for rechargeable batteries
journal, January 2014

Stabilizing lithium metal using ionic liquids for long-lived batteries
journal, June 2016

Stable cycling of high-voltage lithium metal batteries in ether electrolytes
journal, July 2018

Fluorine-donating electrolytes enable highly reversible 5-V-class Li metal batteries
journal, January 2018

A superconcentrated ether electrolyte for fast-charging Li-ion batteries
journal, January 2013

Complexes of Lithium Imide Salts with Tetraglyme and Their Polyelectrolyte Composite Materials
journal, January 2004

Electrolytes for solid-state lithium rechargeable batteries: recent advances and perspectives
journal, January 2011

Extended Electrochemical Window of Solid Electrolytes via Heterogeneous Multilayered Structure for High‐Voltage Lithium Metal Batteries
journal, January 2019

Ionic-Liquid-Based Polymer Electrolytes for Battery Applications
journal, November 2015

Quantifying inactive lithium in lithium metal batteries
journal, August 2019

High rate and stable cycling of lithium metal anode
journal, February 2015

Oxidative-Stability Enhancement and Charge Transport Mechanism in Glyme–Lithium Salt Equimolar Complexes
journal, August 2011