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Title: A lithium–oxygen battery with a long cycle life in an air-like atmosphere [Lithium-oxygen batteries with long cycle life in a realistic air atmosphere]

Abstract

Lithium-air batteries are considered to be a potential alternative to lithium-ion batteries for transportation applications, owing to their high theoretical specific energy. So far, however, such systems have been largely restricted to pure oxygen environments (lithium oxygen batteries) and have a limited cycle life owing to side reactions involving the cathode, anode and electrolyte. In the presence of nitrogen, carbon dioxide and water vapour, these side reactions can become even more complex. Moreover, because of the need to store oxygen, the volumetric energy densities of lithium-oxygen systems may be too small for practical applications. Here we report a system comprising a lithium carbonate-based protected anode, a molybdenum disulfide cathode and an ionic liquid/di methyl sulfoxide electrolyte that operates as a lithium-air battery in a simulated air atmosphere with a long cycle life of up to 700 cycles. We perform computational studies to provide insight into the operation of the system in this environment. Furthermore this demonstration of a lithium-oxygen battery with a long cycle life in an air-like atmosphere is an important step towards the development of this field beyond lithium-ion technology, with a possibility to obtain much higher specific energy densities than for conventional lithium ion batteries.

Authors:
 [1];  [2];  [2];  [3];  [2];  [2];  [3];  [3];  [2];  [2];  [2];  [2];  [4];  [3];  [2];  [2];  [3];  [2]
+ Show Author Affiliations
  1. Univ. of Illinois at Chicago, Chicago, IL (United States); Illinois Inst. of Technology, Chicago, IL (United States)
  2. Univ. of Illinois at Chicago, Chicago, IL (United States)
  3. Argonne National Lab. (ANL), Argonne, IL (United States)
  4. California State Univ., Northridge, CA (United States)
Publication Date:
Research Org.:
Argonne National Laboratory (ANL), Argonne, IL (United States); Energy Frontier Research Centers (EFRC) (United States). Center for Electrochemical Energy Science (CEES)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Materials Sciences & Engineering Division; USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities Division; National Science Foundation (NSF); Univ. of Chicago, Materials Research Science & Engineering Center (MRSEC); USDOE Office of Science (SC), Basic Energy Sciences (BES). Joint Center for Energy Storage Research (JCESR)
OSTI Identifier:
1508362
Grant/Contract Number:  
AC02-06CH11357
Resource Type:
Accepted Manuscript
Journal Name:
Nature (London)
Additional Journal Information:
Journal Name: Nature (London); Journal Volume: 555; Journal Issue: 7697; Journal ID: ISSN 0028-0836
Publisher:
Nature Publishing Group
Country of Publication:
United States
Language:
English
Subject:
25 ENERGY STORAGE

Citation Formats

Asadi, Mohammad, Sayahpour, Baharak, Abbasi, Pedram, Ngo, Anh T., Karis, Klas, Jokisaari, Jacob R., Liu, Cong, Narayanan, Badri, Gerard, Marc, Yasaei, Poya, Hu, Xuan, Mukherjee, Arijita, Lau, Kah Chun, Assary, Rajeev S., Khalili-Araghi, Fatemeh, Klie, Robert F., Curtiss, Larry A., and Salehi-Khojin, Amin. A lithium–oxygen battery with a long cycle life in an air-like atmosphere [Lithium-oxygen batteries with long cycle life in a realistic air atmosphere]. United States: N. p., 2018. Web. doi:10.1038/nature25984.
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Asadi, Mohammad, Sayahpour, Baharak, Abbasi, Pedram, Ngo, Anh T., Karis, Klas, Jokisaari, Jacob R., Liu, Cong, Narayanan, Badri, Gerard, Marc, Yasaei, Poya, Hu, Xuan, Mukherjee, Arijita, Lau, Kah Chun, Assary, Rajeev S., Khalili-Araghi, Fatemeh, Klie, Robert F., Curtiss, Larry A., & Salehi-Khojin, Amin. A lithium–oxygen battery with a long cycle life in an air-like atmosphere [Lithium-oxygen batteries with long cycle life in a realistic air atmosphere]. United States. https://doi.org/10.1038/nature25984
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Asadi, Mohammad, Sayahpour, Baharak, Abbasi, Pedram, Ngo, Anh T., Karis, Klas, Jokisaari, Jacob R., Liu, Cong, Narayanan, Badri, Gerard, Marc, Yasaei, Poya, Hu, Xuan, Mukherjee, Arijita, Lau, Kah Chun, Assary, Rajeev S., Khalili-Araghi, Fatemeh, Klie, Robert F., Curtiss, Larry A., and Salehi-Khojin, Amin. Thu . "A lithium–oxygen battery with a long cycle life in an air-like atmosphere [Lithium-oxygen batteries with long cycle life in a realistic air atmosphere]". United States. https://doi.org/10.1038/nature25984. https://www.osti.gov/servlets/purl/1508362.
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@article{osti_1508362,
title = {A lithium–oxygen battery with a long cycle life in an air-like atmosphere [Lithium-oxygen batteries with long cycle life in a realistic air atmosphere]},
author = {Asadi, Mohammad and Sayahpour, Baharak and Abbasi, Pedram and Ngo, Anh T. and Karis, Klas and Jokisaari, Jacob R. and Liu, Cong and Narayanan, Badri and Gerard, Marc and Yasaei, Poya and Hu, Xuan and Mukherjee, Arijita and Lau, Kah Chun and Assary, Rajeev S. and Khalili-Araghi, Fatemeh and Klie, Robert F. and Curtiss, Larry A. and Salehi-Khojin, Amin},
abstractNote = {Lithium-air batteries are considered to be a potential alternative to lithium-ion batteries for transportation applications, owing to their high theoretical specific energy. So far, however, such systems have been largely restricted to pure oxygen environments (lithium oxygen batteries) and have a limited cycle life owing to side reactions involving the cathode, anode and electrolyte. In the presence of nitrogen, carbon dioxide and water vapour, these side reactions can become even more complex. Moreover, because of the need to store oxygen, the volumetric energy densities of lithium-oxygen systems may be too small for practical applications. Here we report a system comprising a lithium carbonate-based protected anode, a molybdenum disulfide cathode and an ionic liquid/di methyl sulfoxide electrolyte that operates as a lithium-air battery in a simulated air atmosphere with a long cycle life of up to 700 cycles. We perform computational studies to provide insight into the operation of the system in this environment. Furthermore this demonstration of a lithium-oxygen battery with a long cycle life in an air-like atmosphere is an important step towards the development of this field beyond lithium-ion technology, with a possibility to obtain much higher specific energy densities than for conventional lithium ion batteries.},
doi = {10.1038/nature25984},
journal = {Nature (London)},
number = 7697,
volume = 555,
place = {United States},
year = {Thu Mar 22 00:00:00 EDT 2018},
month = {Thu Mar 22 00:00:00 EDT 2018}
}
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    Trace fluorinated-carbon-nanotube-induced lithium dendrite elimination for high-performance lithium–oxygen cells
    journal, January 2020

    • Cheng, Hao; Mao, Yangjun; Lu, Yunhao
    • Nanoscale, Vol. 12, Issue 5
    • DOI: 10.1039/c9nr09749j

    Protecting the Lithium Metal Anode for a Safe Flexible Lithium-Air Battery in Ambient Air
    journal, October 2019

    • Liu, Tong; Feng, Xi-lan; Jin, Xin
    • Angewandte Chemie International Edition, Vol. 58, Issue 50
    • DOI: 10.1002/anie.201911229

    Electrolytes for Rechargeable Lithium–Air Batteries
    journal, February 2020

    • Lai, Jingning; Xing, Yi; Chen, Nan
    • Angewandte Chemie International Edition, Vol. 59, Issue 8
    • DOI: 10.1002/anie.201903459

    A versatile functionalized ionic liquid to boost the solution-mediated performances of lithium-oxygen batteries
    journal, February 2019

    Building Better Batteries in the Solid State: A Review
    journal, November 2019

    • Mauger, Alain; Julien, Christian M.; Paolella, Andrea
    • Materials, Vol. 12, Issue 23, p. 3892
    • DOI: 10.3390/ma12233892

    Energy Harvesting Sources, Storage Devices and System Topologies for Environmental Wireless Sensor Networks: A Review
    journal, July 2018

    • Prauzek, Michal; Konecny, Jaromir; Borova, Monika
    • Sensors, Vol. 18, Issue 8
    • DOI: 10.3390/s18082446
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