Material Dimensionality Effects on Electron Transfer Rates Between CsPbBr3 and CdSe Nanoparticles
Abstract
Films containing mixtures of zero- or two-dimensional nanostructures (quantum dots or nanoplatelets) were prepared in order to investigate the impacts of dimensionality on electronic interactions. Electron transfer from CsPbBr3 to CdSe was observed in all of the mixtures, regardless of particle dimensionality, and characterized via static and transient absorption and photoluminescence spectroscopies. We find that mixtures containing nanoplatelets, either as the electron donor (CsPbBr3) or acceptor (CdSe), undergo charge transfer more rapidly than those containing quantum dots. These results bolster the use of one- or two-dimensional nanomaterials in the place of zero-dimensional quantum dots in the design of related optoelectronic devices such as solar cells, light-emitting diodes, and photocatalysts and further offer the prospect of fewer required hopping events to transport carriers due to the larger spatial extent of the particles.
- Authors:
-
- Northwestern Univ., Evanston, IL (United States). Dept. of Chemistry
- Argonne National Lab. (ANL), Argonne, IL (United States). Center for Nanoscale Materials
- Federal Inst. of Technology (ETH), Zurich (Switzerland). Dept. of Chemistry and Applied Biosciences; Empa - Swiss Federal Laboratories for Materials Science and Technology, Dübendorf (Switzerland)
- Northwestern Univ., Evanston, IL (United States). Dept. of Chemistry; Argonne National Lab. (ANL), Argonne, IL (United States). Center for Nanoscale Materials
- Publication Date:
- Research Org.:
- Argonne National Lab. (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1491800
- Grant/Contract Number:
- AC02-06CH11357
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Nano Letters
- Additional Journal Information:
- Journal Volume: 18; Journal Issue: 8; Journal ID: ISSN 1530-6984
- Publisher:
- American Chemical Society
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 77 NANOSCIENCE AND NANOTECHNOLOGY; dimensionality; electron transfer; Nanoplatelets; perovskites; spectroscopy
Citation Formats
Brumberg, Alexandra, Diroll, Benjamin T., Nedelcu, Georgian, Sykes, Matthew E., Liu, Yuzi, Harvey, Samantha M., Wasielewski, Michael R., Kovalenko, Maksym V., and Schaller, Richard D. Material Dimensionality Effects on Electron Transfer Rates Between CsPbBr3 and CdSe Nanoparticles. United States: N. p., 2018.
Web. doi:10.1021/acs.nanolett.8b01238.
Brumberg, Alexandra, Diroll, Benjamin T., Nedelcu, Georgian, Sykes, Matthew E., Liu, Yuzi, Harvey, Samantha M., Wasielewski, Michael R., Kovalenko, Maksym V., & Schaller, Richard D. Material Dimensionality Effects on Electron Transfer Rates Between CsPbBr3 and CdSe Nanoparticles. United States. https://doi.org/10.1021/acs.nanolett.8b01238
Brumberg, Alexandra, Diroll, Benjamin T., Nedelcu, Georgian, Sykes, Matthew E., Liu, Yuzi, Harvey, Samantha M., Wasielewski, Michael R., Kovalenko, Maksym V., and Schaller, Richard D. Tue .
"Material Dimensionality Effects on Electron Transfer Rates Between CsPbBr3 and CdSe Nanoparticles". United States. https://doi.org/10.1021/acs.nanolett.8b01238. https://www.osti.gov/servlets/purl/1491800.
@article{osti_1491800,
title = {Material Dimensionality Effects on Electron Transfer Rates Between CsPbBr3 and CdSe Nanoparticles},
author = {Brumberg, Alexandra and Diroll, Benjamin T. and Nedelcu, Georgian and Sykes, Matthew E. and Liu, Yuzi and Harvey, Samantha M. and Wasielewski, Michael R. and Kovalenko, Maksym V. and Schaller, Richard D.},
abstractNote = {Films containing mixtures of zero- or two-dimensional nanostructures (quantum dots or nanoplatelets) were prepared in order to investigate the impacts of dimensionality on electronic interactions. Electron transfer from CsPbBr3 to CdSe was observed in all of the mixtures, regardless of particle dimensionality, and characterized via static and transient absorption and photoluminescence spectroscopies. We find that mixtures containing nanoplatelets, either as the electron donor (CsPbBr3) or acceptor (CdSe), undergo charge transfer more rapidly than those containing quantum dots. These results bolster the use of one- or two-dimensional nanomaterials in the place of zero-dimensional quantum dots in the design of related optoelectronic devices such as solar cells, light-emitting diodes, and photocatalysts and further offer the prospect of fewer required hopping events to transport carriers due to the larger spatial extent of the particles.},
doi = {10.1021/acs.nanolett.8b01238},
journal = {Nano Letters},
number = 8,
volume = 18,
place = {United States},
year = {Tue Jun 26 00:00:00 EDT 2018},
month = {Tue Jun 26 00:00:00 EDT 2018}
}
Web of Science
Figures / Tables:
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