Electrochemical Properties of Electrodes Derived from NaTi3O6OH·2H2O in Sodium and Lithium Cells
Abstract
Materials derived from the layered compound NaTi3O6OH·2H2O, also known as “sodium nonatitanate” or NNT, have recently been found to undergo reversible sodium or lithium intercalation processes at very low potentials. While practical discharge capacities in lithium cells can be above 200 mAh/g, making them of interest for high-energy applications, the presence of mobile sodium in the materials complicates the cycling behavior. A simple ion-exchange process prior to incorporation in electrochemical cells removes all sodium ions, producing the lithiated form of the material. The lithiated material (LNT) performs similarly to NNT in lithium cells, although coulombic inefficiencies are somewhat higher. A comparison is made between the behavior of NNT in sodium cells and that of NNT and the lithiated analog in lithium cells.
- Authors:
-
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Environmental Energy Technologies Division
- Publication Date:
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC); LBNL Laboratory Directed Research and Development (LDRD) Program
- OSTI Identifier:
- 1469152
- Report Number(s):
- LBNL-181397
Journal ID: ISSN 0013-4651; ir:181397
- Grant/Contract Number:
- AC02-05CH11231
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of the Electrochemical Society
- Additional Journal Information:
- Journal Volume: 162; Journal Issue: 1; Journal ID: ISSN 0013-4651
- Publisher:
- The Electrochemical Society
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE
Citation Formats
Seshadri, Dhruv, Shirpour, Mona, and Doeff, Marca. Electrochemical Properties of Electrodes Derived from NaTi3O6OH·2H2O in Sodium and Lithium Cells. United States: N. p., 2014.
Web. doi:10.1149/2.0391501jes.
Seshadri, Dhruv, Shirpour, Mona, & Doeff, Marca. Electrochemical Properties of Electrodes Derived from NaTi3O6OH·2H2O in Sodium and Lithium Cells. United States. https://doi.org/10.1149/2.0391501jes
Seshadri, Dhruv, Shirpour, Mona, and Doeff, Marca. Wed .
"Electrochemical Properties of Electrodes Derived from NaTi3O6OH·2H2O in Sodium and Lithium Cells". United States. https://doi.org/10.1149/2.0391501jes. https://www.osti.gov/servlets/purl/1469152.
@article{osti_1469152,
title = {Electrochemical Properties of Electrodes Derived from NaTi3O6OH·2H2O in Sodium and Lithium Cells},
author = {Seshadri, Dhruv and Shirpour, Mona and Doeff, Marca},
abstractNote = {Materials derived from the layered compound NaTi3O6OH·2H2O, also known as “sodium nonatitanate” or NNT, have recently been found to undergo reversible sodium or lithium intercalation processes at very low potentials. While practical discharge capacities in lithium cells can be above 200 mAh/g, making them of interest for high-energy applications, the presence of mobile sodium in the materials complicates the cycling behavior. A simple ion-exchange process prior to incorporation in electrochemical cells removes all sodium ions, producing the lithiated form of the material. The lithiated material (LNT) performs similarly to NNT in lithium cells, although coulombic inefficiencies are somewhat higher. A comparison is made between the behavior of NNT in sodium cells and that of NNT and the lithiated analog in lithium cells.},
doi = {10.1149/2.0391501jes},
journal = {Journal of the Electrochemical Society},
number = 1,
volume = 162,
place = {United States},
year = {Wed Nov 12 00:00:00 EST 2014},
month = {Wed Nov 12 00:00:00 EST 2014}
}
Web of Science
Works referenced in this record:
A Mixed Alkali Metal Titanate with the Lepidocrocite-like Layered Structure. Preparation, Crystal Structure, Protonic Form, and Acid−Base Intercalation Properties
journal, December 1998
- Sasaki, Takayoshi; Kooli, Fathi; Iida, Masaki
- Chemistry of Materials, Vol. 10, Issue 12
A multifunctional 3.5 V iron-based phosphate cathode for rechargeable batteries
journal, September 2007
- Ellis, B. L.; Makahnouk, W. R. M.; Makimura, Y.
- Nature Materials, Vol. 6, Issue 10
New materials based on a layered sodium titanate for dual electrochemical Na and Li intercalation systems
journal, January 2013
- Shirpour, Mona; Cabana, Jordi; Doeff, Marca
- Energy & Environmental Science, Vol. 6, Issue 8
Synthesis, structure, and electrochemical Li-ion intercalation properties of Li2Ti3O7 with Na2Ti3O7-type layered structure
journal, January 2008
- Chiba, K.; Kijima, N.; Takahashi, Y.
- Solid State Ionics, Vol. 178, Issue 33-34
Rationalization of Intercalation Potential and Redox Mechanism for A 2 Ti 3 O 7 (A = Li, Na)
journal, December 2013
- Rousse, Gwenaelle; Arroyo-de Dompablo, M. Elena; Senguttuvan, Premkumar
- Chemistry of Materials, Vol. 25, Issue 24
Hybrid-Ion
journal, January 2006
- Barker, J.; Gover, R. K. B.; Burns, P.
- Electrochemical and Solid-State Letters, Vol. 9, Issue 4
The Impact of Intentionally Added Water to the Electrolyte of Li-Ion Cells: II. Cells with Lithium Titanate Negative Electrodes
journal, December 2013
- Burns, J. C.; Sinha, N. N.; Jain, Gaurav
- Journal of The Electrochemical Society, Vol. 161, Issue 3
The ion exchange of strontium on sodium titanate Na4Ti9O20.xH2O
journal, June 1987
- Lehto, J.; Clearfield, A.
- Journal of Radioanalytical and Nuclear Chemistry Letters, Vol. 118, Issue 1
New ion exchange materials for use in a 82Sr/82Rb generator
journal, December 2004
- Sylvester, P.; Möller, T.; Adams, T. W.
- Applied Radiation and Isotopes, Vol. 61, Issue 6
Recent advances in magnetic structure determination by neutron powder diffraction
journal, October 1993
- Rodríguez-Carvajal, Juan
- Physica B: Condensed Matter, Vol. 192, Issue 1-2
Review on electrode–electrolyte solution interactions, related to cathode materials for Li-ion batteries
journal, March 2007
- Aurbach, Doron; Markovsky, Boris; Salitra, Gregory
- Journal of Power Sources, Vol. 165, Issue 2
Sodium Nonatitanate: a Highly Selective Inorganic ion Exchanger for Strontium
journal, June 2001
- Yates, S. F.; Sylvester, P.
- Separation Science and Technology, Vol. 36, Issue 5-6
Structure analysis of titanate nanorods by automated electron diffraction tomography
journal, May 2011
- Andrusenko, Iryna; Mugnaioli, Enrico; Gorelik, Tatiana E.
- Acta Crystallographica Section B Structural Science, Vol. 67, Issue 3
Na 2 Ti 3 O 7 : Lowest Voltage Ever Reported Oxide Insertion Electrode for Sodium Ion Batteries
journal, September 2011
- Senguttuvan, Premkumar; Rousse, Gwenaëlle; Seznec, Vincent
- Chemistry of Materials, Vol. 23, Issue 18
Ion-exchange between Na2Ti3O7 and H2Ti3O7 nanosheets at different pH levels: An experimental and first-principles study
journal, June 2014
- An, Yongliang; Wang, Dongjun; Wu, Chen
- Physica E: Low-dimensional Systems and Nanostructures, Vol. 60
Ion exchange and dehydration of layered [sodium and potassium] titanates, Na2Ti3O7 and K2Ti4O9
journal, December 1982
- Izawa, H.; Kikkawa, S.; Koizumi, M.
- The Journal of Physical Chemistry, Vol. 86, Issue 25
Lepidocrocite-type Layered Titanate Structures: New Lithium and Sodium Ion Intercalation Anode Materials
journal, April 2014
- Shirpour, Mona; Cabana, Jordi; Doeff, Marca
- Chemistry of Materials, Vol. 26, Issue 8
Works referencing / citing this record:
The State and Challenges of Anode Materials Based on Conversion Reactions for Sodium Storage
journal, March 2018
- Wu, Chao; Dou, Shi-Xue; Yu, Yan
- Small, Vol. 14, Issue 22
Removing structural water from sodium titanate anodes towards barrier-free ion diffusion for sodium ion batteries
journal, January 2017
- Zhang, Qing; Zhang, Tianqi; Wei, Yaqing
- Journal of Materials Chemistry A, Vol. 5, Issue 35
Dual anode materials for lithium- and sodium-ion batteries
journal, January 2018
- Luo, Yuqing; Tang, Yijian; Zheng, Shasha
- Journal of Materials Chemistry A, Vol. 6, Issue 10
Sodium-based batteries: from critical materials to battery systems
journal, January 2019
- Li, Fang; Wei, Zengxi; Manthiram, Arumugam
- Journal of Materials Chemistry A, Vol. 7, Issue 16