Insights into the dual-electrode characteristics of layered Na0.5Ni0.25Mn0.75O2 materials for sodium-ion batteries
Abstract
Sodium-ion batteries are now close to replacing lithium-ion batteries because they provide superior alternative energy storage solutions that are in great demand, particularly for large-scale applications. To that end, the present study is focused on the properties of a new type of dual-electrode material, Na0.5Ni0.25Mn0.75O2, synthesized using a mixed hydroxycarbonate route. Cyclic voltammetry confirms that redox couples, at high and low voltage ranges, are facilitated by the unique features and properties of this dual-electrode, through sodium ion deintercalation/intercalation into the layered Na0.5Ni0.25Mn0.25O2 material. This material provides superior performance for Na-ion batteries, as evidenced by the fabricated sodium cell that yielded initial charge discharge capacities of 125/218 mAh g-1 in the voltage range of 1.5-4.4 V at 0.5 C. At a low voltage range (1.5-2.6 V), the anode cell delivered discharge charge capacities of 100/99 mAh g-1 with 99% capacity retention, which corresponds to highly reversible redox reaction of the Mn4+/3+ reduction and the Mn3+/4+ oxidation observed at 1.85 and 2.06 V, respectively. The symmetric Na-ion cell, fabricated using Na0.5Ni0.25Mn0.25O2, yielded initial charge discharge capacities of 196/187 μAh at 107 μA. Lastly, these results encourage the further development of new types of futuristic sodium-ion battery-based energy storage systems.
- Authors:
- Publication Date:
- Research Org.:
- Argonne National Lab. (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- Ulsan National Institute of Science and Technology (UNIST); National Research Foundation of Korea (NRF); Argonne National Laboratory, Laboratory Directed Research and Development (LDRD); USDOE
- OSTI Identifier:
- 1369041
- Grant/Contract Number:
- AC02-06CH11357
- Resource Type:
- Accepted Manuscript
- Journal Name:
- ACS Applied Materials and Interfaces
- Additional Journal Information:
- Journal Volume: 9; Journal Issue: 12; Journal ID: ISSN 1944-8244
- Publisher:
- American Chemical Society (ACS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; 25 ENERGY STORAGE; Chargedischarge cycling; Dual electrode; Layered P2-type structure; Mixed hydroxy-carbonate; Symmetric sodium-ion batteries.
Citation Formats
Manikandan, Palanisamy, Kim, Hyunwoo, Heo, Seongwoo, Lee, Eungje, and Kim, Youngsik. Insights into the dual-electrode characteristics of layered Na0.5Ni0.25Mn0.75O2 materials for sodium-ion batteries. United States: N. p., 2017.
Web. doi:10.1021/acsami.6b15355.
Manikandan, Palanisamy, Kim, Hyunwoo, Heo, Seongwoo, Lee, Eungje, & Kim, Youngsik. Insights into the dual-electrode characteristics of layered Na0.5Ni0.25Mn0.75O2 materials for sodium-ion batteries. United States. https://doi.org/10.1021/acsami.6b15355
Manikandan, Palanisamy, Kim, Hyunwoo, Heo, Seongwoo, Lee, Eungje, and Kim, Youngsik. Thu .
"Insights into the dual-electrode characteristics of layered Na0.5Ni0.25Mn0.75O2 materials for sodium-ion batteries". United States. https://doi.org/10.1021/acsami.6b15355. https://www.osti.gov/servlets/purl/1369041.
@article{osti_1369041,
title = {Insights into the dual-electrode characteristics of layered Na0.5Ni0.25Mn0.75O2 materials for sodium-ion batteries},
author = {Manikandan, Palanisamy and Kim, Hyunwoo and Heo, Seongwoo and Lee, Eungje and Kim, Youngsik},
abstractNote = {Sodium-ion batteries are now close to replacing lithium-ion batteries because they provide superior alternative energy storage solutions that are in great demand, particularly for large-scale applications. To that end, the present study is focused on the properties of a new type of dual-electrode material, Na0.5Ni0.25Mn0.75O2, synthesized using a mixed hydroxycarbonate route. Cyclic voltammetry confirms that redox couples, at high and low voltage ranges, are facilitated by the unique features and properties of this dual-electrode, through sodium ion deintercalation/intercalation into the layered Na0.5Ni0.25Mn0.25O2 material. This material provides superior performance for Na-ion batteries, as evidenced by the fabricated sodium cell that yielded initial charge discharge capacities of 125/218 mAh g-1 in the voltage range of 1.5-4.4 V at 0.5 C. At a low voltage range (1.5-2.6 V), the anode cell delivered discharge charge capacities of 100/99 mAh g-1 with 99% capacity retention, which corresponds to highly reversible redox reaction of the Mn4+/3+ reduction and the Mn3+/4+ oxidation observed at 1.85 and 2.06 V, respectively. The symmetric Na-ion cell, fabricated using Na0.5Ni0.25Mn0.25O2, yielded initial charge discharge capacities of 196/187 μAh at 107 μA. Lastly, these results encourage the further development of new types of futuristic sodium-ion battery-based energy storage systems.},
doi = {10.1021/acsami.6b15355},
journal = {ACS Applied Materials and Interfaces},
number = 12,
volume = 9,
place = {United States},
year = {Thu Mar 09 00:00:00 EST 2017},
month = {Thu Mar 09 00:00:00 EST 2017}
}
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