Stable organic thin-film transistors
Abstract
Organic thin-film transistors (OTFTs) can be fabricated at moderate temperatures and through cost-effective solution-based processes on a wide range of low-cost flexible and deformable substrates. Although the charge mobility of state-of-the-art OTFTs is superior to that of amorphous silicon and approaches that of amorphous oxide thin-film transistors (TFTs), their operational stability generally remains inferior and a point of concern for their commercial deployment. We report on an exhaustive characterization of OTFTs with an ultrathin bilayer gate dielectric comprising the amorphous fluoropolymer CYTOP and an Al2O3:HfO2 nanolaminate. Threshold voltage shifts measured at room temperatureovertimeperiods upto5.9×105 s do not vary monotonically and remain below 0.2 V in microcrystalline OTFTs (mc-OTFTs) with field-effect carrier mobility values up to 1.6 cm2 V-1 s-1. Modeling of these shifts as a function of time with a double stretched-exponential (DSE) function suggests that two compensating aging mechanisms are at play and responsible for this high stability. The measured threshold voltage shifts at temperatures up to 75°C represent at least a one-order-of-magnitude improvement in the operational stability over previous reports, bringing OTFT technologies to a performance level comparable to that reported in the scientific literature for other commercial TFTs technologies.
- Authors:
-
- Georgia Inst. of Technology, Atlanta, GA (United States)
- Publication Date:
- Research Org.:
- North Carolina State University, Raleigh, NC (United States)
- Sponsoring Org.:
- USDOE National Nuclear Security Administration (NNSA)
- OSTI Identifier:
- 1438013
- Grant/Contract Number:
- NA0002576
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Science Advances
- Additional Journal Information:
- Journal Volume: 4; Journal Issue: 1; Journal ID: ISSN 2375-2548
- Publisher:
- AAAS
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 42 ENGINEERING
Citation Formats
Jia, Xiaojia, Fuentes-Hernandez, Canek, Wang, Cheng-Yin, Park, Youngrak, and Kippelen, Bernard. Stable organic thin-film transistors. United States: N. p., 2018.
Web. doi:10.1126/sciadv.aao1705.
Jia, Xiaojia, Fuentes-Hernandez, Canek, Wang, Cheng-Yin, Park, Youngrak, & Kippelen, Bernard. Stable organic thin-film transistors. United States. https://doi.org/10.1126/sciadv.aao1705
Jia, Xiaojia, Fuentes-Hernandez, Canek, Wang, Cheng-Yin, Park, Youngrak, and Kippelen, Bernard. Fri .
"Stable organic thin-film transistors". United States. https://doi.org/10.1126/sciadv.aao1705. https://www.osti.gov/servlets/purl/1438013.
@article{osti_1438013,
title = {Stable organic thin-film transistors},
author = {Jia, Xiaojia and Fuentes-Hernandez, Canek and Wang, Cheng-Yin and Park, Youngrak and Kippelen, Bernard},
abstractNote = {Organic thin-film transistors (OTFTs) can be fabricated at moderate temperatures and through cost-effective solution-based processes on a wide range of low-cost flexible and deformable substrates. Although the charge mobility of state-of-the-art OTFTs is superior to that of amorphous silicon and approaches that of amorphous oxide thin-film transistors (TFTs), their operational stability generally remains inferior and a point of concern for their commercial deployment. We report on an exhaustive characterization of OTFTs with an ultrathin bilayer gate dielectric comprising the amorphous fluoropolymer CYTOP and an Al2O3:HfO2 nanolaminate. Threshold voltage shifts measured at room temperatureovertimeperiods upto5.9×105 s do not vary monotonically and remain below 0.2 V in microcrystalline OTFTs (mc-OTFTs) with field-effect carrier mobility values up to 1.6 cm2 V-1 s-1. Modeling of these shifts as a function of time with a double stretched-exponential (DSE) function suggests that two compensating aging mechanisms are at play and responsible for this high stability. The measured threshold voltage shifts at temperatures up to 75°C represent at least a one-order-of-magnitude improvement in the operational stability over previous reports, bringing OTFT technologies to a performance level comparable to that reported in the scientific literature for other commercial TFTs technologies.},
doi = {10.1126/sciadv.aao1705},
journal = {Science Advances},
number = 1,
volume = 4,
place = {United States},
year = {Fri Jan 12 00:00:00 EST 2018},
month = {Fri Jan 12 00:00:00 EST 2018}
}
Web of Science
Figures / Tables:
Works referenced in this record:
Very low bias stress in n -type organic single-crystal transistors
journal, March 2012
- Barra, M.; Di Girolamo, F. V.; Minder, N. A.
- Applied Physics Letters, Vol. 100, Issue 13
High operational and environmental stability of high-mobility conjugated polymer field-effect transistors through the use of molecular additives
journal, December 2016
- Nikolka, Mark; Nasrallah, Iyad; Rose, Bradley
- Nature Materials, Vol. 16, Issue 3
Suppression of threshold voltage shifts in organic thin-film transistors with bilayer gate dielectrics: Suppression of threshold voltage shifts in organic thin-film transistors
journal, February 2013
- Fukuda, Kenjiro; Suzuki, Tatsuya; Kobayashi, Takuma
- physica status solidi (a), Vol. 210, Issue 5
Stable Organic Field-Effect Transistors for Continuous and Nondestructive Sensing of Chemical and Biologically Relevant Molecules in Aqueous Environment
journal, January 2014
- Yun, Minseong; Sharma, Asha; Fuentes-Hernandez, Canek
- ACS Applied Materials & Interfaces, Vol. 6, Issue 3
Systematic Reliability Study of Top-Gate p- and n-Channel Organic Field-Effect Transistors
journal, February 2014
- Hwang, Do Kyung; Fuentes-Hernandez, Canek; Fenoll, Mathieu
- ACS Applied Materials & Interfaces, Vol. 6, Issue 5
Further considerations of non symmetrical dielectric relaxation behaviour arising from a simple empirical decay function
journal, January 1971
- Williams, G.; Watts, D. C.; Dev, S. B.
- Transactions of the Faraday Society, Vol. 67
High-Mobility Field-Effect Transistors Fabricated with Macroscopic Aligned Semiconducting Polymers
journal, February 2014
- Tseng, Hsin-Rong; Phan, Hung; Luo, Chan
- Advanced Materials, Vol. 26, Issue 19
Design of High-Mobility Diketopyrrolopyrrole-Based π-Conjugated Copolymers for Organic Thin-Film Transistors
journal, May 2015
- Yi, Zhengran; Wang, Shuai; Liu, Yunqi
- Advanced Materials, Vol. 27, Issue 24
High mobility diketopyrrolopyrrole (DPP)-based organic semiconductor materials for organic thin film transistors and photovoltaics
journal, January 2013
- Li, Yuning; Sonar, Prashant; Murphy, Leanne
- Energy & Environmental Science, Vol. 6, Issue 6
Improved organic thin-film transistor performance using novel self-assembled monolayers
journal, February 2006
- McDowell, M.; Hill, I. G.; McDermott, J. E.
- Applied Physics Letters, Vol. 88, Issue 7
Organic Field-Effect Transistors with a Bilayer Gate Dielectric Comprising an Oxide Nanolaminate Grown by Atomic Layer Deposition
journal, October 2016
- Wang, Cheng-Yin; Fuentes-Hernandez, Canek; Yun, Minseong
- ACS Applied Materials & Interfaces, Vol. 8, Issue 44
Organic thin-film transistor-driven polymer-dispersed liquid crystal displays on flexible polymeric substrates
journal, February 2002
- Sheraw, C. D.; Zhou, L.; Huang, J. R.
- Applied Physics Letters, Vol. 80, Issue 6, p. 1088-1090
A large-area, flexible pressure sensor matrix with organic field-effect transistors for artificial skin applications
journal, June 2004
- Someya, T.; Sekitani, T.; Iba, S.
- Proceedings of the National Academy of Sciences, Vol. 101, Issue 27, p. 9966-9970
Unification of the time and temperature dependence of dangling-bond-defect creation and removal in amorphous-silicon thin-film transistors
journal, November 1998
- Deane, S. C.; Wehrspohn, R. B.; Powell, M. J.
- Physical Review B, Vol. 58, Issue 19
Organic RFID transponder chip with data rate compatible with electronic product coding
journal, July 2010
- Myny, K.; Steudel, S.; Smout, S.
- Organic Electronics, Vol. 11, Issue 7
Amorphous Oxide Semiconductor TFTs for Displays and Imaging
journal, November 2014
- Nathan, Arokia; Lee, Sungsik; Jeon, Sanghun
- Journal of Display Technology, Vol. 10, Issue 11
49.1: Invited Paper: Emergent Oxide TFT Technologies for Next-Generation AM-OLED Displays
journal, June 2011
- Arai, Toshiaki; Sasaoka, Tatsuya
- SID Symposium Digest of Technical Papers, Vol. 42, Issue 1
Top-gate organic field-effect transistors fabricated on paper with high operational stability
journal, February 2017
- Wang, Cheng-Yin; Fuentes-Hernandez, Canek; Chou, Wen-Fang
- Organic Electronics, Vol. 41
Organic small molecule field-effect transistors with Cytop™ gate dielectric: Eliminating gate bias stress effects
journal, February 2007
- Kalb, W. L.; Mathis, T.; Haas, S.
- Applied Physics Letters, Vol. 90, Issue 9
Thermal annealing effect on the crack development and the stability of 6,13-bis(triisopropylsilylethynyl)-pentacene field-effect transistors with a solution-processed polymer insulator
journal, May 2010
- Bae, Jin-Hyuk; Park, Jaehoon; Keum, Chang-Min
- Organic Electronics, Vol. 11, Issue 5
Origin of the bias stress instability in single-crystal organic field-effect transistors
journal, August 2010
- Lee, B.; Wan, A.; Mastrogiovanni, D.
- Physical Review B, Vol. 82, Issue 8
Low-voltage flexible organic complementary inverters with high noise margin and high dc gain
journal, January 2009
- Zhang, Xiao-Hong; Potscavage, William J.; Choi, Seungkeun
- Applied Physics Letters, Vol. 94, Issue 4
(Invited) All-Solid-State Batteries: A Challenging Route towards 3D Integration
conference, January 2010
- Donders, Merijn; Oudenhoven, Jos; Baggetto, Loic
- 218th ECS Meeting, ECS Transactions
Water-stable organic transistors and their application in chemical and biological sensors
journal, August 2008
- Roberts, M. E.; Mannsfeld, S. C. B.; Queralto, N.
- Proceedings of the National Academy of Sciences, Vol. 105, Issue 34
Top-Gate Organic Field-Effect Transistors with High Environmental and Operational Stability
journal, January 2011
- Hwang, Do Kyung; Fuentes-Hernandez, Canek; Kim, Jungbae
- Advanced Materials, Vol. 23, Issue 10
High-Performance Polymer-Small Molecule Blend Organic Transistors
journal, March 2009
- Hamilton, Richard; Smith, Jeremy; Ogier, Simon
- Advanced Materials, Vol. 21, Issue 10-11, p. 1166-1171
AC Bias-Temperature Stability of a-InGaZnO Thin-Film Transistors With Metal Source/Drain Recessed Electrodes
journal, March 2014
- Yu, Eric Kai-Hsiang; Abe, Katsumi; Kumomi, Hideya
- IEEE Transactions on Electron Devices, Vol. 61, Issue 3
Bias-stress stability of low-voltage p-channel and n-channel organic thin-film transistors on flexible plastic substrates
journal, November 2014
- Bisoyi, Sibani; Zschieschang, Ute; Kang, Myeong Jin
- Organic Electronics, Vol. 15, Issue 11
Amorphous silicon thin film transistor circuit integration for organic LED displays on glass and plastic
journal, September 2004
- Nathan, A.; Kumar, A.; Sakariya, K.
- IEEE Journal of Solid-State Circuits, Vol. 39, Issue 9, p. 1477-1486
Stable Solution-Processed Molecular n -Channel Organic Field-Effect Transistors
journal, July 2012
- Hwang, Do Kyung; Dasari, Raghunath R.; Fenoll, Mathieu
- Advanced Materials, Vol. 24, Issue 32
Dynamics of Threshold Voltage Shifts in Organic and Amorphous Silicon Field-Effect Transistors
journal, October 2007
- Mathijssen, S. G. J.; Cölle, M.; Gomes, H.
- Advanced Materials, Vol. 19, Issue 19
Reliability of low-temperature polysilicon thin-film transistors for flexible electronics application
conference, May 2016
- Xu, Siwei; Sun, Zhipeng; Zhang, Dongli
- 2016 IEEE International Nanoelectronics Conference (INEC)
Bias‐stress‐induced stretched‐exponential time dependence of charge injection and trapping in amorphous thin‐film transistors
journal, March 1993
- Libsch, F. R.; Kanicki, J.
- Applied Physics Letters, Vol. 62, Issue 11
Stable Low-Voltage Operation Top-Gate Organic Field-Effect Transistors on Cellulose Nanocrystal Substrates
journal, February 2015
- Wang, Cheng-Yin; Fuentes-Hernandez, Canek; Liu, Jen-Chieh
- ACS Applied Materials & Interfaces, Vol. 7, Issue 8
High Performance Micro-Crystalline Silicon TFT Using Indirect Thermal Crystallization Technique
journal, October 2010
- Choi, Byung Gook; Kim, Ki-Tae; Bae, Jun Hyeon
- ECS Transactions, Vol. 33, Issue 5
High operational and environmental stability of high-mobility conjugated polymer field-effect transistors through the use of molecular additives.
text, January 2017
- Nikolka, Mark; Nasrallah, Iyad; Rose, Bradley
- Apollo - University of Cambridge Repository
Dynamics of Threshold Voltage Shifts in Organic and Amorphous Silicon Field-Effect Transistors
journal, October 2007
- Mathijssen, S. G. J.; Cölle, M.; Gomes, H.
- Advanced Materials, Vol. 19, Issue 19
Top-Gate Organic Field-Effect Transistors with High Environmental and Operational Stability
journal, January 2011
- Hwang, Do Kyung; Fuentes-Hernandez, Canek; Kim, Jungbae
- Advanced Materials, Vol. 23, Issue 10
Stable Solution-Processed Molecular n -Channel Organic Field-Effect Transistors
journal, July 2012
- Hwang, Do Kyung; Dasari, Raghunath R.; Fenoll, Mathieu
- Advanced Materials, Vol. 24, Issue 32
Design of High-Mobility Diketopyrrolopyrrole-Based π-Conjugated Copolymers for Organic Thin-Film Transistors
journal, May 2015
- Yi, Zhengran; Wang, Shuai; Liu, Yunqi
- Advanced Materials, Vol. 27, Issue 24
Organic Field-Effect Transistors with a Bilayer Gate Dielectric Comprising an Oxide Nanolaminate Grown by Atomic Layer Deposition
journal, October 2016
- Wang, Cheng-Yin; Fuentes-Hernandez, Canek; Yun, Minseong
- ACS Applied Materials & Interfaces, Vol. 8, Issue 44
Stable Organic Field-Effect Transistors for Continuous and Nondestructive Sensing of Chemical and Biologically Relevant Molecules in Aqueous Environment
journal, January 2014
- Yun, Minseong; Sharma, Asha; Fuentes-Hernandez, Canek
- ACS Applied Materials & Interfaces, Vol. 6, Issue 3
High operational and environmental stability of high-mobility conjugated polymer field-effect transistors through the use of molecular additives
journal, December 2016
- Nikolka, Mark; Nasrallah, Iyad; Rose, Bradley
- Nature Materials, Vol. 16, Issue 3
A large-area, flexible pressure sensor matrix with organic field-effect transistors for artificial skin applications
journal, June 2004
- Someya, T.; Sekitani, T.; Iba, S.
- Proceedings of the National Academy of Sciences, Vol. 101, Issue 27, p. 9966-9970
Water-stable organic transistors and their application in chemical and biological sensors
journal, August 2008
- Roberts, M. E.; Mannsfeld, S. C. B.; Queralto, N.
- Proceedings of the National Academy of Sciences, Vol. 105, Issue 34
49.1: Invited Paper: Emergent Oxide TFT Technologies for Next-Generation AM-OLED Displays
journal, June 2011
- Arai, Toshiaki; Sasaoka, Tatsuya
- SID Symposium Digest of Technical Papers, Vol. 42, Issue 1
Very low bias stress in n-type organic single crystal transistors
text, January 2012
- Barra, Mario; Di Girolamo, Flavia V.; Minder, Nikolas A.
- arXiv
Works referencing / citing this record:
Recent Advances in the Bias Stress Stability of Organic Transistors
journal, October 2019
- Park, Sangsik; Kim, Seung Hyun; Choi, Hyun Ho
- Advanced Functional Materials, Vol. 30, Issue 20
High Signal‐to‐Noise Chemical Sensors Based on Compensated Organic Transistor Circuits
journal, August 2019
- Chu, Yingli; Li, Hui; Huang, Jia
- Advanced Materials Technologies, Vol. 4, Issue 10
Charge carrier traps in organic semiconductors: a review on the underlying physics and impact on electronic devices
journal, January 2020
- Haneef, Hamna F.; Zeidell, Andrew M.; Jurchescu, Oana D.
- Journal of Materials Chemistry C, Vol. 8, Issue 3
A computational approach to study the optoelectronic properties of F -BODIPY derivatives at the bulk level for photovoltaic applications
journal, December 2019
- Chaudhry, Aijaz Rasool; Muhammad, Shabbir; Haq, Bakhtiar Ul
- Materials Research Express, Vol. 6, Issue 12
Roadmap to Gigahertz Organic Transistors
journal, November 2019
- Zschieschang, Ute; Borchert, James W.; Giorgio, Michele
- Advanced Functional Materials, Vol. 30, Issue 20
Printed subthreshold organic transistors operating at high gain and ultralow power.
text, January 2019
- Jiang, Chen; Choi, Hyung Woo; Cheng, Xiang
- Apollo - University of Cambridge Repository
Printed subthreshold organic transistors operating at high gain and ultralow power
journal, February 2019
- Jiang, Chen; Choi, Hyung Woo; Cheng, Xiang
- Science, Vol. 363, Issue 6428
Display meets biology: A vision for ubiquitous healthcare platforms
journal, February 2019
- Kim, Chang-Hyun; Kymissis, Ioannis; Bonnassieux, Yvan
- Journal of the Society for Information Display, Vol. 27, Issue 3
Mobility of Air-Stable p-type Polythiophene Field-Effect Transistors Fabricated Using Oxidative Chemical Vapor Deposition
journal, January 2020
- Lee, Sunghwan; Song, Han Wook; Cho, Jae Yong
- Journal of Electronic Materials, Vol. 49, Issue 6
The Motivation for and Challenges to Scaling Down Organic Field‐Effect Transistors
journal, April 2019
- Chan, Paddy Kwok Leung
- Advanced Electronic Materials, Vol. 5, Issue 7
Parylene copolymer gate dielectrics for organic field-effect transistors
journal, January 2019
- Park, Hyunjin; Kwon, Jimin; Ahn, Hyungju
- Journal of Materials Chemistry C, Vol. 7, Issue 21
A Flexible Carbon Nanotube Sen‐Memory Device
journal, January 2020
- Qu, Ting‐Yu; Sun, Yun; Chen, Mao‐Lin
- Advanced Materials, Vol. 32, Issue 9
Electrically Stable Organic Permeable Base Transistors for Display Applications
journal, September 2019
- Dollinger, Felix; Iseke, Henning; Guo, Erjuan
- Advanced Electronic Materials, Vol. 5, Issue 12
Recent Efforts in Understanding and Improving the Nonideal Behaviors of Organic Field‐Effect Transistors
journal, August 2019
- Un, Hio‐Ieng; Wang, Jie‐Yu; Pei, Jian
- Advanced Science, Vol. 6, Issue 20
Polysiloxane–poly(vinyl alcohol) composite dielectrics for high-efficiency low voltage organic thin film transistors
journal, January 2019
- Cao, Jupeng; Wei, Xiaoyun; Che, Yuxuan
- Journal of Materials Chemistry C, Vol. 7, Issue 16
A Review of Vertical Organic Transistors
journal, January 2020
- Kleemann, Hans; Krechan, Kevin; Fischer, Axel
- Advanced Functional Materials, Vol. 30, Issue 20
A Review of Vertical Organic Transistors
text, January 2020
- Kleemann, Hans; Krechan, Kevin; Fischer, Axel
- FID GEO
Repurposing DNA-binding agents as H-bonded organic semiconductors
journal, September 2019
- Zhang, Fengjiao; Lemaur, Vincent; Choi, Wookjin
- Nature Communications, Vol. 10, Issue 1
Flexible and Waterproof Resistive Random‐Access Memory Based on Nitrocellulose for Skin‐Attachable Wearable Devices
journal, November 2019
- Lee, Jin Hyeok; Park, Sung Pyo; Park, Kyungho
- Advanced Functional Materials, Vol. 30, Issue 1
Stability evaluation of ZnO nanosheet based source-gated transistors
journal, February 2019
- Dahiya, A. S.; Sporea, R. A.; Poulin-Vittrant, G.
- Scientific Reports, Vol. 9, Issue 1
Tutorial: Organic field-effect transistors: Materials, structure and operation
journal, August 2018
- Lamport, Zachary A.; Haneef, Hamna F.; Anand, Sajant
- Journal of Applied Physics, Vol. 124, Issue 7
Recent Efforts in Understanding and Improving the Nonideal Behaviors of Organic Field‐Effect Transistors
journal, August 2019
- Un, Hio‐Ieng; Wang, Jie‐Yu; Pei, Jian
- Advanced Science, Vol. 6, Issue 20
A Study on the Stability of Water-Gated Organic Field-Effect-Transistors Based on a Commercial p-Type Polymer
journal, October 2019
- Picca, Rosaria Anna; Manoli, Kyriaki; Macchia, Eleonora
- Frontiers in Chemistry, Vol. 7
Figures / Tables found in this record: