15.3%-Efficient GaAsP Solar Cells on GaP/Si Templates
Abstract
As single-junction Si solar cells approach their practical efficiency limits, a new pathway is necessary to increase efficiency in order to realize more cost-effective photovoltaics. Integrating III-V cells onto Si in a multijunction architecture is a promising approach that can achieve high efficiency while leveraging the infrastructure already in place for Si and III-V technology. In this Letter, we demonstrate a record 15.3%-efficient 1.7 eV GaAsP top cell on GaP/Si, enabled by recent advances in material quality in conjunction with an improved device design and a high-performance antireflection coating. Furthermore, we present a separate Si bottom cell with a 1.7 eV GaAsP optical filter to absorb most of the visible light with an efficiency of 6.3%, showing the feasibility of monolithic III-V/Si tandems with >20% efficiency. Through spectral efficiency analysis, we also compare our results to previously published GaAsP and Si devices, projecting tandem GaAsP/Si efficiencies of up to 25.6% based on current state-of-the-art individual subcells. With the aid of modeling, we further illustrate a realistic path toward 30% GaAsP/Si tandems for high-efficiency, monolithically integrated photovoltaics.
- Authors:
-
- Yale Univ., New Haven, CT (United States). Dept. of Electrical Engineering; National Renewable Energy Lab. (NREL), Golden, CO (United States)
- Univ. of Illinois, Urbana-Champaign, IL (United States). Dept. of Electrical and Computer Engineering
- Yale Univ., New Haven, CT (United States). Dept. of Electrical Engineering
- National Renewable Energy Lab. (NREL), Golden, CO (United States)
- King Juan Carlos Univ., Madrid (Spain). Dept. of Electrical Technology
- Arizona State Univ., Tempe, AZ (United States). School of Electrical, Computer and Energy Engineering
- School of Electrical, Computer and Energy Engineering, Arizona State University, Tempe, Arizona 85287, United States
- Publication Date:
- Research Org.:
- National Renewable Energy Lab. (NREL), Golden, CO (United States)
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE); National Science Foundation (NSF)
- OSTI Identifier:
- 1394745
- Report Number(s):
- NREL/JA-5J00-70182
Journal ID: ISSN 2380-8195
- Grant/Contract Number:
- AC36-08GO28308; DMR-1119826
- Resource Type:
- Accepted Manuscript
- Journal Name:
- ACS Energy Letters
- Additional Journal Information:
- Journal Volume: 2; Journal Issue: 8; Journal ID: ISSN 2380-8195
- Publisher:
- American Chemical Society (ACS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 14 SOLAR ENERGY; solar cells; efficiency; multijunction
Citation Formats
Vaisman, Michelle, Fan, Shizhao, Nay Yaung, Kevin, Perl, Emmett, Martín-Martín, Diego, Yu, Zhengshan J., Leilaeioun, Mehdi, Holman, Zachary C., and Lee, Minjoo L. 15.3%-Efficient GaAsP Solar Cells on GaP/Si Templates. United States: N. p., 2017.
Web. doi:10.1021/acsenergylett.7b00538.
Vaisman, Michelle, Fan, Shizhao, Nay Yaung, Kevin, Perl, Emmett, Martín-Martín, Diego, Yu, Zhengshan J., Leilaeioun, Mehdi, Holman, Zachary C., & Lee, Minjoo L. 15.3%-Efficient GaAsP Solar Cells on GaP/Si Templates. United States. https://doi.org/10.1021/acsenergylett.7b00538
Vaisman, Michelle, Fan, Shizhao, Nay Yaung, Kevin, Perl, Emmett, Martín-Martín, Diego, Yu, Zhengshan J., Leilaeioun, Mehdi, Holman, Zachary C., and Lee, Minjoo L. Wed .
"15.3%-Efficient GaAsP Solar Cells on GaP/Si Templates". United States. https://doi.org/10.1021/acsenergylett.7b00538. https://www.osti.gov/servlets/purl/1394745.
@article{osti_1394745,
title = {15.3%-Efficient GaAsP Solar Cells on GaP/Si Templates},
author = {Vaisman, Michelle and Fan, Shizhao and Nay Yaung, Kevin and Perl, Emmett and Martín-Martín, Diego and Yu, Zhengshan J. and Leilaeioun, Mehdi and Holman, Zachary C. and Lee, Minjoo L.},
abstractNote = {As single-junction Si solar cells approach their practical efficiency limits, a new pathway is necessary to increase efficiency in order to realize more cost-effective photovoltaics. Integrating III-V cells onto Si in a multijunction architecture is a promising approach that can achieve high efficiency while leveraging the infrastructure already in place for Si and III-V technology. In this Letter, we demonstrate a record 15.3%-efficient 1.7 eV GaAsP top cell on GaP/Si, enabled by recent advances in material quality in conjunction with an improved device design and a high-performance antireflection coating. Furthermore, we present a separate Si bottom cell with a 1.7 eV GaAsP optical filter to absorb most of the visible light with an efficiency of 6.3%, showing the feasibility of monolithic III-V/Si tandems with >20% efficiency. Through spectral efficiency analysis, we also compare our results to previously published GaAsP and Si devices, projecting tandem GaAsP/Si efficiencies of up to 25.6% based on current state-of-the-art individual subcells. With the aid of modeling, we further illustrate a realistic path toward 30% GaAsP/Si tandems for high-efficiency, monolithically integrated photovoltaics.},
doi = {10.1021/acsenergylett.7b00538},
journal = {ACS Energy Letters},
number = 8,
volume = 2,
place = {United States},
year = {Wed Jul 26 00:00:00 EDT 2017},
month = {Wed Jul 26 00:00:00 EDT 2017}
}
Web of Science
Works referenced in this record:
Silicon heterojunction solar cell with interdigitated back contacts for a photoconversion efficiency over 26%
journal, March 2017
- Yoshikawa, Kunta; Kawasaki, Hayato; Yoshida, Wataru
- Nature Energy, Vol. 2, Issue 5
Reassessment of the Limiting Efficiency for Crystalline Silicon Solar Cells
journal, October 2013
- Richter, Armin; Hermle, Martin; Glunz, Stefan W.
- IEEE Journal of Photovoltaics, Vol. 3, Issue 4
A mixed-cation lead mixed-halide perovskite absorber for tandem solar cells
journal, January 2016
- McMeekin, D. P.; Sadoughi, G.; Rehman, W.
- Science, Vol. 351, Issue 6269
Semi-transparent perovskite solar cells for tandems with silicon and CIGS
journal, January 2015
- Bailie, Colin D.; Christoforo, M. Greyson; Mailoa, Jonathan P.
- Energy & Environmental Science, Vol. 8, Issue 3
Monolithic perovskite/silicon-heterojunction tandem solar cells processed at low temperature
journal, January 2016
- Albrecht, Steve; Saliba, Michael; Correa Baena, Juan Pablo
- Energy & Environmental Science, Vol. 9, Issue 1
23.6%-efficient monolithic perovskite/silicon tandem solar cells with improved stability
journal, February 2017
- Bush, Kevin A.; Palmstrom, Axel F.; Yu, Zhengshan J.
- Nature Energy, Vol. 2, Issue 4
Efficient Near-Infrared-Transparent Perovskite Solar Cells Enabling Direct Comparison of 4-Terminal and Monolithic Perovskite/Silicon Tandem Cells
journal, August 2016
- Werner, Jérémie; Barraud, Loris; Walter, Arnaud
- ACS Energy Letters, Vol. 1, Issue 2
Efficient Semitransparent Perovskite Solar Cells for 23.0%-Efficiency Perovskite/Silicon Four-Terminal Tandem Cells
journal, July 2016
- Chen, Bo; Bai, Yang; Yu, Zhengshan
- Advanced Energy Materials, Vol. 6, Issue 19
Rubidium Multication Perovskite with Optimized Bandgap for Perovskite-Silicon Tandem with over 26% Efficiency
journal, April 2017
- Duong, The; Wu, YiLiang; Shen, Heping
- Advanced Energy Materials, Vol. 7, Issue 14
A 2-terminal perovskite/silicon multijunction solar cell enabled by a silicon tunnel junction
journal, March 2015
- Mailoa, Jonathan P.; Bailie, Colin D.; Johlin, Eric C.
- Applied Physics Letters, Vol. 106, Issue 12
Zinc tin oxide as high-temperature stable recombination layer for mesoscopic perovskite/silicon monolithic tandem solar cells
journal, December 2016
- Werner, Jérémie; Walter, Arnaud; Rucavado, Esteban
- Applied Physics Letters, Vol. 109, Issue 23
Reliability of III–V concentrator solar cells
journal, September 2010
- Algora, Carlos
- Microelectronics Reliability, Vol. 50, Issue 9-11
A review of solar photovoltaic levelized cost of electricity
journal, December 2011
- Branker, K.; Pathak, M. J. M.; Pearce, J. M.
- Renewable and Sustainable Energy Reviews, Vol. 15, Issue 9
Predicting edge seal performance from accelerated testing
conference, October 2014
- Hardikar, Kedar; Vitkavage, Dan; Saproo, Ajay
- SPIE Solar Energy + Technology, SPIE Proceedings
Life prediction for CIGS solar modules part 1: modeling moisture ingress and degradation: Modeling moisture ingress and degradation
journal, October 2011
- Coyle, Dennis J.
- Progress in Photovoltaics: Research and Applications, Vol. 21, Issue 2
Life prediction for CIGS solar modules part 2: degradation kinetics, accelerated testing, and encapsulant effects: CIGS kinetics, accelerated testing, encapsulant effects
journal, October 2011
- Coyle, Dennis J.; Blaydes, Holly A.; Northey, Rebecca S.
- Progress in Photovoltaics: Research and Applications, Vol. 21, Issue 2
Characterization of Metamorphic GaAsP/Si Materials and Devices for Photovoltaic Applications
journal, December 2010
- Grassman, Tyler J.; Brenner, Mark R.; Gonzalez, Maria
- IEEE Transactions on Electron Devices, Vol. 57, Issue 12
Surface-passivated GaAsP single-nanowire solar cells exceeding 10% efficiency grown on silicon
journal, February 2013
- Holm, Jeppe V.; Jørgensen, Henrik I.; Krogstrup, Peter
- Nature Communications, Vol. 4, Issue 1
Comparison of Direct Growth and Wafer Bonding for the Fabrication of GaInP/GaAs Dual-Junction Solar Cells on Silicon
journal, March 2014
- Dimroth, Frank; Roesener, Tobias; Essig, Stephanie
- IEEE Journal of Photovoltaics, Vol. 4, Issue 2
Metamorphic GaAsP Tunnel Junctions for High-Efficiency III–V/IV Multijunction Solar Cell Technology
journal, September 2014
- Chmielewski, Daniel J.; Grassman, Tyler J.; Carlin, Andrew M.
- IEEE Journal of Photovoltaics, Vol. 4, Issue 5
III-V/Si wafer bonding using transparent, conductive oxide interlayers
journal, June 2015
- Tamboli, Adele C.; van Hest, Maikel F. A. M.; Steiner, Myles A.
- Applied Physics Letters, Vol. 106, Issue 26
Wafer-Bonded GaInP/GaAs//Si Solar Cells With 30% Efficiency Under Concentrated Sunlight
journal, May 2015
- Essig, Stephanie; Benick, Jan; Schachtner, Michael
- IEEE Journal of Photovoltaics, Vol. 5, Issue 3
Realization of GaInP/Si Dual-Junction Solar Cells With 29.8% 1-Sun Efficiency
journal, July 2016
- Essig, Stephanie; Steiner, Myles A.; Allebe, Christophe
- IEEE Journal of Photovoltaics, Vol. 6, Issue 4
Gallium Phosphide Window Layer for Silicon Solar Cells
journal, January 2016
- Feifel, Markus; Rachow, Thomas; Benick, Jan
- IEEE Journal of Photovoltaics, Vol. 6, Issue 1
Monolithic Two-Terminal III–V//Si Triple-Junction Solar Cells With 30.2% Efficiency Under 1-Sun AM1.5g
journal, January 2017
- Cariou, Romain; Benick, Jan; Beutel, Paul
- IEEE Journal of Photovoltaics, Vol. 7, Issue 1
III N V semiconductors for solar photovoltaic applications
journal, July 2002
- Geisz, J. F.; Friedman, D. J.
- Semiconductor Science and Technology, Vol. 17, Issue 8
Spectrum-optimized Si-based III-V multijunction photovoltaics
conference, February 2012
- Grassman, Tyler J.; Carlin, Andrew M.; Grandal, Javier
- SPIE OPTO, SPIE Proceedings
Control and elimination of nucleation-related defects in GaP/Si(001) heteroepitaxy
journal, June 2009
- Grassman, T. J.; Brenner, M. R.; Rajagopalan, S.
- Applied Physics Letters, Vol. 94, Issue 23
GaP-nucleation on exact Si (001) substrates for III/V device integration
journal, January 2011
- Volz, Kerstin; Beyer, Andreas; Witte, Wiebke
- Journal of Crystal Growth, Vol. 315, Issue 1
Nucleation-related defect-free GaP/Si(100) heteroepitaxy via metal-organic chemical vapor deposition
journal, April 2013
- Grassman, T. J.; Carlin, J. A.; Galiana, B.
- Applied Physics Letters, Vol. 102, Issue 14
Growth of antiphase-domain-free GaP on Si substrates by metalorganic chemical vapor deposition using an in situ AsH 3 surface preparation
journal, August 2015
- Warren, Emily L.; Kibbler, Alan E.; France, Ryan M.
- Applied Physics Letters, Vol. 107, Issue 8
In situ controlled heteroepitaxy of single-domain GaP on As-modified Si(100)
journal, December 2015
- Supplie, Oliver; May, Matthias M.; Kleinschmidt, Peter
- APL Materials, Vol. 3, Issue 12
Comparison of GaAsP solar cells on GaP and GaP/Si
journal, August 2013
- Lang, Jordan R.; Faucher, Joseph; Tomasulo, Stephanie
- Applied Physics Letters, Vol. 103, Issue 9
GaAsP solar cells on GaP/Si with low threading dislocation density
journal, July 2016
- Yaung, Kevin Nay; Vaisman, Michelle; Lang, Jordan
- Applied Physics Letters, Vol. 109, Issue 3
Selecting tandem partners for silicon solar cells
journal, September 2016
- Yu, Zhengshan; Leilaeioun, Mehdi; Holman, Zachary
- Nature Energy, Vol. 1, Issue 11
Efficiency calculations of thin‐film GaAs solar cells on Si substrates
journal, November 1985
- Yamaguchi, Masafumi; Amano, Chikara
- Journal of Applied Physics, Vol. 58, Issue 9
Impact of dislocation densities on n+∕p and p+∕n junction GaAs diodes and solar cells on SiGe virtual substrates
journal, July 2005
- Andre, C. L.; Wilt, D. M.; Pitera, A. J.
- Journal of Applied Physics, Vol. 98, Issue 1
GaAsP/Si solar cells and tunnel junctions for III-V/Si tandem devices
conference, June 2016
- Vaisman, Michelle; Yaung, Kevin Nay; Sun, Yukun
- 2016 IEEE 43rd Photovoltaic Specialists Conference (PVSC)
MOCVD-Grown GaP/Si Subcells for Integrated III–V/Si Multijunction Photovoltaics
journal, May 2014
- Grassman, T. J.; Carlin, J. A.; Galiana, B.
- IEEE Journal of Photovoltaics, Vol. 4, Issue 3
Silicon Minority-carrier Lifetime Degradation During Molecular Beam Heteroepitaxial III-V Material Growth
journal, August 2016
- Ding, Laura; Zhang, Chaomin; Nærland, Tine Uberg
- Energy Procedia, Vol. 92
Impact of metal-organic vapor phase epitaxy environment on silicon bulk lifetime for III–V-on-Si multijunction solar cells
journal, May 2014
- García-Tabarés, Elisa; Rey-Stolle, Ignacio
- Solar Energy Materials and Solar Cells, Vol. 124
Surface passivation of crystalline silicon solar cells: a review
journal, January 2000
- Aberle, Armin G.
- Progress in Photovoltaics: Research and Applications, Vol. 8, Issue 5, p. 473-487
Assessment of Rear-Surface Processing Strategies for III–V on Si Multijunction Solar Cells Based on Numerical Simulations
journal, January 2016
- Martin-Martin, Diego; Garcia-Tabares, Elisa; Rey-Stolle, Ignacio
- IEEE Transactions on Electron Devices, Vol. 63, Issue 1
Solar cell efficiency tables (version 48): Solar cell efficiency tables (version 48)
journal, June 2016
- Green, Martin A.; Emery, Keith; Hishikawa, Yoshihiro
- Progress in Photovoltaics: Research and Applications, Vol. 24, Issue 7
Evolution of Bulk c-Si Properties during the Processing of GaP/c-Si Heterojunction Cell
journal, August 2015
- Varache, Renaud; Darnon, Maxime; Descazeaux, Médéric
- Energy Procedia, Vol. 77
Designing Bottom Silicon Solar Cells for Multijunction Devices
journal, March 2015
- Almansouri, Ibraheem; Bremner, Stephen; Ho-Baillie, Anita
- IEEE Journal of Photovoltaics, Vol. 5, Issue 2
Impact of a Metal–Organic Vapor Phase Epitaxy Environment on Silicon Substrates for III–V-on-Si Multijunction Solar Cells
journal, October 2012
- García-Tabarés, Elisa; García, Iván; Lelièvre, Jean-Francois
- Japanese Journal of Applied Physics, Vol. 51, Issue 10S
26.1% thin-film GaAs solar cell using epitaxial lift-off
journal, September 2009
- Bauhuis, G. J.; Mulder, P.; Haverkamp, E. J.
- Solar Energy Materials and Solar Cells, Vol. 93, Issue 9
Optical enhancement of the open-circuit voltage in high quality GaAs solar cells
journal, March 2013
- Steiner, M. A.; Geisz, J. F.; García, I.
- Journal of Applied Physics, Vol. 113, Issue 12
Impact of dislocations on minority carrier electron and hole lifetimes in GaAs grown on metamorphic SiGe substrates
journal, May 2004
- Andre, C. L.; Boeckl, J. J.; Wilt, D. M.
- Applied Physics Letters, Vol. 84, Issue 18
High-efficiency AlGaInP solar cells grown by molecular beam epitaxy
journal, October 2016
- Faucher, J.; Sun, Y.; Jung, D.
- Applied Physics Letters, Vol. 109, Issue 17
InGaAsN solar cells with 1.0 eV band gap, lattice matched to GaAs
journal, February 1999
- Kurtz, Steven R.; Allerman, A. A.; Jones, E. D.
- Applied Physics Letters, Vol. 74, Issue 5
Works referencing / citing this record:
A review of recent progress in heterogeneous silicon tandem solar cells
journal, March 2018
- Yamaguchi, Masafumi; Lee, Kan-Hua; Araki, Kenji
- Journal of Physics D: Applied Physics, Vol. 51, Issue 13
GaAs/silicon PVMirror tandem photovoltaic mini‐module with 29.6% efficiency with respect to the outdoor global irradiance
journal, January 2019
- Yu, Zhengshan J.; Fisher, Kathryn C.; Meng, Xiaodong
- Progress in Photovoltaics: Research and Applications, Vol. 27, Issue 5
How to control defect formation in monolithic III/V hetero-epitaxy on (100) Si? A critical review on current approaches
journal, August 2018
- Kunert, Bernardette; Mols, Yves; Baryshniskova, Marina
- Semiconductor Science and Technology, Vol. 33, Issue 9
Direct Growth of a GaInP/GaAs/Si Triple‐Junction Solar Cell with 22.3% AM1.5g Efficiency
journal, September 2019
- Feifel, Markus; Lackner, David; Ohlmann, Jens
- Solar RRL, Vol. 3, Issue 12
Nanoscale electrical analyses of axial-junction GaAsP nanowires for solar cell applications
journal, January 2020
- Saket, Omar; Himwas, Chalermchai; Piazza, Valerio
- Nanotechnology, Vol. 31, Issue 14
Advanced Electron Microscopy for III/V on Silicon Integration
journal, April 2019
- Beyer, Andreas; Volz, Kerstin
- Advanced Materials Interfaces, Vol. 6, Issue 12
Energy band engineering of InGaN/GaN multi-quantum-well solar cells via AlGaN electron- and hole-blocking layers
journal, July 2018
- Huang, Xuanqi; Chen, Hong; Fu, Houqiang
- Applied Physics Letters, Vol. 113, Issue 4
Design and growth of multi-functional InAsP metamorphic buffers for mid-infrared quantum well lasers on InP
journal, February 2019
- Jung, Daehwan; Yu, Lan; Dev, Sukrith
- Journal of Applied Physics, Vol. 125, Issue 8