White-beam X-ray diffraction and radiography studies on high-boron-containing borosilicate glass at high pressures
Abstract
Multi-angle energy-dispersive X-ray diffraction studies and white-beam X-ray radiography were conducted with a cylindrically shaped (1 mm diameter and 0.7 mm high) high-boron-content borosilicate glass sample (17.6% B2O3) to a pressure of 13.7 GPa using a Paris-Edinburgh (PE) press at Beamline 16-BM-B, HPCAT of the Advanced Photon Source. The measured structure factor S(q) to large q = 19 Å–1 is used to determine information about the internuclear bond distances between various species of atoms within the glass sample. Sample pressure was determined with gold as a pressure standard. The sample height as measured by radiography showed an overall uniaxial compression of 22.5% at 13.7 GPa with 10.6% permanent compaction after decompression to ambient conditions. The reduced pair distribution function G(r) was extracted and Si–O, O–O and Si–Si bond distances were measured as a function of pressure. Lastly, Raman spectroscopy of the pressure recovered sample as compared to starting material showed blue-shift and changes in intensity and widths of Raman bands associated with silicate and four-coordinated boron.
- Authors:
- Publication Date:
- Research Org.:
- Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE; Work for Others (WFO)
- OSTI Identifier:
- 1344287
- Grant/Contract Number:
- AC05-00OR22725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- High Pressure Research
- Additional Journal Information:
- Journal Volume: 37; Journal Issue: 2; Journal ID: ISSN 0895-7959
- Publisher:
- Taylor & Francis
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 43 PARTICLE ACCELERATORS; borosilicate glass; Paris-Edinburgh cell; high pressure; X-ray diffraction
Citation Formats
Ham, Kathryn J., Vohra, Yogesh K., Kono, Yoshio, Wereszczak, Andrew A., and Patel, Parimal. White-beam X-ray diffraction and radiography studies on high-boron-containing borosilicate glass at high pressures. United States: N. p., 2017.
Web. doi:10.1080/08957959.2017.1287263.
Ham, Kathryn J., Vohra, Yogesh K., Kono, Yoshio, Wereszczak, Andrew A., & Patel, Parimal. White-beam X-ray diffraction and radiography studies on high-boron-containing borosilicate glass at high pressures. United States. https://doi.org/10.1080/08957959.2017.1287263
Ham, Kathryn J., Vohra, Yogesh K., Kono, Yoshio, Wereszczak, Andrew A., and Patel, Parimal. Mon .
"White-beam X-ray diffraction and radiography studies on high-boron-containing borosilicate glass at high pressures". United States. https://doi.org/10.1080/08957959.2017.1287263. https://www.osti.gov/servlets/purl/1344287.
@article{osti_1344287,
title = {White-beam X-ray diffraction and radiography studies on high-boron-containing borosilicate glass at high pressures},
author = {Ham, Kathryn J. and Vohra, Yogesh K. and Kono, Yoshio and Wereszczak, Andrew A. and Patel, Parimal},
abstractNote = {Multi-angle energy-dispersive X-ray diffraction studies and white-beam X-ray radiography were conducted with a cylindrically shaped (1 mm diameter and 0.7 mm high) high-boron-content borosilicate glass sample (17.6% B2O3) to a pressure of 13.7 GPa using a Paris-Edinburgh (PE) press at Beamline 16-BM-B, HPCAT of the Advanced Photon Source. The measured structure factor S(q) to large q = 19 Å–1 is used to determine information about the internuclear bond distances between various species of atoms within the glass sample. Sample pressure was determined with gold as a pressure standard. The sample height as measured by radiography showed an overall uniaxial compression of 22.5% at 13.7 GPa with 10.6% permanent compaction after decompression to ambient conditions. The reduced pair distribution function G(r) was extracted and Si–O, O–O and Si–Si bond distances were measured as a function of pressure. Lastly, Raman spectroscopy of the pressure recovered sample as compared to starting material showed blue-shift and changes in intensity and widths of Raman bands associated with silicate and four-coordinated boron.},
doi = {10.1080/08957959.2017.1287263},
journal = {High Pressure Research},
number = 2,
volume = 37,
place = {United States},
year = {Mon Feb 06 00:00:00 EST 2017},
month = {Mon Feb 06 00:00:00 EST 2017}
}
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Works referencing / citing this record:
Pressure Induced Densification and Compression in a Reprocessed Borosilicate Glass
journal, January 2018
- Ham, Kathryn; Kono, Yoshio; Patel, Parimal
- Materials, Vol. 11, Issue 1