A new method for achieving enhanced dielectric response over a wide temperature range

Maurya, Deepam; Sun, Fu -Chang; Pamir Alpay, S.; Priya, Shashank

doi:10.1038/srep15144

Title: A new method for achieving enhanced dielectric response over a wide temperature range

Abstract

We report a novel approach for achieving high dielectric response over a wide temperature range. In this approach, multilayer ceramic heterostructures with constituent compositions having strategically tuned Curie points (TC) were designed and integrated with varying electrical connectivity. Interestingly, these multilayer structures exhibited different dielectric behavior in series and parallel configuration due to variations in electrical boundary conditions resulting in the differences in the strength of the electrostatic coupling. The results are explained using nonlinear thermodynamic model taking into account electrostatic interlayer interaction. We believe that present work will have huge significance in design of high performance ceramic capacitors.

Authors:

Maurya, Deepam ^[1]; Sun, Fu -Chang ^[2]; Pamir Alpay, S. ^[2]; Priya, Shashank ^[1]

Virginia Polytechnic Inst. and State Univ. (Virginia Tech), Blacksburg, VA (United States)
Univ. of Connecticut, Storrs, CT (United States)

Publication Date:: Mon Oct 19 00:00:00 EDT 2015

Research Org.:: California Institute of Technology (CalTech), Pasadena, CA (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1239285

Grant/Contract Number:: FG02-07ER46405

Resource Type:: Accepted Manuscript

Journal Name:: Scientific Reports

Additional Journal Information:: Journal Volume: 5; Journal ID: ISSN 2045-2322

Publisher:: Nature Publishing Group

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE

Citation Formats


                    Maurya, Deepam, Sun, Fu -Chang, Pamir Alpay, S., and Priya, Shashank. A new method for achieving enhanced dielectric response over a wide temperature range.  United States: N. p., 2015. 
Web.  doi:10.1038/srep15144.

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                    Maurya, Deepam, Sun, Fu -Chang, Pamir Alpay, S., & Priya, Shashank. A new method for achieving enhanced dielectric response over a wide temperature range.  United States.  https://doi.org/10.1038/srep15144

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                    Maurya, Deepam, Sun, Fu -Chang, Pamir Alpay, S., and Priya, Shashank. Mon .  
"A new method for achieving enhanced dielectric response over a wide temperature range".  United States.  https://doi.org/10.1038/srep15144.  https://www.osti.gov/servlets/purl/1239285.

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@article{osti_1239285,

  title        = {A new method for achieving enhanced dielectric response over a wide temperature range},

  author       = {Maurya, Deepam and Sun, Fu -Chang and Pamir Alpay, S. and Priya, Shashank},

  abstractNote = {We report a novel approach for achieving high dielectric response over a wide temperature range. In this approach, multilayer ceramic heterostructures with constituent compositions having strategically tuned Curie points (TC) were designed and integrated with varying electrical connectivity. Interestingly, these multilayer structures exhibited different dielectric behavior in series and parallel configuration due to variations in electrical boundary conditions resulting in the differences in the strength of the electrostatic coupling. The results are explained using nonlinear thermodynamic model taking into account electrostatic interlayer interaction. We believe that present work will have huge significance in design of high performance ceramic capacitors.},

  doi          = {10.1038/srep15144},

  journal      = {Scientific Reports},

  number       = ,

  volume       = 5,

  place        = {United States},

  year         = {Mon Oct 19 00:00:00 EDT 2015},

  month        = {Mon Oct 19 00:00:00 EDT 2015}

}

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https://doi.org/10.1038/srep15144

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Cited by: 13 works

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Works referenced in this record:

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Diffuse Ferroelectric Phase Transitions in Ba(Ti1-yZry)O3 Ceramics
journal, November 1982

Hennings, D.; Schnell, A.; Simon, G.
Journal of the American Ceramic Society, Vol. 65, Issue 11
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Works referencing / citing this record:

Topological phase transformations and intrinsic size effects in ferroelectric nanoparticles
journal, January 2017

Mangeri, John; Espinal, Yomery; Jokisaari, Andrea
Nanoscale, Vol. 9, Issue 4
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Formation of polarization needle-like domain and its unusual switching in compositionally graded ferroelectric thin films: an improved phase field model
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An in situ (K _0.5 Na _0.5 )NbO ₃ -doped barium titanate foam framework and its cyanate ester resin composites with temperature-stable dielectric properties and low dielectric loss
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Zheng, Longhui; Yuan, Li; Liang, Guozheng
Materials Chemistry Frontiers, Vol. 3, Issue 4
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Interfacial coupling modulation to the electrocaloric effect of Ba(Zr, Ti)O ₃ multilayered thick films
journal, June 2019

Hou, Ying; Huang, Xiaohua; Zhao, Xiaobo
Journal of Applied Physics, Vol. 125, Issue 21
DOI: 10.1063/1.5092556

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Similar Records

Title: A new method for achieving enhanced dielectric response over a wide temperature range

Abstract

Citation Formats

Diffuse Ferroelectric Phase Transitions in Ba(Ti1-yZry)O3 Ceramics journal, November 1982

High-K Dielectric Ceramics from Donor/Acceptor-Codoped (Ba1−xCax)(Ti1-yZry)O3 (BCTZ) journal, May 1998

Structure property relationships in core-shell BaTiO 3 –LiF ceramics journal, April 1993

A brief introduction to ceramic capacitors journal, May 2010

Barium Zirconate Modified with Lanthanum, a High-Temperature Capacitor Dielectric journal, February 1964

High-Energy Density Capacitors Utilizing 0.7 BaTiO 3 -0.3 BiScO 3 Ceramics journal, August 2009

Nb-Doped 0.9BaTiO3-0.1(Bi0.5Na0.5)TiO3 Ceramics with Stable Dielectric Properties at High Temperature journal, August 2011

Dielectric Relaxation in BaTiO3-Bi(Zn1/2Ti1/2)O3 Ceramics journal, December 2011

High-temperature stable dielectrics in Mn-modified (1-x) Bi0.5Na0.5TiO3-xCaTiO3 ceramics journal, July 2010

High-Temperature Capacitor Based on Ca-Doped Bi0.5Na0.5TiO3-BaTiO3 Ceramics journal, September 2010

Dielectric anomaly due to electrostatic coupling in ferroelectric-paraelectric bilayers and multilayers journal, August 2005

Electric-field penetration into metals: consequences for high-dielectric-constant capacitors journal, April 1999

Thickness dependence of dielectric loss in SrTiO3 thin films journal, July 1998

Investigation of dead-layer thickness in SrRuO3/Ba0.5Sr0.5TiO3/Au thin-film capacitors journal, March 2001

Thickness and dielectric constant of dead layer in Pt/(Ba0.7Sr0.3)TiO3/YBa2Cu3O7−x capacitor journal, January 2004

Origin of the dielectric dead layer in nanoscale capacitors journal, October 2006

X-Ray Diffraction Studies of 180° Ferroelectric Domains in PbTiO 3 / SrTiO 3 Superlattices under an Applied Electric Field journal, May 2010

Ground state and properties of ferroelectric superlattices based on crystals of the perovskite family journal, July 2010

Thickness-driven antiferroelectric-to-ferroelectric phase transition of thin PbZrO3 layers in epitaxial PbZrO3∕Pb(Zr0.8Ti0.2)O3 multilayers journal, September 2007

Superlattices of PbZrO 3 and PbTiO 3 prepared by multi‐ion‐beam sputtering journal, January 1996

Thermodynamics of polydomain ferroelectric bilayers and graded multilayers journal, July 2006

Domain engineering in compositionally graded ferroelectric films for enhanced dielectric response and tunability journal, June 2009

Polarization coupling in ferroelectric multilayers journal, May 2009

Tailoring dielectric properties of ferroelectric-dielectric multilayers journal, January 2014

Enhanced dielectric properties from barium strontium titanate films with strontium titanate buffer layers journal, October 2013

Theoretical studies on the pyroelectric properties of two component composite ferroelectric thin film journal, December 2006

Strong polarization enhancement in asymmetric three-component ferroelectric superlattices journal, January 2005

Asymmetric hysteresis loops and smearing of the dielectric anomaly at the transition temperature due to space charges in ferroelectric thin films journal, August 2010

Asymmetric hysteresis loops and smearing of the dielectric anomaly at the transition temperature due to space charges in ferroelectric thin films journal, August 2010

Tailoring dielectric properties of ferroelectric-dielectric multilayers journal, January 2014

Electrical domain morphologies in compositionally graded ferroelectric films journal, December 2011

High-K (Ba 0.8 Bi 0.2 )(Zn 0.1 Ti 0.9 )O 3 ceramics for high-temperature capacitor applications journal, September 2011

Diffuse Ferroelectric Phase Transitions in Ba(Ti1-yZry)O3 Ceramics journal, November 1982

Base-Metal Electrode-Multilayer Ceramic Capacitors: Past, Present and Future Perspectives journal, January 2003

Topological phase transformations and intrinsic size effects in ferroelectric nanoparticles journal, January 2017

Formation of polarization needle-like domain and its unusual switching in compositionally graded ferroelectric thin films: an improved phase field model journal, January 2019

An in situ (K 0.5 Na 0.5 )NbO 3 -doped barium titanate foam framework and its cyanate ester resin composites with temperature-stable dielectric properties and low dielectric loss journal, January 2019

Interfacial coupling modulation to the electrocaloric effect of Ba(Zr, Ti)O 3 multilayered thick films journal, June 2019

Diffuse Ferroelectric Phase Transitions in Ba(Ti1-yZry)O3 Ceramics
journal, November 1982

High-K Dielectric Ceramics from Donor/Acceptor-Codoped (Ba1−xCax)(Ti1-yZry)O3 (BCTZ)
journal, May 1998

Structure property relationships in core-shell BaTiO ₃ –LiF ceramics
journal, April 1993

A brief introduction to ceramic capacitors
journal, May 2010

Barium Zirconate Modified with Lanthanum, a High-Temperature Capacitor Dielectric
journal, February 1964

High-Energy Density Capacitors Utilizing 0.7 BaTiO ₃ -0.3 BiScO ₃ Ceramics
journal, August 2009

Nb-Doped 0.9BaTiO3-0.1(Bi0.5Na0.5)TiO3 Ceramics with Stable Dielectric Properties at High Temperature
journal, August 2011

Dielectric Relaxation in BaTiO3-Bi(Zn1/2Ti1/2)O3 Ceramics
journal, December 2011

High-temperature stable dielectrics in Mn-modified (1-x) Bi0.5Na0.5TiO3-xCaTiO3 ceramics
journal, July 2010

High-Temperature Capacitor Based on Ca-Doped Bi0.5Na0.5TiO3-BaTiO3 Ceramics
journal, September 2010

Dielectric anomaly due to electrostatic coupling in ferroelectric-paraelectric bilayers and multilayers
journal, August 2005

Electric-field penetration into metals: consequences for high-dielectric-constant capacitors
journal, April 1999

Thickness dependence of dielectric loss in SrTiO3 thin films
journal, July 1998

Investigation of dead-layer thickness in SrRuO3/Ba0.5Sr0.5TiO3/Au thin-film capacitors
journal, March 2001

Thickness and dielectric constant of dead layer in Pt/(Ba0.7Sr0.3)TiO3/YBa2Cu3O7−x capacitor
journal, January 2004

Origin of the dielectric dead layer in nanoscale capacitors
journal, October 2006

X-Ray Diffraction Studies of 180° Ferroelectric Domains in ${PbTiO}_{3} / {SrTiO}_{3}$ Superlattices under an Applied Electric Field
journal, May 2010

Ground state and properties of ferroelectric superlattices based on crystals of the perovskite family
journal, July 2010

Thickness-driven antiferroelectric-to-ferroelectric phase transition of thin PbZrO3 layers in epitaxial PbZrO3∕Pb(Zr0.8Ti0.2)O3 multilayers
journal, September 2007

Superlattices of PbZrO ₃ and PbTiO ₃ prepared by multi‐ion‐beam sputtering
journal, January 1996

Thermodynamics of polydomain ferroelectric bilayers and graded multilayers
journal, July 2006

Domain engineering in compositionally graded ferroelectric films for enhanced dielectric response and tunability
journal, June 2009

Polarization coupling in ferroelectric multilayers
journal, May 2009

Tailoring dielectric properties of ferroelectric-dielectric multilayers
journal, January 2014

Enhanced dielectric properties from barium strontium titanate films with strontium titanate buffer layers
journal, October 2013

Theoretical studies on the pyroelectric properties of two component composite ferroelectric thin film
journal, December 2006

Strong polarization enhancement in asymmetric three-component ferroelectric superlattices
journal, January 2005

Asymmetric hysteresis loops and smearing of the dielectric anomaly at the transition temperature due to space charges in ferroelectric thin films
journal, August 2010

Asymmetric hysteresis loops and smearing of the dielectric anomaly at the transition temperature due to space charges in ferroelectric thin films
journal, August 2010

Tailoring dielectric properties of ferroelectric-dielectric multilayers
journal, January 2014

Electrical domain morphologies in compositionally graded ferroelectric films
journal, December 2011

High-K (Ba _0.8 Bi _0.2 )(Zn _0.1 Ti _0.9 )O ₃ ceramics for high-temperature capacitor applications
journal, September 2011

Diffuse Ferroelectric Phase Transitions in Ba(Ti1-yZry)O3 Ceramics
journal, November 1982

Base-Metal Electrode-Multilayer Ceramic Capacitors: Past, Present and Future Perspectives
journal, January 2003

Topological phase transformations and intrinsic size effects in ferroelectric nanoparticles
journal, January 2017

Formation of polarization needle-like domain and its unusual switching in compositionally graded ferroelectric thin films: an improved phase field model
journal, January 2019

An in situ (K _0.5 Na _0.5 )NbO ₃ -doped barium titanate foam framework and its cyanate ester resin composites with temperature-stable dielectric properties and low dielectric loss
journal, January 2019

Interfacial coupling modulation to the electrocaloric effect of Ba(Zr, Ti)O ₃ multilayered thick films
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