Optimized Substrates and Measurement Approaches for Raman Spectroscopy of Graphene Nanoribbons
Abstract
The on-surface synthesis of graphene nanoribbons (GNRs) allows for the fabrication of atomically precise narrow GNRs. Despite their exceptional properties which can be tuned by ribbon width and edge structure, significant challenges remain for GNR processing and characterization. In this work, Raman spectroscopy is used to characterize different types of GNRs on their growth substrate and track their quality upon substrate transfer. A Raman-optimized (RO) device substrate and an optimized mapping approach are presented that allow for the acquisition of high-resolution Raman spectra, achieving enhancement factors as high as 120 with respect to signals measured on standard SiO2/Si substrates. This approach is well suited to routinely monitor the geometry-dependent low-frequency modes of GNRs. In particular, the radial breathing-like mode (RBLM) and the shear-like mode (SLM) for 5-, 7-, and 9-atom-wide armchair GNRs (AGNRs) are tracked and their frequencies are compared with first-principles calculations.
- Authors:
-
- Empa, Swiss Federal Lab. for Materials Science and Technology, Dübendorf (Switzerland); Univ. of Basel (Switzerland)
- Empa, Swiss Federal Lab. for Materials Science and Technology, Dübendorf (Switzerland)
- Rensselaer Polytechnic Inst., Troy, NY (United States)
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Science (CNMS)
- Empa, Swiss Federal Lab. for Materials Science and Technology, Dübendorf (Switzerland); Univ. of Bern (Switzerland)
- Max Planck Inst. for Polymer Research, Mainz (Germany)
- Max Planck Inst. for Polymer Research, Mainz (Germany); Johannes Gutenberg Univ., Mainz (Germany)
- Publication Date:
- Research Org.:
- Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences (CNMS)
- Sponsoring Org.:
- Swiss National Science Foundation (SNF); European Union’s Horizon 2020; US Department of the Navy, Office of Naval Research (ONR); USDOE Office of Science (SC); Max Planck Society; Binning and Rohrer Nanotechnology Center (BRNC)
- OSTI Identifier:
- 1607085
- Grant/Contract Number:
- AC05-00OR22725; 20PC21_155644; 785219; 754364
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Physica Status Solidi B. Basic Solid State Physics
- Additional Journal Information:
- Journal Volume: 256; Journal Issue: 12; Journal ID: ISSN 0370-1972
- Publisher:
- Wiley-Blackwell
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS; graphene nanoribbons; Raman-optimized substrates; Raman spectroscopy; substrate transfer; vibrational modes
Citation Formats
Overbeck, Jan, Borin Barin, Gabriela, Daniels, Colin, Perrin, Mickael L., Liang, Liangbo, Braun, Oliver, Darawish, Rimah, Burkhardt, Bryanna, Dumslaff, Tim, Wang, Xiao-Ye, Narita, Akimitsu, Müllen, Klaus, Meunier, Vincent, Fasel, Roman, Calame, Michel, and Ruffieux, Pascal. Optimized Substrates and Measurement Approaches for Raman Spectroscopy of Graphene Nanoribbons. United States: N. p., 2019.
Web. doi:10.1002/pssb.201900343.
Overbeck, Jan, Borin Barin, Gabriela, Daniels, Colin, Perrin, Mickael L., Liang, Liangbo, Braun, Oliver, Darawish, Rimah, Burkhardt, Bryanna, Dumslaff, Tim, Wang, Xiao-Ye, Narita, Akimitsu, Müllen, Klaus, Meunier, Vincent, Fasel, Roman, Calame, Michel, & Ruffieux, Pascal. Optimized Substrates and Measurement Approaches for Raman Spectroscopy of Graphene Nanoribbons. United States. https://doi.org/10.1002/pssb.201900343
Overbeck, Jan, Borin Barin, Gabriela, Daniels, Colin, Perrin, Mickael L., Liang, Liangbo, Braun, Oliver, Darawish, Rimah, Burkhardt, Bryanna, Dumslaff, Tim, Wang, Xiao-Ye, Narita, Akimitsu, Müllen, Klaus, Meunier, Vincent, Fasel, Roman, Calame, Michel, and Ruffieux, Pascal. Wed .
"Optimized Substrates and Measurement Approaches for Raman Spectroscopy of Graphene Nanoribbons". United States. https://doi.org/10.1002/pssb.201900343. https://www.osti.gov/servlets/purl/1607085.
@article{osti_1607085,
title = {Optimized Substrates and Measurement Approaches for Raman Spectroscopy of Graphene Nanoribbons},
author = {Overbeck, Jan and Borin Barin, Gabriela and Daniels, Colin and Perrin, Mickael L. and Liang, Liangbo and Braun, Oliver and Darawish, Rimah and Burkhardt, Bryanna and Dumslaff, Tim and Wang, Xiao-Ye and Narita, Akimitsu and Müllen, Klaus and Meunier, Vincent and Fasel, Roman and Calame, Michel and Ruffieux, Pascal},
abstractNote = {The on-surface synthesis of graphene nanoribbons (GNRs) allows for the fabrication of atomically precise narrow GNRs. Despite their exceptional properties which can be tuned by ribbon width and edge structure, significant challenges remain for GNR processing and characterization. In this work, Raman spectroscopy is used to characterize different types of GNRs on their growth substrate and track their quality upon substrate transfer. A Raman-optimized (RO) device substrate and an optimized mapping approach are presented that allow for the acquisition of high-resolution Raman spectra, achieving enhancement factors as high as 120 with respect to signals measured on standard SiO2/Si substrates. This approach is well suited to routinely monitor the geometry-dependent low-frequency modes of GNRs. In particular, the radial breathing-like mode (RBLM) and the shear-like mode (SLM) for 5-, 7-, and 9-atom-wide armchair GNRs (AGNRs) are tracked and their frequencies are compared with first-principles calculations.},
doi = {10.1002/pssb.201900343},
journal = {Physica Status Solidi B. Basic Solid State Physics},
number = 12,
volume = 256,
place = {United States},
year = {Wed Oct 16 00:00:00 EDT 2019},
month = {Wed Oct 16 00:00:00 EDT 2019}
}
Web of Science
Figures / Tables:
Works referenced in this record:
Multiphonon Raman Spectrum of Silicon
journal, April 1973
- Temple, Paul A.; Hathaway, C. E.
- Physical Review B, Vol. 7, Issue 8
Surface-Synthesized Graphene Nanoribbons for Room Temperature Switching Devices: Substrate Transfer and ex Situ Characterization
text, January 2019
- Borin Barin, Gabriela; Fairbrother, Andrew; Rotach, Lukas
- ACS Publications
On-Surface Synthesis of Atomically Precise Graphene Nanoribbons
journal, February 2016
- Talirz, Leopold; Ruffieux, Pascal; Fasel, Roman
- Advanced Materials, Vol. 28, Issue 29
Influence of the Atomic Structure on the Raman Spectra of Graphite Edges
journal, December 2004
- Cançado, L. G.; Pimenta, M. A.; Neves, B. R. A.
- Physical Review Letters, Vol. 93, Issue 24
Making Graphene Nanoribbons Photoluminescent
journal, April 2017
- Senkovskiy, B. V.; Pfeiffer, M.; Alavi, S. K.
- Nano Letters, Vol. 17, Issue 7
Interference-enhanced Raman scattering of F 16 CuPc thin films
journal, February 2016
- Solonenko, D.; Gordan, O. D.; Milekhin, A.
- Journal of Physics D: Applied Physics, Vol. 49, Issue 11
Evolution of the Raman spectra from single-, few-, and many-layer graphene with increasing disorder
journal, September 2010
- Martins Ferreira, E. H.; Moutinho, Marcus V. O.; Stavale, F.
- Physical Review B, Vol. 82, Issue 12
Interference enhanced Raman scattering from very thin absorbing films
journal, January 1980
- Connell, G. A. N.; Nemanich, R. J.; Tsai, C. C.
- Applied Physics Letters, Vol. 36, Issue 1
Bottom-up graphene nanoribbon field-effect transistors
journal, December 2013
- Bennett, Patrick B.; Pedramrazi, Zahra; Madani, Ali
- Applied Physics Letters, Vol. 103, Issue 25
Ultra-narrow metallic armchair graphene nanoribbons
journal, December 2015
- Kimouche, Amina; Ervasti, Mikko M.; Drost, Robert
- Nature Communications, Vol. 6, Issue 1
Graphene nanoribbon heterojunctions
journal, September 2014
- Cai, Jinming; Pignedoli, Carlo A.; Talirz, Leopold
- Nature Nanotechnology, Vol. 9, Issue 11
Raman Spectrum of Graphite
journal, August 1970
- Tuinstra, F.; Koenig, J. L.
- The Journal of Chemical Physics, Vol. 53, Issue 3
Atomically precise bottom-up fabrication of graphene nanoribbons
text, January 2010
- Cai, J. M.; Ruffieux, P.; Jaafar, R.
- Nature Publishing Group
Short-channel field-effect transistors with 9-atom and 13-atom wide graphene nanoribbons
text, January 2017
- Llinas, Juan Pablo; Fairbrother, Andrew; Borin Barin, Gabriela
- Nature Publishing Group
On-Surface Growth Dynamics of Graphene Nanoribbons: The Role of Halogen Functionalization
journal, December 2017
- Di Giovannantonio, Marco; Deniz, Okan; Urgel, José I.
- ACS Nano, Vol. 12, Issue 1
Surface-Synthesized Graphene Nanoribbons for Room Temperature Switching Devices: Substrate Transfer and ex Situ Characterization
journal, March 2019
- Borin Barin, Gabriela; Fairbrother, Andrew; Rotach, Lukas
- ACS Applied Nano Materials, Vol. 2, Issue 4
High-resolution X-ray luminescence extension imaging
journal, February 2021
- Ou, Xiangyu; Qin, Xian; Huang, Bolong
- Nature, Vol. 590, Issue 7846
Structure-dependent electrical properties of graphene nanoribbon devices with graphene electrodes
text, January 2019
- Martini, Leonardo; Chen, Zongping; Mishra, Neeraj
- Elsevier
Ab initiomolecular dynamics for liquid metals
journal, January 1993
- Kresse, G.; Hafner, J.
- Physical Review B, Vol. 47, Issue 1, p. 558-561
On-Surface Synthesis and Characterization of 9-Atom Wide Armchair Graphene Nanoribbons
text, January 2017
- Sanchez-Valencia, Juan Ramon; Ruffieux, Pascal; Dumslaff, Tim
- American Chemical Society
High vacuum synthesis and ambient stability of bottom-up graphene nanoribbons
text, January 2017
- Hintermann, Tobias; Fasel, Roman; Sanchez-Valencia, Juan-Ramon
- Royal Society of Chemistry
On-Surface Synthesis and Characterization of 9-Atom Wide Armchair Graphene Nanoribbons
journal, February 2017
- Talirz, Leopold; Söde, Hajo; Dumslaff, Tim
- ACS Nano, Vol. 11, Issue 2
Oxidized nitinol substrate for interference enhanced Raman scattering of monolayer graphene
journal, January 2016
- Abidi, Irfan Haider; Cagang, Aldrine Abenoja; Tyagi, Abhishek
- RSC Advances, Vol. 6, Issue 9
First-principles Raman spectra of MoS2, WS2 and their heterostructures
journal, January 2014
- Liang, Liangbo; Meunier, Vincent
- Nanoscale, Vol. 6, Issue 10
Perspectives on Carbon Nanotubes and Graphene Raman Spectroscopy
journal, March 2010
- Dresselhaus, Mildred S.; Jorio, Ado; Hofmann, Mario
- Nano Letters, Vol. 10, Issue 3
Dual Path Mechanism in the Thermal Reduction of Graphene Oxide
journal, November 2011
- Larciprete, Rosanna; Fabris, Stefano; Sun, Tao
- Journal of the American Chemical Society, Vol. 133, Issue 43
Energy Gaps in Graphene Nanoribbons
journal, November 2006
- Son, Young-Woo; Cohen, Marvin L.; Louie, Steven G.
- Physical Review Letters, Vol. 97, Issue 21
Graphene oxide as a chemically tunable platform for optical applications
journal, November 2010
- Loh, Kian Ping; Bao, Qiaoliang; Eda, Goki
- Nature Chemistry, Vol. 2, Issue 12
The evolution of Raman spectrum of graphene with the thickness of SiO 2 capping layer on Si substrate
journal, November 2013
- Liu, Chu; Ma, Yaoguang; Li, Weisen
- Applied Physics Letters, Vol. 103, Issue 21
Making graphene visible
journal, August 2007
- Blake, P.; Hill, E. W.; Castro Neto, A. H.
- Applied Physics Letters, Vol. 91, Issue 6
Raman Fingerprints of Atomically Precise Graphene Nanoribbons
journal, May 2016
- Verzhbitskiy, Ivan A.; Corato, Marzio De; Ruini, Alice
- Nano Letters, Vol. 16, Issue 6
Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set
journal, July 1996
- Kresse, G.; Furthmüller, J.
- Computational Materials Science, Vol. 6, Issue 1, p. 15-50
On-Surface Synthesis of Atomically Precise Graphene Nanoribbons
text, January 2016
- Ruffieux, Pascal; Fasel, Roman; Talirz, Leopold
- Wiley-VCH
Seamless Staircase Electrical Contact to Semiconducting Graphene Nanoribbons
journal, September 2017
- Ma, Chuanxu; Liang, Liangbo; Xiao, Zhongcan
- Nano Letters, Vol. 17, Issue 10
Optical Interference Substrates for Nanoparticles and Two-Dimensional Materials
journal, January 2013
- Bacsa, Wolfgang S.; Pavlenko, Ekaterina; Tishkova, Victoria
- Nanomaterials and Nanotechnology, Vol. 3
Short-channel field-effect transistors with 9-atom and 13-atom wide graphene nanoribbons
journal, September 2017
- Llinas, Juan Pablo; Fairbrother, Andrew; Borin Barin, Gabriela
- Nature Communications, Vol. 8, Issue 1
High vacuum synthesis and ambient stability of bottom-up graphene nanoribbons
journal, January 2017
- Fairbrother, Andrew; Sanchez-Valencia, Juan-Ramon; Lauber, Beat
- Nanoscale, Vol. 9, Issue 8
Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set
journal, October 1996
- Kresse, G.; Furthmüller, J.
- Physical Review B, Vol. 54, Issue 16, p. 11169-11186
First principles phonon calculations in materials science
journal, November 2015
- Togo, Atsushi; Tanaka, Isao
- Scripta Materialia, Vol. 108
Vibrational properties of graphene nanoribbons by first-principles calculations
journal, October 2009
- Gillen, Roland; Mohr, Marcel; Thomsen, Christian
- Physical Review B, Vol. 80, Issue 15
Atomically precise bottom-up fabrication of graphene nanoribbons
journal, July 2010
- Cai, Jinming; Ruffieux, Pascal; Jaafar, Rached
- Nature, Vol. 466, Issue 7305
Linear optical properties in the projector-augmented wave methodology
journal, January 2006
- Gajdoš, M.; Hummer, K.; Kresse, G.
- Physical Review B, Vol. 73, Issue 4
Raman-active modes in graphene nanoribbons
journal, September 2010
- Gillen, Roland; Mohr, Marcel; Maultzsch, Janina
- physica status solidi (b), Vol. 247, Issue 11-12
Field-Effect Transistors Based on Networks of Highly Aligned, Chemically Synthesized N = 7 Armchair Graphene Nanoribbons
journal, March 2018
- Passi, Vikram; Gahoi, Amit; Senkovskiy, Boris V.
- ACS Applied Materials & Interfaces, Vol. 10, Issue 12
Electronic Structure of Atomically Precise Graphene Nanoribbons
journal, July 2012
- Ruffieux, Pascal; Cai, Jinming; Plumb, Nicholas C.
- ACS Nano, Vol. 6, Issue 8
Interference effect on Raman spectrum of graphene on
journal, September 2009
- Yoon, Duhee; Moon, Hyerim; Son, Young-Woo
- Physical Review B, Vol. 80, Issue 12
Engineering of robust topological quantum phases in graphene nanoribbons
journal, August 2018
- Gröning, Oliver; Wang, Shiyong; Yao, Xuelin
- Nature, Vol. 560, Issue 7717
Structure-dependent electrical properties of graphene nanoribbon devices with graphene electrodes
journal, May 2019
- Martini, Leonardo; Chen, Zongping; Mishra, Neeraj
- Carbon, Vol. 146
On-Surface Growth Dynamics of Graphene Nanoribbons: The Role of Halogen Functionalization
text, January 2018
- Di Giovannantonio, Marco; Deniz, Okan; Urgel, José I.
- American Chemical Society
pyGDM—A python toolkit for full-field electro-dynamical simulations and evolutionary optimization of nanostructures
dataset, January 2018
- Wiecha, Peter R.
- Mendeley
Vibrational properties of graphene nanoribbons by first-principles calculations
text, January 2009
- Gillen, Roland; Mohr, Marcel; Maultzsch, Janina
- arXiv
First principles phonon calculations in materials science
preprint, January 2015
- Togo, Atsushi; Tanaka, Isao
- arXiv
On-Surface Synthesis of Atomically Precise Graphene Nanoribbons
journal, February 2016
- Talirz, Leopold; Ruffieux, Pascal; Fasel, Roman
- Advanced Materials, Vol. 28, Issue 29
Raman Fingerprints of Atomically Precise Graphene Nanoribbons
journal, May 2016
- Verzhbitskiy, Ivan A.; Corato, Marzio De; Ruini, Alice
- Nano Letters, Vol. 16, Issue 6
Field-Effect Transistors Based on Networks of Highly Aligned, Chemically Synthesized N = 7 Armchair Graphene Nanoribbons
journal, March 2018
- Passi, Vikram; Gahoi, Amit; Senkovskiy, Boris V.
- ACS Applied Materials & Interfaces, Vol. 10, Issue 12
Ultra-narrow metallic armchair graphene nanoribbons
journal, December 2015
- Kimouche, Amina; Ervasti, Mikko M.; Drost, Robert
- Nature Communications, Vol. 6, Issue 1
Theoretical study of the vibrational edge modes in graphene nanoribbons
journal, November 2008
- Vandescuren, M.; Hermet, P.; Meunier, V.
- Physical Review B, Vol. 78, Issue 19
First principles phonon calculations in materials science
preprint, January 2015
- Togo, Atsushi; Tanaka, Isao
- arXiv
pyGDM -- A python toolkit for full-field electro-dynamical simulations and evolutionary optimization of nanostructures
text, January 2018
- Wiecha, Peter R.
- arXiv
Optical Interference Substrates for Nanoparticles and Two-Dimensional Materials
journal, January 2013
- Bacsa, Wolfgang S.; Pavlenko, Ekaterina; Tishkova, Victoria
- Nanomaterials and Nanotechnology, Vol. 3
Works referencing / citing this record:
Well-defined sub-nanometer graphene ribbons synthesized inside carbon nanotubes
journal, January 2021
- Kuzmany, Hans; Shi, Lei; Martinati, Miles
- Carbon, Vol. 171
Optimized Graphene Electrodes for contacting Graphene Nanoribbons
preprint, January 2021
- Braun, Oliver; Overbeck, Jan; Abbassi, Maria El
- arXiv
Figures / Tables found in this record: