Dense monolayer films of atomically precise graphene nanoribbons on metallic substrates enabled by direct contact transfer of molecular precursors
Abstract
Atomically precise graphene nanoribbons (GNRs) of two types, chevron GNRs and N = 7 straight armchair GNRs (7-AGNRs), have been synthesized through a direct contact transfer (DCT) of molecular precursors on Au(111) and gradual annealing. This method provides an alternative to the conventional approach for the deposition of molecules on surfaces by sublimation and simplifies preparation of dense monolayer films of GNRs. The DCT method allows deposition of molecules on a surface in their original state and then studying their gradual transformation to polymers to GNRs by scanning tunneling microscopy (STM) upon annealing. We performed STM characterization of the precursors of chevron GNRs and 7-AGNRs, and demonstrate that the assemblies of the intermediates of the GNR synthesis are stabilized by π–π interactions. This conclusion was supported by the density functional theory calculations. Thus, the resulting monolayer films of GNRs have sufficient coverage and density of nanoribbons for ex situ characterization by spectroscopic methods, such as Raman spectroscopy, and may prove useful for the future GNR device studies.
- Authors:
-
- Univ. of Nebraska, Lincoln, NE (United States). Dept. of Chemistry
- Univ. of Nebraska, Lincoln, NE (United States). Dept. of Physics and Astronomy
- Brookhaven National Lab. (BNL), Upton, NY (United States). Center for Functional Nanomaterials (CFN)
- Univ. of Nebraska, Lincoln, NE (United States). Dept. of Chemistry and Nebraska Center for Materials and Nanoscience
- Univ. of Nebraska, Lincoln, NE (United States). Dept. of Physics and Astronomy and Nebraska Center for Materials and Nanoscience
- Univ. of Nebraska, Lincoln, NE (United States). Dept. of Chemistry and Nebraska Center for Materials and Nanoscience; National Univ. of Science and Technology (MISiS), Moscow (Russia)
- Publication Date:
- Research Org.:
- Brookhaven National Lab. (BNL), Upton, NY (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES); US Department of the Navy, Office of Naval Research (ONR); National Science Foundation (NSF); Materials Research Science and Engineering Center (MRSEC); Nebraska Nanoscale Facility; National Univ. of Science and Technology (MISiS), Moscow (Russia)
- OSTI Identifier:
- 1426453
- Report Number(s):
- BNL-203341-2018-JAAM
Journal ID: ISSN 2040-3364; NANOHL
- Grant/Contract Number:
- SC0012704; N00014-16-1-2899; CHE-1455330; DMR-1420645; ECCS-1542182; K2-2016- 033
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Nanoscale
- Additional Journal Information:
- Journal Volume: 9; Journal Issue: 47; Journal ID: ISSN 2040-3364
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; 77 NANOSCIENCE AND NANOTECHNOLOGY; 75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; 46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND TECHNOLOGY
Citation Formats
Teeter, Jacob D., Costa, Paulo S., Zahl, Percy, Vo, Timothy H., Shekhirev, Mikhail, Xu, Wenwu, Zeng, Xiao Cheng, Enders, Axel, and Sinitskii, Alexander. Dense monolayer films of atomically precise graphene nanoribbons on metallic substrates enabled by direct contact transfer of molecular precursors. United States: N. p., 2017.
Web. doi:10.1039/C7NR06027K.
Teeter, Jacob D., Costa, Paulo S., Zahl, Percy, Vo, Timothy H., Shekhirev, Mikhail, Xu, Wenwu, Zeng, Xiao Cheng, Enders, Axel, & Sinitskii, Alexander. Dense monolayer films of atomically precise graphene nanoribbons on metallic substrates enabled by direct contact transfer of molecular precursors. United States. https://doi.org/10.1039/C7NR06027K
Teeter, Jacob D., Costa, Paulo S., Zahl, Percy, Vo, Timothy H., Shekhirev, Mikhail, Xu, Wenwu, Zeng, Xiao Cheng, Enders, Axel, and Sinitskii, Alexander. Thu .
"Dense monolayer films of atomically precise graphene nanoribbons on metallic substrates enabled by direct contact transfer of molecular precursors". United States. https://doi.org/10.1039/C7NR06027K. https://www.osti.gov/servlets/purl/1426453.
@article{osti_1426453,
title = {Dense monolayer films of atomically precise graphene nanoribbons on metallic substrates enabled by direct contact transfer of molecular precursors},
author = {Teeter, Jacob D. and Costa, Paulo S. and Zahl, Percy and Vo, Timothy H. and Shekhirev, Mikhail and Xu, Wenwu and Zeng, Xiao Cheng and Enders, Axel and Sinitskii, Alexander},
abstractNote = {Atomically precise graphene nanoribbons (GNRs) of two types, chevron GNRs and N = 7 straight armchair GNRs (7-AGNRs), have been synthesized through a direct contact transfer (DCT) of molecular precursors on Au(111) and gradual annealing. This method provides an alternative to the conventional approach for the deposition of molecules on surfaces by sublimation and simplifies preparation of dense monolayer films of GNRs. The DCT method allows deposition of molecules on a surface in their original state and then studying their gradual transformation to polymers to GNRs by scanning tunneling microscopy (STM) upon annealing. We performed STM characterization of the precursors of chevron GNRs and 7-AGNRs, and demonstrate that the assemblies of the intermediates of the GNR synthesis are stabilized by π–π interactions. This conclusion was supported by the density functional theory calculations. Thus, the resulting monolayer films of GNRs have sufficient coverage and density of nanoribbons for ex situ characterization by spectroscopic methods, such as Raman spectroscopy, and may prove useful for the future GNR device studies.},
doi = {10.1039/C7NR06027K},
journal = {Nanoscale},
number = 47,
volume = 9,
place = {United States},
year = {Thu Nov 16 00:00:00 EST 2017},
month = {Thu Nov 16 00:00:00 EST 2017}
}
Works referenced in this record:
Generalized Gradient Approximation Made Simple
journal, October 1996
- Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias
- Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868
New advances in nanographene chemistry
journal, January 2015
- Narita, Akimitsu; Wang, Xiao-Ye; Feng, Xinliang
- Chemical Society Reviews, Vol. 44, Issue 18
A Guide to the Design of Electronic Properties of Graphene Nanoribbons
journal, November 2012
- Yazyev, Oleg V.
- Accounts of Chemical Research, Vol. 46, Issue 10
Precursor Geometry Determines the Growth Mechanism in Graphene Nanoribbons
journal, January 2017
- Schulz, Fabian; Jacobse, Peter H.; Canova, Filippo Federici
- The Journal of Physical Chemistry C, Vol. 121, Issue 5
On-surface synthesis of graphene nanoribbons with zigzag edge topology
journal, March 2016
- Ruffieux, Pascal; Wang, Shiyong; Yang, Bo
- Nature, Vol. 531, Issue 7595
The Chemical Structure of a Molecule Resolved by Atomic Force Microscopy
journal, August 2009
- Gross, L.; Mohn, F.; Moll, N.
- Science, Vol. 325, Issue 5944
On-Surface Synthesis of Atomically Precise Graphene Nanoribbons
journal, February 2016
- Talirz, Leopold; Ruffieux, Pascal; Fasel, Roman
- Advanced Materials, Vol. 28, Issue 29
Synthesis of wide atomically precise graphene nanoribbons from para-oligophenylene based molecular precursor
journal, October 2014
- Abdurakhmanova, Nasiba; Amsharov, Nadja; Stepanow, Sebastian
- Carbon, Vol. 77
Controllable conversion of quasi-freestanding polymer chains to graphene nanoribbons
journal, March 2017
- Ma, Chuanxu; Xiao, Zhongcan; Zhang, Honghai
- Nature Communications, Vol. 8, Issue 1
Bottom-up graphene nanoribbon field-effect transistors
journal, December 2013
- Bennett, Patrick B.; Pedramrazi, Zahra; Madani, Ali
- Applied Physics Letters, Vol. 103, Issue 25
Ultra-narrow metallic armchair graphene nanoribbons
journal, December 2015
- Kimouche, Amina; Ervasti, Mikko M.; Drost, Robert
- Nature Communications, Vol. 6, Issue 1
Aligning the Band Gap of Graphene Nanoribbons by Monomer Doping
journal, March 2013
- Bronner, Christopher; Stremlau, Stephan; Gille, Marie
- Angewandte Chemie International Edition, Vol. 52, Issue 16
63. The symmetrical dianthryls. Part I
journal, January 1949
- Bell, F.; Waring, D. H.
- Journal of the Chemical Society (Resumed)
Epitaxial growth of aligned atomically precise chevron graphene nanoribbons on Cu(111)
journal, January 2017
- Teeter, Jacob D.; Costa, Paulo S.; Mehdi Pour, Mohammad
- Chemical Communications, Vol. 53, Issue 60
Large-scale solution synthesis of narrow graphene nanoribbons
journal, February 2014
- Vo, Timothy H.; Shekhirev, Mikhail; Kunkel, Donna A.
- Nature Communications, Vol. 5, Issue 1
Atomically precise bottom-up fabrication of graphene nanoribbons
journal, July 2010
- Cai, Jinming; Ruffieux, Pascal; Jaafar, Rached
- Nature, Vol. 466, Issue 7305
Graphene nanoribbon heterojunctions
journal, September 2014
- Cai, Jinming; Pignedoli, Carlo A.; Talirz, Leopold
- Nature Nanotechnology, Vol. 9, Issue 11
From molecules to solids with the DMol3 approach
journal, November 2000
- Delley, B.
- The Journal of Chemical Physics, Vol. 113, Issue 18
Quasiparticle Energies and Band Gaps in Graphene Nanoribbons
journal, November 2007
- Yang, Li; Park, Cheol-Hwan; Son, Young-Woo
- Physical Review Letters, Vol. 99, Issue 18
Ultrahigh-vacuum scanning tunneling microscopy and spectroscopy of single-walled carbon nanotubes on hydrogen-passivated Si(100) surfaces
journal, December 2003
- Albrecht, P. M.; Lyding, J. W.
- Applied Physics Letters, Vol. 83, Issue 24
An all‐electron numerical method for solving the local density functional for polyatomic molecules
journal, January 1990
- Delley, B.
- The Journal of Chemical Physics, Vol. 92, Issue 1
Atomically controlled substitutional boron-doping of graphene nanoribbons
journal, August 2015
- Kawai, Shigeki; Saito, Shohei; Osumi, Shinichiro
- Nature Communications, Vol. 6, Issue 1
Interfacial Self-Assembly of Atomically Precise Graphene Nanoribbons into Uniform Thin Films for Electronics Applications
journal, December 2016
- Shekhirev, Mikhail; Vo, Timothy H.; Mehdi Pour, Mohammad
- ACS Applied Materials & Interfaces, Vol. 9, Issue 1
Accurate Molecular Van Der Waals Interactions from Ground-State Electron Density and Free-Atom Reference Data
journal, February 2009
- Tkatchenko, Alexandre; Scheffler, Matthias
- Physical Review Letters, Vol. 102, Issue 7
Self-Assembly Strategy for Fabricating Connected Graphene Nanoribbons
journal, October 2015
- Han, Patrick; Akagi, Kazuto; Federici Canova, Filippo
- ACS Nano, Vol. 9, Issue 12
The influence of edge structure on the electronic properties of graphene quantum dots and nanoribbons
journal, February 2009
- Ritter, Kyle A.; Lyding, Joseph W.
- Nature Materials, Vol. 8, Issue 3
Spatially Resolved Electronic Structures of Atomically Precise Armchair Graphene Nanoribbons
journal, December 2012
- Huang, Han; Wei, Dacheng; Sun, Jiatao
- Scientific Reports, Vol. 2, Issue 1
Molecular bandgap engineering of bottom-up synthesized graphene nanoribbon heterojunctions
journal, January 2015
- Chen, Yen-Chia; Cao, Ting; Chen, Chen
- Nature Nanotechnology, Vol. 10, Issue 2
Novel Oligo(9,10-anthrylene)s: Models for Electron Transfer and High-Spin Formation
journal, May 1995
- Mueller, Uwe; Baumgarten, Martin
- Journal of the American Chemical Society, Vol. 117, Issue 21
Synthesis of Graphene Nanoribbons by Ambient-Pressure Chemical Vapor Deposition and Device Integration
journal, November 2016
- Chen, Zongping; Zhang, Wen; Palma, Carlos-Andres
- Journal of the American Chemical Society, Vol. 138, Issue 47
Solution-Synthesized Chevron Graphene Nanoribbons Exfoliated onto H:Si(100)
journal, December 2016
- Radocea, Adrian; Sun, Tao; Vo, Timothy H.
- Nano Letters, Vol. 17, Issue 1
Scanning tunneling microscopy studies of pulse deposition of dinuclear organometallic molecules on Au(111)
journal, January 2008
- Guo, Song; Alex Kandel, S.
- The Journal of Chemical Physics, Vol. 128, Issue 1
Revealing the Electronic Structure of Silicon Intercalated Armchair Graphene Nanoribbons by Scanning Tunneling Spectroscopy
journal, March 2017
- Deniz, Okan; Sánchez-Sánchez, Carlos; Dumslaff, Tim
- Nano Letters, Vol. 17, Issue 4
Purely Armchair or Partially Chiral: Noncontact Atomic Force Microscopy Characterization of Dibromo-Bianthryl-Based Graphene Nanoribbons Grown on Cu(111)
journal, July 2016
- Sánchez-Sánchez, Carlos; Dienel, Thomas; Deniz, Okan
- ACS Nano, Vol. 10, Issue 8
Laterally extended atomically precise graphene nanoribbons with improved electrical conductivity for efficient gas sensing
journal, October 2017
- Mehdi Pour, Mohammad; Lashkov, Andrey; Radocea, Adrian
- Nature Communications, Vol. 8, Issue 1
On-Surface Synthesis and Characterization of 9-Atom Wide Armchair Graphene Nanoribbons
journal, February 2017
- Talirz, Leopold; Söde, Hajo; Dumslaff, Tim
- ACS Nano, Vol. 11, Issue 2
Half-metallic graphene nanoribbons
journal, November 2006
- Son, Young-Woo; Cohen, Marvin L.; Louie, Steven G.
- Nature, Vol. 444, Issue 7117
From Graphene Nanoribbons on Cu(111) to Nanographene on Cu(110): Critical Role of Substrate Structure in the Bottom-Up Fabrication Strategy
journal, August 2015
- Simonov, Konstantin A.; Vinogradov, Nikolay A.; Vinogradov, Alexander S.
- ACS Nano, Vol. 9, Issue 9
Site-Specific Substitutional Boron Doping of Semiconducting Armchair Graphene Nanoribbons
journal, July 2015
- Cloke, Ryan R.; Marangoni, Tomas; Nguyen, Giang D.
- Journal of the American Chemical Society, Vol. 137, Issue 28
Submolecular Imaging by Noncontact Atomic Force Microscopy with an Oxygen Atom Rigidly Connected to a Metallic Probe
journal, December 2015
- Mönig, Harry; Hermoso, Diego R.; Díaz Arado, Oscar
- ACS Nano, Vol. 10, Issue 1
Suppression of electron–vibron coupling in graphene nanoribbons contacted via a single atom
journal, June 2013
- van der Lit, Joost; Boneschanscher, Mark P.; Vanmaekelbergh, Daniël
- Nature Communications, Vol. 4, Issue 1
Heterostructures through Divergent Edge Reconstruction in Nitrogen-Doped Segmented Graphene Nanoribbons
journal, August 2016
- Marangoni, Tomas; Haberer, Danny; Rizzo, Daniel J.
- Chemistry - A European Journal, Vol. 22, Issue 37
Nitrogen-Doping Induced Self-Assembly of Graphene Nanoribbon-Based Two-Dimensional and Three-Dimensional Metamaterials
journal, August 2015
- Vo, Timothy H.; Perera, U. Gayani E.; Shekhirev, Mikhail
- Nano Letters, Vol. 15, Issue 9
Recent advances in submolecular resolution with scanning probe microscopy
journal, March 2011
- Gross, Leo
- Nature Chemistry, Vol. 3, Issue 4