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Title: Directed Self-Assembly of MOF-Derived Nanoparticles toward Hierarchical Structures for Enhanced Catalytic Activity in CO Oxidation

Abstract

The controllable self-assembly of nanomaterials remains a great challenge in nanotechnological applications, especially for the hierarchical structure with high complexity. Herein, by taking the advantage of highly dispersed metal nodes and mild thermal stability of metal-organic frameworks (MOFs), the self-assembly of nanoparticles is directed from MOFs to construct CuO hierarchical structures, which have an inherited octahedral framework consisting of the microspheres, nanowires, and polyhedrons, respectively. Unlike the conventional self-assembly in a solution media (such as solvent and molten solid), the assembly in this work is the first demonstration through a solution-free approach. Finally, compared to the general MOF-derived CuO octahedron, the assembled hierarchical CuO structure exhibits much enhanced catalytic activity in CO oxidation thanks to the exposure of more active sites during the assembly.

Authors:
 [1];  [2];  [2];  [3];  [4];  [2];  [2];  [4];  [2];  [3];  [2]; ORCiD logo [3]
+ Show Author Affiliations
  1. Nanjing Tech Univ. (China); Argonne National Lab. (ANL), Argonne, IL (United States)
  2. Nanjing Tech Univ. (China)
  3. Argonne National Lab. (ANL), Argonne, IL (United States)
  4. Nanjing Forest Univ. (China)
Publication Date:
Research Org.:
Argonne National Laboratory (ANL), Argonne, IL (United States)
Sponsoring Org.:
USDOE Office of Energy Efficiency and Renewable Energy (EERE); National Key Research and Development Program of China; National Natural Science Foundation of China (NSFC); National Science Funds for Distinguished Young Scholars; Natural Science Foundation (NSF); China Scholarship Council; China National Postdoctoral Council
OSTI Identifier:
1605901
Alternate Identifier(s):
OSTI ID: 1574036
Grant/Contract Number:  
AC02-06CH11357; 2017YFA0207201; 21574065; 21604038; 21908105; BK20160975; BK20160993; 2016M591837; 201608320067; 20170020; AC02‐06CH11357
Resource Type:
Accepted Manuscript
Journal Name:
Advanced Energy Materials
Additional Journal Information:
Journal Volume: 9; Journal Issue: 48; Journal ID: ISSN 1614-6832
Publisher:
Wiley
Country of Publication:
United States
Language:
English
Subject:
42 ENGINEERING; catalyst; hierarchical structure; metal-organic framework; self-assembly; solution-free

Citation Formats

Zhang, Suoying, Li, Hang, Liu, Pengfei, Ma, Lu, Li, Licheng, Zhang, Weina, Meng, Fanchen, Li, Long, Yang, Zhuhong, Wu, Tianpin, Huo, Fengwei, and Lu, Jun. Directed Self-Assembly of MOF-Derived Nanoparticles toward Hierarchical Structures for Enhanced Catalytic Activity in CO Oxidation. United States: N. p., 2019. Web. doi:10.1002/aenm.201901754.
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Zhang, Suoying, Li, Hang, Liu, Pengfei, Ma, Lu, Li, Licheng, Zhang, Weina, Meng, Fanchen, Li, Long, Yang, Zhuhong, Wu, Tianpin, Huo, Fengwei, & Lu, Jun. Directed Self-Assembly of MOF-Derived Nanoparticles toward Hierarchical Structures for Enhanced Catalytic Activity in CO Oxidation. United States. https://doi.org/10.1002/aenm.201901754
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Zhang, Suoying, Li, Hang, Liu, Pengfei, Ma, Lu, Li, Licheng, Zhang, Weina, Meng, Fanchen, Li, Long, Yang, Zhuhong, Wu, Tianpin, Huo, Fengwei, and Lu, Jun. Tue . "Directed Self-Assembly of MOF-Derived Nanoparticles toward Hierarchical Structures for Enhanced Catalytic Activity in CO Oxidation". United States. https://doi.org/10.1002/aenm.201901754. https://www.osti.gov/servlets/purl/1605901.
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@article{osti_1605901,
title = {Directed Self-Assembly of MOF-Derived Nanoparticles toward Hierarchical Structures for Enhanced Catalytic Activity in CO Oxidation},
author = {Zhang, Suoying and Li, Hang and Liu, Pengfei and Ma, Lu and Li, Licheng and Zhang, Weina and Meng, Fanchen and Li, Long and Yang, Zhuhong and Wu, Tianpin and Huo, Fengwei and Lu, Jun},
abstractNote = {The controllable self-assembly of nanomaterials remains a great challenge in nanotechnological applications, especially for the hierarchical structure with high complexity. Herein, by taking the advantage of highly dispersed metal nodes and mild thermal stability of metal-organic frameworks (MOFs), the self-assembly of nanoparticles is directed from MOFs to construct CuO hierarchical structures, which have an inherited octahedral framework consisting of the microspheres, nanowires, and polyhedrons, respectively. Unlike the conventional self-assembly in a solution media (such as solvent and molten solid), the assembly in this work is the first demonstration through a solution-free approach. Finally, compared to the general MOF-derived CuO octahedron, the assembled hierarchical CuO structure exhibits much enhanced catalytic activity in CO oxidation thanks to the exposure of more active sites during the assembly.},
doi = {10.1002/aenm.201901754},
journal = {Advanced Energy Materials},
number = 48,
volume = 9,
place = {United States},
year = {Tue Nov 12 00:00:00 EST 2019},
month = {Tue Nov 12 00:00:00 EST 2019}
}
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Journal Article:
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https://doi.org/10.1002/aenm.201901754
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Works referenced in this record:

Novel MOF-Derived Co@N-C Bifunctional Catalysts for Highly Efficient Zn-Air Batteries and Water Splitting
journal, January 2018

  • Zhang, Mingdao; Dai, Quanbin; Zheng, Hegen
  • Advanced Materials, Vol. 30, Issue 10
  • DOI: 10.1002/adma.201705431

A Chemically Functionalizable Nanoporous Material [Cu3(TMA)2(H2O)3]n
journal, February 1999

MOF-derived Nanoporous Carbon as Intracellular Drug Delivery Carriers
journal, May 2014

  • Torad, Nagy L.; Li, Yunqi; Ishihara, Shinsuke
  • Chemistry Letters, Vol. 43, Issue 5
  • DOI: 10.1246/cl.131174

MOF-templated formation of porous CuO hollow octahedra for lithium-ion battery anode materials
journal, January 2013

  • Wu, Renbing; Qian, Xukun; Yu, Feng
  • Journal of Materials Chemistry A, Vol. 1, Issue 37
  • DOI: 10.1039/c3ta12621h

The effect of water adsorption on the structure of the carboxylate containing metal–organic frameworks Cu-BTC, Mg-MOF-74, and UiO-66
journal, January 2013

  • DeCoste, Jared B.; Peterson, Gregory W.; Schindler, Bryan J.
  • Journal of Materials Chemistry A, Vol. 1, Issue 38
  • DOI: 10.1039/c3ta12497e

CuO/Cu 2 O porous composites: shape and composition controllable fabrication inherited from metal organic frameworks and further application in CO oxidation
journal, January 2015

  • Zhang, Suoying; Liu, Hong; Sun, Chencheng
  • Journal of Materials Chemistry A, Vol. 3, Issue 10
  • DOI: 10.1039/C5TA00249D

Regioselective surface encoding of nanoparticles for programmable self-assembly
journal, December 2018

Self-assembly of self-limiting monodisperse supraparticles from polydisperse nanoparticles
journal, August 2011

  • Xia, Yunsheng; Nguyen, Trung Dac; Yang, Ming
  • Nature Nanotechnology, Vol. 6, Issue 9
  • DOI: 10.1038/nnano.2011.121

Correction to Postsynthetic Tuning of Metal–Organic Frameworks for Targeted Applications
journal, January 2018

Formation of Colloidal CuO Nanocrystallites and Their Spherical Aggregation and Reductive Transformation to Hollow Cu 2 O Nanospheres
journal, February 2005

  • Chang, Yu; Teo, Joong Jiat; Zeng, Hua Chun
  • Langmuir, Vol. 21, Issue 3
  • DOI: 10.1021/la047671l

Directed Self-Assembly of Nanoparticles
journal, June 2010

  • Grzelczak, Marek; Vermant, Jan; Furst, Eric M.
  • ACS Nano, Vol. 4, Issue 7
  • DOI: 10.1021/nn100869j

Structural properties and catalytic activity of a novel ternary CuO/gC3N4/Bi2O3 photocatalyst
journal, August 2018

Zeolitic imidazolate framework (ZIF-8) derived nanoporous carbon: the effect of carbonization temperature on the supercapacitor performance in an aqueous electrolyte
journal, January 2016

  • Young, Christine; Salunkhe, Rahul R.; Tang, Jing
  • Physical Chemistry Chemical Physics, Vol. 18, Issue 42
  • DOI: 10.1039/C6CP05555A

Rational Design of Metal-Organic Framework Derived Hollow NiCo 2 O 4 Arrays for Flexible Supercapacitor and Electrocatalysis
journal, January 2017

Self-organized architectures from assorted DNA-framed nanoparticles
journal, June 2016

  • Liu, Wenyan; Halverson, Jonathan; Tian, Ye
  • Nature Chemistry, Vol. 8, Issue 9
  • DOI: 10.1038/nchem.2540

Programmable materials and the nature of the DNA bond
journal, February 2015

Effects of Functionalization, Catenation, and Variation of the Metal Oxide and Organic Linking Units on the Low-Pressure Hydrogen Adsorption Properties of Metal−Organic Frameworks
journal, February 2006

  • Rowsell, Jesse L. C.; Yaghi, Omar M.
  • Journal of the American Chemical Society, Vol. 128, Issue 4, p. 1304-1315
  • DOI: 10.1021/ja056639q

Role of self-assembly in construction of inorganic nanostructural materials
journal, August 2012

How Far Can We Push Chemical Self-Assembly?
journal, July 2005

Virtual High Throughput Screening Confirmed Experimentally: Porous Coordination Polymer Hydration
journal, November 2009

  • Low, John J.; Benin, Annabelle I.; Jakubczak, Paulina
  • Journal of the American Chemical Society, Vol. 131, Issue 43
  • DOI: 10.1021/ja9061344

Metal–Organic-Frameworks-Derived General Formation of Hollow Structures with High Complexity
journal, July 2013

  • Zhang, Lei; Wu, Hao Bin; Lou, Xiong Wen (David)
  • Journal of the American Chemical Society, Vol. 135, Issue 29
  • DOI: 10.1021/ja401727n

Metal Organic Framework Derived Materials: Progress and Prospects for the Energy Conversion and Storage
journal, July 2018

  • Indra, Arindam; Song, Taeseup; Paik, Ungyu
  • Advanced Materials, Vol. 30, Issue 39
  • DOI: 10.1002/adma.201705146

Synthesis, structural properties, and catalytic behavior of Cu-BTC and mixed-linker Cu-BTC-PyDC in the oxidation of benzene derivatives
journal, July 2011

Advances in the development of power supplies for the Internet of Everything
journal, June 2019

Formation of Fe 2 O 3 Microboxes with Hierarchical Shell Structures from Metal–Organic Frameworks and Their Lithium Storage Properties
journal, October 2012

  • Zhang, Lei; Wu, Hao Bin; Madhavi, Srinivasan
  • Journal of the American Chemical Society, Vol. 134, Issue 42
  • DOI: 10.1021/ja307475c

Nonisotropic Self-Assembly of Nanoparticles: From Compact Packing to Functional Aggregates
journal, May 2018

  • Bouju, Xavier; Duguet, Étienne; Gauffre, Fabienne
  • Advanced Materials, Vol. 30, Issue 27
  • DOI: 10.1002/adma.201706558

Metal–organic frameworks as selectivity regulators for hydrogenation reactions
journal, October 2016

Quasi-MOF: Exposing Inorganic Nodes to Guest Metal Nanoparticles for Drastically Enhanced Catalytic Activity
journal, April 2018

From Metal-Organic Frameworks to Single-Atom Fe Implanted N-doped Porous Carbons: Efficient Oxygen Reduction in Both Alkaline and Acidic Media
journal, June 2018

  • Jiao, Long; Wan, Gang; Zhang, Rui
  • Angewandte Chemie International Edition, Vol. 57, Issue 28
  • DOI: 10.1002/anie.201803262

Water-Mediated Mars–Van Krevelen Mechanism for CO Oxidation on Ceria-Supported Single-Atom Pt 1 Catalyst
journal, December 2016

Demanding energy from carbon
journal, September 2019

Cu 2 O–CuO Hollow Nanospheres as a Heterogeneous Catalyst for Synergetic Oxidation of CO
journal, July 2018

  • Wei, Bo; Yang, Nating; Pang, Fei
  • The Journal of Physical Chemistry C, Vol. 122, Issue 34
  • DOI: 10.1021/acs.jpcc.8b04690

Single Cobalt Atoms with Precise N-Coordination as Superior Oxygen Reduction Reaction Catalysts
journal, August 2016

  • Yin, Peiqun; Yao, Tao; Wu, Yuen
  • Angewandte Chemie International Edition, Vol. 55, Issue 36
  • DOI: 10.1002/anie.201604802

Activation of surface lattice oxygen in single-atom Pt/CeO 2 for low-temperature CO oxidation
journal, December 2017

Light-enabled reversible self-assembly and tunable optical properties of stable hairy nanoparticles
journal, January 2018

  • Chen, Yihuang; Wang, Zewei; He, Yanjie
  • Proceedings of the National Academy of Sciences, Vol. 115, Issue 7
  • DOI: 10.1073/pnas.1714748115

Spontaneous Weaving of Graphitic Carbon Networks Synthesized by Pyrolysis of ZIF-67 Crystals
journal, April 2017

  • Zhang, Wei; Jiang, Xiangfen; Wang, Xuebin
  • Angewandte Chemie International Edition, Vol. 56, Issue 29
  • DOI: 10.1002/anie.201701252

Facile synthesis of submicron Cu2O and CuO crystallites from a solid metallorganic molecular precursor
journal, September 2006

Self-assembly of self-limiting monodisperse supraparticles from polydisperse nanoparticles
journal, July 2012

  • Xia, Yunsheng; Nguyen, Trung Dac; Yang, Ming
  • Nature Nanotechnology, Vol. 7, Issue 7
  • DOI: 10.1038/nnano.2012.106

Single Cobalt Atoms with Precise N-Coordination as Superior Oxygen Reduction Reaction Catalysts
journal, August 2016

Spontaneous Weaving of Graphitic Carbon Networks Synthesized by Pyrolysis of ZIF-67 Crystals
journal, April 2017

Role of self-assembly in construction of inorganic nanostructural materials
journal, November 2012

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