skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Three novel indium MOFs derived from dicarboxylate ligands: Syntheses, structures and photoluminescent properties

Abstract

The self-assembly of InCl{sub 3} with 1,4-phenylenediacetic acid (1,4-H{sub 2}pda), 1,3-benzendicarboxylic acid (1,3-H{sub 2}bdc) and 1,4-cyclohexanedicarboxylic acid (1,4- H{sub 2}chdc) generates three new In(III) MOFs, (Me{sub 2}NH{sub 2})[In(cis-1,4-pda){sub 2}] (1), HIn(1,3-bdc){sub 2}{center_dot}2DMF (2) and In(OH)(trans-1,4-chdc) (3) (Me{sub 2}NH=dimethylamine, DMF=N, N'-dimethylformamide). Compound 1 displays a novel 1D no-planar double chain. Although a mixture of cis- and trans-1,4-H{sub 2}pda was used, the product of compound 1 is a single phase with only cis-pda{sup 2-} ligands. Compound 2 possesses a 2D square lattice with sql topology. Interestingly, in compound 2, the 4-connected building unit containing InO{sub 6} octahedron is firstly occurred in In-MOFs. Compound 3 is built up from the infinite metal-oxide chains cross-linked by trans-1,4-chdc{sup 2-} to form 3D framework with rhombus-shaped channels. Furthermore, compounds 1-3 present intense solid-state fluorescent emissions at room temperature. - Graphical abstract: Three new In-MOFs based on different dicaboxylate acids display 1D chain, 2D layer and 3D open-framework, respectively and show strong luminescence emissions at room temperature. Highlights: Black-Right-Pointing-Pointer Three new indium metal-organic frameworks have been solvothermal synthesized. Black-Right-Pointing-Pointer The structural variation is attributed to the diverse coordination modes of ligands. Black-Right-Pointing-Pointer Compounds 1-3 exhibit 1D double chain, 2D layer and 3D open-framework, respectively. Black-Right-Pointing-Pointer These compoundsmore » exhibit strong solid-state luminescence emission at room temperature.« less

Authors:
; ; ; ;  [1];  [1];  [2]
  1. College of Chemistry, Jilin University, Changchun 130012 (China)
  2. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012 (China)
Publication Date:
OSTI Identifier:
22012149
Resource Type:
Journal Article
Journal Name:
Journal of Solid State Chemistry
Additional Journal Information:
Journal Volume: . 190; Other Information: Copyright (c) 2012 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA); Journal ID: ISSN 0022-4596
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; 36 MATERIALS SCIENCE; FLUORESCENCE; INDIUM; LAYERS; LIGANDS; OXIDES; PHOTOLUMINESCENCE; SOLIDS; SYNTHESIS; TETRAGONAL LATTICES; TOPOLOGY

Citation Formats

Wang Liping, Song Tianyou, Li Chao, Xia Jing, Wang Shengyan, Wang Li, E-mail: lwang99@jlu.edu.cn, and Xu Jianing. Three novel indium MOFs derived from dicarboxylate ligands: Syntheses, structures and photoluminescent properties. United States: N. p., 2012. Web. doi:10.1016/J.JSSC.2012.02.049.
Wang Liping, Song Tianyou, Li Chao, Xia Jing, Wang Shengyan, Wang Li, E-mail: lwang99@jlu.edu.cn, & Xu Jianing. Three novel indium MOFs derived from dicarboxylate ligands: Syntheses, structures and photoluminescent properties. United States. doi:10.1016/J.JSSC.2012.02.049.
Wang Liping, Song Tianyou, Li Chao, Xia Jing, Wang Shengyan, Wang Li, E-mail: lwang99@jlu.edu.cn, and Xu Jianing. Fri . "Three novel indium MOFs derived from dicarboxylate ligands: Syntheses, structures and photoluminescent properties". United States. doi:10.1016/J.JSSC.2012.02.049.
@article{osti_22012149,
title = {Three novel indium MOFs derived from dicarboxylate ligands: Syntheses, structures and photoluminescent properties},
author = {Wang Liping and Song Tianyou and Li Chao and Xia Jing and Wang Shengyan and Wang Li, E-mail: lwang99@jlu.edu.cn and Xu Jianing},
abstractNote = {The self-assembly of InCl{sub 3} with 1,4-phenylenediacetic acid (1,4-H{sub 2}pda), 1,3-benzendicarboxylic acid (1,3-H{sub 2}bdc) and 1,4-cyclohexanedicarboxylic acid (1,4- H{sub 2}chdc) generates three new In(III) MOFs, (Me{sub 2}NH{sub 2})[In(cis-1,4-pda){sub 2}] (1), HIn(1,3-bdc){sub 2}{center_dot}2DMF (2) and In(OH)(trans-1,4-chdc) (3) (Me{sub 2}NH=dimethylamine, DMF=N, N'-dimethylformamide). Compound 1 displays a novel 1D no-planar double chain. Although a mixture of cis- and trans-1,4-H{sub 2}pda was used, the product of compound 1 is a single phase with only cis-pda{sup 2-} ligands. Compound 2 possesses a 2D square lattice with sql topology. Interestingly, in compound 2, the 4-connected building unit containing InO{sub 6} octahedron is firstly occurred in In-MOFs. Compound 3 is built up from the infinite metal-oxide chains cross-linked by trans-1,4-chdc{sup 2-} to form 3D framework with rhombus-shaped channels. Furthermore, compounds 1-3 present intense solid-state fluorescent emissions at room temperature. - Graphical abstract: Three new In-MOFs based on different dicaboxylate acids display 1D chain, 2D layer and 3D open-framework, respectively and show strong luminescence emissions at room temperature. Highlights: Black-Right-Pointing-Pointer Three new indium metal-organic frameworks have been solvothermal synthesized. Black-Right-Pointing-Pointer The structural variation is attributed to the diverse coordination modes of ligands. Black-Right-Pointing-Pointer Compounds 1-3 exhibit 1D double chain, 2D layer and 3D open-framework, respectively. Black-Right-Pointing-Pointer These compounds exhibit strong solid-state luminescence emission at room temperature.},
doi = {10.1016/J.JSSC.2012.02.049},
journal = {Journal of Solid State Chemistry},
issn = {0022-4596},
number = ,
volume = . 190,
place = {United States},
year = {2012},
month = {6}
}