Crystal-growth-dominated fabrication of metal-organic frameworks with orderly distributed hierarchical porosity
Abstract
Constructing architectures with hierarchical porosity has been widely considered as the most efficient way to bypass the problems related to slow mass transfer and inaccessibility of internal space in MOFs. Now, a crystal-growth-dominated strategy is proposed to fabricate hierarchically porous MOFs (HP-MOFs). When the crystal growth is dominated by the monomer attachment, the aggregation of nonionic surfactant or polymer can be easily captured and released during the crystal growth process, resulting in the formation and ordering hierarchical pores along the radial direction. Furthermore, owing to the accelerated mass diffusion and more exposed active sites of this design, HP-MOFs exhibited an enhanced catalytic efficiency in styrene oxidation.
- Authors:
-
- Nanjing Univ. of Technology (China). State Key Lab. of Materials-Oriented Chemical Engineering (MCE)
- Nanjing Univ. of Technology (China). Key Lab. of Flexible Electronics (KLOFE) & Inst. of Advanced Materials (IAM)
- Argonne National Lab. (ANL), Lemont, IL (United States)
- Publication Date:
- Research Org.:
- Argonne National Lab. (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE), Office of Vehicle Technologies (VTO); National Key Research and Development Program of China; National Natural Science Foundation of China (NSFC); China Postdoctoral Science Foundation; China Scholarship Council
- OSTI Identifier:
- 1657510
- Grant/Contract Number:
- AC02-06CH11357; 2017YFA0207201; 21574065; 21604038; 201608320067
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Angewandte Chemie
- Additional Journal Information:
- Journal Volume: 59; Journal Issue: 6; Journal ID: ISSN 0044-8249
- Publisher:
- German Chemical Society
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; crystal growth; hierarchical porosity; metal-organic frameworks; nanostructures; styrene
Citation Formats
Li, Hang, Meng, Fanchen, Zhang, Suoying, Wang, Liguang, Li, Matthew, Ma, Lu, Zhang, Weina, Zhang, Wenlei, Yang, Zhuhong, Wu, Tianpin, Lee, Sungsik, Huo, Fengwei, and Lu, Jun. Crystal-growth-dominated fabrication of metal-organic frameworks with orderly distributed hierarchical porosity. United States: N. p., 2020.
Web. doi:10.1002/anie.201912972.
Li, Hang, Meng, Fanchen, Zhang, Suoying, Wang, Liguang, Li, Matthew, Ma, Lu, Zhang, Weina, Zhang, Wenlei, Yang, Zhuhong, Wu, Tianpin, Lee, Sungsik, Huo, Fengwei, & Lu, Jun. Crystal-growth-dominated fabrication of metal-organic frameworks with orderly distributed hierarchical porosity. United States. https://doi.org/10.1002/anie.201912972
Li, Hang, Meng, Fanchen, Zhang, Suoying, Wang, Liguang, Li, Matthew, Ma, Lu, Zhang, Weina, Zhang, Wenlei, Yang, Zhuhong, Wu, Tianpin, Lee, Sungsik, Huo, Fengwei, and Lu, Jun. Mon .
"Crystal-growth-dominated fabrication of metal-organic frameworks with orderly distributed hierarchical porosity". United States. https://doi.org/10.1002/anie.201912972. https://www.osti.gov/servlets/purl/1657510.
@article{osti_1657510,
title = {Crystal-growth-dominated fabrication of metal-organic frameworks with orderly distributed hierarchical porosity},
author = {Li, Hang and Meng, Fanchen and Zhang, Suoying and Wang, Liguang and Li, Matthew and Ma, Lu and Zhang, Weina and Zhang, Wenlei and Yang, Zhuhong and Wu, Tianpin and Lee, Sungsik and Huo, Fengwei and Lu, Jun},
abstractNote = {Constructing architectures with hierarchical porosity has been widely considered as the most efficient way to bypass the problems related to slow mass transfer and inaccessibility of internal space in MOFs. Now, a crystal-growth-dominated strategy is proposed to fabricate hierarchically porous MOFs (HP-MOFs). When the crystal growth is dominated by the monomer attachment, the aggregation of nonionic surfactant or polymer can be easily captured and released during the crystal growth process, resulting in the formation and ordering hierarchical pores along the radial direction. Furthermore, owing to the accelerated mass diffusion and more exposed active sites of this design, HP-MOFs exhibited an enhanced catalytic efficiency in styrene oxidation.},
doi = {10.1002/anie.201912972},
journal = {Angewandte Chemie},
number = 6,
volume = 59,
place = {United States},
year = {Mon Feb 03 00:00:00 EST 2020},
month = {Mon Feb 03 00:00:00 EST 2020}
}
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