On understanding bandgap bowing and optoelectronic quality in Pb–Sn alloy hybrid perovskites
Abstract
Experimental insights regarding bandgap evolution in hybrid perovskite alloys and the optimal small-bandgap absorber composition desired for next-generation perovskite tandems.
- Authors:
-
[1];
- Department of Materials Science and Engineering, University of Washington, Seattle, USA
- Department of Chemical Engineering, Molecular Engineering and Sciences Institute, University of Washington, Seattle, USA
- Department of Materials Science and Engineering, University of Washington, Seattle, USA, Department of Materials Science & Engineering
- Publication Date:
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1529021
- Grant/Contract Number:
- EE0006710; EE0008563
- Resource Type:
- Publisher's Accepted Manuscript
- Journal Name:
- Journal of Materials Chemistry. A
- Additional Journal Information:
- Journal Name: Journal of Materials Chemistry. A Journal Volume: 7 Journal Issue: 27; Journal ID: ISSN 2050-7488
- Publisher:
- Royal Society of Chemistry (RSC)
- Country of Publication:
- United Kingdom
- Language:
- English
Citation Formats
Rajagopal, Adharsh, Stoddard, Ryan J., Hillhouse, Hugh W., and Jen, Alex K. -Y.. On understanding bandgap bowing and optoelectronic quality in Pb–Sn alloy hybrid perovskites. United Kingdom: N. p., 2019.
Web. doi:10.1039/C9TA05308E.
Rajagopal, Adharsh, Stoddard, Ryan J., Hillhouse, Hugh W., & Jen, Alex K. -Y.. On understanding bandgap bowing and optoelectronic quality in Pb–Sn alloy hybrid perovskites. United Kingdom. https://doi.org/10.1039/C9TA05308E
Rajagopal, Adharsh, Stoddard, Ryan J., Hillhouse, Hugh W., and Jen, Alex K. -Y.. Tue .
"On understanding bandgap bowing and optoelectronic quality in Pb–Sn alloy hybrid perovskites". United Kingdom. https://doi.org/10.1039/C9TA05308E.
@article{osti_1529021,
title = {On understanding bandgap bowing and optoelectronic quality in Pb–Sn alloy hybrid perovskites},
author = {Rajagopal, Adharsh and Stoddard, Ryan J. and Hillhouse, Hugh W. and Jen, Alex K. -Y.},
abstractNote = {Experimental insights regarding bandgap evolution in hybrid perovskite alloys and the optimal small-bandgap absorber composition desired for next-generation perovskite tandems.},
doi = {10.1039/C9TA05308E},
journal = {Journal of Materials Chemistry. A},
number = 27,
volume = 7,
place = {United Kingdom},
year = {2019},
month = {7}
}
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https://doi.org/10.1039/C9TA05308E
https://doi.org/10.1039/C9TA05308E
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Works referenced in this record:
Chemical Management for Colorful, Efficient, and Stable Inorganic–Organic Hybrid Nanostructured Solar Cells
journal, March 2013
- Noh, Jun Hong; Im, Sang Hyuk; Heo, Jin Hyuck
- Nano Letters, Vol. 13, Issue 4, p. 1764-1769
Stabilizing Perovskite Structures by Tuning Tolerance Factor: Formation of Formamidinium and Cesium Lead Iodide Solid-State Alloys
journal, December 2015
- Li, Zhen; Yang, Mengjin; Park, Ji-Sang
- Chemistry of Materials, Vol. 28, Issue 1
Hybrid organic—inorganic perovskites: low-cost semiconductors with intriguing charge-transport properties
journal, January 2016
- Brenner, Thomas M.; Egger, David A.; Kronik, Leeor
- Nature Reviews Materials, Vol. 1, Issue 1
Overcoming the Photovoltage Plateau in Large Bandgap Perovskite Photovoltaics
journal, May 2018
- Rajagopal, Adharsh; Stoddard, Ryan J.; Jo, Sae Byeok
- Nano Letters, Vol. 18, Issue 6
Cation-Induced Band-Gap Tuning in Organohalide Perovskites: Interplay of Spin–Orbit Coupling and Octahedra Tilting
journal, May 2014
- Amat, Anna; Mosconi, Edoardo; Ronca, Enrico
- Nano Letters, Vol. 14, Issue 6
Homogenized halides and alkali cation segregation in alloyed organic-inorganic perovskites
journal, February 2019
- Correa-Baena, Juan-Pablo; Luo, Yanqi; Brenner, Thomas M.
- Science, Vol. 363, Issue 6427
Disorder effects on the density of states of the II-VI semiconductor alloys Te, Te, and Te
journal, January 1991
- Wei, Su-Huai; Zunger, Alex
- Physical Review B, Vol. 43, Issue 2
Dynamic Stereochemical Activity of the Sn 2+ Lone Pair in Perovskite CsSnBr 3
journal, September 2016
- Fabini, Douglas H.; Laurita, Geneva; Bechtel, Jonathon S.
- Journal of the American Chemical Society, Vol. 138, Issue 36
Methylammonium-free, high-performance, and stable perovskite solar cells on a planar architecture
journal, October 2018
- Turren-Cruz, Silver-Hamill; Hagfeldt, Anders; Saliba, Michael
- Science, Vol. 362, Issue 6413
Synthetic Approaches for Halide Perovskite Thin Films
journal, November 2018
- Dunlap-Shohl, Wiley A.; Zhou, Yuanyuan; Padture, Nitin P.
- Chemical Reviews, Vol. 119, Issue 5
Thermodynamic stability of mixed Pb:Sn methyl-ammonium halide perovskites: Thermodynamic stability of M−0.35exA0.35ex(Pb:Sn)X3
journal, June 2016
- Korshunova, Ksenia; Winterfeld, Lars; Beenken, Wichard J. D.
- physica status solidi (b), Vol. 253, Issue 10
Band alignment of the hybrid halide perovskites CH 3 NH 3 PbCl 3 , CH 3 NH 3 PbBr 3 and CH 3 NH 3 PbI 3
journal, January 2015
- Butler, Keith T.; Frost, Jarvist M.; Walsh, Aron
- Materials Horizons, Vol. 2, Issue 2
Bandgap Optimization of Perovskite Semiconductors for Photovoltaic Applications
journal, January 2018
- Xiao, Zewen; Zhou, Yuanyuan; Hosono, Hideo
- Chemistry - A European Journal, Vol. 24, Issue 10
Improved efficiency and stability of Pb–Sn binary perovskite solar cells by Cs substitution
journal, January 2016
- Liu, Xiao; Yang, Zhibin; Chueh, Chu-Chen
- Journal of Materials Chemistry A, Vol. 4, Issue 46
Detailed balance limit of the efficiency of tandem solar cells
journal, May 1980
- Vos, A. De
- Journal of Physics D: Applied Physics, Vol. 13, Issue 5
A re-examination of the relationship between lattice strain, octahedral tilt angle and octahedral strain in rhombohedral perovskites
journal, December 1996
- Thomas, N. W.
- Acta Crystallographica Section B Structural Science, Vol. 52, Issue 6
Theory of electronic structure evolution in GaAsN and GaPN alloys
journal, August 2001
- Kent, P. R. C.; Zunger, Alex
- Physical Review B, Vol. 64, Issue 11
Resolving the Physical Origin of Octahedral Tilting in Halide Perovskites
journal, June 2016
- Lee, Jung-Hoon; Bristowe, Nicholas C.; Lee, June Ho
- Chemistry of Materials, Vol. 28, Issue 12
Electronic structure of ZnS, ZnSe, ZnTe, and their pseudobinary alloys
journal, August 1987
- Bernard, James E.; Zunger, Alex
- Physical Review B, Vol. 36, Issue 6
Band Gap Tuning via Lattice Contraction and Octahedral Tilting in Perovskite Materials for Photovoltaics
journal, August 2017
- Prasanna, Rohit; Gold-Parker, Aryeh; Leijtens, Tomas
- Journal of the American Chemical Society, Vol. 139, Issue 32
Short- and long-range-order effects on the electronic properties of III-V semiconductor alloys
journal, April 1995
- Mäder, Kurt A.; Zunger, Alex
- Physical Review B, Vol. 51, Issue 16
Mechanism of Tin Oxidation and Stabilization by Lead Substitution in Tin Halide Perovskites
journal, August 2017
- Leijtens, Tomas; Prasanna, Rohit; Gold-Parker, Aryeh
- ACS Energy Letters, Vol. 2, Issue 9
Electronic structure and density of states of the random As, , and As semiconductor alloys
journal, October 1991
- Magri, Rita; Froyen, Sverre; Zunger, Alex
- Physical Review B, Vol. 44, Issue 15
Toward Long-Term Stability: Single-Crystal Alloys of Cesium-Containing Mixed Cation and Mixed Halide Perovskite
journal, December 2018
- Chen, Liang; Tan, Yan-Yan; Chen, Zhi-Xin
- Journal of the American Chemical Society, Vol. 141, Issue 4
Interplay of Structural and Optoelectronic Properties in Formamidinium Mixed Tin-Lead Triiodide Perovskites
journal, June 2018
- Parrott, Elizabeth S.; Green, Thomas; Milot, Rebecca L.
- Advanced Functional Materials, Vol. 28, Issue 33
Antagonism between Spin–Orbit Coupling and Steric Effects Causes Anomalous Band Gap Evolution in the Perovskite Photovoltaic Materials CH 3 NH 3 Sn 1– x Pb x I 3
journal, August 2015
- Im, Jino; Stoumpos, Constantinos C.; Jin, Hosub
- The Journal of Physical Chemistry Letters, Vol. 6, Issue 17
Reducing Saturation-Current Density to Realize High-Efficiency Low-Bandgap Mixed Tin-Lead Halide Perovskite Solar Cells
journal, November 2018
- Li, Chongwen; Song, Zhaoning; Zhao, Dewei
- Advanced Energy Materials, Vol. 9, Issue 3
Anomalous Band Gap Behavior in Mixed Sn and Pb Perovskites Enables Broadening of Absorption Spectrum in Solar Cells
journal, May 2014
- Hao, Feng; Stoumpos, Constantinos C.; Chang, Robert P. H.
- Journal of the American Chemical Society, Vol. 136, Issue 22
Toward Perovskite Solar Cell Commercialization: A Perspective and Research Roadmap Based on Interfacial Engineering
journal, June 2018
- Rajagopal, Adharsh; Yao, Kai; Jen, Alex K. -Y.
- Advanced Materials, Vol. 30, Issue 32
Perovskite Materials for Light-Emitting Diodes and Lasers
journal, May 2016
- Veldhuis, Sjoerd A.; Boix, Pablo P.; Yantara, Natalia
- Advanced Materials, Vol. 28, Issue 32
Tunable Near-Infrared Luminescence in Tin Halide Perovskite Devices
journal, June 2016
- Lai, May L.; Tay, Timothy Y. S.; Sadhanala, Aditya
- The Journal of Physical Chemistry Letters, Vol. 7, Issue 14
Highly Efficient Perovskite-Perovskite Tandem Solar Cells Reaching 80% of the Theoretical Limit in Photovoltage
journal, July 2017
- Rajagopal, Adharsh; Yang, Zhibin; Jo, Sae Byeok
- Advanced Materials, Vol. 29, Issue 34
Structure and Properties of Sr 1− x Ca x Mn 0.5 Ru 0.5 O 3 Perovskites: Using Chemical Pressure to Control Mn/Ru Mixed Valency
journal, June 2010
- Ricciardo, Rebecca A.; Cuthbert, Heather L.; Woodward, Patrick M.
- Chemistry of Materials, Vol. 22, Issue 11
Band-gap nonlinearity in perovskite structured solid solutions
journal, January 2010
- Lee, Soonil; Levi, Roni D.; Qu, Weiguo
- Journal of Applied Physics, Vol. 107, Issue 2
Structural Origin of Optical Bowing in Semiconductor Alloys
journal, August 1983
- Zunger, Alex; Jaffe, J. E.
- Physical Review Letters, Vol. 51, Issue 8
Stable Low-Bandgap Pb-Sn Binary Perovskites for Tandem Solar Cells
journal, August 2016
- Yang, Zhibin; Rajagopal, Adharsh; Chueh, Chu-Chen
- Advanced Materials, Vol. 28, Issue 40
Effects of chemical pressure on the magnetic ground states of the osmate double perovskites and
journal, September 2015
- Morrow, Ryan; Yan, Jiaqiang; McGuire, Michael A.
- Physical Review B, Vol. 92, Issue 9
Bandgap calculations and trends of organometal halide perovskites
journal, August 2014
- Castelli, Ivano E.; García-Lastra, Juan María; Thygesen, Kristian S.
- APL Materials, Vol. 2, Issue 8
Composition and Interface Engineering for Efficient and Thermally Stable Pb-Sn Mixed Low-Bandgap Perovskite Solar Cells
journal, October 2018
- Chi, Dan; Huang, Shihua; Zhang, Meiying
- Advanced Functional Materials, Vol. 28, Issue 51
Strain Tuning of Tin–Halide and Lead–Halide Perovskites: A First-Principles Atomic and Electronic Structure Study
journal, September 2015
- Grote, Christopher; Berger, Robert F.
- The Journal of Physical Chemistry C, Vol. 119, Issue 40
Origin of Pronounced Nonlinear Band Gap Behavior in Lead–Tin Hybrid Perovskite Alloys
journal, May 2018
- Goyal, Anuj; McKechnie, Scott; Pashov, Dimitar
- Chemistry of Materials, Vol. 30, Issue 11
Spontaneous Octahedral Tilting in the Cubic Inorganic Cesium Halide Perovskites CsSnX 3 and CsPbX 3 (X = F, Cl, Br, I)
journal, September 2017
- Yang, Ruo Xi; Skelton, Jonathan M.; da Silva, E. Lora
- The Journal of Physical Chemistry Letters, Vol. 8, Issue 19
Compound semiconductor alloys: From atomic-scale structure to bandgap bowing
journal, September 2015
- Schnohr, C. S.
- Applied Physics Reviews, Vol. 2, Issue 3
Mixed A-Cation Perovskites for Solar Cells: Atomic-Scale Insights Into Structural Distortion, Hydrogen Bonding, and Electronic Properties
journal, July 2018
- Ghosh, Dibyajyoti; Smith, Alexander R.; Walker, Alison B.
- Chemistry of Materials, Vol. 30, Issue 15
Photoluminescence and Photoconductivity to Assess Maximum Open-Circuit Voltage and Carrier Transport in Hybrid Perovskites and Other Photovoltaic Materials
journal, June 2018
- Braly, Ian L.; Stoddard, Ryan J.; Rajagopal, Adharsh
- The Journal of Physical Chemistry Letters, Vol. 9, Issue 13
Homogenous Alloys of Formamidinium Lead Triiodide and Cesium Tin Triiodide for Efficient Ideal-Bandgap Perovskite Solar Cells
journal, July 2017
- Zong, Yingxia; Wang, Ning; Zhang, Lin
- Angewandte Chemie International Edition, Vol. 56, Issue 41
Lead and HTM Free Stable Two-Dimensional Tin Perovskites with Suitable Band Gap for Solar Cell Applications
journal, December 2018
- Zimmermann, Iwan; Aghazada, Sadig; Nazeeruddin, Mohammad Khaja
- Angewandte Chemie International Edition, Vol. 58, Issue 4
Quasi-Fermi level splitting and sub-bandgap absorptivity from semiconductor photoluminescence
journal, November 2014
- Katahara, John K.; Hillhouse, Hugh W.
- Journal of Applied Physics, Vol. 116, Issue 17
Defect Passivation via a Graded Fullerene Heterojunction in Low-Bandgap Pb–Sn Binary Perovskite Photovoltaics
journal, October 2017
- Rajagopal, Adharsh; Liang, Po-Wei; Chueh, Chu-Chen
- ACS Energy Letters, Vol. 2, Issue 11
Tin–lead halide perovskites with improved thermal and air stability for efficient all-perovskite tandem solar cells
journal, January 2018
- Leijtens, Tomas; Prasanna, Rohit; Bush, Kevin A.
- Sustainable Energy & Fuels, Vol. 2, Issue 11
Progress in Theoretical Study of Metal Halide Perovskite Solar Cell Materials
journal, August 2017
- Xiao, Zewen; Yan, Yanfa
- Advanced Energy Materials, Vol. 7, Issue 22
Promises and challenges of perovskite solar cells
journal, November 2017
- Correa-Baena, Juan-Pablo; Saliba, Michael; Buonassisi, Tonio
- Science, Vol. 358, Issue 6364
Dipolar cations confer defect tolerance in wide-bandgap metal halide perovskites
journal, August 2018
- Tan, Hairen; Che, Fanglin; Wei, Mingyang
- Nature Communications, Vol. 9, Issue 1
Influence of Rb/Cs Cation-Exchange on Inorganic Sn Halide Perovskites: From Chemical Structure to Physical Properties
journal, March 2017
- Jung, Young-Kwang; Lee, Ji-Hwan; Walsh, Aron
- Chemistry of Materials, Vol. 29, Issue 7
Perovskite precursor solution chemistry: from fundamentals to photovoltaic applications
journal, January 2019
- Jung, Minsu; Ji, Sang-Geun; Kim, Gwisu
- Chemical Society Reviews, Vol. 48, Issue 7
Inert Pair Effects in Tin and Lead Dihalides: Crystal Structure of Tin(II) Bromide
journal, January 2000
- Abrahams, I.; Demetriou, D. Z.
- Journal of Solid State Chemistry, Vol. 149, Issue 1
Enhancing Defect Tolerance and Phase Stability of High-Bandgap Perovskites via Guanidinium Alloying
journal, May 2018
- Stoddard, Ryan J.; Rajagopal, Adharsh; Palmer, Ray L.
- ACS Energy Letters, Vol. 3, Issue 6
Ideal Bandgap Organic-Inorganic Hybrid Perovskite Solar Cells
journal, November 2017
- Yang, Zhibin; Rajagopal, Adharsh; Jen, Alex K. -Y.
- Advanced Materials, Vol. 29, Issue 47
Detailed Balance Limit of Efficiency of p‐n Junction Solar Cells
journal, March 1961
- Shockley, William; Queisser, Hans J.
- Journal of Applied Physics, Vol. 32, Issue 3, p. 510-519
Octahedral tilting instabilities in inorganic halide perovskites
journal, February 2018
- Bechtel, Jonathon S.; Van der Ven, Anton
- Physical Review Materials, Vol. 2, Issue 2
Stabilized Wide Bandgap Perovskite Solar Cells by Tin Substitution
journal, November 2016
- Yang, Zhibin; Rajagopal, Adharsh; Jo, Sae Byeok
- Nano Letters, Vol. 16, Issue 12
Solution-processed semiconductors for next-generation photodetectors
journal, January 2017
- García de Arquer, F. Pelayo; Armin, Ardalan; Meredith, Paul
- Nature Reviews Materials, Vol. 2, Issue 3
Role of Organic Counterion in Lead- and Tin-Based Two-Dimensional Semiconducting Iodide Perovskites and Application in Planar Solar Cells
journal, October 2016
- Mao, Lingling; Tsai, Hsinhan; Nie, Wanyi
- Chemistry of Materials, Vol. 28, Issue 21
Steric engineering of metal-halide perovskites with tunable optical band gaps
journal, December 2014
- Filip, Marina R.; Eperon, Giles E.; Snaith, Henry J.
- Nature Communications, Vol. 5, Issue 1
Perovskite-perovskite tandem photovoltaics with optimized band gaps
journal, October 2016
- Eperon, Giles E.; Leijtens, Tomas; Bush, Kevin A.
- Science, Vol. 354, Issue 6314
Efficient two-terminal all-perovskite tandem solar cells enabled by high-quality low-bandgap absorber layers
journal, November 2018
- Zhao, Dewei; Chen, Cong; Wang, Changlei
- Nature Energy, Vol. 3, Issue 12