Na-Ion Intercalation and Charge Storage Mechanism in Two-Dimensional Vanadium Carbide
Abstract
Two-dimensional vanadium carbide MXene containing surface functional groups (denoted as V2CTx, where Tx are surface functional groups) was synthesized and studied as anode material for Na-ion batteries. V2CTx anode exhibits reversible charge storage with good cycling stability and high rate capability through electrochemical test. The charge storage mechanism of V2CTx material during Na+ intercalation/deintercalation and the redox reaction of vanadium were studied using a combination of synchrotron based X-ray diffraction (XRD), hard X-ray absorption near edge spectroscopy (XANES) and soft X-ray absorption spectroscopy (sXAS). Experimental evidence of a major contribution of redox reaction of vanadium to the charge storage and the reversible capacity of V2CTx during sodiation/desodiation process have been provided through V K-edge XANES and V L2,3-edge sXAS results. A correlation between the CO32- content and Na+ intercalation/deintercalation states in the V2CTx electrode observed from C and O K-edge in sXAS results imply that some additional charge storage reactions may take place between the Na+-intercalated V2CTx and the carbonate based non-aqueous electrolyte. The results of this study will provide valuable information for the further studies on V2CTx as anode material for Na-ion batteries and capacitors.
- Authors:
-
- Brookhaven National Lab. (BNL), Upton, NY (United States). Chemistry Division
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source
- Chinese Academy of Sciences (CAS), Beijing (China). Inst. of Physics
- Drexel Univ., Philadelphia, PA (United States). Dept.of Materials Science and Engineering, A.J Drexel Nanomaterials Inst.
- Argonne National Lab. (ANL), Argonne, IL (United States). X-ray Science Division
- Publication Date:
- Research Org.:
- Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States). Advanced Light Source (ALS); Brookhaven National Laboratory (BNL), Upton, NY (United States); Argonne National Laboratory (ANL), Argonne, IL (United States); SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States); Energy Frontier Research Centers (EFRC) (United States). Fluid Interface Reactions, Structures and Transport Center (FIRST)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V); Chinese Academy of Sciences
- OSTI Identifier:
- 1366345
- Alternate Identifier(s):
- OSTI ID: 1401559; OSTI ID: 1415478; OSTI ID: 1425427
- Report Number(s):
- BNL-113977-2017-JA
Journal ID: ISSN 1614-6832; R&D Project: MA453MAEA; VT1201000
- Grant/Contract Number:
- SC00112704; AC02-05CH11231; AC02-06CH11357; AC02-76SF00515; SC0012704; AC02‐76SF00515; AC02‐06CH11357
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Advanced Energy Materials
- Additional Journal Information:
- Journal Volume: 7; Journal Issue: 20; Journal ID: ISSN 1614-6832
- Publisher:
- Wiley
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; MXene; vanadium carbide; sodium-ion battery; charge storage; X-ray absorption spectroscopy; X-ray absorption; spectroscopy; sodium‐ion batteries; X‐ray absorption spectroscopy
Citation Formats
Bak, Seong -Min, Qiao, Ruimin, Yang, W., Lee, Ssungsik, Yu, X., Anasori, B., Lee, H., Gogotsi, Y., and Yang, Xiao -Qing. Na-Ion Intercalation and Charge Storage Mechanism in Two-Dimensional Vanadium Carbide. United States: N. p., 2017.
Web. doi:10.1002/aenm.201700959.
Bak, Seong -Min, Qiao, Ruimin, Yang, W., Lee, Ssungsik, Yu, X., Anasori, B., Lee, H., Gogotsi, Y., & Yang, Xiao -Qing. Na-Ion Intercalation and Charge Storage Mechanism in Two-Dimensional Vanadium Carbide. United States. https://doi.org/10.1002/aenm.201700959
Bak, Seong -Min, Qiao, Ruimin, Yang, W., Lee, Ssungsik, Yu, X., Anasori, B., Lee, H., Gogotsi, Y., and Yang, Xiao -Qing. Fri .
"Na-Ion Intercalation and Charge Storage Mechanism in Two-Dimensional Vanadium Carbide". United States. https://doi.org/10.1002/aenm.201700959. https://www.osti.gov/servlets/purl/1366345.
@article{osti_1366345,
title = {Na-Ion Intercalation and Charge Storage Mechanism in Two-Dimensional Vanadium Carbide},
author = {Bak, Seong -Min and Qiao, Ruimin and Yang, W. and Lee, Ssungsik and Yu, X. and Anasori, B. and Lee, H. and Gogotsi, Y. and Yang, Xiao -Qing},
abstractNote = {Two-dimensional vanadium carbide MXene containing surface functional groups (denoted as V2CTx, where Tx are surface functional groups) was synthesized and studied as anode material for Na-ion batteries. V2CTx anode exhibits reversible charge storage with good cycling stability and high rate capability through electrochemical test. The charge storage mechanism of V2CTx material during Na+ intercalation/deintercalation and the redox reaction of vanadium were studied using a combination of synchrotron based X-ray diffraction (XRD), hard X-ray absorption near edge spectroscopy (XANES) and soft X-ray absorption spectroscopy (sXAS). Experimental evidence of a major contribution of redox reaction of vanadium to the charge storage and the reversible capacity of V2CTx during sodiation/desodiation process have been provided through V K-edge XANES and V L2,3-edge sXAS results. A correlation between the CO32- content and Na+ intercalation/deintercalation states in the V2CTx electrode observed from C and O K-edge in sXAS results imply that some additional charge storage reactions may take place between the Na+-intercalated V2CTx and the carbonate based non-aqueous electrolyte. The results of this study will provide valuable information for the further studies on V2CTx as anode material for Na-ion batteries and capacitors.},
doi = {10.1002/aenm.201700959},
journal = {Advanced Energy Materials},
number = 20,
volume = 7,
place = {United States},
year = {Fri Jul 14 00:00:00 EDT 2017},
month = {Fri Jul 14 00:00:00 EDT 2017}
}
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