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Title: Interlayer bond polarizability model for stacking-dependent low-frequency Raman scattering in layered materials

Abstract

A simple model is developed to reveal the stacking dependence of Raman intensities of interlayer vibrations in 2D materials.

Authors:
ORCiD logo [1]; ORCiD logo [2]; ORCiD logo [2]; ORCiD logo [3]
  1. Rensselaer Polytechnic Inst., Troy, NY (United States); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
  2. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
  3. Rensselaer Polytechnic Inst., Troy, NY (United States)
Publication Date:
Research Org.:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Sponsoring Org.:
USDOE Office of Science (SC)
OSTI Identifier:
1399929
Grant/Contract Number:  
AC05-00OR22725
Resource Type:
Accepted Manuscript
Journal Name:
Nanoscale
Additional Journal Information:
Journal Volume: 9; Journal ID: ISSN 2040-3364
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE

Citation Formats

Liang, Liangbo, Puretzky, Alexander A., Sumpter, Bobby G., and Meunier, Vincent. Interlayer bond polarizability model for stacking-dependent low-frequency Raman scattering in layered materials. United States: N. p., 2017. Web. doi:10.1039/c7nr05839j.
Liang, Liangbo, Puretzky, Alexander A., Sumpter, Bobby G., & Meunier, Vincent. Interlayer bond polarizability model for stacking-dependent low-frequency Raman scattering in layered materials. United States. doi:10.1039/c7nr05839j.
Liang, Liangbo, Puretzky, Alexander A., Sumpter, Bobby G., and Meunier, Vincent. Fri . "Interlayer bond polarizability model for stacking-dependent low-frequency Raman scattering in layered materials". United States. doi:10.1039/c7nr05839j. https://www.osti.gov/servlets/purl/1399929.
@article{osti_1399929,
title = {Interlayer bond polarizability model for stacking-dependent low-frequency Raman scattering in layered materials},
author = {Liang, Liangbo and Puretzky, Alexander A. and Sumpter, Bobby G. and Meunier, Vincent},
abstractNote = {A simple model is developed to reveal the stacking dependence of Raman intensities of interlayer vibrations in 2D materials.},
doi = {10.1039/c7nr05839j},
journal = {Nanoscale},
number = ,
volume = 9,
place = {United States},
year = {2017},
month = {9}
}

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Cited by: 7 works
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Works referenced in this record:

Raman characterization of AB- and ABC-stacked few-layer graphene by interlayer shear modes
journal, April 2016


Mapping of Low-Frequency Raman Modes in CVD-Grown Transition Metal Dichalcogenides: Layer Number, Stacking Orientation and Resonant Effects
journal, January 2016

  • O’Brien, Maria; McEvoy, Niall; Hanlon, Damien
  • Scientific Reports, Vol. 6, Issue 1
  • DOI: 10.1038/srep19476

Coupled Spin and Valley Physics in Monolayers of MoS 2 and Other Group-VI Dichalcogenides
journal, May 2012


Relation between Photoelasticity, Electrostriction, and First-Order Raman Effect in Crystals of the Diamond Structure
journal, December 1967


Interface Coupling in Twisted Multilayer Graphene by Resonant Raman Spectroscopy of Layer Breathing Modes
journal, June 2015


Progress, Challenges, and Opportunities in Two-Dimensional Materials Beyond Graphene
journal, March 2013

  • Butler, Sheneve Z.; Hollen, Shawna M.; Cao, Linyou
  • ACS Nano, Vol. 7, Issue 4, p. 2898-2926
  • DOI: 10.1021/nn400280c

Phonon and Raman scattering of two-dimensional transition metal dichalcogenides from monolayer, multilayer to bulk material
journal, January 2015

  • Zhang, Xin; Qiao, Xiao-Fen; Shi, Wei
  • Chemical Society Reviews, Vol. 44, Issue 9
  • DOI: 10.1039/C4CS00282B

Spin and pseudospins in layered transition metal dichalcogenides
journal, April 2014

  • Xu, Xiaodong; Yao, Wang; Xiao, Di
  • Nature Physics, Vol. 10, Issue 5
  • DOI: 10.1038/nphys2942

Strongly enhanced charge-density-wave order in monolayer NbSe2
journal, July 2015

  • Xi, Xiaoxiang; Zhao, Liang; Wang, Zefang
  • Nature Nanotechnology, Vol. 10, Issue 9, p. 765-769
  • DOI: 10.1038/nnano.2015.143

Stacking-Dependent Interlayer Coupling in Trilayer MoS 2 with Broken Inversion Symmetry
journal, November 2015


Stacking-dependent band gap and quantum transport in trilayer graphene
journal, September 2011

  • Bao, W.; Jing, L.; Velasco, J.
  • Nature Physics, Vol. 7, Issue 12
  • DOI: 10.1038/nphys2103

Low-Frequency Interlayer Raman Modes to Probe Interface of Twisted Bilayer MoS 2
journal, January 2016


Raman Signature of Graphene Superlattices
journal, November 2011

  • Carozo, Victor; Almeida, Clara M.; Ferreira, Erlon H. M.
  • Nano Letters, Vol. 11, Issue 11
  • DOI: 10.1021/nl201370m

Observation of an electrically tunable band gap in trilayer graphene
journal, September 2011

  • Lui, Chun Hung; Li, Zhiqiang; Mak, Kin Fai
  • Nature Physics, Vol. 7, Issue 12
  • DOI: 10.1038/nphys2102

Ultralow-frequency Raman system down to 10 cm −1 with longpass edge filters and its application to the interface coupling in t(2+2)LGs
journal, May 2016

  • Lin, M. -L.; Ran, F. -R.; Qiao, X. -F.
  • Review of Scientific Instruments, Vol. 87, Issue 5
  • DOI: 10.1063/1.4952384

Interlayer Electronic Coupling in Arbitrarily Stacked MoS 2 Bilayers Controlled by Interlayer S–S Interaction
journal, December 2014

  • Cao, Boxiao; Li, Tianshu
  • The Journal of Physical Chemistry C, Vol. 119, Issue 2
  • DOI: 10.1021/jp5101736

The experimental observation of quantum Hall effect of l=3 chiral quasiparticles in trilayer graphene
journal, September 2011

  • Zhang, Liyuan; Zhang, Yan; Camacho, Jorge
  • Nature Physics, Vol. 7, Issue 12
  • DOI: 10.1038/nphys2104

The ABC of 2D materials
journal, July 2015


Raman spectroscopy of shear and layer breathing modes in multilayer MoS 2
journal, March 2013


Lattice vibrations and Raman scattering in two-dimensional layered materials beyond graphene
journal, September 2016


Coupling and Stacking Order of ReS 2 Atomic Layers Revealed by Ultralow-Frequency Raman Spectroscopy
journal, January 2016


Interlayer interactions in anisotropic atomically thin rhenium diselenide
journal, October 2015


Valley-dependent spin polarization in bulk MoS2 with broken inversion symmetry
journal, July 2014


Low frequency Raman spectroscopy of few-atomic-layer thick hBN crystals
journal, June 2017


The shear mode of multilayer graphene
journal, February 2012

  • Tan, P. H.; Han, W. P.; Zhao, W. J.
  • Nature Materials, Vol. 11, Issue 4
  • DOI: 10.1038/nmat3245

Observation of piezoelectricity in free-standing monolayer MoS2
journal, December 2014


Raman Spectroscopy Study of Rotated Double-Layer Graphene: Misorientation-Angle Dependence of Electronic Structure
journal, June 2012


Raman spectroscopy as a versatile tool for studying the properties of graphene
journal, April 2013


Evolution of interlayer coupling in twisted molybdenum disulfide bilayers
journal, September 2014

  • Liu, Kaihui; Zhang, Liming; Cao, Ting
  • Nature Communications, Vol. 5, Issue 1
  • DOI: 10.1038/ncomms5966

First-principles Raman spectra of MoS2, WS2 and their heterostructures
journal, January 2014


Filter-based ultralow-frequency Raman measurement down to 2 cm −1 for fast Brillouin spectroscopy measurement
journal, May 2017

  • Liu, Xue-Lu; Liu, He-Nan; Wu, Jiang-Bin
  • Review of Scientific Instruments, Vol. 88, Issue 5
  • DOI: 10.1063/1.4983144

Stacking-dependent shear modes in trilayer graphene
journal, January 2015

  • Lui, Chun Hung; Ye, Zhipeng; Keiser, Courtney
  • Applied Physics Letters, Vol. 106, Issue 4
  • DOI: 10.1063/1.4906579

Low-Frequency Raman Fingerprints of Two-Dimensional Metal Dichalcogenide Layer Stacking Configurations
journal, May 2015


Interlayer breathing and shear modes in NbSe 2 atomic layers
journal, August 2016


Tailoring the Electronic Structure in Bilayer Molybdenum Disulfide via Interlayer Twist
journal, June 2014

  • van der Zande, Arend M.; Kunstmann, Jens; Chernikov, Alexey
  • Nano Letters, Vol. 14, Issue 7
  • DOI: 10.1021/nl501077m

Ultralow-Frequency Collective Compression Mode and Strong Interlayer Coupling in Multilayer Black Phosphorus
journal, February 2016


Review on the Raman spectroscopy of different types of layered materials
journal, January 2016

  • Zhang, Xin; Tan, Qing-Hai; Wu, Jiang-Bin
  • Nanoscale, Vol. 8, Issue 12
  • DOI: 10.1039/C5NR07205K

Anharmonic phonons in few-layer MoS 2 : Raman spectroscopy of ultralow energy compression and shear modes
journal, May 2013


Revealing the Preferred Interlayer Orientations and Stackings of Two-Dimensional Bilayer Gallium Selenide Crystals
journal, January 2015

  • Li, Xufan; Basile, Leonardo; Yoon, Mina
  • Angewandte Chemie International Edition, Vol. 54, Issue 9
  • DOI: 10.1002/anie.201409743

Anomalous Lattice Vibrations of Single- and Few-Layer MoS 2
journal, March 2010

  • Lee, Changgu; Yan, Hugen; Brus, Louis E.
  • ACS Nano, Vol. 4, Issue 5
  • DOI: 10.1021/nn1003937

Measurement of layer breathing mode vibrations in few-layer graphene
journal, March 2013


Interlayer Breathing and Shear Modes in Few-Trilayer MoS 2 and WSe 2
journal, February 2013

  • Zhao, Yanyuan; Luo, Xin; Li, Hai
  • Nano Letters, Vol. 13, Issue 3
  • DOI: 10.1021/nl304169w

Probing the Interlayer Coupling of Twisted Bilayer MoS 2 Using Photoluminescence Spectroscopy
journal, September 2014

  • Huang, Shengxi; Ling, Xi; Liang, Liangbo
  • Nano Letters, Vol. 14, Issue 10
  • DOI: 10.1021/nl5014597

Plasma-assisted fabrication of monolayer phosphorene and its Raman characterization
journal, May 2014


Hofstadter’s butterfly and the fractal quantum Hall effect in moiré superlattices
journal, May 2013


Piezoelectricity of single-atomic-layer MoS2 for energy conversion and piezotronics
journal, October 2014


Van der Waals heterostructures
journal, July 2013

  • Geim, A. K.; Grigorieva, I. V.
  • Nature, Vol. 499, Issue 7459, p. 419-425
  • DOI: 10.1038/nature12385

Electric Field Effect in Atomically Thin Carbon Films
journal, October 2004


Spectroscopic Signatures of AA′ and AB Stacking of Chemical Vapor Deposited Bilayer MoS 2
journal, October 2015


Anisotropic Electron-Photon and Electron-Phonon Interactions in Black Phosphorus
journal, March 2016


Recent Advances in Two-Dimensional Materials beyond Graphene
journal, October 2015


Raman Signatures of Polytypism in Molybdenum Disulfide
journal, January 2016


Low-frequency interlayer vibration modes in two-dimensional layered materials
journal, June 2016

  • Ji, Jianting; Dong, Shan; Zhang, Anmin
  • Physica E: Low-dimensional Systems and Nanostructures, Vol. 80
  • DOI: 10.1016/j.physe.2016.01.040

Low-Frequency Interlayer Breathing Modes in Few-Layer Black Phosphorus
journal, May 2015


Crystal structure and interatomic distances in GaSe
journal, October 1975


Volume Bragg gratings as ultra-narrow and multiband optical filters
conference, June 2012

  • Glebov, Alexei L.; Mokhun, Oleksiy; Rapaport, Alexandra
  • SPIE Photonics Europe, SPIE Proceedings
  • DOI: 10.1117/12.923575

Unusual Angular Dependence of the Raman Response in Black Phosphorus
journal, February 2015

  • Ribeiro, Henrique B.; Pimenta, Marcos A.; de Matos, Christiano J. S.
  • ACS Nano, Vol. 9, Issue 4
  • DOI: 10.1021/acsnano.5b00698

Twisted MoSe 2 Bilayers with Variable Local Stacking and Interlayer Coupling Revealed by Low-Frequency Raman Spectroscopy
journal, January 2016


Multiwall Nanotubes, Multilayers, and Hybrid Nanostructures: New Frontiers for Technology and Raman Spectroscopy
journal, March 2013

  • Bonaccorso, Francesco; Tan, Ping-Heng; Ferrari, Andrea C.
  • ACS Nano, Vol. 7, Issue 3
  • DOI: 10.1021/nn400758r

Observation of interlayer phonon modes in van der Waals heterostructures
journal, April 2015


The chemistry of two-dimensional layered transition metal dichalcogenide nanosheets
journal, April 2013

  • Chhowalla, Manish; Shin, Hyeon Suk; Eda, Goki
  • Nature Chemistry, Vol. 5, Issue 4, p. 263-275
  • DOI: 10.1038/nchem.1589

Trilayer graphene is a semimetal with a gate-tunable band overlap
journal, April 2009

  • Craciun, M. F.; Russo, S.; Yamamoto, M.
  • Nature Nanotechnology, Vol. 4, Issue 6
  • DOI: 10.1038/nnano.2009.89

Stacking effects on the electronic and optical properties of bilayer transition metal dichalcogenides MoS 2 , MoSe 2 , WS 2 , and WSe 2
journal, February 2014


Stacking in Bulk and Bilayer Hexagonal Boron Nitride
journal, July 2013


Raman scattering intensities in α-quartz: A first-principles investigation
journal, February 2001


Single-layer MoS2 transistors
journal, January 2011

  • Radisavljevic, B.; Radenovic, A.; Brivio, J.
  • Nature Nanotechnology, Vol. 6, Issue 3, p. 147-150
  • DOI: 10.1038/nnano.2010.279

Observation of Van Hove singularities in twisted graphene layers
journal, November 2009

  • Li, Guohong; Luican, A.; Lopes dos Santos, J. M. B.
  • Nature Physics, Vol. 6, Issue 2
  • DOI: 10.1038/nphys1463

Control of valley polarization in monolayer MoS2 by optical helicity
journal, June 2012


Monolayer behaviour in bulk ReS2 due to electronic and vibrational decoupling
journal, February 2014

  • Tongay, Sefaattin; Sahin, Hasan; Ko, Changhyun
  • Nature Communications, Vol. 5, Issue 1
  • DOI: 10.1038/ncomms4252

Valley and band structure engineering of folded MoS2 bilayers
journal, August 2014


Low-frequency Raman modes and electronic excitations in atomically thin MoS 2 films
journal, December 2012


Rapid and Nondestructive Identification of Polytypism and Stacking Sequences in Few-Layer Molybdenum Diselenide by Raman Spectroscopy
journal, July 2015

  • Lu, Xin; Utama, M. Iqbal Bakti; Lin, Junhao
  • Advanced Materials, Vol. 27, Issue 30
  • DOI: 10.1002/adma.201501086

Polytypism and unexpected strong interlayer coupling in two-dimensional layered ReS 2
journal, January 2016

  • Qiao, Xiao-Fen; Wu, Jiang-Bin; Zhou, Linwei
  • Nanoscale, Vol. 8, Issue 15
  • DOI: 10.1039/C6NR01569G