Search Menu
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information
Search Scholarly Publications

Title: Theoretical Investigation of Charge Transfer in Metal Organic Frameworks for Electrochemical Device Applications

Abstract

For electrochemical device applications metal organic frameworks (MOFs) must exhibit suitable conduction properties. To this end, we have performed computational studies of intermolecular charge transfer in MOFs consisting of hexa-ZrIV nodes and tetratopic carboxylate linkers. This includes an examination of the electronic structure of linkers that are derived from tetraphenyl benzene $$1$$, tetraphenyl pyrene $$2$$, and tetraphenyl porphyrin $$3$$ molecules. These results are used to determine charge transfer propensities in MOFs, within the framework of Marcus theory, including an analysis of the key parameters (charge transfer integral $$t$$, reorganization energy $$λ$$, and free energy change $ΔG^o$) and evaluation of figures of merit for charge transfer based on the chemical structures of the linkers. This qualitative analysis indicates that delocalization of the HOMO/LUMO on terminal substituents increases $$t$$ and decreases $$λ$$, while weaker binding to counterions decreases $ΔG^o$, leading to better charge transfer propensity. Subsequently, we study hole transfer in the linker $$2$$ containing MOFs, NU-901 and NU-1000, in detail and describe mechanisms (hopping and superexchange) that may be operative under different electrochemical conditions. Comparisons with experiment are provided where available. On the basis of the redox and catalytic activity of nodes and linkers, we propose three possible schemes for constructing electrochemical devices for catalysis. We believe that the results of this study will lay the foundation for future experimental work on this topic.

Authors:
 [1];  [1]
+ Show Author Affiliations
  1. Energy Frontier Research Centers (EFRC) (United States). Argonne-Northwestern Solar Energy Research Center (ANSER)
Publication Date:
Research Org.:
Energy Frontier Research Centers (EFRC) (United States). Argonne-Northwestern Solar Energy Research Center (ANSER)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1387804
Grant/Contract Number:  
SC0001059
Resource Type:
Accepted Manuscript
Journal Name:
Journal of Physical Chemistry. C
Additional Journal Information:
Journal Volume: 119; Journal Issue: 43; Related Information: ANSER partners with Northwestern University (lead); Argonne National Laboratory; University of Chicago; University of Illinois, Urbana-Champaign; Yale University; Journal ID: ISSN 1932-7447
Publisher:
American Chemical Society
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; catalysis (homogeneous); catalysis (heterogeneous); solar (photovoltaic); solar (fuels); photosynthesis (natural and artificial); bio-inspired; hydrogen and fuel cells; electrodes - solar; defects; charge transport; spin dynamics; membrane; materials and chemistry by design; optics; synthesis (novel materials); synthesis (self-assembly)

Citation Formats

Patwardhan, Sameer, and Schatz, George C. Theoretical Investigation of Charge Transfer in Metal Organic Frameworks for Electrochemical Device Applications. United States: N. p., 2015. Web. doi:10.1021/acs.jpcc.5b06065.
Copy to clipboard
Patwardhan, Sameer, & Schatz, George C. Theoretical Investigation of Charge Transfer in Metal Organic Frameworks for Electrochemical Device Applications. United States. https://doi.org/10.1021/acs.jpcc.5b06065
Copy to clipboard
Patwardhan, Sameer, and Schatz, George C. Mon . "Theoretical Investigation of Charge Transfer in Metal Organic Frameworks for Electrochemical Device Applications". United States. https://doi.org/10.1021/acs.jpcc.5b06065. https://www.osti.gov/servlets/purl/1387804.
Copy to clipboard
@article{osti_1387804,
title = {Theoretical Investigation of Charge Transfer in Metal Organic Frameworks for Electrochemical Device Applications},
author = {Patwardhan, Sameer and Schatz, George C.},
abstractNote = {For electrochemical device applications metal organic frameworks (MOFs) must exhibit suitable conduction properties. To this end, we have performed computational studies of intermolecular charge transfer in MOFs consisting of hexa-ZrIV nodes and tetratopic carboxylate linkers. This includes an examination of the electronic structure of linkers that are derived from tetraphenyl benzene $1$, tetraphenyl pyrene $2$, and tetraphenyl porphyrin $3$ molecules. These results are used to determine charge transfer propensities in MOFs, within the framework of Marcus theory, including an analysis of the key parameters (charge transfer integral $t$, reorganization energy $λ$, and free energy change $ΔG^o$) and evaluation of figures of merit for charge transfer based on the chemical structures of the linkers. This qualitative analysis indicates that delocalization of the HOMO/LUMO on terminal substituents increases $t$ and decreases $λ$, while weaker binding to counterions decreases $ΔG^o$, leading to better charge transfer propensity. Subsequently, we study hole transfer in the linker $2$ containing MOFs, NU-901 and NU-1000, in detail and describe mechanisms (hopping and superexchange) that may be operative under different electrochemical conditions. Comparisons with experiment are provided where available. On the basis of the redox and catalytic activity of nodes and linkers, we propose three possible schemes for constructing electrochemical devices for catalysis. We believe that the results of this study will lay the foundation for future experimental work on this topic.},
doi = {10.1021/acs.jpcc.5b06065},
journal = {Journal of Physical Chemistry. C},
number = 43,
volume = 119,
place = {United States},
year = {Mon Oct 12 00:00:00 EDT 2015},
month = {Mon Oct 12 00:00:00 EDT 2015}
}
Copy to clipboard
Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1021/acs.jpcc.5b06065
Copyright Statement
Other availability
Search WorldCat Search WorldCat to find libraries that may hold this journal
Citation Metrics:
Cited by: 59 works
Citation information provided by
Web of Science
Save / Share:
Export Metadata
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.

Works referenced in this record:

Hybrid porous solids past, present, future
journal, January 2008

  • Férey, Gérard
  • Chem. Soc. Rev., Vol. 37, Issue 1, p. 191-214
  • DOI: 10.1039/B618320B

The Chemistry and Applications of Metal-Organic Frameworks
journal, August 2013

  • Furukawa, H.; Cordova, K. E.; O'Keeffe, M.
  • Science, Vol. 341, Issue 6149, p. 1230444-1230444
  • DOI: 10.1126/science.1230444

Metal-Organic Frameworks: A Rapidly Growing Class of Versatile Nanoporous Materials
journal, October 2010

  • Meek, Scott T.; Greathouse, Jeffery A.; Allendorf, Mark D.
  • Advanced Materials, Vol. 23, Issue 2
  • DOI: 10.1002/adma.201002854

A New Zirconium Inorganic Building Brick Forming Metal Organic Frameworks with Exceptional Stability
journal, October 2008

  • Cavka, Jasmina Hafizovic; Jakobsen, Søren; Olsbye, Unni
  • Journal of the American Chemical Society, Vol. 130, Issue 42, p. 13850-13851
  • DOI: 10.1021/ja8057953

Exceptional chemical and thermal stability of zeolitic imidazolate frameworks
journal, June 2006

  • Park, K. S.; Ni, Z.; Cote, A. P.
  • Proceedings of the National Academy of Sciences, Vol. 103, Issue 27, p. 10186-10191
  • DOI: 10.1073/pnas.0602439103

A Chromium Terephthalate-Based Solid with Unusually Large Pore Volumes and Surface Area
journal, September 2005

  • Ferey, G.; Mellot-Draznieks, C.; Serre, C.
  • Science, Vol. 309, Issue 5743, p. 2040-2042
  • DOI: 10.1126/science.1116275

High thermal and chemical stability in pyrazolate-bridged metal–organic frameworks with exposed metal sites
journal, January 2011

  • Colombo, Valentina; Galli, Simona; Choi, Hye Jin
  • Chemical Science, Vol. 2, Issue 7, p. 1311-1319
  • DOI: 10.1039/c1sc00136a

Are Zr 6 -based MOFs water stable? Linker hydrolysis vs. capillary-force-driven channel collapse
journal, January 2014

  • Mondloch, Joseph E.; Katz, Michael J.; Planas, Nora
  • Chemical Communications, Vol. 50, Issue 64
  • DOI: 10.1039/C4CC02401J

Metal–Organic Frameworks for Separations
journal, September 2011

  • Li, Jian-Rong; Sculley, Julian; Zhou, Hong-Cai
  • Chemical Reviews, Vol. 112, Issue 2, p. 869-932
  • DOI: 10.1021/cr200190s

De novo synthesis of a metal–organic framework material featuring ultrahigh surface area and gas storage capacities
journal, September 2010

  • Farha, Omar K.; Özgür Yazaydın, A.; Eryazici, Ibrahim
  • Nature Chemistry, Vol. 2, Issue 11, p. 944-948
  • DOI: 10.1038/nchem.834

Ultrahigh Porosity in Metal-Organic Frameworks
journal, July 2010

Enantioselective catalysis with homochiral metal–organic frameworks
journal, January 2009

  • Ma, Liqing; Abney, Carter; Lin, Wenbin
  • Chemical Society Reviews, Vol. 38, Issue 5, p. 1248-1256
  • DOI: 10.1039/b807083k

Metal–organic framework materials as catalysts
journal, January 2009

  • Lee, JeongYong; Farha, Omar K.; Roberts, John
  • Chemical Society Reviews, Vol. 38, Issue 5, p. 1450-1459
  • DOI: 10.1039/b807080f

A Roadmap to Implementing Metal-Organic Frameworks in Electronic Devices: Challenges and Critical Directions
journal, September 2011

  • Allendorf, Mark D.; Schwartzberg, Adam; Stavila, Vitalie
  • Chemistry - A European Journal, Vol. 17, Issue 41, p. 11372-11388
  • DOI: 10.1002/chem.201101595

Doping Metal–Organic Frameworks for Water Oxidation, Carbon Dioxide Reduction, and Organic Photocatalysis
journal, August 2011

  • Wang, Cheng; Xie, Zhigang; deKrafft, Kathryn E.
  • Journal of the American Chemical Society, Vol. 133, Issue 34, p. 13445-13454
  • DOI: 10.1021/ja203564w

Mixed-Valence Li/Fe-Based Metal–Organic Frameworks with Both Reversible Redox and Sorption Properties
journal, April 2007

  • Férey, Gérard; Millange, Franck; Morcrette, Mathieu
  • Angewandte Chemie International Edition, Vol. 46, Issue 18
  • DOI: 10.1002/anie.200605163

Co8-MOF-5 as electrode for supercapacitors
journal, February 2012

Metal–Organic Framework Thin Films Composed of Free-Standing Acicular Nanorods Exhibiting Reversible Electrochromism
journal, December 2013

  • Kung, Chung-Wei; Wang, Timothy Chiaan; Mondloch, Joseph E.
  • Chemistry of Materials, Vol. 25, Issue 24
  • DOI: 10.1021/cm403726v

Conductivity, Doping, and Redox Chemistry of a Microporous Dithiolene-Based Metal−Organic Framework
journal, July 2010

  • Kobayashi, Yoji; Jacobs, Benjamin; Allendorf, Mark D.
  • Chemistry of Materials, Vol. 22, Issue 14
  • DOI: 10.1021/cm101238m

Mechanism of Charge Transport along Zinc Porphyrin-Based Molecular Wires
journal, March 2009

  • Kocherzhenko, Aleksey A.; Patwardhan, Sameer; Grozema, Ferdinand C.
  • Journal of the American Chemical Society, Vol. 131, Issue 15
  • DOI: 10.1021/ja809174y

A general relationship between disorder, aggregation and charge transport in conjugated polymers
journal, August 2013

  • Noriega, Rodrigo; Rivnay, Jonathan; Vandewal, Koen
  • Nature Materials, Vol. 12, Issue 11
  • DOI: 10.1038/nmat3722

High-Performance Air-Stable n-Channel Organic Thin Film Transistors Based on Halogenated Perylene Bisimide Semiconductors
journal, May 2009

  • Schmidt, Rüdiger; Oh, Joon Hak; Sun, Ya-Sen
  • Journal of the American Chemical Society, Vol. 131, Issue 17
  • DOI: 10.1021/ja901077a

Quasi Temperature Independent Electron Mobility in Hexagonal Columnar Mesophases of an H-Bonded Benzotristhiophene Derivative
journal, January 2010

  • Demenev, Andrey; Eichhorn, S. Holger; Taerum, Tyler
  • Chemistry of Materials, Vol. 22, Issue 4
  • DOI: 10.1021/cm902453z

Understanding Structure−Mobility Relations for Perylene Tetracarboxydiimide Derivatives
journal, July 2009

  • Marcon, Valentina; Breiby, Dag W.; Pisula, Wojciech
  • Journal of the American Chemical Society, Vol. 131, Issue 32
  • DOI: 10.1021/ja900963v

Efficient Charge Transport in Semisynthetic Zinc Chlorin Dye Assemblies
journal, September 2012

  • Patwardhan, Sameer; Sengupta, Sanchita; Siebbeles, Laurens D. A.
  • Journal of the American Chemical Society, Vol. 134, Issue 39
  • DOI: 10.1021/ja3075192

Biosupramolecular Nanowires from Chlorophyll Dyes with Exceptional Charge-Transport Properties
journal, May 2012

  • Sengupta, Sanchita; Ebeling, Daniel; Patwardhan, Sameer
  • Angewandte Chemie International Edition, Vol. 51, Issue 26
  • DOI: 10.1002/anie.201201961

Delocalization and Mobility of Charge Carriers in Covalent Organic Frameworks
journal, May 2011

  • Patwardhan, Sameer; Kocherzhenko, Aleksey A.; Grozema, Ferdinand C.
  • The Journal of Physical Chemistry C, Vol. 115, Issue 23
  • DOI: 10.1021/jp202399u

Electrical conductive coordination polymers
journal, January 2012

  • Givaja, Gonzalo; Amo-Ochoa, Pilar; Gómez-García, Carlos J.
  • Chem. Soc. Rev., Vol. 41, Issue 1
  • DOI: 10.1039/C1CS15092H

Cation-Dependent Intrinsic Electrical Conductivity in Isostructural Tetrathiafulvalene-Based Microporous Metal–Organic Frameworks
journal, January 2015

  • Park, Sarah S.; Hontz, Eric R.; Sun, Lei
  • Journal of the American Chemical Society, Vol. 137, Issue 5
  • DOI: 10.1021/ja512437u

Solvothermal Preparation of an Electrocatalytic Metalloporphyrin MOF Thin Film and its Redox Hopping Charge-Transfer Mechanism
journal, January 2014

  • Ahrenholtz, Spencer R.; Epley, Charity C.; Morris, Amanda J.
  • Journal of the American Chemical Society, Vol. 136, Issue 6
  • DOI: 10.1021/ja410684q

High Charge Mobility in a Tetrathiafulvalene-Based Microporous Metal–Organic Framework
journal, July 2012

  • Narayan, Tarun C.; Miyakai, Tomoyo; Seki, Shu
  • Journal of the American Chemical Society, Vol. 134, Issue 31
  • DOI: 10.1021/ja3059827

High Electrical Conductivity in Ni 3 (2,3,6,7,10,11-hexaiminotriphenylene) 2 , a Semiconducting Metal–Organic Graphene Analogue
journal, April 2014

  • Sheberla, Dennis; Sun, Lei; Blood-Forsythe, Martin A.
  • Journal of the American Chemical Society, Vol. 136, Issue 25
  • DOI: 10.1021/ja502765n

Mn 2 (2,5-disulfhydrylbenzene-1,4-dicarboxylate): A Microporous Metal–Organic Framework with Infinite (−Mn–S−) ∞ Chains and High Intrinsic Charge Mobility
journal, May 2013

  • Sun, Lei; Miyakai, Tomoyo; Seki, Shu
  • Journal of the American Chemical Society, Vol. 135, Issue 22
  • DOI: 10.1021/ja4037516

Million-Fold Electrical Conductivity Enhancement in Fe 2 (DEBDC) versus Mn 2 (DEBDC) (E = S, O)
journal, May 2015

  • Sun, Lei; Hendon, Christopher H.; Minier, Mikael A.
  • Journal of the American Chemical Society, Vol. 137, Issue 19
  • DOI: 10.1021/jacs.5b02897

Tunable Electrical Conductivity in Metal-Organic Framework Thin-Film Devices
journal, December 2013

  • Talin, A. Alec; Centrone, Andrea; Ford, Alexandra C.
  • Science, Vol. 343, Issue 6166, p. 66-69
  • DOI: 10.1126/science.1246738

Tunneling Electrical Connection to the Interior of Metal–Organic Frameworks
journal, June 2015

  • Han, Shuangbing; Warren, Scott C.; Yoon, Seok Min
  • Journal of the American Chemical Society, Vol. 137, Issue 25
  • DOI: 10.1021/jacs.5b03263

Directed Growth of Electroactive Metal-Organic Framework Thin Films Using Electrophoretic Deposition
journal, July 2014

  • Hod, Idan; Bury, Wojciech; Karlin, David M.
  • Advanced Materials, Vol. 26, Issue 36
  • DOI: 10.1002/adma.201401940

Bias-Switchable Permselectivity and Redox Catalytic Activity of a Ferrocene-Functionalized, Thin-Film Metal–Organic Framework Compound
journal, February 2015

  • Hod, Idan; Bury, Wojciech; Gardner, Daniel M.
  • The Journal of Physical Chemistry Letters, Vol. 6, Issue 4
  • DOI: 10.1021/acs.jpclett.5b00019

Porphyrin-based metal–organic framework thin films for electrochemical nitrite detection
journal, September 2015

Nanoscale Light-Harvesting Metal-Organic Frameworks
journal, May 2011

  • Zhang, Xuanjun; Ballem, Mohamed Ali; Hu, Zhang-Jun
  • Angewandte Chemie International Edition, Vol. 50, Issue 25
  • DOI: 10.1002/anie.201007277

Light-Harvesting and Ultrafast Energy Migration in Porphyrin-Based Metal–Organic Frameworks
journal, December 2012

  • Son, Ho-Jin; Jin, Shengye; Patwardhan, Sameer
  • Journal of the American Chemical Society, Vol. 135, Issue 2
  • DOI: 10.1021/ja310596a

Energy Transfer Dynamics in Metal−Organic Frameworks
journal, September 2010

  • Kent, Caleb A.; Mehl, Brian P.; Ma, Liqing
  • Journal of the American Chemical Society, Vol. 132, Issue 37
  • DOI: 10.1021/ja102804s

Rigidifying Fluorescent Linkers by Metal–Organic Framework Formation for Fluorescence Blue Shift and Quantum Yield Enhancement
journal, May 2014

  • Wei, Zhangwen; Gu, Zhi-Yuan; Arvapally, Ravi K.
  • Journal of the American Chemical Society, Vol. 136, Issue 23
  • DOI: 10.1021/ja5006866

Turn-On Fluorescence in Tetraphenylethylene-Based Metal–Organic Frameworks: An Alternative to Aggregation-Induced Emission
journal, December 2011

  • Shustova, Natalia B.; McCarthy, Brian D.; Dincă, Mircea
  • Journal of the American Chemical Society, Vol. 133, Issue 50
  • DOI: 10.1021/ja209327q

Solution Processable MOF Yellow Phosphor with Exceptionally High Quantum Efficiency
journal, November 2014

  • Gong, Qihan; Hu, Zhichao; Deibert, Benjamin J.
  • Journal of the American Chemical Society, Vol. 136, Issue 48
  • DOI: 10.1021/ja509446h

Charge Transport in Organic Semiconductors
journal, April 2007

  • Coropceanu, Veaceslav; Cornil, Jérôme; da Silva Filho, Demetrio A.
  • Chemical Reviews, Vol. 107, Issue 4
  • DOI: 10.1021/cr050140x

Charge and Energy Transfer Dynamics in Molecular Systems
book, February 2011

Absolute Rates of Hole Transfer in DNA
journal, October 2005

  • Senthilkumar, Kittusamy; Grozema, Ferdinand C.; Guerra, Célia Fonseca
  • Journal of the American Chemical Society, Vol. 127, Issue 42
  • DOI: 10.1021/ja054257e

Chemistry with ADF
journal, January 2001

  • te Velde, G.; Bickelhaupt, F. M.; Baerends, E. J.
  • Journal of Computational Chemistry, Vol. 22, Issue 9, p. 931-967
  • DOI: 10.1002/jcc.1056

Charge transport in columnar stacked triphenylenes: Effects of conformational fluctuations on charge transfer integrals and site energies
journal, November 2003

  • Senthilkumar, K.; Grozema, F. C.; Bickelhaupt, F. M.
  • The Journal of Chemical Physics, Vol. 119, Issue 18
  • DOI: 10.1063/1.1615476

Structure and Electronic Spectra of Purine–Methyl Viologen Charge Transfer Complexes
journal, December 2013

  • Jalilov, Almaz S.; Patwardhan, Sameer; Singh, Arunoday
  • The Journal of Physical Chemistry B, Vol. 118, Issue 1
  • DOI: 10.1021/jp410348b

Synthesis, Structure, and Metalation of Two New Highly Porous Zirconium Metal–Organic Frameworks
journal, June 2012

  • Morris, William; Volosskiy, Boris; Demir, Selcuk
  • Inorganic Chemistry, Vol. 51, Issue 12, p. 6443-6445
  • DOI: 10.1021/ic300825s

Zirconium-Metalloporphyrin PCN-222: Mesoporous Metal-Organic Frameworks with Ultrahigh Stability as Biomimetic Catalysts
journal, August 2012

  • Feng, Dawei; Gu, Zhi-Yuan; Li, Jian-Rong
  • Angewandte Chemie International Edition, Vol. 51, Issue 41
  • DOI: 10.1002/anie.201204475

Importance of the Reorganization Energy Barrier in Computational Design of Porphyrin-Based Solar Cells with Cobalt-Based Redox Mediators
journal, May 2015

  • Ørnsø, Kristian B.; Jónsson, Elvar Ö.; Jacobsen, Karsten W.
  • The Journal of Physical Chemistry C, Vol. 119, Issue 23
  • DOI: 10.1021/jp512627e

Perfluoroalkane Functionalization of NU-1000 via Solvent-Assisted Ligand Incorporation: Synthesis and CO2 Adsorption Studies
journal, October 2013

  • Deria, Pravas; Mondloch, Joseph E.; Tylianakis, Emmanuel
  • Journal of the American Chemical Society, Vol. 135, Issue 45, p. 16801-16804
  • DOI: 10.1021/ja408959g

Solvent and electrolyte effects on the kinetics of ferrocenium-ferrocene self-exchange. A reevaluation
journal, March 1989

  • Nielson, Roger M.; McManis, George E.; Safford, Lance K.
  • The Journal of Physical Chemistry, Vol. 93, Issue 5
  • DOI: 10.1021/j100342a086

Chemical Reactions Catalyzed by Metalloporphyrin-Based Metal-Organic Frameworks
journal, June 2013

    Sort by:
    [ × clear filter / sort ]

    Works referencing / citing this record:

    Metal-Organic Frameworks-Based Electrocatalysis: Insight and Future Perspectives
    journal, September 2018

    Highly efficient visible-light-driven photocatalytic degradation of rhodamine B by a novel Z-scheme Ag 3 PO 4 /MIL-101/NiFe 2 O 4 composite
    journal, January 2018

    • Zhou, Tianhong; Zhang, Guozhen; Zhang, Hongwei
    • Catalysis Science & Technology, Vol. 8, Issue 9
    • DOI: 10.1039/c8cy00182k

    Tuning the iron redox state inside a microporous porphyrinic metal organic framework
    journal, January 2017

    • Abeykoon, Brian; Grenèche, Jean-Marc; Jeanneau, Erwann
    • Dalton Transactions, Vol. 46, Issue 2
    • DOI: 10.1039/c6dt04208b

    Accelerated proton transmission in metal–organic frameworks for the efficient reduction of CO 2 in aqueous solutions
    journal, January 2019

    • Mao, Fangxin; Jin, Yan-Huan; Liu, Peng Fei
    • Journal of Materials Chemistry A, Vol. 7, Issue 40
    • DOI: 10.1039/c9ta07967j

    Enhancement of visible-light-driven CO 2 reduction performance using an amine-functionalized zirconium metal–organic framework
    journal, January 2018

    • Sun, Manying; Yan, Siyu; Sun, Yujia
    • Dalton Transactions, Vol. 47, Issue 3
    • DOI: 10.1039/c7dt04062h

    Prospects for electroactive and conducting framework materials
    journal, May 2019

    • Murase, Ryuichi; Ding, Bowen; Gu, Qinyi
    • Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences, Vol. 377, Issue 2149
    • DOI: 10.1098/rsta.2018.0226

    Isomorphism combined with intercalation methods to construct a hybrid electrode material for high-energy storage capacitors
    journal, January 2019

    • Sun, Taotao; Yue, Liguo; Wu, Ning
    • Journal of Materials Chemistry A, Vol. 7, Issue 43
    • DOI: 10.1039/c9ta08696j

    Metal–Organic Frameworks Toward Electrocatalytic Applications
    journal, June 2019

    • Li, Jun-Hong; Wang, Yi-Sen; Chen, Yu-Chuan
    • Applied Sciences, Vol. 9, Issue 12
    • DOI: 10.3390/app9122427
      Sort by:
      [ × clear filter / sort ]

      Similar Records in DOE PAGES and OSTI.GOV collections: